KR101099320B1 - Wallpaper containing absorbing counteractive for removing volatile organic compounds and formaldehyde - Google Patents

Abstract

PURPOSE: A wallpaper containing an adsorbing/neutralizing agent is provided to purify indoor air and generate anion. CONSTITUTION: A wallpaper containing an adsorbing/neutralizing agent for removing volatile organic compounds and formaldehyde contains one selected among loess powder, charcoal powder, jade powder, or elvan powder in an emulsifying solution. A method for fabricating the wallpaper comprises: a step of preparing a first mixture containing one of glucose and urea in a mixture solution containing water, acrylic acid, and ethyl alcohol; a step of preparing a second mixture; and a step of irradiating radiation to the second mixture.

Description

WALLPAPER CONTAINING ABSORBING COUNTERACTIVE FOR REMOVING VOLATILE ORGANIC COMPOUNDS AND FORMALDEHYDE}

The present invention relates to a wallpaper containing an adsorptive neutralizer for removing volatile organic compounds (VOC) and formaldehyde (HCHO), and more particularly, a wallpaper containing an adsorbent neutralizing agent, and loess powder or charcoal on the wallpaper. Add powder, jade powder or elvan powder to use as wall finishing material, and add adsorbing neutralizer to adhesive for adhering the wallpaper to the wall to formaldehyde, ammonia and volatile organic compounds (VOC) generated in new buildings. Adsorption and decomposition removal to prevent sick house syndrome, cancer prevention and atopy improvement, reducing stress, purifying indoor air or negative ion generation and far-infrared radiation to promote human benefits.

In general, wallpaper, which is part of the wall finishing material, has various patterns and materials, and thus plays an important role as an interior interior material.

In addition to being used as a simple finishing material, wallpaper has a great influence on the emotional growth and change of human beings and contributes to the creation of health and hygiene in the indoor environment.

When the wallpaper is used as a finishing material on the wall in a new building, the volatilized organic compounds and formaldehyde are generated in the wallpaper or interior building finishing material.

The volatile organic compounds refer to organic compounds and formaldehyde which exist in gaseous form at room temperature in the air, and the numbers shown are hundreds of species, most of which are contained as carcinogens, and benzene, toluene, chloroform, Acetone, styrene and the like are well known.

On the other hand, substances that cause sick house syndrome are most commonly emitted after 6 months of construction, especially in adhesives used for attaching wallpaper, floors, tiles, etc., up to 10 years after construction. It can also act as a factor that continues to endanger health.

For this reason, the Ministry of Environment recently revised and implemented the Act on Indoor Air Quality Management of Multi-use Facilities, which greatly strengthens indoor air management of apartments and multi-use facilities such as apartments.

 However, in the building built before the revision, substances causing the sick house syndrome are still being released, and in order to solve the problem, researches on materials that can remove or reduce the substances causing the sick house syndrome have been actively conducted.

Due to volatile organic compounds and formaldehyde, which are the causative agents of the sick house syndrome, there is a problem of serious deterioration of health and serious stress on the human body due to serious threats to the human body.

In order to solve the above problems, the present invention is added to the wallpaper containing the adsorbing neutralizing agent, ocher powder or charcoal powder or jade powder or ganban stone powder to the wallpaper used as a wall finishing material, the wallpaper is adhered to the wall surface Adsorption neutralizer is added to the adhesive to adsorb and decompose formaldehyde, ammonia and volatile organic compounds (VOC) generated in new buildings to prevent sick house syndrome, prevent cancer, improve atopy and reduce stress. An object of the present invention is to provide a wallpaper containing an adsorption neutralizing agent for removing volatile organic compounds (VOC) and formaldehyde (HCHO), which are intended to benefit the human body by purifying air or generating anions and emitting far infrared rays.

In order to achieve the above object, the present invention provides a mixture of water, acrylic acid and ethyl alcohol, the first mixture of any one selected from glucose or urea, and the first mixture of glycan or hydroxylamine And a second admixture mixed with any one selected, and a wallpaper containing an adsorption degrading neutralizer composed of an emulsion containing a polymer by irradiating the second admixture with radiation.

In addition, the emulsion is characterized in that gelled with zeolite or color sac.

In addition, the mixture is characterized in that the mixture is added to the wallpaper by adding any one selected from ocher powder or charcoal powder or jade powder or elvan powder to the emulsion.

