KR20060000376A - A spray type coating solusion with antitoxic and antibiosis - Google Patents

A spray type coating solusion with antitoxic and antibiosis Download PDF

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KR20060000376A
KR20060000376A KR1020040049211A KR20040049211A KR20060000376A KR 20060000376 A KR20060000376 A KR 20060000376A KR 1020040049211 A KR1020040049211 A KR 1020040049211A KR 20040049211 A KR20040049211 A KR 20040049211A KR 20060000376 A KR20060000376 A KR 20060000376A
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natural
inorganic binder
phytoncide
spray type
coating liquid
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정영호
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정영호
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic

Abstract

본 발명은 신규 건축 내장재로부터 방출되는 포름알데히드 등과 같은 휘발성 유기화합물을 효과적으로 제거함과 동시에 향균성도 우수한 항독항균성 스프레이 타입 코팅액에 관한 것으로서, 보다 구체적으로는 수성 무기 바인더액 내에 입도가 1~1,000㎚인 천연 음이온 방사 물질과 천연 피톤치드(Phitoncide)가 아래와 같은 조성비로 분산되어 있는 것을 특징으로 한다.The present invention relates to an anti-toxic antibacterial spray type coating liquid which effectively removes volatile organic compounds such as formaldehyde and the like from the new building interior materials and has excellent antibacterial properties. More specifically, the present invention relates to a natural inorganic binder liquid having a particle size of 1 to 1,000 nm. The anion emitting material and natural phytoncide are dispersed in the following composition ratios.

- 아 래 -                        -Below-

·수성 무기 바인더액 : 65.0~98.9중량%Aqueous inorganic binder solution: 65.0 ~ 98.9% by weight

·천연 음이온 방사 물질 : 1.0~30.0중량%Natural anion emitting material: 1.0 ~ 30.0 wt%

·천연 피톤치드 : 0.1~5.0중량%Natural phytoncide: 0.1 ~ 5.0 wt%

항균항독성, 스프레이, 코팅액, 건축내장재, 휘발성 유기화합물, 수성 무기 바인더액, 천연음이온, 피톤치드.Antibacterial antitoxicity, spray, coating liquid, building interior materials, volatile organic compounds, aqueous inorganic binder liquid, natural anion, phytoncide.

Description

항독항균성 스프레이 타입 코팅액 {A spray type coating solusion with antitoxic and antibiosis}A spray type coating solusion with antitoxic and antibiosis

본 발명은 항균항독성 스프레이 타입 코팅액에 관한 것으로서, 보다 구체적으로는 건축자재나 가구로부터 방출되는 포름알데히드 등의 휘발성 유기화합물을 효과적으로 분해, 제거함과 동시에 원적외선 방출기능과 항균기능을 구비한 항균항독성 스프레이 타입 코팅액에 관한 것이다.The present invention relates to an antimicrobial anti-toxic spray type coating liquid, and more particularly, to effectively decompose and remove volatile organic compounds such as formaldehyde emitted from building materials and furniture, and at the same time, anti-microbial anti-toxicity with far infrared ray emission function and antibacterial function. It relates to a spray type coating liquid.

최근 신축한 건물의 건축내장재로부터 방출되는 포름알데히드 등의 휘발성 유기화합물로 인해 실내공기가 오염되어 사람에게 두통, 호흡기 질환, 피부 알르레기 등을 일으키는 식크 하우스(Sick House) 증후군이 사회적 문제로 대두되고 있다.Recently, Sick House syndrome, which causes indoor air pollution due to volatile organic compounds such as formaldehyde emitted from building interior materials of new buildings, causes headaches, respiratory diseases, and skin allergies, has become a social problem. .

포름알데히드 등의 휘발성 유기화합물을 분해, 제거하는 종래의 코팅액으로는 나노 분말화된 광촉매(이산화티탄)가 분산되어 있는 코팅액이 널리 사용되고 있다.As a conventional coating liquid for decomposing and removing volatile organic compounds such as formaldehyde, a coating liquid in which nanopowdered photocatalyst (titanium dioxide) is dispersed is widely used.

