KR100767234B1 - 불포화 말단을 함유한 분지 폴리아미드류 - Google Patents
불포화 말단을 함유한 분지 폴리아미드류 Download PDFInfo
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- KR100767234B1 KR100767234B1 KR1020050034692A KR20050034692A KR100767234B1 KR 100767234 B1 KR100767234 B1 KR 100767234B1 KR 1020050034692 A KR1020050034692 A KR 1020050034692A KR 20050034692 A KR20050034692 A KR 20050034692A KR 100767234 B1 KR100767234 B1 KR 100767234B1
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- acid
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- lactams
- branched polyamides
- diamine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/04—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/36—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino acids, polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J177/00—Adhesives based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Adhesives based on derivatives of such polymers
- C09J177/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/21—Paper; Textile fabrics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/13—Morphological aspects
- C08G2261/132—Morphological aspects branched or hyperbranched
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Polyamides (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Organic Insulating Materials (AREA)
- Paints Or Removers (AREA)
Abstract
Description
MFI | 겔의 수준 (단위: %, 가교를 의미함) | 겔의 수준 (단위: %, 가교를 의미함) | DMA | |||||
g/10분 단위 | 2 % 과산화물 사용 | 4 % 벤조페논 사용 | 160 ℃ 에서의 G' (MPa) | |||||
130 ℃ 에서 2.16 ㎏ | Brabender 믹서기로 처리 | UV 용융 (D 램프, 350-450 nm, 1100 mJ/㎠) 후 | β-선하에서의 처리 후 | |||||
실시예 | 출발물질의 중량을 기준으로한 조성물의 중량% | Luperox 230, 155 ℃ | Luperox 231, 140 ℃ | 26 초 | 13 초 | 50 kGy | 100 kGy | |
1 | 6/11/12 = 35/30/35 + 0.2% DETA + 1.6% 크로톤산 + 1.14% HMDA | 19 | 78.8 % | 80.4 % | 83.90 % | 32.80 % | 0.18 | 0.27 |
2 | 6/6.6/11/12 = 30/15/10/45 + 1.37% 펜타에리트리톨 + 3.46% 크로톤산 | 21.4 | 79.8 % | 78.2 % | 86.40 % | 37.20 % | 0.018 | 0.09 |
3 | 6/11/12 = 35/30/35 + 0.2% DETA + 3.62% 운데실렌산 + 1.14% HMDA | 11 | - | - | - | 67.6 % | 0.64 | 1.12 |
4 | 6/6.6/12 = 40/25/35 + 0.2% DETA + 3.62% 운데실렌산 + 1.14% HMDA | 8.8 | - | - | 46.3 % | 0.75 | 1.05 | |
Luperox 230 은 n-부틸 4,4-디(tert-부틸퍼록시)발러레이트, CAS No. 995-33-5 를 나타낸다. Luperox 231 은 1,1-디(tert-부틸퍼록시)-3,3,5-트리메틸시클로헥산, CAS No. 6731-36-8 을 나타낸다. DMA 는 동적 기계적 분석 (dynamic mechanical analysis) 를 나타낸다. |
Claims (11)
- 하기로 이루어진, 불포화 말단을 함유한 분지 (branched) 폴리아미드류:ㆍ 아민, 산 및 히드록실 형태로 이루어진 군에서 선택되는 2 개 이상의 관능기를 가지는 다관능성 단량체 (A) 로부터 유래하는 하나 이상의 단위로서, 상기 다관능성 단량체 (A) 가 디에틸렌트리아민, 멜리트산, 2,2-디메틸올프로피온산 및 펜타에리트리톨로 이루어진 군에서 선택되는 단위, 및ㆍ 하나 이상의 불포화 일산 (monoacid) 의 존재 하에서, 축합으로부터 야기되는 적어도 하기의 서열들,▷ 2 개 이상의 상이한 락탐,▷ 또는, 하나 이상의 락탐, 하나 이상의 디카르복실산 및 하나 이상의 디아민,▷ 또는, 락탐 및 α,ω-아미노카르복실산,▷ 또는 디아민 및 이산 (diacid) 중 하나,로서, (A) 와 상기 단량체들의 조합에 관하여 (A) 의 비율이 9 중량% 미만인 분지 폴리아미드류.
- 삭제
- 제 1 항에 있어서, 상기 코폴리아미드 서열들이 적어도 카프로락탐 및 라우릴락탐을 함유하는 폴리아미드류.
