KR100722171B1 - 촉매 시스템, 이의 제조방법, 및 에틸렌과 공액 디엔과의공중합체의 제조방법 - Google Patents

촉매 시스템, 이의 제조방법, 및 에틸렌과 공액 디엔과의공중합체의 제조방법 Download PDF

Info

Publication number
KR100722171B1
KR100722171B1 KR1020000059816A KR20000059816A KR100722171B1 KR 100722171 B1 KR100722171 B1 KR 100722171B1 KR 1020000059816 A KR1020000059816 A KR 1020000059816A KR 20000059816 A KR20000059816 A KR 20000059816A KR 100722171 B1 KR100722171 B1 KR 100722171B1
Authority
KR
South Korea
Prior art keywords
formula
group
copolymer
alkyl
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020000059816A
Other languages
English (en)
Korean (ko)
Other versions
KR20010050962A (ko
Inventor
바르보땡파니
브와송크리스토프
스피츠로제
Original Assignee
소시에떼 드 테크놀로지 미쉐린
미쉐린 러쉐르슈 에 떼크니크 에스.에이.
아르끄마 프랑스
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 소시에떼 드 테크놀로지 미쉐린, 미쉐린 러쉐르슈 에 떼크니크 에스.에이., 아르끄마 프랑스 filed Critical 소시에떼 드 테크놀로지 미쉐린
Publication of KR20010050962A publication Critical patent/KR20010050962A/ko
Application granted granted Critical
Publication of KR100722171B1 publication Critical patent/KR100722171B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/68—Vanadium, niobium, tantalum or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/083—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic polyenes, i.e. containing two or more carbon-to-carbon double bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020000059816A 1999-10-12 2000-10-11 촉매 시스템, 이의 제조방법, 및 에틸렌과 공액 디엔과의공중합체의 제조방법 Expired - Fee Related KR100722171B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9912798A FR2799468B1 (fr) 1999-10-12 1999-10-12 Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
FR99/12798 1999-10-12

Publications (2)

Publication Number Publication Date
KR20010050962A KR20010050962A (ko) 2001-06-25
KR100722171B1 true KR100722171B1 (ko) 2007-05-29

Family

ID=9550906

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020000059816A Expired - Fee Related KR100722171B1 (ko) 1999-10-12 2000-10-11 촉매 시스템, 이의 제조방법, 및 에틸렌과 공액 디엔과의공중합체의 제조방법

Country Status (9)

Country Link
US (2) US6569799B1 (enExample)
EP (2) EP1092731B1 (enExample)
JP (1) JP4806784B2 (enExample)
KR (1) KR100722171B1 (enExample)
CN (1) CN1205238C (enExample)
AT (1) ATE537196T1 (enExample)
BR (1) BR0004778B1 (enExample)
CA (1) CA2321362C (enExample)
FR (1) FR2799468B1 (enExample)

