KR101007451B1 - 폴리카보네이트 성형 조성물 및 표면 미감이 개선된 제품 - Google Patents
폴리카보네이트 성형 조성물 및 표면 미감이 개선된 제품 Download PDFInfo
- Publication number
- KR101007451B1 KR101007451B1 KR1020057012434A KR20057012434A KR101007451B1 KR 101007451 B1 KR101007451 B1 KR 101007451B1 KR 1020057012434 A KR1020057012434 A KR 1020057012434A KR 20057012434 A KR20057012434 A KR 20057012434A KR 101007451 B1 KR101007451 B1 KR 101007451B1
- Authority
- KR
- South Korea
- Prior art keywords
- bis
- hydroxyphenyl
- hydroxy
- propane
- molding composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000203 mixture Substances 0.000 title claims abstract description 99
- 238000000465 moulding Methods 0.000 title claims abstract description 68
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 67
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 67
- 239000003607 modifier Substances 0.000 claims abstract description 50
- 229920000642 polymer Polymers 0.000 claims abstract description 34
- 230000007547 defect Effects 0.000 claims abstract description 32
- 229920001400 block copolymer Polymers 0.000 claims abstract description 31
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 18
- 229920001515 polyalkylene glycol Polymers 0.000 claims abstract description 15
- 150000002334 glycols Chemical class 0.000 claims abstract description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 46
- -1 Hydroxy-3-methylphenyl Chemical group 0.000 claims description 43
- 238000000034 method Methods 0.000 claims description 30
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 19
- 239000001257 hydrogen Substances 0.000 claims description 19
- 229930185605 Bisphenol Natural products 0.000 claims description 15
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 15
- 125000005647 linker group Chemical group 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 229920001223 polyethylene glycol Polymers 0.000 claims description 13
- LVLNPXCISNPHLE-UHFFFAOYSA-N 2-[(4-hydroxyphenyl)methyl]phenol Chemical compound C1=CC(O)=CC=C1CC1=CC=CC=C1O LVLNPXCISNPHLE-UHFFFAOYSA-N 0.000 claims description 12
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 12
- 150000002431 hydrogen Chemical class 0.000 claims description 12
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000002202 Polyethylene glycol Substances 0.000 claims description 10
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 9
- 125000001118 alkylidene group Chemical group 0.000 claims description 8
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 125000002947 alkylene group Chemical group 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- 150000003457 sulfones Chemical class 0.000 claims description 7
- 150000005207 1,3-dihydroxybenzenes Chemical class 0.000 claims description 6
- MQCPOLNSJCWPGT-UHFFFAOYSA-N 2,2'-Bisphenol F Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1O MQCPOLNSJCWPGT-UHFFFAOYSA-N 0.000 claims description 6
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 6
- YMTYZTXUZLQUSF-UHFFFAOYSA-N 3,3'-Dimethylbisphenol A Chemical compound C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=CC=2)=C1 YMTYZTXUZLQUSF-UHFFFAOYSA-N 0.000 claims description 6
- TUJHKTMBIVIOOV-UHFFFAOYSA-N 3-(4-hydroxyphenyl)-1,1,3-trimethyl-2h-inden-5-ol Chemical class C12=CC(O)=CC=C2C(C)(C)CC1(C)C1=CC=C(O)C=C1 TUJHKTMBIVIOOV-UHFFFAOYSA-N 0.000 claims description 6