In addition, the mixture is characterized in that the top coating or embossed on the wallpaper.

In addition, the emulsion is characterized in that it is mixed with the adhesive.

In addition, the emulsion is characterized in that the wallpaper is applied or impregnated, adhered or sprayed on the wallpaper.

Further, a first mixture in which any one selected from glucose or urea is further mixed in a mixed solution of water, acrylic acid and ethyl alcohol, a second mixture in which glycic acid is mixed with the first mixture, and sodium citrate in the second mixture. 3 to 10 parts by weight of any one selected from sodium tartarate, sodium malate, and sodium ascorbate to adjust the pH, and the third mixture is composed of an emulsion containing a polymer by irradiation with radiation It is characterized by consisting of the wallpaper containing the adsorption decomposition neutralizing agent.

In addition, the emulsion is characterized in that it is mixed with the adhesive.

In addition, it is characterized in that by adding any one selected from ocher powder or charcoal powder or jade powder or elvan powder to the emulsion.

In addition, the mixture is characterized in that the top coating or embossed on the wallpaper.

In addition, the emulsion is characterized in that the wallpaper is applied or impregnated, adhered or sprayed on the wallpaper.

 The present invention is added to the wallpaper containing the adsorbing neutralizing agent, ocher powder or charcoal powder or jade powder to the wallpaper used as a wall finishing material, by adding an adsorbing neutralizer to the adhesive for adhering the wallpaper to the wall in a new building Formaldehyde, ammonia, and volatile organic compounds (VOCs) generated are adsorbed and decomposed to prevent sick house syndrome, cancer prevention, atopy improvement, and stress.

In addition, the emulsion or zeolite, which is an adsorption neutralizing agent contained in the wallpaper of the present invention, has the effect of adsorbing and decomposing ammonia and odor or tobacco odor.

In addition, the ocher powder or charcoal powder or jade powder or ganban stone powder is further added to the emulsion or zeolite contained in the wallpaper of the present invention to give a beneficial effect on the human body by generating anion process and far-infrared radiation.

1 is a schematic diagram showing the adsorption decomposition process of the emulsion or zeolite contained in the wallpaper according to the present invention.
Figure 2 is a schematic diagram showing a product applied to the emulsion or zeolite in addition to the wallpaper according to the present invention.

In order to fully understand the present invention, preferred embodiments of the present invention will be described with reference to the accompanying drawings.

The embodiments of the present invention may be modified in various forms, and the scope of the present invention should not be construed as being limited to the embodiments described in detail below. The present embodiments are provided to explain the present invention more safely to those having ordinary skill in the art.

Therefore, the shape of the elements in the drawings and the like may be exaggerated to emphasize a more clear description. It should be noted that the same members in each drawing are sometimes shown with the same reference numerals.

In addition, detailed descriptions of well-known functions and configurations that are determined to unnecessarily obscure the subject matter of the present invention are omitted.

1 is a schematic view showing the adsorption decomposition process of the emulsion or zeolite contained in the wallpaper according to the present invention, Figure 2 is a schematic diagram showing a product applied to the emulsion or zeolite in addition to the wallpaper according to the present invention.

Referring to the embodiment of the wallpaper containing the adsorption neutralizing agent for removing volatile organic compounds (VOC) and formaldehyde (HCHO) according to the present invention, and shown in Figures 1 and 2 as follows.

The present invention provides a mixture of water, acrylic acid and ethyl alcohol, the first mixture of which glucose is further mixed, the second mixture of glycic acid or hydroxycinamine mixed in the first mixture, and radiation to the second mixture. Irradiation results in an emulsion containing the polymer.

It is comprised by apply | coating or impregnating, adhering, or spraying the said emulsion liquid to a wallpaper.

In addition, the emulsion is gelled with zeolite or color sac.

Further, the ocher powder or charcoal powder or jade powder is further mixed with the wallpaper containing the emulsion to purify indoor air or generate negative ions and emit far-infrared rays to promote human benefits.

A mixture of ocher powder or charcoal powder or jade powder further added to the emulsion is top coated or embossed on the wallpaper.

The wallpaper containing the emulsion is a volatile organic compound by removing the volatile organic compound (VOC) or formaldehyde (HCHO) generated in the sick house syndrome by the adsorption neutralizing agent, which is the emulsion as shown in FIG. (VOC) or formaldehyde (HCHO) to eliminate the threat of human health in advance.

