KR101409242B1 - Furniture Surface material - Google Patents

Furniture Surface material Download PDF

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KR101409242B1
KR101409242B1 KR1020130133310A KR20130133310A KR101409242B1 KR 101409242 B1 KR101409242 B1 KR 101409242B1 KR 1020130133310 A KR1020130133310 A KR 1020130133310A KR 20130133310 A KR20130133310 A KR 20130133310A KR 101409242 B1 KR101409242 B1 KR 101409242B1
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weight
adsorption
parts
coating
furniture
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KR1020130133310A
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Korean (ko)
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이민호
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(주)그라프톤코리아
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47BTABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
    • A47B97/00Furniture or accessories for furniture, not provided for in other groups of this subclass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/06Ethers; Acetals; Ketals; Ortho-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/092Polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/101Esters; Ether-esters of monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/15Heterocyclic compounds having oxygen in the ring
    • C08K5/151Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1545Six-membered rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/43Thickening agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a furniture surface material with a function capable of adsorbing and dissolving harmful substances and volatile organic compounds, wherein the material improves a removal function for, through absorption and neutralization, formaldehyde and volatile organic compounds contained in a paint and an adhesive used for manufacturing furniture (furniture using MDF) by attaching a sheet which is formed by coating an adsorption neutralization coating layer on a film based on an adsorption neutralization coating agent prepared by mixing copolymers, ethyl cellosolve, thickeners, methylparaben; and extends period of usage.

Description

유해물질 및 휘발성 유기화합물을 흡착 분해하는 성능이 코팅된 가구 표면재{Furniture Surface material}[0001] Furniture surface material capable of adsorbing and decomposing harmful substances and volatile organic compounds,

본 발명은 유해물질 및 휘발성 유기화합물을 흡착 분해하는 성능이 코팅된 가구 표면재에 관한 것으로서, 더욱 상세하게는, 코폴리머와, 에틸셀로솔브와, 증점제와, 메틸파라벤이 혼합교반되어 흡착중화코팅제로 필름상에 흡착중화코팅층을 형성한 시트지를 가구에 부착하여 가구(PB(particle board)/MDF 재료를 사용한 가구)를 제조시 사용되는 도료 및 접착제에 포함되어 있는 포름알데히드, 휘발성 유기화합을 탁월하게 흡착 분해하여 제거하는 기능을 한차원 높이고, 그 사용연한을 장기적으로 사용하도록 한 포름알데히드 및 휘발성 유기화합물을 흡착분해코팅제가 가구의 상부에 코팅되어 유해물질 및 휘발성 유기화합물을 흡착 분해하는 성능이 코팅된 가구 표면재에 관한 것이다.The present invention relates to a furniture surface material coated with a capability of adsorbing and decomposing harmful substances and volatile organic compounds, and more particularly, It is excellent in formaldehyde and volatile organic compounds contained in paints and adhesives used in manufacturing furniture (PB (particle board / MDF material)) by attaching a sheet with adsorption neutralization coating layer on the film. The adsorption and decomposition of formaldehyde and volatile organic compounds, which have been used for a long period of time, have been improved by one-dimensional enhancement of the function of adsorption, decomposition and elimination. The coating on the upper part of the furniture is capable of adsorbing and decomposing harmful substances and volatile organic compounds And the like.

일반적으로 새로운 집을 새로운 건축자재로 건축하여 세울 수 있으나, 이러한 새집의 건축자재에서 발생되는 휘발성 유기용제, 포름알데히드 등으로 인해 발생되는 새집 증후군에 시달리게 되므로 시간과 비용을 들여 건축된 새집에 살수 없다는 현상이 발생되어 사회문제가 제기되는 점이 있어 이를 해결하려고 다방면으로 연구 노력이 되어 왔다.Generally, a new house can be constructed as a new building material. However, since it is affected by sick house syndrome caused by volatile organic solvents and formaldehyde generated from the building materials of these new houses, it is impossible to live in a new house built with time and money And social problems have been raised, and various efforts have been made to solve them.

또한, 그 밖의 생활환경으로부터 발생되는 휘발성유기화합물, 암모니아, 기타 잡냄새등과 같은 유해물질을 제거할 수 있는 연구가 다양하게 실시되어 왔다.In addition, various studies have been conducted to remove harmful substances such as volatile organic compounds, ammonia, and other odors generated from other living environments.