Families Citing this family (140)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100826080B1 (ko) * 2001-12-27 2008-04-29 삼성토탈 주식회사 고용융체 강도를 갖는 에틸렌/디엔 공중합체의 제조방법
JP5301073B2 (ja) * 2002-10-16 2013-09-25 コンパニー ゼネラール デ エタブリッスマン ミシュラン エチレン／ブタジエンコポリマー、触媒系及びその合成方法
WO2004044018A2 (en) * 2002-11-07 2004-05-27 Dow Global Technologies, Inc. Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby
FR2858817B1 (fr) * 2003-08-13 2006-02-03 Michelin Soc Tech Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres
US7294649B2 (en) * 2004-12-17 2007-11-13 Roche Diagnostics Operatins, Inc. Methamphetamine derivatives and conjugates for immunoassay
JP2009503243A (ja) * 2005-08-04 2009-01-29 ザ リージェンツ オブ ザ ユニヴァーシティー オブ コロラド， ア ボディー コーポレイト ラジカル重合用触媒
FR2893029B1 (fr) 2005-11-09 2009-01-16 Michelin Soc Tech Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede
FR2893028B1 (fr) * 2005-11-09 2008-02-15 Michelin Soc Tech Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede
FR2893030B1 (fr) * 2006-10-17 2011-04-15 Michelin Soc Tech Copolymere ethylene/butadiene
US7741418B2 (en) * 2007-12-31 2010-06-22 Bridgestone Corporation Process for producing polydienes
CN102549024B (zh) * 2009-08-07 2015-04-08 株式会社普利司通 生产共聚物的方法
FR2954332B1 (fr) 2009-12-22 2012-01-13 Michelin Soc Tech Article notamment pneumatique avec melange de caoutchouc externe comportant un sel de lanthanide
JP5823674B2 (ja) * 2010-07-30 2015-11-25 株式会社ブリヂストン 共役ジエン化合物と非共役オレフィンとの共重合体
EP2599808B1 (en) * 2010-07-30 2017-01-25 Bridgestone Corporation Method for controlling chain structure in copolymers
JP5557642B2 (ja) * 2010-07-30 2014-07-23 株式会社ブリヂストン 共役ジエン化合物と非共役オレフィンとの共重合体
JP5917809B2 (ja) * 2010-11-30 2016-05-18 株式会社ブリヂストン 共重合体及びその製造方法、並びに、ゴム組成物、架橋ゴム組成物、及びタイヤ
JP5932224B2 (ja) * 2011-02-04 2016-06-08 株式会社ブリヂストン 共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
KR101592907B1 (ko) * 2011-02-04 2016-02-11 가부시키가이샤 브리지스톤 공중합체, 고무 조성물, 타이어 사이드용 고무 조성물, 가교 고무 조성물 및 타이어
JP5731217B2 (ja) * 2011-02-04 2015-06-10 株式会社ブリヂストン 共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
RU2608312C2 (ru) 2011-02-05 2017-01-17 Бриджстоун Корпорейшн Лантаноидный комплексный катализатор и способ полимеризации с его применением
JP5612511B2 (ja) * 2011-02-28 2014-10-22 株式会社ブリヂストン ゴム組成物、架橋ゴム組成物、及びタイヤ
CN104903358B (zh) 2012-09-30 2017-11-17 株式会社普利司通 有机金属催化剂络合物及采用其的聚合方法
WO2014055868A1 (en) 2012-10-04 2014-04-10 Bridgestone Corporation Organometallic complex catalyst and polymerization method employing same
FR3001223B1 (fr) * 2013-01-22 2015-03-06 Michelin & Cie Composition de caoutchouc comprenant un elastomere dienique fortement sature
US10017595B2 (en) 2014-05-30 2018-07-10 Bridgestone Corporation Metallic complex catalyst and polymerization methods employing same
EP3148938B1 (en) * 2014-05-31 2020-07-08 Bridgestone Corporation Metallic complex catalyst, polymerization methods employing same
FR3037588B1 (fr) 2015-06-19 2017-05-19 Michelin & Cie Copolymere elastomere thermoplastique a base d'elastomere dienique et de polypropylene, compositions le comprenant et procede de preparation
EP3363824B1 (en) * 2015-10-16 2024-05-01 Bridgestone Corporation Multicomponent copolymer, rubber composition, cross-linked rubber composition, rubber product, and tire
WO2017065300A1 (ja) * 2015-10-16 2017-04-20 株式会社ブリヂストン 多元共重合体、樹脂組成物、架橋樹脂組成物、及び製品
FR3044007B1 (fr) 2015-11-19 2017-12-08 Michelin & Cie Bande de roulement pour pneumatique d'avion
FR3044010A1 (fr) 2015-11-19 2017-05-26 Michelin & Cie Bande de roulement pour pneumatique d'avion
FR3044241A1 (fr) * 2015-12-01 2017-06-02 Michelin & Cie Systeme catalytique comprenant un metallocene de terre rare
FR3044662B1 (fr) 2015-12-03 2017-12-08 Michelin & Cie Systeme catalytique preforme comprenant un metallocene de terre rare
FR3044663B1 (fr) 2015-12-08 2017-12-29 Michelin & Cie Copolymere monofonctionnel ou telechelique de 1,3-butadiene et d'ethylene.
FR3044664B1 (fr) 2015-12-08 2017-12-29 Michelin & Cie Copolymere monofonctionnel ou telechelique de 1,3-diene et d'ethylene ou d'alpha-monoolefine.
FR3045613B1 (fr) 2015-12-17 2017-12-15 Michelin & Cie Copolymere d'ethylene et de butadiene de microstructure homogene
FR3045612B1 (fr) 2015-12-17 2017-12-15 Michelin & Cie Copolymere d'ethylene et de butadiene de microstructure homogene
FR3045633B1 (fr) 2015-12-22 2017-12-15 Michelin & Cie Pneumatique comprenant une composition de caoutchouc comprenant un elastomere dienique substitue