The emulsion produced as described above is coated or impregnated or adhered or sprayed onto cloth, nonwoven fabric, paper, and wood in addition to wallpaper to be used as a product as shown in FIG.

In addition, the volatile organic compound (VOC) or formaldehyde (HCHO) which is the cause of the sick house syndrome due to the emulsion when the wallpaper is used as the adhesive on the wall wall is used as the adhesive on the wall is composed by mixing with the adhesive in the emulsion of the present invention ) To effectively desorb and desorb.

Example 1

The present invention provides a mixture of water, acrylic acid and ethyl alcohol, the first mixture of which glucose is further mixed, the second mixture of glycic acid or hydroxycinamine mixed in the first mixture, and radiation to the second mixture. It investigated and the emulsion containing the polymer was obtained.

The emulsion thus obtained is coated or impregnated, impregnated, or sprayed on the wallpaper to be contained in the wallpaper.

Thus, deodorization test to remove formaldehyde (HCHO) from the wallpaper containing the emulsion was carried out as shown in Table 1 below, the emulsion was effectively removed formaldehyde (HCH).

                                   Test result     Test method                Deodorization Test (Formaldehyde HCHO)     Elapsed time   blank concentration (ppm)   sample concentration (ppm)      Deodorization rate (%)        0         80         80         -       30         77          5       93.5       60         75          3       96.0       90         73          2       97.3      120         71          One       98.6     Test Methods

 Further, as shown in Table 2, formaldehyde (HCHO) was reduced in the wallpaper containing the emulsion.

The present invention provides a first mixture of urea further mixed with a mixture of water, acrylic acid and ethyl alcohol, a second mixture of glycic acid or hydroxycinamine mixed with the first mixture, and radiation to the second mixture. Irradiation results in an emulsion containing the polymer.

It is comprised by apply | coating or impregnating, adhering, or spraying the said emulsion liquid to a wallpaper.

In addition, the emulsion is gelled with zeolite or color sac.

Further, the ocher powder or charcoal powder or jade powder is further mixed with the wallpaper containing the emulsion to purify indoor air or generate negative ions and emit far-infrared rays to promote human benefits.

A mixture of ocher powder or charcoal powder or jade powder further added to the emulsion is top coated or embossed on the wallpaper.

The wallpaper containing the emulsion is a volatile organic compound by removing the volatile organic compound (VOC) or formaldehyde (HCHO) generated in the sick house syndrome by the adsorption neutralizing agent, which is the emulsion as shown in FIG. (VOC) or formaldehyde (HCHO) to eliminate the threat of human health in advance.

The emulsion produced as described above is coated or impregnated or adhered or sprayed onto cloth, nonwoven fabric, paper, and wood in addition to wallpaper to be used as a product as shown in FIG.

In addition, the volatile organic compound (VOC) or formaldehyde (HCHO) which is the cause of the sick house syndrome due to the emulsion when the wallpaper is used as the adhesive on the wall wall is used as the adhesive on the wall is composed by mixing with the adhesive in the emulsion of the present invention ) To effectively desorb and desorb.

Example 2

The present invention provides a mixture of water, acrylic acid and ethyl alcohol, the first mixture of which glucose is further mixed, the second mixture of glycic acid or hydroxycinamine mixed in the first mixture, and radiation to the second mixture. It investigated and the emulsion containing the polymer was obtained.

The emulsion thus obtained is coated or impregnated, impregnated, or sprayed on the wallpaper to be contained in the wallpaper.

Thus, deodorization test to remove formaldehyde (HCHO) from the wallpaper containing the emulsion was carried out as shown in Table 3 below, the emulsion was effectively removed formaldehyde (HCH).

                                   Test result     Test method                Deodorization Test (Formaldehyde HCHO)     Elapsed time   blank concentration (ppm)   sample concentration (ppm)      Deodorization rate (%)        0         80         80         -       30         77          5       93.5       60         75          3       96.0       90         73          2       97.3      120         71          One       98.6     Test Methods

  Further, as shown in Table 4, formaldehyde (HCHO) was reduced in the wallpaper containing the emulsion.