또한, 가구를 PB/MDF 재질로 사용하여 제작시 PB/MDF를 제조시 사용되는 접착제 또는 도료에 포함되어 있는 휘발성 유기용제(휘발성 유기화합물), 포름알데히드 성분 등이 함유되어 있게 되는 것이다.In addition, when the furniture is used as a PB / MDF material, volatile organic solvents (volatile organic compounds) and formaldehyde components contained in the adhesive or paint used in manufacturing the PB / MDF are contained.

이러하게 PB/MDF가구를 새로이 제작하여 사용시, 이 가구에 사용된 도료 및 접착제로 인한 휘발성 유기화합물 등은 인체에 유해한 것으로서, 새로구입한 가구를 처음 사용시 이 가구에 사용된 도료 및 접착제 포함된 휘발성 유기화합물은 가구를 사용하는 사용자의 인체에 유해성분이 그대로 노출되어 인체의 건강에 해가 되는 문제점이 있었다.When PB / MDF furniture is newly made and used, the volatile organic compounds due to the paint and adhesive used in the furniture are harmful to human body. Therefore, when the new furniture is used for the first time, Organic compounds have a problem in that harmful substances are exposed to the human body of the user who uses the furniture, which is detrimental to the health of the human body.

또한, 이러한 인체에 유해한 성분을 제거하기 위해 다양한 연구와 노력으로 새로 제작된 가구가 주거환경에 사용될시 새로 제작된 가구에서 발생되는 휘발성 화학적 유해물질을 효과적으로 중화 제거하지 못하였고, 새로 제작되어 유해물질을 발생시키는 유해물질을 중화 및 제거를 할 수 있는 사용기간을 오랫동안 유지시키지 못하는 많은 문제점이 있었다.In addition, various researches and efforts have been made to remove harmful constituents from the human body. When the newly manufactured furniture is used in the residential environment, it can not effectively neutralize the volatile chemical harmful substances generated in the newly manufactured furniture. There is a problem in that the use period for neutralizing and removing toxic substances that generate toxic substances can not be maintained for a long time.

상기와 같은 문제점을 해결하기 위해서, 본 발명은 코폴리머와, 에틸셀로솔브와, 증점제와, 메틸파라벤이 혼합교반되어 흡착중화코팅제로 필름상에 흡착중화코팅층을 형성한 시트지를 가구에 부착하여 가구(PB/MDF 재료를 사용한 가구)를 제조시 사용되는 도료 및 접착제에 포함되어 있는 포름알데히드, 휘발성유기화합을 탁월하게 흡착중화하여 제거하는 기능을 한차원 높이고, 그 사용연한을 장기적으로 사용하도록 한 새로운 포름알데히드 및 암모니아 유기화합물을 흡착중화코팅제가 상부에 코팅된 시트지를 제공하는데 그 목적이 있다.In order to solve the above-mentioned problems, the present invention relates to a method for manufacturing a film, which comprises adhering a sheet to which a copolymer, ethylcellosolve, a thickener and methylparaben are mixed and stirred to form an adsorption neutralized coating layer on a film with an adsorption neutralization coating, The function to neutralize and neutralize the formaldehyde and volatile organic compounds contained in the paints and adhesives used in manufacturing the furniture (PB / MDF materials) is excellently enhanced, and the use life is long-term It is an object of the present invention to provide a sheet on which a new neutralized formaldehyde and ammonia organic compound adsorbing coating is coated.

이와 같은 목적을 달성하기 위해서, 본 발명은 요소(UREA), 글루코스(GLUCOSE), N,N-디메칠아크릴 아마이드 폴리머(N,N-DIMETHYL ACRYL AMIDE POLYMER), 시트르산(CITRIC ACID), 소듐시트레이트(SODIUM CITRATE), 물이 혼합된 코폴리머(COPOLYMER) 50중량부와, 에틸셀로솔브(EHTHYL CELLOSOLVE) 49중량부와, 증점제(THICHENER) 0.85중량부와, 메틸파라벤(METHYLPAREBEN) 0.15중량부를 준비하여 이를 혼합 교반된 흡착중화코팅제(a)가 필름(p)상에 코팅되는 것을 특징으로 한다.In order to achieve the above object, the present invention provides a method for producing a liquid crystal composition comprising UREA, GLUCOSE, N, N-DIMETHYL ACRYLAMIDE POLYMER, CITRIC ACID, 50 parts by weight of a copolymer of SODIUM CITRATE and water, 49 parts by weight of ETHTHYL CELLOSOLVE, 0.85 part by weight of THICHENER and 0.15 part by weight of METHYLPAREBEN were prepared. And the mixed neutralized adsorption neutralizing coating agent (a) is coated on the film (p).

