KR101164043B1 - 지지 중합 촉매 - Google Patents

지지 중합 촉매 Download PDF

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Publication number
KR101164043B1
KR101164043B1 KR1020067003647A KR20067003647A KR101164043B1 KR 101164043 B1 KR101164043 B1 KR 101164043B1 KR 1020067003647 A KR1020067003647 A KR 1020067003647A KR 20067003647 A KR20067003647 A KR 20067003647A KR 101164043 B1 KR101164043 B1 KR 101164043B1
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KR
South Korea
Prior art keywords
polymerization catalyst
hydrogen
supported
sir
catalyst according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
KR1020067003647A
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English (en)
Korean (ko)
Other versions
KR20070028277A (ko
Inventor
그랜트 베렌트 자콥센
브라이언 스티븐 킴벌리
세르지오 마스트로얀니
Original Assignee
이네오스 유럽 리미티드
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Filing date
Publication date
Priority claimed from GB0319773A external-priority patent/GB0319773D0/en
Priority claimed from GB0407817A external-priority patent/GB0407817D0/en
Application filed by 이네오스 유럽 리미티드 filed Critical 이네오스 유럽 리미티드
Publication of KR20070028277A publication Critical patent/KR20070028277A/ko
Application granted granted Critical
Publication of KR101164043B1 publication Critical patent/KR101164043B1/ko
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1020067003647A 2003-08-22 2004-08-04 지지 중합 촉매 Expired - Lifetime KR101164043B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB0319773A GB0319773D0 (en) 2003-08-22 2003-08-22 Supported polymerisation catalysts
GB0319773.8 2003-08-22
GB0407817.6 2004-04-06
GB0407817A GB0407817D0 (en) 2004-04-06 2004-04-06 Supported polymerisation catalysts
PCT/GB2004/003360 WO2005019275A1 (en) 2003-08-22 2004-08-04 Supported polymerisation catalysts

Related Child Applications (1)

Application Number Title Priority Date Filing Date
KR1020127008190A Division KR20120039069A (ko) 2003-08-22 2004-08-04 지지 중합 촉매

Publications (2)

Publication Number Publication Date
KR20070028277A KR20070028277A (ko) 2007-03-12
KR101164043B1 true KR101164043B1 (ko) 2012-07-18

Family

ID=34219624

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1020067003647A Expired - Lifetime KR101164043B1 (ko) 2003-08-22 2004-08-04 지지 중합 촉매
KR1020127008190A Ceased KR20120039069A (ko) 2003-08-22 2004-08-04 지지 중합 촉매

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1020127008190A Ceased KR20120039069A (ko) 2003-08-22 2004-08-04 지지 중합 촉매

Country Status (9)

Country Link
US (1) US7678726B2 (https=)
EP (1) EP1656394B1 (https=)
JP (1) JP5296982B2 (https=)
KR (2) KR101164043B1 (https=)
CA (1) CA2534836C (https=)
ES (1) ES2391973T3 (https=)
MY (1) MY145998A (https=)
TW (1) TWI391411B (https=)
WO (1) WO2005019275A1 (https=)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2357363T3 (es) 2005-05-10 2011-04-25 Ineos Europe Limited Nuevos copolímeros.
EP1731536A1 (en) 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Supported polymerisation catalysts
EP1731537A1 (en) * 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Supported polymerisation catalysts
US20090036621A1 (en) * 2006-01-11 2009-02-05 Grant Berent Jacobsen Catalyst System
EP1834983A1 (en) * 2006-03-14 2007-09-19 Ineos Europe Limited Polymer films
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
EP1930348A1 (en) * 2006-12-05 2008-06-11 Ineos Manufacturing France SAS Supported catalyst system
EP1935909A1 (en) * 2006-12-21 2008-06-25 Ineos Europe Limited Copolymers and films thereof
EP2133367A1 (en) 2008-06-09 2009-12-16 INEOS Manufacturing Belgium NV Novel Copolymers
EP2177548A1 (en) 2008-10-14 2010-04-21 Ineos Europe Limited Copolymers and films thereof
JP2010174208A (ja) * 2009-02-02 2010-08-12 Sumitomo Chemical Co Ltd オレフィン重合触媒、オレフィン重合触媒の製造方法、及びオレフィン重合体の製造方法
EP2348057A1 (en) 2010-01-21 2011-07-27 INEOS Manufacturing Belgium NV Novel polymers
CN102286114A (zh) * 2010-06-21 2011-12-21 中国石油天然气股份有限公司 一种茂金属催化剂的负载方法
GB201012273D0 (en) 2010-07-22 2010-09-08 Ineos Mfg Belguim Nv Polymer compositon
EP2410011A1 (en) 2010-07-23 2012-01-25 INEOS Manufacturing Belgium NV Polyethylene composition
EP2465876A1 (en) 2010-12-15 2012-06-20 INEOS Manufacturing Belgium NV Activating supports
ES2665545T3 (es) 2011-10-17 2018-04-26 Ineos Europe Ag Control del proceso de desgasificación del polímero
EP2785786B1 (en) 2011-12-01 2018-05-30 Ineos Europe AG Polymer blends
EP2791189B1 (en) 2011-12-14 2018-05-02 Ineos Europe AG Novel polymers
US20150030852A1 (en) 2012-01-26 2015-01-29 Ineos Europe Ag Copolymers for wire and cable applications
US8604115B1 (en) 2013-03-07 2013-12-10 King Fahd University Of Petroleum And Minerals Ethylene/propylene copolymer nanocomposite
ES2975017T3 (es) 2015-07-09 2024-07-02 Ineos Europe Ag Copolímeros y películas de los mismos

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000514130A (ja) * 1997-01-10 2000-10-24 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー コーポレイション 活性が増大されたオレフィン重合用触媒組成物

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI104825B (fi) * 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
US5783512A (en) * 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
JPH10212308A (ja) * 1997-01-31 1998-08-11 Nippon Poriorefuin Kk メタロセン触媒およびポリオレフィンの製造方法
DE19737306A1 (de) * 1997-08-27 1999-03-04 Basf Ag Katalysatorzubereitung für die (Co)polymerisation von Alk-l-enen
TWI300782B (en) * 2002-08-29 2008-09-11 Ineos Europe Ltd Supported polymerisation catalysts

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000514130A (ja) * 1997-01-10 2000-10-24 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー コーポレイション 活性が増大されたオレフィン重合用触媒組成物

Also Published As

Publication number Publication date
TW200513471A (en) 2005-04-16
JP2007503479A (ja) 2007-02-22
TWI391411B (zh) 2013-04-01
CA2534836C (en) 2012-11-27
WO2005019275A1 (en) 2005-03-03
US7678726B2 (en) 2010-03-16
KR20120039069A (ko) 2012-04-24
EP1656394B1 (en) 2012-10-03
MY145998A (en) 2012-06-15
EP1656394A1 (en) 2006-05-17
ES2391973T3 (es) 2012-12-03
US20060223695A1 (en) 2006-10-05
KR20070028277A (ko) 2007-03-12
JP5296982B2 (ja) 2013-09-25
CA2534836A1 (en) 2005-03-03

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