The present invention provides a mixture of water, acrylic acid and ethyl alcohol, the first mixture of glucose further mixed, the second mixture of glycic acid in the first mixture, sodium citrate and sodium stannate in the second mixture, Sodium malate and any one selected from sodium ascorbate are mixed with 3 to 10 parts by weight of a third mixture to adjust the pH, and the third mixture is irradiated with radiation to produce an emulsion containing polymer.

It is comprised by apply | coating or impregnating, adhering, or spraying the said emulsion liquid to a wallpaper.

In addition, the emulsion is gelled with zeolite or color sac.

Further, the ocher powder or charcoal powder or jade powder is further mixed with the wallpaper containing the emulsion to purify indoor air or generate negative ions and emit far-infrared rays to promote human benefits.

A mixture of ocher powder or charcoal powder or jade powder further added to the emulsion is top coated or embossed on the wallpaper.

The wallpaper containing the emulsion is a volatile organic compound by removing the volatile organic compound (VOC) or formaldehyde (HCHO) generated in the sick house syndrome by the adsorption neutralizing agent, which is the emulsion as shown in FIG. (VOC) or formaldehyde (HCHO) to eliminate the threat of human health in advance.

The emulsion produced as described above is coated or impregnated or adhered or sprayed onto cloth, nonwoven fabric, paper, and wood in addition to wallpaper to be used as a product as shown in FIG.

In addition, the volatile organic compound (VOC) or formaldehyde (HCHO) which is the cause of the sick house syndrome due to the emulsion when the wallpaper is used as the adhesive on the wall wall is used as the adhesive on the wall is composed by mixing with the adhesive in the emulsion of the present invention ) To effectively desorb and desorb.

Example 3

The present invention provides a mixture of water, acrylic acid and ethyl alcohol, the first mixture of glucose further mixed, the second mixture of glycic acid in the first mixture, sodium citrate and sodium stannate in the second mixture, 3 to 10 parts by weight of any one selected from sodium malate and sodium ascorbate were mixed to adjust the pH, and the third mixture was irradiated with radiation to obtain an emulsion containing polymer.

The emulsion thus obtained is coated or impregnated, impregnated, or sprayed on the wallpaper to be contained in the wallpaper.

Thus, deodorization test to remove formaldehyde (HCHO) from the wallpaper containing the emulsion was carried out as shown in Table 5 below, the emulsion was effectively removed formaldehyde (HCH).

                                   Test result     Test method                Deodorization Test (Formaldehyde HCHO)     Elapsed time   blank concentration (ppm)   sample concentration (ppm)      Deodorization rate (%)        0         80         80         -       30         77          5       93.5       60         75          3       96.0       90         73          2       97.3      120         71          One       98.6     Test Methods

  Further, as shown in Table 6, formaldehyde (HCHO) was reduced in the wallpaper containing the emulsion.

The present invention provides a mixture of water, acrylic acid and ethyl alcohol, the first mixture of which urea is further mixed, the second mixture of glycic acid in the first mixture, sodium citrate and sodium stannate in the second mixture, Sodium malate and any one selected from sodium ascorbate are mixed with 3 to 10 parts by weight of a third mixture to adjust the pH, and the third mixture is irradiated with radiation to produce an emulsion containing polymer.

It is comprised by apply | coating or impregnating, adhering, or spraying the said emulsion liquid to a wallpaper.

In addition, the emulsion is gelled with zeolite or color sac.

Further, the ocher powder or charcoal powder or jade powder is further mixed with the wallpaper containing the emulsion to purify indoor air or generate negative ions and emit far-infrared rays to promote human benefits.

A mixture of ocher powder or charcoal powder or jade powder further added to the emulsion is top coated or embossed on the wallpaper.

The wallpaper containing the emulsion is a volatile organic compound by removing the volatile organic compound (VOC) or formaldehyde (HCHO) generated in the sick house syndrome by the adsorption neutralizing agent, which is the emulsion as shown in FIG. (VOC) or formaldehyde (HCHO) to eliminate the threat of human health in advance.

The emulsion produced as described above is coated or impregnated or adhered or sprayed onto cloth, nonwoven fabric, paper, and wood in addition to wallpaper to be used as a product as shown in FIG.

In addition, the volatile organic compound (VOC) or formaldehyde (HCHO) which is the cause of the sick house syndrome due to the emulsion when the wallpaper is used as the adhesive on the wall wall is used as the adhesive on the wall is composed by mixing with the adhesive in the emulsion of the present invention ) To effectively desorb and desorb.