또한, 상기 교반은 3000RPM에서 10분내지 15분동안 이루어지는 것을 특징으로 한다.Further, the stirring is performed at 3000 RPM for 10 minutes to 15 minutes.

또한, 상기 흡착중화코팅제(a)는 상기 필름(p)상에 도포 및 스프레이되어 흡착중화코팅층(c)으로 건조되는 것을 특징으로 한다.In addition, the adsorption neutralizing coating agent (a) is applied and sprayed on the film (p) and dried with the adsorption neutralizing coating layer (c).

또한, 상기 흡착중화코팅제(a)는 용액상태로 구성되는 것을 특징으로 한다.In addition, the adsorption neutralizing coating agent (a) is characterized by being in a solution state.

또한, 상기 코폴리머(COPOLYMER)의 구성비는 요소(UREA) 17중량부와, 글루코스(GLUCOSE) 3중량부와, N,N-디메칠아크릴 아마이드 폴리머(N,N-DIMETHYL ACRYL AMIDE POLYMER) 1중량부와, 시트르산(CITRIC ACID) 3,5중량부와, 소듐시트레이트(SODIUM CITRATE) 3.5중량부와 물 72중량부로 구성되는 것을 특징으로 한다.The composition ratio of the copolymer was 17 parts by weight of UREA, 3 parts by weight of GLUCOSE and 1 part by weight of N, N-dimethylacrylamide polymer (N, N-dimethylacrylamide polymer) , 3.5 parts by weight of citric acid (CITRIC ACID), 3.5 parts by weight of sodium citrate (Sodium Citrate) and 72 parts by weight of water.

본 발명은 코폴리머와, 에틸셀로솔브와, 증점제와, 메틸파라벤이 혼합교반되어 흡착중화코팅제로 필름상에 흡착중화코팅층을 형성한 시트지를 가구에 부착하여 가구(MDF 재료를 사용한 가구)를 제조시 사용되는 도료 및 접착제에 포함되어 있는 포름알데히드, 휘발성유기화합을 탁월하게 흡착중화하여 제거하는 기능을 한차원 높이고, 그 사용연한을 장기적으로 사용하는 효과가 있다.The present invention relates to a method for manufacturing a sheet-like product, which comprises the steps of mixing a copolymer, ethylcellosolve, a thickener, and methylparaben in a mixer to form a neutralized coating layer on a film with an adsorption neutralizing coating, The function of neutralizing and removing adsorbed formaldehyde and volatile organic compounds contained in paints and adhesives used in manufacturing can be improved in one dimension, and the use life of the adhesive can be long-term.

도 1은 본 발명에 따른 시트지의 제조방법 개략도.
도 2는 본 발명에 따른 필름상의 코팅층을 나타낸 개략단면도.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view of a method for producing a sheet according to the present invention; FIG.
2 is a schematic cross-sectional view of a coating layer on a film according to the present invention.

본 발명을 충분히 이해하기 위해서 본 발명의 바람직한 실시예를 첨부 도면을 참조하여 설명한다.For a better understanding of the present invention, a preferred embodiment of the present invention will be described with reference to the accompanying drawings.

본 발명의 실시예는 여러가지 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상세히 설명하는 실시예로 한정되는 것으로 해석되어서는 안된다. 본 실시예는 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 안전하게 설명하기 위하여 제공되는 것이다.The embodiments of the present invention may be modified in various forms, and the scope of the present invention should not be construed as being limited to the embodiments described in detail below. The present embodiments are provided to explain the present invention more safely to those having ordinary skill in the art.

