KR100737016B1 - 전촉매, 촉매 시스템 및 올레핀 중합에서의 용도 - Google Patents
전촉매, 촉매 시스템 및 올레핀 중합에서의 용도 Download PDFInfo
- Publication number
- KR100737016B1 KR100737016B1 KR1020027009004A KR20027009004A KR100737016B1 KR 100737016 B1 KR100737016 B1 KR 100737016B1 KR 1020027009004 A KR1020027009004 A KR 1020027009004A KR 20027009004 A KR20027009004 A KR 20027009004A KR 100737016 B1 KR100737016 B1 KR 100737016B1
- Authority
- KR
- South Korea
- Prior art keywords
- group
- formula
- independently
- ligand
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48133800A | 2000-01-12 | 2000-01-12 | |
| US09/481,338 | 2000-01-12 | ||
| US09/753,482 | 2001-01-03 | ||
| US09/753,482 US6696380B2 (en) | 2000-01-12 | 2001-01-03 | Procatalysts, catalyst systems, and use in olefin polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20020063309A KR20020063309A (ko) | 2002-08-01 |
| KR100737016B1 true KR100737016B1 (ko) | 2007-07-09 |
Family
ID=23911568
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020027009004A Expired - Lifetime KR100737016B1 (ko) | 2000-01-12 | 2001-01-11 | 전촉매, 촉매 시스템 및 올레핀 중합에서의 용도 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US6696380B2 (https=) |
| JP (2) | JP4856342B2 (https=) |
| KR (1) | KR100737016B1 (https=) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6696380B2 (en) * | 2000-01-12 | 2004-02-24 | Darryl Stephen Williams | Procatalysts, catalyst systems, and use in olefin polymerization |
| EP1506974A1 (en) | 2003-08-04 | 2005-02-16 | DSM IP Assets B.V. | Process for the preparation of a metalloorganic compound comprising at least one imine ligand |
| WO2005014601A2 (en) * | 2003-08-04 | 2005-02-17 | Dsm Ip Assets B.V. | Process for the preparation of a polyolefin |
| US7547751B2 (en) * | 2003-08-04 | 2009-06-16 | Dsm Ip Assets B.V. | Process for the preparation of a polyolefin |
| US20070004875A1 (en) * | 2005-06-22 | 2007-01-04 | Fina Technology, Inc. | Cocatalysts useful for improving polyethylene film properties |
| US20070004876A1 (en) * | 2005-06-22 | 2007-01-04 | Fina Technology, Inc. | Cocatalysts for olefin polymerizations |
| KR100828719B1 (ko) * | 2005-10-18 | 2008-05-09 | 주식회사 엘지화학 | 비메탈로센계 에틸렌 중합 촉매 및 이를 이용한 에틸렌중합 방법 |
| JP2007119514A (ja) * | 2005-10-25 | 2007-05-17 | Japan Polypropylene Corp | α−オレフィン重合用触媒成分、α−オレフィン重合用触媒、及びα−オレフィン重合体の製造方法 |
| US8003558B2 (en) * | 2008-07-29 | 2011-08-23 | Basf Corporation | Internal donor for olefin polymerization catalysts |
| US8202954B2 (en) * | 2010-02-19 | 2012-06-19 | Dow Global Technologies Llc | Metal-ligand complexes and catalysts |
| KR101007072B1 (ko) * | 2010-12-03 | 2011-01-12 | 대한엔지니어링 주식회사 | 광케이블 보호용 지지구 |
| EP2923756B1 (en) | 2012-11-26 | 2018-05-30 | Braskem S.A. | Metallocene catalyst supported by hybrid supporting means, process for producing same, polymerization process for producing an ethylene homopolymer or copolymer with broad or bimodal molar mass distribution, use of the supported metallocene catalyst and ethylene polymer with broad or bimodal molar mass distribution |
| KR101374480B1 (ko) * | 2012-12-14 | 2014-03-13 | 삼성토탈 주식회사 | 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조 방법 |
| CN112759676B (zh) * | 2019-10-21 | 2023-08-15 | 中国石油化工股份有限公司 | 一种用于制备聚烯烃固体催化剂组分、催化剂及其应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3714133A (en) | 1969-05-13 | 1973-01-30 | Maruzen Petrochem Co Ltd | PROCESS FOR PREPARING ALTERNATING COPOLYMER OF BUTADIENE AND alpha -OLEFINE AND NOVEL ALTERNATING COPOLYMER OF BUTADIENE AND alpha -OLEFINE CONTAINING CIS-CONFIGURATION BUTADIENE UNIT |
| JPS60112803A (ja) | 1983-11-25 | 1985-06-19 | Ube Ind Ltd | エチレンの重合法 |