상기의 광촉매(이산화티탄)는 1960년대에 일본에서 개발되어 1980년대부터 환경 오염물질 처리 촉매로 상업화된 것으로서, 태양광이 조사되면, 특히 에너지 준위가 높은 자외선 영역에서, 활성화되어 대기 중에 존재하는 수분과 자체의 산소에 의해 수퍼 옥사이드 이온(super oxide ion, O2-)과 하이드록실 이온(Hydroxyl ion OH-)을 방출하여, 이들 이온들이 포름알데히드 등과 같은 휘발성 유기화합물을 산화분해 시키는 촉매제이다.The photocatalyst (titanium dioxide) was developed in Japan in the 1960s and commercialized as an environmental pollutant treatment catalyst since the 1980s. When sunlight is irradiated, moisture is activated in the ultraviolet region, especially in the high energy level, in the atmosphere. Superoxide ions (O 2 −) and hydroxyl ions (Hydroxyl ion OH—) are released by their own oxygen, and these ions are catalysts for oxidative decomposition of volatile organic compounds such as formaldehyde.

그러나, 나노 분말화된 이산화티탄(TiO2)이 분산되어 있는 종래의 코팅액은 태양광에 의한 자외선 에너지 준위가 높은 실외에서는 휘발성 유기화합물을 효과적으로 산화분해 시키지만, 자외선의 조사량이 낮은 실내에서는, 특히 야간에는, 휘발성 유기화합물을 효과적으로 산화분해 시킬 수 없는 문제가 있었다.However, the conventional coating liquid in which nano-powdered titanium dioxide (TiO 2 ) is dispersed effectively oxidizes volatile organic compounds outdoors in the high UV energy level due to sunlight, but indoors at low irradiation dose, especially at night There is a problem in that volatile organic compounds cannot be effectively oxidatively decomposed.

한편, 또 다른 종래기술로는 천연식물에서 추출한 피톤치드(Phitoncide)를 코팅액에 첨가하여 피톤치드와 휘발성 유기화합물의 화학반응으로 휘발성 유기화합물을 제거하는 코팅액도 알려져 있으나, 이 경우 화학 당량적인 면에서 과량의 피톤치드가 소모되며 그 효과도 오래 지속되지 않고 반응속도도 낮은 등의 여러 문제가 있었다.Meanwhile, another conventional technique is also known that a coating solution for removing volatile organic compounds by chemical reaction between phytoncide and volatile organic compounds by adding phytoncide extracted from natural plants to the coating solution, but in this case, an excessive amount in terms of chemical equivalents is known. The phytoncide was consumed and its effects did not last long and the reaction rate was low.

한편, 또 다른 종래기술로는 대기중에 수분과 반응하여 광촉매와 같이 수퍼옥사이드 이온과 하이드록실 이온을 발생시키는 톨마린(Tourmaline), 모나자이트(Monazite), 산호석 등의 광물질을 페이스트상의 수성 에멀션 수지에 첨가하여 제조한 페이스트상 코팅액도 사용되고 있으나, 상기의 페이스트상 코팅액은 프라이머 기능을 갖고 있어 코팅된 마감재 위에 벽지 등의 2차 실내 마감재를 처리 해야 하기 때문에 이들 2차 실내 마감재에 의해 코팅액으로 부터의 음이온 발생이 차단되어 휘발성 유기화합물의 분해제거 효과가 저하되는 문제가 있었다.Meanwhile, another conventional technique is to add minerals such as tomaline, monazite, coral stone, etc., which react with water in the air to generate superoxide ions and hydroxyl ions, such as photocatalysts, to a paste-based aqueous emulsion resin. The paste-like coating solution prepared by the present invention is also used, but since the paste-like coating solution has a primer function, the secondary interior finishes, such as wallpaper, must be treated on the coated finish. There was a problem that the blocking is reduced the degradation effect of the volatile organic compounds.