따라서 도면에서의 요소의 형상 등은 보다 명확한 설명을 강조하기 위해서 과장되어 표현될 수 있다. 각 도면에서 동일한 부재는 동일한 참조부호로 도시한 경우가 있음을 유의하여야 한다.Therefore, the shapes and the like of the elements in the drawings can be exaggeratedly expressed to emphasize a clearer description. It should be noted that in the drawings, the same members are denoted by the same reference numerals.

또한, 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 공지 기능 및 구성에 대한 상세한 기술은 생략된다.Further, detailed descriptions of well-known functions and configurations that may be unnecessarily obscured by the gist of the present invention are omitted.

도 1은 본 발명에 따른 시트지의 제조방법 개략도이고, 도 2는 본 발명에 따른 필름상의 코팅층을 나타낸 개략단면도이다.FIG. 1 is a schematic view of a method for producing a sheet according to the present invention, and FIG. 2 is a schematic sectional view showing a coating layer on a film according to the present invention.

본 발명에 따른 포름알데히드 및 휘발성 유기화합물을 흡착중화코팅제가 상부에 코팅된 시트지는 도 1 및 도 2를 참고하여 실시예를 들어 상세하게 설명하면 다음과 같다.The sheet of the present invention on which a formaldehyde and a volatile organic compound are adsorbed on a neutralization coating agent will be described in detail with reference to FIG. 1 and FIG.

본 발명에 따른 흡착중화코팅제의 제조방법은 아래 실시예와 같다.The method for preparing the adsorption neutralization coating agent according to the present invention is the same as the following examples.

[실시예][Example]

본 발명에 따른 흡착중화코팅제(a)에 필요한 요소(UREA), 글루코스(GLUCOSE), N,N-디메칠아크릴 아마이드 폴리머(N,N-DIMETHYL ACRYL AMIDE POLYMER), 시트르산(CITRIC ACID), 소듐시트레이트(SODIUM CITRATE), 물이 혼합된 코폴리머(COPOLYMER) 50중량부와, 에틸셀로솔브(EHTHYL CELLOSOLVE) 49중량부와, 증점제(THICHENER) 0.85중량부와, 메틸파라벤(METHYLPAREBEN) 0.15중량부를 준비하여 준다.(UREA), glucose (GLUCOSE), N, N-dimethylacrylamide polymer, citric acid, sodium sulfate and the like necessary for the adsorption neutralization coating agent (a) 50 parts by weight of COPOLYMER mixed with water, 49 parts by weight of ETHTHYL CELLOSOLVE, 0.85 part by weight of THICHENER and 0.15 part by weight of METHYLPAREBEN Get ready.

그리고, 요소(UREA), 글루코스(GLUCOSE), N,N-디메칠아크릴 아마이드 폴리머(N,N-DIMETHYL ACRYL AMIDE POLYMER), 시트르산(CITRIC ACID), 소듐시트레이트(SODIUM CITRATE), 물이 혼합된 코폴리머(COPOLYMER) 50중량부와, 에틸셀로솔브(EHTHYL CELLOSOLVE) 49중량부와, 증점제(THICHENER) 0.85중량부와, 메틸파라벤(METHYLPAREBEN) 0.15중량부를 혼합 교반시켜 상기 흡착중화코팅제(a)를 제조하여 준다.A mixture of UREA, GLUCOSE, N, N-DIMETHYL ACRYLAMIDE POLYMER, CITRIC ACID, SODIUM CITRATE, 50 parts by weight of a copolymer (COPOLYMER), 49 parts by weight of ETHTHYL CELLOSOLVE, 0.85 part by weight of THICHENER and 0.15 part by weight of METHYLPAREBEN were mixed and stirred to prepare the adsorption neutralizing coating (a) .

상기 교반은 3000RPM에서 10분내지 15분동안 하여주는 것은 최적의 상기 흡착중화코팅제(a)로 혼합교반하여 흡착 및 중화효과를 보다 탁월하게 높여주고, 흡착 및 중화효과를 장기간 지속시켜줄 수 있도록 하기 위함이다.The agitation is carried out at 3000 RPM for 10 minutes to 15 minutes in order to enhance the adsorption and neutralization effect more effectively by mixing and stirring with the optimal adsorption neutralizing coating agent (a), and to maintain adsorption and neutralization effect for a long time to be.

또한, 상기 흡착중화코팅제(a)는 용액상태로 구성되는 것이 바람직하다.In addition, the adsorption neutralizing coating agent (a) is preferably in a solution state.