Family Cites Families (75)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1016022B (de) | 1954-01-19 | 1957-09-19 | Dr Dr E H Karl Ziegler | Verfahren zur Herstellung von hochmolekularen Polyaethylenen |
| US2981725A (en) | 1955-11-16 | 1961-04-25 | Shell Oil Co | Process for polymerizing olefins |
| USB632416I5 (https=) | 1956-03-01 | 1976-03-09 | ||
| BE635904A (https=) | 1962-08-06 | 1963-12-02 | ||
| US3313791A (en) | 1964-03-24 | 1967-04-11 | Avisun Corp | Olefin polymerization in the presence of a catalyst comprising ticl3 raix2 and a chelate of an aluminum compound |
| US3489736A (en) | 1965-04-23 | 1970-01-13 | Showa Denko Kk | Polymerization of olefins |
| US3534006A (en) | 1966-03-25 | 1970-10-13 | Toray Industries | Methods of polymerizing alpha-olefins with a transition metal and a bis(dialkylaluminumoxy)alkane compound |
| US3723348A (en) | 1967-03-20 | 1973-03-27 | Du Pont | Coordination catalyst |
| FR1550186A (https=) | 1967-08-31 | 1968-12-20 | ||
| NL157609B (nl) | 1968-05-06 | 1978-08-15 | Montedison Spa | Werkwijze om een katalysator te bereiden om alkenen te polymeriseren, alsmede gevormde voorwerpen, vervaardigd volgens deze werkwijze. |
| US3676415A (en) | 1968-06-27 | 1972-07-11 | Hoechst Ag | Process for polymerizing {60 -olefins |
| US3919180A (en) | 1968-07-03 | 1975-11-11 | Bridgestone Tire Co Ltd | Method of producing alternating copolymers of donor monomer and acceptor monomer from not less than three monomers |
| US3644318A (en) | 1968-08-21 | 1972-02-22 | Hoechst Ag | Process for the polymerization of olefins |
| US3652705A (en) | 1968-10-03 | 1972-03-28 | Mitsui Petrochemical Ind | Process for the oligomerization of ethylene |
| US3655812A (en) | 1969-03-03 | 1972-04-11 | Exxon Research Engineering Co | Process for producing linear alpha olefins |
| US3637897A (en) | 1969-03-03 | 1972-01-25 | Exxon Research Engineering Co | Process for producing linear alpha olefins |
| DE2110195C3 (de) | 1970-03-11 | 1975-07-31 | Snam Progetti S.P.A., Mailand (Italien) | Aluminiumverbindung, Verfahren zu ihrer Herstellung und ihre Verwendung bei der Polymerisation von Olefinen, konjugierten oder nicht-konjugierten Dienen oder Gemischen davon |
| CA970899A (en) | 1970-03-17 | 1975-07-08 | Kiyoshige Hayashi | PROCESS FOR PREPARING AN ALTERNATING COPOLYMER OF AN .alpha.-OLEFIN AND A CONJUGATED DIENE |
| US3737417A (en) | 1970-05-07 | 1973-06-05 | Maruzen Petrochem Co Ltd | Process for preparing an alternating copolymer of an alpha-olefin and a conjugated diene |
| US4003712A (en) | 1970-07-29 | 1977-01-18 | Union Carbide Corporation | Fluidized bed reactor |
| NO136797C (no) | 1970-09-25 | 1977-11-09 | Union Carbide Corp | Fremgangsm}te for polymerisering av etylen med modifisert katalysator |
| US4012573A (en) | 1970-10-09 | 1977-03-15 | Basf Aktiengesellschaft | Method of removing heat from polymerization reactions of monomers in the gas phase |
| US3786032A (en) | 1970-11-20 | 1974-01-15 | Ici Ltd | Vinyl polymerization |
| NL161467C (nl) | 1970-12-02 | 1980-02-15 | Stamicarbon | Werkwijze voor het polymeriseren van etheen. |
| US3709853A (en) | 1971-04-29 | 1973-01-09 | Union Carbide Corp | Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts |
| IT953411B (it) | 1972-02-15 | 1973-08-10 | Snam Progetti | Produzione di lubrificanti sinteti ci da alfa olefine con un sistema catalitico ternario |
| US3862257A (en) | 1972-04-17 | 1975-01-21 | Exxon Research Engineering Co | Modified ziegler catalyst for alpha olefin wax synthesis |