- 제 1 항에 있어서, 상기 코폴리아미드 서열들이 적어도 카프로락탐, 헥사메틸렌디아민 및 아디프산을 함유하는 폴리아미드류.
- 제 1 항에 있어서, 상기 불포화 일산이 크로톤산 또는 운데실렌산인 폴리아미드류.
- 사슬-제한제로서의 불포화 일산의 존재하에서, 하기의 축합이 수행되는, 제 1 항에 따른 폴리아미드류의 제조 방법:▷ 2 개 이상의 상이한 락탐,▷ 또는, 하나 이상의 락탐, 하나 이상의 디카르복실산 및 하나 이상의 디아민,▷ 또는, 락탐 및 α,ω-아미노카르복실산,▷ 또는, 디아민 및 이산 중 하나(이때 2 개 이상의 관능기를 가지는 다관능성 단량체 (A) 가 상기 폴리아미드 서열들의 단량체들의 축합 반응 동안 존재하거나 또는 이어서 첨가되는 것이 가능하고, 촉매를 첨가하는 것이 가능하다).
- 제 1 항에 따른 불포화 말단을 함유한 분지 폴리아미드류를 함유한 열가융성 (thermofusible) 접착제.
- 제 1 항에 따른 불포화 말단을 함유한 분지 폴리아미드류를 열가융성 접착제로서 사용하는 방법.
- 전기 케이블을 피복하기 위하여 제 1 항에 따른 불포화 말단을 함유한 분지 폴리아미드류를 사용하는 방법.
- 삭제
- 삭제
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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FR04.04382 | 2004-04-26 | ||
FR0404382 | 2004-04-26 |
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KR20060047481A KR20060047481A (ko) | 2006-05-18 |
KR100767234B1 true KR100767234B1 (ko) | 2007-10-17 |
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KR1020050034692A KR100767234B1 (ko) | 2004-04-26 | 2005-04-26 | 불포화 말단을 함유한 분지 폴리아미드류 |
Country Status (6)
Country | Link |
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US (1) | US8642716B2 (ko) |
EP (1) | EP1591468B1 (ko) |
JP (2) | JP4248514B2 (ko) |
KR (1) | KR100767234B1 (ko) |
CN (1) | CN100584874C (ko) |
CA (1) | CA2503662C (ko) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1591468B1 (fr) * | 2004-04-26 | 2016-10-19 | Arkema France | Reactifs thermo-adhesifs a base des copolyamides ou copolyamide-bloc-polyethers reticulables |
JP2013544314A (ja) * | 2010-12-03 | 2013-12-12 | ビーエーエスエフ ソシエタス・ヨーロピア | 架橋ポリアミド |
FR2974095B1 (fr) * | 2011-04-13 | 2014-08-22 | Rhodia Operations | Polyamide stabilise |
CN103635510B (zh) * | 2011-07-01 | 2015-10-21 | 帝斯曼知识产权资产管理有限公司 | 具有不同嵌段的支链聚酰胺 |
CN104558588B (zh) * | 2013-10-22 | 2017-09-29 | 中国石油化工股份有限公司 | 一种尼龙聚合物及其制备方法 |
FR3026108B1 (fr) * | 2014-09-23 | 2018-07-13 | Arkema France | Composition pour adhesif thermoplastique, adhesif thermoplastique, leurs procedes de fabrication et leurs utilisations |
FR3073774B1 (fr) | 2017-11-22 | 2019-11-15 | Hexcel Reinforcements | Materiau de renfort comprenant une couche poreuse en un polymere thermoplastique partiellement reticule et procedes associes |
CN113248971B (zh) * | 2021-04-24 | 2022-06-10 | 深圳市撒比斯科技有限公司 | 一种高耐水性的光敏电子墨水 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0147267B2 (fr) | 1983-11-23 | 1994-01-26 | Elf Atochem S.A. | Production de macromères polyamides portant au moins une insaturation à chacune des deux extrémites de la séquence polyamide |
US5378798A (en) * | 1992-07-10 | 1995-01-03 | Shell Oil Company | Composition and process for coating metallic substrates |
US6391982B1 (en) | 1999-06-29 | 2002-05-21 | Degussa Ag | Highly branched polyamide graft copolymers |
KR20020062953A (ko) * | 2000-10-06 | 2002-07-31 | 아토피나 | 그라프트된 폴리아미드-블록 및 가요성 폴리올레핀공중합체의 혼합물 |
Family Cites Families (14)
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US3114711A (en) * | 1961-03-31 | 1963-12-17 | California Research Corp | Lubricant composition |
US3470079A (en) * | 1966-05-18 | 1969-09-30 | Ppg Industries Inc | Highly radiation-sensitive telomerized polyamides |