본 발명의 목적은 상기의 종래 문제점들을 해소할 수 있도록 벽지 등의 2차 마감재나 온돌마루 및 가구에 직접 스프레이 코팅이 가능하여 휘발성 유기물질의 분해제거 효과가 매우 우수함과 동시에 원적외선 방출기능과 항균기능도 갖는 향균향독성 스프레이 타입 항독항균성 코팅액을 제공하기 위한 것이다.The purpose of the present invention is to spray the coating directly on the secondary finishing materials such as wallpaper or ondol floor and furniture to solve the above-mentioned problems is very excellent in the decomposition and removal effect of volatile organic materials and at the same time far infrared emission function and antibacterial function It is to provide an antimicrobial antibacterial spray type antimicrobial coating liquid having.

본 발명은 투명성과 접착성이 우수하여 가구 및 온돌마루 등의 2차 마감재에 직접 스프레이 방식으로 코팅 가능한 항독항균성 코팅액을 제공하고자 한다.The present invention is to provide an anti-toxic antimicrobial coating liquid that can be directly coated on the secondary finishing materials such as furniture and ondol flooring by spraying method excellent in transparency and adhesion.

또한, 본 발명은 건축자제등으로 부터 방출되는 포름알데히드 등의 휘발성 유기화합물을 효과적으로 분해제거할 수 있고, 이와 동시에 원적외선 방출기능과 항균기능도 구비하는 항독항균성 스프레이 타입 코팅제를 제공하고자 한다.
In addition, the present invention is to provide an anti-toxic anti-bacterial spray type coating agent that can effectively decompose and remove volatile organic compounds such as formaldehyde emitted from building materials, etc., and at the same time also has a far infrared ray emission function and antibacterial function.

이와 같은 과제들을 달성하기 위한 본 발명의 항독항균성 스프레이 타입 코팅액은, 수성 무기 바인더액 내에 입도가 1~1,000㎚인 천연 음이온 방사 물질과 천연 피톤치드(Phitoncide)가 아래와 같은 조성비로 분산되어 있는 것을 특징으로 한다.The anti-toxic antimicrobial spray type coating liquid of the present invention for achieving the above problems is characterized in that the natural anion emitting material and natural phytoncide having a particle size of 1 to 1,000 nm are dispersed in an aqueous inorganic binder liquid at the following composition ratio. do.

- 아 래 -                        -Below-

·수성 무기 바인더액 : 65.0~98.9중량%Aqueous inorganic binder solution: 65.0 ~ 98.9% by weight

·천연 음이온 방사 물질 : 1.0~30.0중량%Natural anion emitting material: 1.0 ~ 30.0 wt%

·천연 피톤치드 : 0.1~5.0중량%Natural phytoncide: 0.1 ~ 5.0 wt%

이하, 본 발명을 상세하게 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated in detail.

본 발명은 수성 무기 바인더 내에 입자크기가 나노수준인 천연 음이온 방사물질과 천연 피톤치드(Phitoncide)가 분산되어 있다.In the present invention, a natural anion emitting material having a particle size and a natural phytoncide are dispersed in an aqueous inorganic binder.

상기 수성 무기 바인더액의 구체적인 예는 소디움 실리케이트 수용액, 리튬 실리케이트 수용액, 실리카 나노-졸 수용액 등이다.Specific examples of the aqueous inorganic binder liquid include sodium silicate aqueous solution, lithium silicate aqueous solution, silica nano-sol aqueous solution and the like.

수성 무기 바인더액의 함량은 전체 코팅액 중량 대비 85.0~98.9중량%, 더욱 바람직하기로는 87~98.5중량%이다.The content of the aqueous inorganic binder liquid is 85.0 to 99.8% by weight, more preferably 87 to 98.5% by weight based on the total weight of the coating liquid.