| JPS554762B2 (https=) | 1972-05-10 | 1980-01-31 | ||
| US3917575A (en) | 1972-11-11 | 1975-11-04 | Nippon Oil Co Ltd | Process for production of polyolefins |
| GB1472541A (en) | 1974-07-16 | 1977-05-04 | Ici Ltd | Catalyst composition and use thereof in polymerisation of halide monomers |
| US3948869A (en) | 1974-04-08 | 1976-04-06 | The Firestone Tire & Rubber Company | Process for polymerizing conjugated dienes |
| US4105847A (en) | 1974-11-26 | 1978-08-08 | Mitsui Toatsu Chemicals Inc. | Method for polymerization of ethylene |
| US4011382A (en) | 1975-03-10 | 1977-03-08 | Union Carbide Corporation | Preparation of low and medium density ethylene polymer in fluid bed reactor |
| DE2553179A1 (de) | 1975-11-27 | 1977-06-08 | Hoechst Ag | Verfahren zur herstellung eines katalysators |
| US4256866A (en) | 1976-06-16 | 1981-03-17 | Standard Oil Company (Indiana) | Polymerization process |
| GB1579725A (en) | 1976-07-12 | 1980-11-26 | Shell Int Research | Preparation of violet tici3 |
| DE2801541A1 (de) | 1978-01-14 | 1979-07-19 | Hoechst Ag | Aethylencopolymere und ihre verwendung zur herstellung von folien |
| US4302566A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Preparation of ethylene copolymers in fluid bed reactor |
| JPS603324B2 (ja) | 1978-12-28 | 1985-01-28 | 三井化学株式会社 | エチレン共重合体の製造方法 |
| CA1152056A (en) | 1979-06-11 | 1983-08-16 | Brian L. Goodall | Process for the stereospecific polymerization of an alpha-olefin and an alpha-olefin polymerization catalyst system |
| US4363904A (en) | 1979-06-18 | 1982-12-14 | Union Carbide Corporation | High tear strength polymers |
| DE3040044A1 (de) | 1979-10-23 | 1981-09-03 | Japan Ep Rubber Co., Ltd., Yokkaichi, Mie | Verfahren zur herstellung eines kautschukartigen olefincopolymeren |
| JPS595603B2 (ja) * | 1979-12-08 | 1984-02-06 | 旭化成株式会社 | オレフイン重合用触媒 |
| DE3100736A1 (de) | 1981-01-13 | 1982-08-26 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von traegerkatalysatoren fuer die polymerisation von (alpha)-olefinen |
| US4409126A (en) | 1981-10-22 | 1983-10-11 | The Dow Chemical Company | Ultra high efficiency catalyst for polymerizing olefins |
| US4451626A (en) | 1981-10-22 | 1984-05-29 | The Dow Chemical Company | Process for polymerizing alpha-olefins |
| US4481301A (en) | 1981-12-04 | 1984-11-06 | Mobil Oil Corporation | Highly active catalyst composition for polymerizing alpha-olefins |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4482639A (en) | 1982-09-15 | 1984-11-13 | The Standard Oil Company | Catalysts for the polymerization of ethylene |
| US4727123A (en) | 1983-04-14 | 1988-02-23 | The Standard Oil Company | Catalysts for the polymerization of conjugated dienes |
| US4540756A (en) | 1983-11-01 | 1985-09-10 | Hercules Incorporated | Process for making low crystallinity polyolefins |
| US4603185A (en) | 1983-12-27 | 1986-07-29 | The Standard Oil Company | Catalytic process for the polymerization of acetylene |
| FR2565591B1 (fr) | 1984-06-08 | 1986-08-29 | Inst Francais Du Petrole | Procede de fabrication d'un copolymere ethylene-butene-1 a partir d'ethylene |
| US4601994A (en) | 1985-06-21 | 1986-07-22 | The Dow Chemical Company | Method for preparing supported TiIII catalysts |
| USRE33683E (en) | 1986-01-24 | 1991-09-03 | Mobil Oil Corporation | Catalyst composition for polymerizing alpha-olefins |
| FR2618786B1 (fr) | 1987-07-31 | 1989-12-01 | Bp Chimie Sa | Procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US5037997A (en) | 1988-02-23 | 1991-08-06 | Institut Khimicheskoi Fiziki An Sssr | Method of preparing 1-butene and/or hexenes |