- CGFCKPWPXHKFPU-UHFFFAOYSA-N 3-chloro-4-[1-(2-chloro-4-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=C(O)C=C(Cl)C=1C(C)C1=CC=C(O)C=C1Cl CGFCKPWPXHKFPU-UHFFFAOYSA-N 0.000 claims description 6
- MLDIQALUMKMHCC-UHFFFAOYSA-N 4,4-Bis(4-hydroxyphenyl)heptane Chemical compound C=1C=C(O)C=CC=1C(CCC)(CCC)C1=CC=C(O)C=C1 MLDIQALUMKMHCC-UHFFFAOYSA-N 0.000 claims description 6
- ACEMPBSQAVZNEJ-UHFFFAOYSA-N 4-[(4-hydroxy-3-methoxy-2,6-dimethylphenyl)methyl]-2-methoxy-3,5-dimethylphenol Chemical compound C1=C(O)C(OC)=C(C)C(CC=2C(=C(OC)C(O)=CC=2C)C)=C1C ACEMPBSQAVZNEJ-UHFFFAOYSA-N 0.000 claims description 6
- DTOMAXGIWFLDMR-UHFFFAOYSA-N 4-[(4-hydroxy-3-nitrophenyl)methyl]-2-nitrophenol Chemical compound C1=C([N+]([O-])=O)C(O)=CC=C1CC1=CC=C(O)C([N+]([O-])=O)=C1 DTOMAXGIWFLDMR-UHFFFAOYSA-N 0.000 claims description 6
- UMPGNGRIGSEMTC-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol Chemical compound C1C(C)CC(C)(C)CC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UMPGNGRIGSEMTC-UHFFFAOYSA-N 0.000 claims description 6
- IJWIRZQYWANBMP-UHFFFAOYSA-N 4-[2-(4-hydroxy-3-propan-2-ylphenyl)propan-2-yl]-2-propan-2-ylphenol Chemical compound C1=C(O)C(C(C)C)=CC(C(C)(C)C=2C=C(C(O)=CC=2)C(C)C)=C1 IJWIRZQYWANBMP-UHFFFAOYSA-N 0.000 claims description 6
- DUKMWXLEZOCRSO-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-1-phenylpropan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)CC1=CC=CC=C1 DUKMWXLEZOCRSO-UHFFFAOYSA-N 0.000 claims description 6
- GNVVDBSIPRMGSG-UHFFFAOYSA-N 4-[3-(4-hydroxyphenyl)-1-methyl-3-propan-2-ylcyclohexyl]phenol Chemical compound C1C(C(C)C)(C=2C=CC(O)=CC=2)CCCC1(C)C1=CC=C(O)C=C1 GNVVDBSIPRMGSG-UHFFFAOYSA-N 0.000 claims description 6
- VTXAKTSKRDNBMV-UHFFFAOYSA-N C=1C(Cl)(Cl)C(O)(O)C(Cl)(Cl)CC=1C(C)(C)C1=CC(Cl)(Cl)C(O)(O)C(Cl)(Cl)C1 Chemical compound C=1C(Cl)(Cl)C(O)(O)C(Cl)(Cl)CC=1C(C)(C)C1=CC(Cl)(Cl)C(O)(O)C(Cl)(Cl)C1 VTXAKTSKRDNBMV-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 150000002430 hydrocarbons Chemical group 0.000 claims description 6
- MNZMMCVIXORAQL-UHFFFAOYSA-N naphthalene-2,6-diol Chemical compound C1=C(O)C=CC2=CC(O)=CC=C21 MNZMMCVIXORAQL-UHFFFAOYSA-N 0.000 claims description 6
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 claims description 5
- VFGGYIRERLPSDV-UHFFFAOYSA-N 1-(4-hydroxyphenyl)-1,3,3-trimethyl-2h-inden-5-ol Chemical class C12=CC=C(O)C=C2C(C)(C)CC1(C)C1=CC=C(O)C=C1 VFGGYIRERLPSDV-UHFFFAOYSA-N 0.000 claims description 5
- XQOAPEATHLRJMI-UHFFFAOYSA-N 2-ethyl-4-[2-(3-ethyl-4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C1=C(O)C(CC)=CC(C(C)(C)C=2C=C(CC)C(O)=CC=2)=C1 XQOAPEATHLRJMI-UHFFFAOYSA-N 0.000 claims description 5
- SVOBELCYOCEECO-UHFFFAOYSA-N 4-[1-(4-hydroxy-3-methylphenyl)cyclohexyl]-2-methylphenol Chemical compound C1=C(O)C(C)=CC(C2(CCCCC2)C=2C=C(C)C(O)=CC=2)=C1 SVOBELCYOCEECO-UHFFFAOYSA-N 0.000 claims description 5
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 claims description 5
- BKTRENAPTCBBFA-UHFFFAOYSA-N 4-[2-(4-hydroxy-3-phenylphenyl)propan-2-yl]-2-phenylphenol Chemical compound C=1C=C(O)C(C=2C=CC=CC=2)=CC=1C(C)(C)C(C=1)=CC=C(O)C=1C1=CC=CC=C1 BKTRENAPTCBBFA-UHFFFAOYSA-N 0.000 claims description 5
- YZYGDZRBLOLVDY-UHFFFAOYSA-N 4-[cyclohexyl-(4-hydroxyphenyl)methyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)C1CCCCC1 YZYGDZRBLOLVDY-UHFFFAOYSA-N 0.000 claims description 5
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052794 bromium Inorganic materials 0.000 claims description 5
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 239000011574 phosphorus Substances 0.000 claims description 5