한편, 상기의 천연 음이온 방사물질은 톨마린(Tourmaline), 모나자이트(Monazite), 귀양석, 및 산호석 중에서 선택된 1종 또는 2종 이상의 광물로서, 1~1,000㎚의 입도를 갖는다. 보다 바람직한 천연 음이온 방사물질의 직경 입도는 20~580㎚이다.On the other hand, the natural anion radiating material is one or two or more minerals selected from tomaline (Tourmaline), Monazite (Monazite), yangyangseok, and coral stone, and has a particle size of 1 ~ 1,000nm. The diameter of the more preferable natural anion emitting material is 20-580 nm.

상기 천연 음이온 방사물질의 함량은 전체 코팅액 중량 대비 1~30중량%, 더욱 바람직하기로는 1~10중량%이다.The content of the natural anion emitting material is 1 to 30% by weight, more preferably 1 to 10% by weight relative to the total coating liquid weight.

상기 천연 음이온 방사물질은 대기중에 수분과 반응하여 포름알데히드 등과 같은 휘발성 유기화합물을 분해제거시키는 수퍼옥사이드 이온과 하이드록실 이온을 방출한다.The natural anion emitter releases superoxide ions and hydroxyl ions that react with water in the atmosphere to decompose and remove volatile organic compounds such as formaldehyde.

천연 피톤치드(Phitoncide)의 함량은 전체 코팅액 중량 대비 0.1~5중량%, 보다 바람직하기로는 0.5~3중량%이다.The content of natural phytoncide is 0.1 to 5% by weight, more preferably 0.5 to 3% by weight based on the total weight of the coating liquid.

천연 피톤치드는 항균기능을 향상시키고 스트레스 호르몬을 감소시켜 실내공기를 천연의 숲속 공기와 같이 정화하는 역할을 한다.Natural phytoncide improves antibacterial function and decreases stress hormones to purify indoor air like natural forest air.

본 발명은 FT-IR 스펙트로메터로 40℃에서 측정한 원적외선 방사율이 91.7% 수준이고, 음이온 방사량이 9,000~2,500개/cc 수준이고, 공기 유압식 가스테크(Gasteck)방법으로 측정한 3시간 경과 후 휘발성 유기화합물의 분해제거율이 70~99% 수준이고, ASTM G-21 방법으로 4주간 포도상균을 배양하여도 포도상균이 증식되지 않는 수준으로 항균성이 우수하다.According to the present invention, the FT-IR spectrometer measures 91.7% of far-infrared emissivity measured at 40 ° C., anion emission is 9,000 ~ 2,500 / cc level, and volatile after 3 hours measured by air hydraulic gastech method. The decomposition and removal rate of the organic compound is 70 ~ 99%, and the staphylococcus bacteria do not proliferate even after culturing the staphylococci for 4 weeks by the ASTM G-21 method.

이하, 실시예를 통하여 본 발명을 보다 구체적으로 살펴본다. 그러나 본 발명은 하기 실시예에만 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples. However, the present invention is not limited only to the following examples.

실시예 1Example 1

초미립화 분산기에 소디움 실리케이트 수용액(수성 무기 바인더액)94.25g을 투입한 후, 계속해서 여기에 천연 음이온 방사 물질로 톨마린 1.25g과 모나자이트 3.2g과 산호석 0.8g을 동시에 투입, 교반한다. 계속해서 교반속도를 서서히 상승시키면서 상기 천연 음이온 방사물질들의 입도를 체크하여 평균 입도가 524㎚가 되면 교반속도를 다시 100rpm으로 낮춘다.After adding 94.25 g of an aqueous solution of sodium silicate (aqueous inorganic binder solution) to the ultrafine dispersing disperser, thereafter, 1.25 g of tomarin and 3.2 g of monazite and 0.8 g of coral stone were simultaneously added and stirred as a natural anion emitting material. Subsequently, while slowly increasing the stirring speed, the particle size of the natural anion emitting materials is checked, and when the average particle size reaches 524 nm, the stirring speed is lowered to 100 rpm again.