이와 같이 용액상태로 구성되는 것은 필름(p)상 또는 표면에 용액상태로 도포 및 스프레이되어 흡착중화코팅층(c)을 용이하게 형성하도록 하기 위함이다.Such a solution state is intended to facilitate the formation of the adsorption neutralized coating layer (c) by coating and spraying on the film (p) or surface in a solution state.

상기 흡착중화코팅층(c)은 상기 필름(p)상의 표면에 일정한 두께로 도포되어 시트지(b)를 구성되는 것이 것이 바람직하다.It is preferable that the adsorption neutralizing coating layer (c) is applied to the surface of the film (p) to a predetermined thickness to constitute the sheet (b).

한편, 코폴리머(COPOLYMER)의 중량비는 요소(UREA) 17중량부와, 글루코스(GLUCOSE) 3중량부와, N,N-디메칠아크릴 아마이드 폴리머(N,N-DIMETHYL ACRYL AMIDE POLYMER) 1중량부와, 시트르산(CITRIC ACID) 3,5중량부와, 소듐시트레이트(SODIUM CITRATE) 3.5중량부와 물 72중량부로 구성하여 주는 것이 바람직하다.The weight ratio of the copolymer (COPOLYMER) was 17 parts by weight of UREA, 3 parts by weight of GLUCOSE and 1 part by weight of N, N-dimethylacrylamide polymer (N, N-dimethylacrylamide polymer) And 3.5 parts by weight of citric acid (CITRIC ACID), 3.5 parts by weight of sodium citrate (Sodium Citrate) and 72 parts by weight of water.

상기와 같이 제조된 상기 흡착중화코팅제(a)는 필름(p)상에 도포 및 스프레이되어 흡착중화코팅층(c)으로 건조되어 시트지(b)를 구성되게 한다. The adsorption neutralizing coating agent (a) prepared as described above is applied and sprayed on the film (p) and dried to a neutralized neutralized coating layer (c) to form the sheet (b).

또한, 상기 흡착중화코팅제(a)는 상기 필름(p)상에 도포 및 스프레이되어 흡착중화코팅층(c)을 형성하여 건조 시켜준다.Also, the adsorption neutralization coating agent (a) is coated and sprayed on the film (p) to form an adsorption neutralization coating layer (c) and then dried.

이러하게 상기 필름(p)상에 상기 흡착중화코팅제(a)로 상기 흡착중화코팅층이 형성되어 상기 시트지(b)로서 물품에 부착되어 그 물품인 PB/MDF의 재질로 제작된 가구에 사용되어 지는 도료 및 접착제에는 휘발성화합물인 Formaldehyde, Benzene Toluene, Ethyl Benzene, MP-Xylene, Styrene, O-Xylen, 등과 같은 유해성분이 포함되어 있을 경우 상기 흡착중화코팅층(c)은 그 물품인 PB/MDF가구에 포함되어 있는 휘발성화합물인 Formaldehyde, Benzene Toluene, Ethyl Benzene, MP-Xylene, Styrene, O-Xylen, 등과 같은 유해성분을 흡착 및 중화시켜준다.Thus, the adsorption neutralizing coating layer is formed on the film (p) by the adsorption neutralizing coating agent (a) and attached to the article as the sheet paper (b) to be used for the furniture made of PB / MDF material When the paint and adhesive contain toxic components such as formaldehyde, benzene toluene, ethyl benzene, MP-Xylene, styrene, O-Xylen, etc., the adsorption neutralization coating layer (c) is included in the PB / MDF furniture It absorbs and neutralizes toxic components such as Formaldehyde, Benzene Toluene, Ethyl Benzene, MP-Xylene, Styrene and O-Xylen which are volatile compounds.

상술하는 본 발명의 상기 흡착중화코팅제(a)를 휘발성화합물인 Formaldehyde, Benzene Toluene, Ethyl Benzene, MP-Xylene, Styrene, O-Xylen, 등과 같은 유해성분을 흡착하여 중화시키는 실험을 본 발명(Grafton Mix코팅)과 일반 우레탄 코팅을 아래 표1 내지 표 4와 같이 비교하여 실시하였다.Experiments for adsorbing and neutralizing harmful components such as formaldehyde, benzene toluene, ethyl benzene, MP-Xylene, styrene, and O-Xylen, which are volatile compounds, of the adsorption neutralization coating agent (a) Coating) and a general urethane coating were compared as shown in Tables 1 to 4 below.