BE792796A (fr) * | 1971-12-16 | 1973-03-30 | Du Pont | Interpolymeres de polyamide condenses a l'etat fondu solubles ala temperature ambiante |
DE2504514A1 (de) * | 1974-02-12 | 1975-08-14 | Ciba Geigy Ag | Fluorierte carbonsaeureamide und ihre polymerisationsprodukte |
US4377536A (en) * | 1980-01-25 | 1983-03-22 | Plastics Engineering Company | Polyamide derivatives having unsaturated terminal amic acid groups |
JPS5734557A (en) * | 1980-08-07 | 1982-02-24 | Toray Ind Inc | Preventing method for sticking of surface of water-developable photosensitive polyamide resin layer |
FR2554451B1 (fr) * | 1983-11-04 | 1986-03-28 | Atochem | Nouveaux macromeres polyamides insatures, leurs preparation et applications |
US5786086A (en) * | 1996-01-02 | 1998-07-28 | Union Camp Corporation | Conductive wire coating |
FR2766197B1 (fr) | 1997-07-17 | 1999-09-03 | Nyltech Italia | Copolyamide thermoplastique, composition a base de ce copolyamide thermoplastique |
CA2298580A1 (en) * | 1997-08-08 | 1999-02-18 | The Procter & Gamble Company | Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith |
FR2794465B1 (fr) * | 1999-05-21 | 2001-08-24 | Atofina | Polyamides hydrodispersibles a insaturations ethyleniques aux extremites |
US6680264B2 (en) | 2001-07-12 | 2004-01-20 | Colgate-Palmolive Co. | Glass cleaning wipe |
DE10217433A1 (de) | 2002-04-18 | 2003-10-30 | Basf Ag | Inhärent vernetzbare Polyamide |
EP1591468B1 (fr) * | 2004-04-26 | 2016-10-19 | Arkema France | Reactifs thermo-adhesifs a base des copolyamides ou copolyamide-bloc-polyethers reticulables |
-
2005
- 2005-04-14 EP EP05290820.9A patent/EP1591468B1/fr active Active
- 2005-04-19 CA CA2503662A patent/CA2503662C/fr not_active Expired - Fee Related
- 2005-04-25 CN CN200510067483A patent/CN100584874C/zh active Active
- 2005-04-25 JP JP2005126151A patent/JP4248514B2/ja active Active
- 2005-04-25 US US11/113,762 patent/US8642716B2/en active Active
- 2005-04-26 KR KR1020050034692A patent/KR100767234B1/ko active IP Right Grant
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2008
- 2008-07-23 JP JP2008189252A patent/JP2008297556A/ja active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0147267B2 (fr) | 1983-11-23 | 1994-01-26 | Elf Atochem S.A. | Production de macromères polyamides portant au moins une insaturation à chacune des deux extrémites de la séquence polyamide |
US5378798A (en) * | 1992-07-10 | 1995-01-03 | Shell Oil Company | Composition and process for coating metallic substrates |
US6391982B1 (en) | 1999-06-29 | 2002-05-21 | Degussa Ag | Highly branched polyamide graft copolymers |
KR20020062953A (ko) * | 2000-10-06 | 2002-07-31 | 아토피나 | 그라프트된 폴리아미드-블록 및 가요성 폴리올레핀공중합체의 혼합물 |
Also Published As
Publication number | Publication date |
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JP4248514B2 (ja) | 2009-04-02 |
CN1724579A (zh) | 2006-01-25 |
CA2503662C (fr) | 2013-04-02 |
CA2503662A1 (fr) | 2005-10-26 |
EP1591468A1 (fr) | 2005-11-02 |
CN100584874C (zh) | 2010-01-27 |
EP1591468B1 (fr) | 2016-10-19 |
JP2005320537A (ja) | 2005-11-17 |
KR20060047481A (ko) | 2006-05-18 |
US20050245680A1 (en) | 2005-11-03 |
US8642716B2 (en) | 2014-02-04 |
JP2008297556A (ja) | 2008-12-11 |
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