- 229920001451 polypropylene glycol Polymers 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- MWLPIAFTYWBDLO-UHFFFAOYSA-N 4-[2-[2-(4-hydroxyphenyl)propan-2-yl]-6-methylcyclohexyl]phenol Chemical compound CC1CCCC(C(C)(C)C=2C=CC(O)=CC=2)C1C1=CC=C(O)C=C1 MWLPIAFTYWBDLO-UHFFFAOYSA-N 0.000 claims description 4
- 125000002723 alicyclic group Chemical group 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims 3
- YCSVMCYCFDEOMM-UHFFFAOYSA-N 4-(cyclohexylmethyl)phenol Chemical compound C1=CC(O)=CC=C1CC1CCCCC1 YCSVMCYCFDEOMM-UHFFFAOYSA-N 0.000 claims 1
- FNFYXIMJKWENNK-UHFFFAOYSA-N 4-[(2,4-dihydroxyphenyl)methyl]benzene-1,3-diol Chemical compound OC1=CC(O)=CC=C1CC1=CC=C(O)C=C1O FNFYXIMJKWENNK-UHFFFAOYSA-N 0.000 claims 1
- BOHACIVBOZRDLK-UHFFFAOYSA-N 4-[1-(2,4-dihydroxyphenyl)ethyl]benzene-1,3-diol Chemical compound C=1C=C(O)C=C(O)C=1C(C)C1=CC=C(O)C=C1O BOHACIVBOZRDLK-UHFFFAOYSA-N 0.000 claims 1
- FLDQVTCCQPVZCV-UHFFFAOYSA-N C1(=CC=CC=C1)C=1C(=C(C=CC1O)C(C)(C)C1=C(C(=C(C=C1)O)C1=CC=CC=C1)O)O Chemical compound C1(=CC=CC=C1)C=1C(=C(C=CC1O)C(C)(C)C1=C(C(=C(C=C1)O)C1=CC=CC=C1)O)O FLDQVTCCQPVZCV-UHFFFAOYSA-N 0.000 claims 1
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- 239000000523 sample Substances 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 8
- 230000008569 process Effects 0.000 description 7
- 229960001755 resorcinol Drugs 0.000 description 7
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 125000001624 naphthyl group Chemical group 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- ZJYVOSGUICQZHC-UHFFFAOYSA-N 2-butyl-2-ethyl-1-(2,4,6-tritert-butylphenyl)propane-1,3-diol;phosphorous acid Chemical compound OP(O)O.CCCCC(CC)(CO)C(O)C1=C(C(C)(C)C)C=C(C(C)(C)C)C=C1C(C)(C)C ZJYVOSGUICQZHC-UHFFFAOYSA-N 0.000 description 2
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 125000000449 nitro group Chemical class [O-][N+](*)=O 0.000 description 2
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- 238000005809 transesterification reaction Methods 0.000 description 1
- 125000002469 tricosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
- QEDNBHNWMHJNAB-UHFFFAOYSA-N tris(8-methylnonyl) phosphite Chemical compound CC(C)CCCCCCCOP(OCCCCCCCC(C)C)OCCCCCCCC(C)C QEDNBHNWMHJNAB-UHFFFAOYSA-N 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/331,209 | 2002-12-30 | ||
| US10/331,209 US6825266B2 (en) | 2002-12-30 | 2002-12-30 | Polycarbonate molding compositions and articles with improved surface aesthetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20050092727A KR20050092727A (ko) | 2005-09-22 |
| KR101007451B1 true KR101007451B1 (ko) | 2011-01-12 |
Family
ID=32654678
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020057012434A Expired - Lifetime KR101007451B1 (ko) | 2002-12-30 | 2003-11-25 | 폴리카보네이트 성형 조성물 및 표면 미감이 개선된 제품 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6825266B2 (enExample) |
| EP (1) | EP1581594B1 (enExample) |
| JP (1) | JP2006512447A (enExample) |
| KR (1) | KR101007451B1 (enExample) |
| CN (1) | CN100554332C (enExample) |
| AU (1) | AU2003291194A1 (enExample) |
| WO (1) | WO2004061004A1 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016089028A1 (ko) * | 2014-12-04 | 2016-06-09 | 주식회사 엘지화학 | 폴리카보네이트 수지 조성물 |
| US9580597B2 (en) | 2014-12-04 | 2017-02-28 | Lg Chem, Ltd. | Polycarbonate composition and article comprising the same |
| US9732186B2 (en) | 2014-09-05 | 2017-08-15 | Lg Chem, Ltd. | Copolycarbonate and composition comprising the same |