(( GraftonGrafton MixMix 코팅은 본 발명의 The coating may be applied to 흡착중화코팅제로With adsorption neutralization coating agent 코팅된 것을 말한다) Coated < / RTI > 종합결과(1)Overall results (1) (Unit : mg/㎡.hr)(Unit: mg / m 2. Hr) CHCH IDID DayDay FormaldehydeFormaldehyde BenzeneBenzene TolueneToluene Ethyl BenzeneEthyl Benzene MP-XyleneMP-Xylene StyreneStyrene O-XyleneO-Xylene 5VOC5VOC UnknownUnknown TVOCTVOC CH_01CH_01 우레탄코팅Urethane coating 1일차Day 1 (1)(One) 0.006 0.006 N.DN.D. 0.436 0.436 0.272 0.272 0.153 0.153 0.082 0.082 0.051 0.051 1.027 1.027 0.740 0.740 1.668 1.668 (2)(2) 0.009 0.009 N.DN.D. 0.437 0.437 0.262 0.262 0.150 0.150 0.084 0.084 0.052 0.052 1.019 1.019 0.700 0.700 1.641 1.641 MeanMean 0.0080.008 N.DN.D. 0.4370.437 0.2670.267 0.1510.151 0.0830.083 0.0510.051 1.0231.023 0.720.72 1.6651.665 SDSD 0.0 0.0 0.0 0.0 0.3 0.3 3.7 3.7 1.6 1.6 3.0 3.0 2.3 2.3 0.8 0.8 5.5 5.5 2.8 2.8 4일차Day 4 (1)(One) 0.0030.003 N.DN.D. 0.3760.376 0.2260.226 0.1230.123 0.0610.061 0.0420.042 0.8570.857 0.6480.648 1.4391.439 (2)(2) N.DN.D. N.DN.D. 0.3890.389 0.2370.237 0.1280.128 0.0640.064 0.0440.044 0.8910.891 0.6380.638 1.461.46 MeanMean 0.0030.003 N.DN.D. 0.3820.382 0.2320.232 0.1260.126 0.0630.063 0.0430.043 0.8740.874 0.6430.643 1.451.45 SDSD 00 00 3.33.3 4.54.5 4.44.4 4.64.6 2.92.9 3.93.9 1.61.6 1.51.5 CH_02CH_02 Grafton Mix코팅Grafton Mix Coating 1일차Day 1 (1)(One) 0.0020.002 N.DN.D. 0.0860.086 0.0910.091 0.0510.051 0.0590.059 0.0240.024 0.3240.324 0.6310.631 0.9290.929 (2)(2) 0.0010.001 N.DN.D. 0.0920.092 0.0960.096 0.0530.053 0.0620.062 0.0260.026 0.340.34 0.6380.638 0.9510.951 MeanMean 0.0010.001 N.DN.D. 0.0890.089 0.0930.093 0.0520.052 0.060.06 0.0250.025 0.3320.332 0.6340.634 0.940.94 SDSD 00 00 00 00 00 00 00 00 00 00 4일차Day 4 (1)(One) 0.0010.001 N.DN.D. 0.1020.102 0.1080.108 0.0580.058 0.0640.064 0.030.03 0.3760.376 0.6560.656 0.900 0.900 (2)(2) 0.0010.001 N.DN.D. 0.1060.106 0.1060.106 0.0610.061 0.0690.069 0.030.03 0.3910.391 0.7020.702 0.8040.804 MeanMean 0.0010.001 N.DN.D. 0.1040.104 0.1040.104 0.060.06 0.0670.067 0.030.03 0.3840.384 0.6790.679 0.0340.034 SDSD 00 00 00 3.43.4 4.44.4 88 1.41.4 3.93.9 7.47.4 6.26.2