계속해서, 여기에 천연 피톤치드를 0.5g 투입하여 골고루 혼합하여 코팅액을 제조하였다.Subsequently, 0.5 g of natural phytoncide was added thereto and mixed evenly to prepare a coating solution.

제조한 코팅액의 각종 물성을 앞에서 설명한 방법으로 측정한 결과는 표 1과 같다.The physical properties of the prepared coating solution measured by the method described above are shown in Table 1.

실시예 2Example 2

초미립화 분산기에 소디움 실리케이트 수용액(수성 무기 바인더액)93.75g을 투입한 후, 계속해서 여기에 천연 음이온 방사 물질로 톨마린 1.25g을 모나자이트 4.0g을 동시에 투입, 교반한다. 계속해서 교반속도를 서서히 상승시키면서 상기 천연 음이온 방사물질들의 입도를 체크하여 평균 입도가 400㎚가 되면 교반속도를 다시 100rpm으로 낮춘다.93.75 g of an aqueous sodium silicate solution (aqueous inorganic binder solution) was added to the ultrafine dispersing dispersion, and then, 1.25 g of tomarinine and 4.0 g of monazite were added and stirred at the same time as a natural anion emitting material. Subsequently, while slowly increasing the stirring speed, the particle size of the natural anion emitting materials is checked, and when the average particle size reaches 400 nm, the stirring speed is lowered to 100 rpm again.

계속해서, 여기에 천연 피톤치드를 1.0g 투입하여 골고루 혼합하여 코팅액을 제조하였다.Subsequently, 1.0 g of natural phytoncide was added thereto and mixed evenly to prepare a coating solution.

제조한 코팅액의 각종 물성을 앞에서 설명한 방법으로 측정한 결과는 표 1과 같다.The physical properties of the prepared coating solution measured by the method described above are shown in Table 1.

물성 측정 결과Physical property measurement result 구분division 실시예 1Example 1 실시예 2Example 2 원적외선 방사율(%)Far Infrared Emissivity (%) 91.791.7 92.092.0 음이온 방사량(개/cc)Negative ion radiation amount (pcs / cc) 1,5301,530 1,6101,610 코팅후 3시간 경과후 휘발성 유기화합물의 분해제거율(%)Degradation and removal rate of volatile organic compounds after 3 hours after coating (%) 톨루엔toluene 70.070.0 72.072.0 포름알데히드Formaldehyde 71.071.0 70.070.0 유화수소Emulsified hydrogen 71.571.5 72.072.0 암모니아ammonia 99.099.0 99.299.2 아세트 알데히드Acetaldehyde 81.081.0 80.580.5

본 발명은 온돌마루 등의 2차 마감재에 직접 스프레이 방식으로 코팅 가능하며, 건축자제로부터 방출되는 포름알데히드 등의 휘발성 유기화합물을 효과적으로 분해제거함과 동시에 원적외선을 방출하여 건강에 좋고 항균기능도 갖는다.The present invention can be directly coated on the secondary finishing materials such as ondol flooring by spraying, effectively decomposes and removes volatile organic compounds such as formaldehyde emitted from building materials, and emits far-infrared rays for health and antibacterial function.

이에 따라, 본 발명은 가구 및 온돌마루와 같은 건축자재용 코팅제, 차량 내부자재용 코팅제, 의류 및 신발용 탈취제 등으로 유용하다.
Accordingly, the present invention is useful as a coating material for building materials such as furniture and ondol flooring, a coating material for vehicle interior materials, and a deodorant for clothes and shoes.