| US5320994A (en) | 1988-06-23 | 1994-06-14 | Norsolor | Process for preparing a catalyst for the polymerization of olefins |
| US5039766A (en) | 1988-06-28 | 1991-08-13 | Sumitomo Chemical Company, Limited | Liquid catalyst component, catalyst system containing said component and process for producing ethylene-alpha-olefin copolymer using said catalyst system |
| US5134104A (en) | 1988-06-28 | 1992-07-28 | Sumitomo Chemical Company, Limited | Liquid catalyst component, catalyst system containing said component and process for producing ethylene-α-olefin copolymer using said catalyst system |
| NO176841C (no) | 1989-04-27 | 1995-06-07 | Sumitomo Chemical Co | Flytende katalysatorkomponent, katalysatorsystem inneholdende denne og fremgangsmåte for fremstilling av etylen - lefin-kopolymerer ved anvendelse av katalysatorsystemet |
| US5021595A (en) | 1990-03-02 | 1991-06-04 | Exxon Chemical Patents Inc. | Transition metal catalyst composition for olefin polymerization |
| JP2999217B2 (ja) * | 1990-04-27 | 2000-01-17 | 三井化学株式会社 | オレフィン重合用触媒およびオレフィンの重合方法 |
| US5231151A (en) | 1991-01-18 | 1993-07-27 | The Dow Chemical Company | Silica supported transition metal catalyst |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5468707A (en) | 1992-12-01 | 1995-11-21 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Coordination catalyst systems |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| DE4332786A1 (de) | 1993-09-27 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von ultrahochmolekularem Polyethylen mit hoher Schüttdichte |
| JPH07173214A (ja) | 1993-10-27 | 1995-07-11 | Nippon Oil Co Ltd | オレフィン類重合用触媒成分 |
| SG81898A1 (en) | 1995-08-11 | 2001-07-24 | Sumitomo Chemical Co | Olefin polymerization catalyst component, olefin polymerization catalyst and process for producing olefin polymer |
| US5756610A (en) | 1997-01-10 | 1998-05-26 | Industrail Technoloy Research Institute | Titanium (III) bases and β-diketonate coordinated catalyst composition for preparing high-syndiotacticity polystyrene and processes using the same |
| US5777120A (en) | 1997-03-14 | 1998-07-07 | University Of Iowa Research Foundation | Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts |
| EP0915104B1 (en) * | 1997-04-03 | 2007-06-06 | Tosoh Akzo Corporation | Catalyst for alpha-olefin polymerization |
| KR100240519B1 (ko) * | 1997-09-11 | 2000-01-15 | 유현식 | 새로운 올레핀 중합용 킬레이트 촉매 및 이를 이용한 올레핀중합 방법 |
| US6696380B2 (en) * | 2000-01-12 | 2004-02-24 | Darryl Stephen Williams | Procatalysts, catalyst systems, and use in olefin polymerization |
-
2001
- 2001-01-03 US US09/753,482 patent/US6696380B2/en not_active Expired - Lifetime
- 2001-01-11 KR KR1020027009004A patent/KR100737016B1/ko not_active Expired - Lifetime
- 2001-01-11 JP JP2001551112A patent/JP4856342B2/ja not_active Expired - Lifetime
-
2011
- 2011-06-15 JP JP2011133385A patent/JP2011208154A/ja active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3714133A (en) | 1969-05-13 | 1973-01-30 | Maruzen Petrochem Co Ltd | PROCESS FOR PREPARING ALTERNATING COPOLYMER OF BUTADIENE AND alpha -OLEFINE AND NOVEL ALTERNATING COPOLYMER OF BUTADIENE AND alpha -OLEFINE CONTAINING CIS-CONFIGURATION BUTADIENE UNIT |
| JPS60112803A (ja) | 1983-11-25 | 1985-06-19 | Ube Ind Ltd | エチレンの重合法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003529631A (ja) | 2003-10-07 |
| JP2011208154A (ja) | 2011-10-20 |
| JP4856342B2 (ja) | 2012-01-18 |
| US6696380B2 (en) | 2004-02-24 |
| US20010051587A1 (en) | 2001-12-13 |
| KR20020063309A (ko) | 2002-08-01 |
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