(( GraftonGrafton MixMix 코팅은 본 발명의 The coating may be applied to 흡착중화코팅제로With adsorption neutralization coating agent 코팅된 것을 말한다) Coated < / RTI > aNameaName FormaldehydeFormaldehyde BenzeneBenzene TolueneToluene Ethyl BenzeneEthyl Benzene MP-XyleneMP-Xylene StyreneStyrene O-XyleneO-Xylene 5VOC5VOC UnknownUnknown 우레탄코팅Urethane coating 0.0080.008 -                  - 0.4370.437 0.2670.267 0.151 0.151 0.083 0.083 0.051 0.051 1.023 1.023 0.720 0.720 Grafton Mix코팅Grafton Mix Coating 0.0010.001 -                  - 0.0890.089 0.0930.093 0.0520.052 0.060.06 0.0250.025 0.3320.332 0.6340.634 우레탄코팅Urethane coating 0.0030.003 -                  - 0.3820.382 0.0930.093 0.052 0.052 0.060 0.060 0.025 0.025 0.332 0.332 0.634 0.634 Grafton Mix코팅Grafton Mix Coating 0.0010.001 -                  - 0.0890.089 0.1030.103 0.060 0.060 0.067 0.067 0.030 0.030 0.383 0.383 0.679 0.679

Figure 112013100547319-pat00001
Figure 112013100547319-pat00001

Figure 112013100547319-pat00002
Figure 112013100547319-pat00002

상기 표 1 내지 표 4와 같이, 상기 흡착중화코팅제(a)인 본 발명(Grafton Mix코팅)은 일반 우레탄을 사용하여 코팅된 코팅층보다 Formaldehyde, Benzene Toluene, Ethyl Benzene, MP-Xylene, Styrene, O-Xylene인 유해 화학성분을 효과적으로 흡착 및 중화시키는 알 수 가 있다.As shown in Tables 1 to 4, the present invention (Grafton Mix coating) as the adsorptive neutralization coating (a) can be applied to a coating layer coated with a urethane, such as formaldehyde, benzene toluene, ethyl benzene, MP- It is known that Xylene effectively adsorbs and neutralizes harmful chemical components.

따라서, 상기 흡착중화코팅제(a)가 필름(p)상에 도포되어 상기 시트지(b)로 구성되어 상기 시트지가 , 가구, 생활용품 등 다양한 물품의 표면에 부착되어 새로이 제작된 가구 또는 PB/MDF재질로 제작된 가구에 사용되는 도료 또는 접착제에 포함되어 있는 포름알데히드, 암모니아, 휘발성 유해화합물을 효과적으로 흡착 및 중화시키는 것이다.Therefore, when the absorbent neutralizing coating agent (a) is applied on the film (p) and is composed of the sheet paper (b), the sheet is attached to the surface of various articles such as furniture, It effectively adsorbs and neutralizes formaldehyde, ammonia and volatile harmful compounds contained in paints or adhesives used in furniture made of materials.

이상에서 설명된 본 발명에 따른 실시예는 예시적인 것에 불과하며, 본 발명 속하는 기술분야의 통상의 지식을 가진 자라면 이로부터 다양한 변형 및 균등한 타 실시예가 가능하다는 점을 잘 알 수 있을 것이다. 그러므로 본 발명은 상세한 설명에서 언급되는 형태로만 한정되는 것은 아님을 잘 이해할 수 있을 것이다.While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the invention. It is therefore to be understood that the invention is not limited to the form set forth in the detailed description.

따라서 본 발명의 진정한 기술적 보호범위는 첨부된 특허등록청구범위의 기술적 사상에 의해 정해져야 할 것이다. 또한, 본 발명은 첨부된 청구범위에 의해 정의되는 본 발명의 정신과 그 범위내에 있는 모든 변형물과 균등물 및 대체물을 포함하는 것으로 이해되어야 한다.Accordingly, the true scope of the present invention should be determined by the technical idea of the appended claims. It is also to be understood that the invention includes all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.

a : 흡착중화코팅제 b : 시트지
p : 필름 c : 흡착중화코팅층
a: adsorption neutralization coating agent b: sheet paper
p: film c: adsorption neutralization coating layer

Claims (3)