Example 4

The present invention provides a mixture of water, acrylic acid and ethyl alcohol, the first mixture of which urea is further mixed, the second mixture of glycic acid in the first mixture, sodium citrate and sodium stannate in the second mixture, 3 to 10 parts by weight of any one selected from sodium malate and sodium ascorbate were mixed to adjust the pH, and the third mixture was irradiated with radiation to obtain an emulsion containing polymer.

The emulsion thus obtained is coated or impregnated, impregnated, or sprayed on the wallpaper to be contained in the wallpaper.

Thus, deodorization test to remove formaldehyde (HCHO) from the wallpaper containing the emulsion was carried out as shown in Table 7 below, the emulsion was effectively removed formaldehyde (HCH).

                                   Test result     Test method                Deodorization Test (Formaldehyde HCHO)     Elapsed time   blank concentration (ppm)   sample concentration (ppm)      Deodorization rate (%)        0         80         80         -       30         77          5       93.5       60         75          3       96.0       90         73          2       97.3      120         71          One       98.6     Test Methods

 In addition, as shown in Table 8, formaldehyde (HCHO) was reduced in the wallpaper containing the emulsion.

As described above, the present invention can effectively remove formaldehyde (HCHO) from the wallpaper containing the adsorptive neutralizer composed of the emulsion through Examples 1 to 4, and in addition to the volatile organic compounds (VOC) and ammonia can be effectively removed. Can be.

In this way, the wallpaper of the present invention removes formaldehyde (HCHO) and volatile organic compounds (VOC) generated in the sick house syndrome to remove harmful substances to the human body caused by the sick house syndrome to prevent the health impaired to the human body, ammonia or It is possible to effectively remove other harmful substances.

Therefore, the wallpaper of the present invention is to reduce the stress caused by cancer prevention and atopy, and birdhouse syndrome caused in the human body due to sick house syndrome.

It will be apparent to those skilled in the art that various modifications and equivalent arrangements may be made therein without departing from the scope of the present invention. . Therefore, it will be understood that the present invention is not limited to the forms mentioned in the above detailed description.

Therefore, the true technical protection scope of the present invention will be defined by the technical spirit of the appended claims. It is also to be understood that the present invention includes all modifications, equivalents and substitutions within the spirit and scope of the invention as defined by the appended claims.

Claims (11)

A first mixture in which any one selected from glucose or urea is further mixed with a mixed solution of water, acrylic acid and ethyl alcohol, and a second mixture in which any one selected from glycic acid or hydroxylamine is mixed with the first mixture, Irradiating the second mixture is composed of wallpaper containing the adsorption decomposition neutralizing agent composed of an emulsion containing a polymer by irradiation with radiation,
In the wallpaper containing the adsorption decomposition neutralizing agent for removing the volatile organic compound (VOC) and formaldehyde (HCHO) gelated with the zeolite or color bladder,
Adsorption to remove volatile organic compounds (VOC) and formaldehyde (HCHO), characterized in that the mixed mixture is added to the emulsion by adding any one selected from ocher powder or charcoal powder or jade powder or ganban stone powder to the emulsion. Wallpaper containing decomposing neutralizer. delete delete The method of claim 1,
A wallpaper containing an adsorption decomposition neutralizing agent for removing volatile organic compounds (VOC) and formaldehyde (HCHO), characterized in that the mixture is top coated or embossed on the wallpaper. The method of claim 1,
A wallpaper containing an adsorption decomposition neutralizing agent for removing volatile organic compounds (VOC) and formaldehyde (HCHO), characterized in that the emulsion is mixed with an adhesive. delete delete The method of claim 1,
A wallpaper containing an adsorption decomposition neutralizing agent for removing volatile organic compounds (VOC) and formaldehyde (HCHO), characterized in that the emulsion is mixed with an adhesive. The method of claim 1,
Adsorption decomposition neutralizer for removing volatile organic compounds (VOC) and formaldehyde (HCHO), characterized in that the mixture is added to the emulsion by adding any one selected from ocher powder or charcoal powder or jade powder or ganban stone powder Wallpaper. The method of claim 9,
A wallpaper containing an adsorption decomposition neutralizing agent for removing volatile organic compounds (VOC) and formaldehyde (HCHO), characterized in that the mixture is top coated or embossed on the wallpaper. delete

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