| US9969841B2 (en) | 2014-12-04 | 2018-05-15 | Lg Chem, Ltd. | Copolycarbonate and composition comprising the same |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4541029B2 (ja) * | 2004-05-20 | 2010-09-08 | 出光興産株式会社 | 遮光性高反射積層シート及びそれを用いてなる熱成形体及び筐体 |
| JP5378736B2 (ja) * | 2008-09-22 | 2013-12-25 | 帝人株式会社 | 難燃性芳香族ポリカーボネート樹脂組成物 |
| DE102009039121A1 (de) * | 2009-08-28 | 2011-03-03 | Bayer Materialscience Ag | Erzeugnisse mit verbesserter Flammwidrigkeit |
| US9878476B2 (en) | 2011-10-28 | 2018-01-30 | Ticona Llc | System and process for molding polymeric articles while reducing gate blush |
| US8993671B2 (en) * | 2011-11-24 | 2015-03-31 | Sabic Global Technolgies B.V. | Poly(aliphatic ester)-polycarbonate copolymer/polylactic acid blend |
| KR101476525B1 (ko) * | 2012-02-03 | 2014-12-24 | 주식회사 엘지화학 | 신규한 폴리오르가노실록산, 이를 포함하는 폴리카보네이트 수지 조성물 및 개질 폴리카보네이트 수지 |
| DE112013000211B4 (de) * | 2012-02-03 | 2018-06-21 | Lg Chem. Ltd. | Polyorganosiloxan, Verfahren zum Herstellen von Polyorganosiloxan und mit dem Polyorganosiloxan modifiziertes Polycarbonatharz |
| US9127155B2 (en) | 2012-04-11 | 2015-09-08 | Sabic Global Technologies B.V. | Phosphorus free flame retardant composition |
| TWI683867B (zh) * | 2014-12-02 | 2020-02-01 | 日商帝人股份有限公司 | 聚碳酸酯樹脂組成物及其所成的成形品 |
| KR20170122713A (ko) * | 2015-03-26 | 2017-11-06 | 스미카 폴리카르보네이트 가부시키가이샤 | 폴리카르보네이트 수지 조성물 및 광학용 성형품 |
| KR101946535B1 (ko) | 2015-07-24 | 2019-02-11 | 주식회사 엘지화학 | 신규한 폴리오르가노실록산, 및 이를 사용하여 제조되는 코폴리카보네이트 |
| KR102543776B1 (ko) * | 2015-08-27 | 2023-06-14 | 이데미쓰 고산 가부시키가이샤 | 폴리카보네이트계 수지 조성물 및 그 성형품 |
| CN113956457A (zh) * | 2021-11-16 | 2022-01-21 | 丹阳市精通眼镜技术创新服务中心有限公司 | 一种pc基防蓝光树脂及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5100960A (en) * | 1989-03-15 | 1992-03-31 | Bayer Aktiengesellschaft | Thermoplastic molding compositions of a polysiloxane block copolycarbonate and a polycarbonate based on certain dihydroxydiphenylcycloalkanes |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4123436A (en) | 1976-12-16 | 1978-10-31 | General Electric Company | Polycarbonate composition plasticized with esters |
| DE3629546A1 (de) | 1986-08-30 | 1988-03-03 | Bayer Ag | Schlagzaehe, flammwidrige formmassen |
| DE3704488A1 (de) * | 1987-02-13 | 1988-08-25 | Bayer Ag | Antistatische, thermoplastische formmassen auf basis von polycarbonaten und vinylaromatpolymerisaten |
| DE4036415A1 (de) | 1990-11-15 | 1992-05-21 | Bayer Ag | Polycarbonat-siloxan-copolymere mit perfluoralkylphenoxy-endgruppen |
| DE69224937T2 (de) | 1991-07-01 | 1998-10-22 | Gen Electric | Polycarbonat-Polysiloxan-Blockcopolymere |
| US5530083A (en) | 1994-07-21 | 1996-06-25 | General Electric Company | Silicone-polycarbonate block copolymers and polycarbonate blends having reduced haze, and method for making |
| US6868371B1 (en) | 1999-05-03 | 2005-03-15 | General Electric Company | System and method to quantify appearance defects in molded plastic parts |
| US6143859A (en) | 1999-08-09 | 2000-11-07 | General Electric Company | Copolycarbonate preparation by solid state polymerization |
-
2002
- 2002-12-30 US US10/331,209 patent/US6825266B2/en not_active Expired - Lifetime
-
2003
- 2003-11-25 WO PCT/US2003/037851 patent/WO2004061004A1/en not_active Ceased
- 2003-11-25 KR KR1020057012434A patent/KR101007451B1/ko not_active Expired - Lifetime
- 2003-11-25 CN CNB2003801094294A patent/CN100554332C/zh not_active Expired - Fee Related