요소(UREA), 글루코스(GLUCOSE), N,N-디메칠아크릴 아마이드 폴리머(N,N-DIMETHYL ACRYL AMIDE POLYMER), 시트르산(CITRIC ACID), 소듐시트레이트(SODIUM CITRATE), 물이 혼합된 코폴리머(COPOLYMER) 50중량부와, 에틸셀로솔브(EHTHYL CELLOSOLVE) 49중량부와, 증점제(THICHENER) 0.85중량부와, 메틸파라벤(METHYLPAREBEN) 0.15중량부를 준비하여 이를 혼합하여 3000RPM에서 10분내지 15분동안 교반된 흡착중화코팅제(a)가 필름(p)상에 코팅되는 것을 특징으로 하는 유해물질 및 휘발성 유기화합물을 흡착 분해하는 성능이 코팅된 가구 표면재.(UREA), GLUCOSE, N, N-DIMETHYL ACRYLAMIDE POLYMER, CITRIC ACID, SODIUM CITRATE, water-mixed copolymers , 50 parts by weight of COPOLYMER, 49 parts by weight of ETHTHYL CELLOSOLVE, 0.85 part by weight of THICHENER, and 0.15 part by weight of METHYLPAREBEN were prepared and mixed at 3000 RPM for 10 minutes to 15 minutes Characterized in that the agitated adsorption neutralizing coating (a) is coated on the film (p). 제 1항에 있어서,
상기 흡착중화코팅제(a)는 상기 필름(p)상에 도포 및 스프레이되어 흡착중화코팅층(c)으로 건조되는 것을 특징으로 하는 유해물질 및 휘발성 유기화합물을 흡착 분해하는 성능이 코팅된 가구 표면재.
The method according to claim 1,
Characterized in that the adsorption neutralizing coating agent (a) is coated and sprayed on the film (p) and dried as a neutralized adsorption neutralizing coating layer (c).
제 1항에 있어서,
상기 코폴리머(COPOLYMER)의 구성비는 요소(UREA) 17중량부와, 글루코스(GLUCOSE) 3중량부와, N,N-디메칠아크릴 아마이드 폴리머(N,N-DIMETHYL ACRYL AMIDE POLYMER) 1중량부와, 시트르산(CITRIC ACID) 3,5중량부와, 소듐시트레이트(SODIUM CITRATE) 3.5중량부와 물 72중량부로 구성되는 것을 특징으로 하는 유해물질 및 휘발성 유기화합물을 흡착 분해하는 성능이 코팅된 가구 표면재.
The method according to claim 1,
The composition ratio of the copolymer was 17 parts by weight of UREA, 3 parts by weight of GLUCOSE and 1 part by weight of N, N-dimethylacrylamide polymer (N, N-dimethylacrylamide polymer) , 3.5 parts by weight of citric acid (CITRIC ACID), 3.5 parts by weight of sodium citrate (SODIUM CITRATE) and 72 parts by weight of water. .
KR1020130133310A 2013-11-05 2013-11-05 Furniture Surface material KR101409242B1 (en)

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KR101559683B1 (en) * 2014-10-17 2015-10-13 삼성물산 주식회사 Coating method and coating material
CN105315839A (en) * 2015-01-26 2016-02-10 云南宏斌绿色食品有限公司 Salt-tolerant acid-proof anticorrosion coating and application thereof to pickled vegetable pickling pool
KR101614502B1 (en) 2015-10-12 2016-04-29 주식회사 대영디자인 Hazardous materials of wood panels using a closed-shell oysters reduction methods and wood panel manufacturing method
KR102259486B1 (en) * 2020-10-26 2021-06-02 주식회사 한국엔시산업 manufacturing method for eco-friendly furniture exterior material
KR102466309B1 (en) 2022-05-23 2022-11-17 (주)아모스아인스가구 Metal frame coating agent for furniture

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101559683B1 (en) * 2014-10-17 2015-10-13 삼성물산 주식회사 Coating method and coating material
CN105315839A (en) * 2015-01-26 2016-02-10 云南宏斌绿色食品有限公司 Salt-tolerant acid-proof anticorrosion coating and application thereof to pickled vegetable pickling pool
KR101614502B1 (en) 2015-10-12 2016-04-29 주식회사 대영디자인 Hazardous materials of wood panels using a closed-shell oysters reduction methods and wood panel manufacturing method
KR102259486B1 (en) * 2020-10-26 2021-06-02 주식회사 한국엔시산업 manufacturing method for eco-friendly furniture exterior material
KR102466309B1 (en) 2022-05-23 2022-11-17 (주)아모스아인스가구 Metal frame coating agent for furniture

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