Claims (3)

수성 무기 바인더액 내에 입도가 1~1,000㎚인 천연 음이온 방사 물질과 천연 피톤치드(Phitoncide)가 아래와 같은 조성비로 분산되어 있는 것을 특징으로 하는 항독항균성 스프레이 타입 코팅액.An anti-toxic antimicrobial spray type coating liquid comprising a natural anion emitting substance having a particle size of 1 to 1,000 nm and a natural phytoncide dispersed in an aqueous inorganic binder liquid at a composition ratio as follows. - 아 래 -                        -Below- ·수성 무기 바인더액 : 65.0~98.9중량%Aqueous inorganic binder solution: 65.0 ~ 98.9% by weight ·천연 음이온 방사 물질 : 1.0~30.0중량%Natural anion emitting material: 1.0 ~ 30.0 wt% ·천연 피톤치드 : 0.1~5.0중량%Natural phytoncide: 0.1 ~ 5.0 wt% 1항에 있어서, 수성 무기 바인더액이 소디움 실리케이트 수용액, 리튬 실리케이트 수용액 및 실리카 나노-졸 수용액 중에서 선택된 1종인 것을 특징으로 하는 항독항균성 스프레이 타입 코팅액.The anti-toxic antimicrobial spray type coating liquid according to claim 1, wherein the aqueous inorganic binder liquid is one selected from an aqueous sodium silicate solution, an aqueous lithium silicate solution, and an aqueous silica nano-sol solution. 1항에 있어서, 천연 음이온 방사물질이 톨마린(Tourmaline), 모나자이트(Monazite), 귀양석 및 산호석 중에서 선택된 1종 또는 2종 이상의 광물질인 것을 특징으로 하는 항독항균성 스프레이 타입 코팅액.The anti-toxic antimicrobial spray type coating liquid according to claim 1, wherein the natural anion emitter is one or two or more minerals selected from tomaline, monazite, jewels and corals.
KR1020040049211A 2004-06-29 2004-06-29 A spray type coating solusion with antitoxic and antibiosis KR20060000376A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050043826A (en) * 2005-04-06 2005-05-11 이해왕 Tourmaline water natural binder and coating fluid
KR20060072179A (en) * 2004-12-22 2006-06-28 안승갑 Composition of construction material for radiating an ultrared line and ion, their process and their material
KR100787875B1 (en) * 2006-10-12 2007-12-27 (주)나노테크 Natural friendly paints for wallpaper and manufacturing wallpaper by using it
KR100977351B1 (en) * 2009-09-29 2010-08-20 우인창 Composition for nail-care and nail-caring method
KR101251814B1 (en) * 2011-07-28 2013-04-12 다이텍연구원 Process Of Producing Organic―Inorganic Hybrid Finishing Agent For Fabrics Having High Durability
KR101698740B1 (en) * 2016-06-30 2017-01-24 이근일 Liquid Composition Comprising Silicate Salt and Phytoncide, Manufacturing Method Thereof
WO2023277439A1 (en) * 2021-06-30 2023-01-05 명전바이오 주식회사 Environment-friendly disinfectant composition, for preventing infectious disease, having excellent antimicrobial and deodorizing performance by containing liquid sodium silicate, and environment-friendly disinfectant, for preventing infectious disease, comprising same

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060072179A (en) * 2004-12-22 2006-06-28 안승갑 Composition of construction material for radiating an ultrared line and ion, their process and their material
KR20050043826A (en) * 2005-04-06 2005-05-11 이해왕 Tourmaline water natural binder and coating fluid
KR100787875B1 (en) * 2006-10-12 2007-12-27 (주)나노테크 Natural friendly paints for wallpaper and manufacturing wallpaper by using it
KR100977351B1 (en) * 2009-09-29 2010-08-20 우인창 Composition for nail-care and nail-caring method
KR101251814B1 (en) * 2011-07-28 2013-04-12 다이텍연구원 Process Of Producing Organic―Inorganic Hybrid Finishing Agent For Fabrics Having High Durability
KR101698740B1 (en) * 2016-06-30 2017-01-24 이근일 Liquid Composition Comprising Silicate Salt and Phytoncide, Manufacturing Method Thereof
WO2023277439A1 (en) * 2021-06-30 2023-01-05 명전바이오 주식회사 Environment-friendly disinfectant composition, for preventing infectious disease, having excellent antimicrobial and deodorizing performance by containing liquid sodium silicate, and environment-friendly disinfectant, for preventing infectious disease, comprising same

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