- 2003-11-25 AU AU2003291194A patent/AU2003291194A1/en not_active Abandoned
- 2003-11-25 JP JP2004565117A patent/JP2006512447A/ja active Pending
- 2003-11-25 EP EP03783789A patent/EP1581594B1/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5100960A (en) * | 1989-03-15 | 1992-03-31 | Bayer Aktiengesellschaft | Thermoplastic molding compositions of a polysiloxane block copolycarbonate and a polycarbonate based on certain dihydroxydiphenylcycloalkanes |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9732186B2 (en) | 2014-09-05 | 2017-08-15 | Lg Chem, Ltd. | Copolycarbonate and composition comprising the same |
| US9745418B2 (en) | 2014-09-05 | 2017-08-29 | Lg Chem, Ltd. | Copolycarbonate and composition comprising the same |
| US9840585B2 (en) | 2014-12-04 | 2017-12-12 | Lg Chem, Ltd. | Polycarbonate resin composition |
| US9868818B2 (en) | 2014-12-04 | 2018-01-16 | Lg Chem, Ltd. | Copolycarbonate and composition containing the same |
| US9745417B2 (en) | 2014-12-04 | 2017-08-29 | Lg Chem, Ltd. | Copolycarbonate and composition comprising the same |
| US9745466B2 (en) | 2014-12-04 | 2017-08-29 | Lg Chem, Ltd. | Copolycarbonate and composition containing the same |
| US9580597B2 (en) | 2014-12-04 | 2017-02-28 | Lg Chem, Ltd. | Polycarbonate composition and article comprising the same |
| US9751979B2 (en) | 2014-12-04 | 2017-09-05 | Lg Chem, Ltd. | Copolycarbonate and composition containing the same |
| US9777112B2 (en) | 2014-12-04 | 2017-10-03 | Lg Chem, Ltd. | Copolycarbonate resin composition |
| US9809677B2 (en) | 2014-12-04 | 2017-11-07 | Lg Chem, Ltd. | Polycarbonate composition and article comprising the same |
| WO2016089028A1 (ko) * | 2014-12-04 | 2016-06-09 | 주식회사 엘지화학 | 폴리카보네이트 수지 조성물 |
| US9718958B2 (en) | 2014-12-04 | 2017-08-01 | Lg Chem, Ltd. | Copolycarbonate and composition containing the same |
| US9902853B2 (en) | 2014-12-04 | 2018-02-27 | Lg Chem, Ltd. | Copolycarbonate and composition comprising the same |
| US9969841B2 (en) | 2014-12-04 | 2018-05-15 | Lg Chem, Ltd. | Copolycarbonate and composition comprising the same |
| US10011716B2 (en) | 2014-12-04 | 2018-07-03 | Lg Chem, Ltd. | Copolycarbonate composition and article containing the same |
| US10081730B2 (en) | 2014-12-04 | 2018-09-25 | Lg Chem, Ltd. | Polycarbonate-based resin composition and molded article thereof |
| US10174194B2 (en) | 2014-12-04 | 2019-01-08 | Lg Chem, Ltd. | Copolycarbonate and composition comprising the same |
| US10196516B2 (en) | 2014-12-04 | 2019-02-05 | Lg Chem, Ltd. | Copolycarbonate resin composition and article including the same |
| US10240038B2 (en) | 2014-12-04 | 2019-03-26 | Lg Chem, Ltd. | Flame resistant polycarbate based resin composition and molded articles thereof |
| US10240037B2 (en) | 2014-12-04 | 2019-03-26 | Lg Chem, Ltd. | Polycarbonate-based resin composition and molded article thereof |
| US10294365B2 (en) | 2014-12-04 | 2019-05-21 | Lg Chem, Ltd. | Polycarbonate-based resin composition and molded article thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| US6825266B2 (en) | 2004-11-30 |
| US20040127635A1 (en) | 2004-07-01 |
| JP2006512447A (ja) | 2006-04-13 |
| EP1581594A1 (en) | 2005-10-05 |
| CN1745144A (zh) | 2006-03-08 |
| KR20050092727A (ko) | 2005-09-22 |
| WO2004061004A1 (en) | 2004-07-22 |
| EP1581594B1 (en) | 2013-03-27 |
| AU2003291194A1 (en) | 2004-07-29 |
| CN100554332C (zh) | 2009-10-28 |
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