WO2017170654A1 (en) 2016-03-31 2017-10-05 Compagnie Generale Des Etablissements Michelin A tire having a tread comprising a rubber composition
EP3436287B1 (en) 2016-03-31 2019-12-25 Compagnie Générale des Etablissements Michelin A tire having a tread comprising a rubber composition
FR3054221A1 (fr) * 2016-07-25 2018-01-26 Compagnie Generale Des Etablissements Michelin Systeme catalytique preforme comprenant un metallocene de terre rare
FR3054220A1 (fr) 2016-07-25 2018-01-26 Compagnie Generale Des Etablissements Michelin Systeme catalytique preforme comprenant un metallocene de terre rare
FR3054222A1 (fr) 2016-07-25 2018-01-26 Compagnie Generale Des Etablissements Michelin Procede de preparation d'un systeme catalytique a base d'un metallocene de terre rare
FR3059254A1 (fr) * 2016-11-30 2018-06-01 Compagnie Generale Des Etablissements Michelin Systeme catalytique preforme comprenant un metallocene de terre rare
FR3060007A1 (fr) 2016-12-09 2018-06-15 Compagnie Generale Des Etablissements Michelin Terpolymeres d'ethylene, de 1,3-butadiene ou d'isoprene, et d'une alpha-monoolefine aromatique
FR3060004B1 (fr) 2016-12-09 2019-05-24 Compagnie Generale Des Etablissements Michelin Compose organometallique ayant une fonction iminophosphorane
FR3063732A1 (fr) 2017-03-08 2018-09-14 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate polyfonctionnel
FR3063731A1 (fr) 2017-03-08 2018-09-14 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un acrylate de zinc
FR3065005A1 (fr) 2017-04-10 2018-10-12 Compagnie Generale Des Etablissements Michelin Bande de roulement pour pneumatique a base d'un elastomere dienique fortement sature
FR3065004A1 (fr) 2017-04-10 2018-10-12 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc a base d'un elastomere dienique fortement sature et d'un sel dithiosulfate
FR3065216A1 (fr) 2017-04-18 2018-10-19 Compagnie Generale Des Etablissements Michelin Synthese en continu de copolymere d'ethylene et de butadiene
FR3065215A1 (fr) * 2017-04-18 2018-10-19 Compagnie Generale Des Etablissements Michelin Synthese en continu de copolymere d'ethylene et de butadiene
FR3067354B1 (fr) 2017-06-08 2020-10-23 Centre Nat Rech Scient Copolymere fonctionnel d'ethylene et de 1,3-butadiene
FR3067355A1 (fr) 2017-06-08 2018-12-14 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc
FR3067353B1 (fr) 2017-06-08 2020-10-23 Centre Nat Rech Scient Copolymere fonctionnel d'un 1,3-diene et d'une olefine
WO2019077232A1 (fr) 2017-10-19 2019-04-25 Compagnie Generale Des Etablissements Michelin Procede de synthese de polymeres blocs
WO2019077233A1 (fr) 2017-10-19 2019-04-25 Compagnie Generale Des Etablissements Michelin Polymeres blocs ayant a la fois des unités diéniques et des unités monooléfine
EP3697825B1 (fr) 2017-10-19 2024-07-31 Compagnie Générale des Etablissements Michelin Polymeres blocs dieniques et ethyleniques avec des unites cycliques hydrocarbonees et saturees
JP7321154B2 (ja) 2017-10-19 2023-08-04 コンパニー ゼネラール デ エタブリッスマン ミシュラン ブロックポリマー
CN111201256A (zh) 2017-10-19 2020-05-26 米其林集团总公司 嵌段聚合物
CN108057460B (zh) * 2017-12-04 2020-07-14 苏州大学 二硅胺稀土配合物在催化碳化二亚胺和二苯基膦的膦氢化反应中的应用
WO2019110924A1 (fr) 2017-12-06 2019-06-13 Compagnie Generale Des Etablissements Michelin Stratifié élastomère
CN111448062A (zh) 2017-12-06 2020-07-24 米其林集团总公司 弹性体层压件
FR3085165B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085167B1 (fr) 2018-08-23 2020-07-31 Michelin & Cie Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085166B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085684B1 (fr) 2018-09-11 2021-06-04 Michelin & Cie Composition de caoutchouc
FR3085683B1 (fr) 2018-09-11 2020-10-23 Michelin & Cie Pneumatique
FR3086948B1 (fr) 2018-10-09 2020-12-04 Michelin & Cie Composition de caoutchouc
FR3086949B1 (fr) 2018-10-09 2020-12-04 Michelin & Cie Composition de caoutchouc
FR3087443B3 (fr) 2018-10-23 2020-10-23 Michelin & Cie Composition de caoutchouc
FR3088328B3 (fr) 2018-11-09 2020-12-04 Michelin & Cie Elastomere dienique fonctionnel et composition de caoutchouc
FR3090639A3 (fr) 2018-12-20 2020-06-26 Michelin & Cie Terpolymères d’éthylène, de 1,3-butadiène et d’une α-monooléfine aromatique.
FR3090663A3 (fr) 2018-12-21 2020-06-26 Michelin & Cie Bande de roulement pour pneumatique
FR3090654A3 (fr) 2018-12-21 2020-06-26 Michelin & Cie Composition de caoutchouc
FR3090661A3 (fr) 2018-12-21 2020-06-26 Michelin & Cie Bande de roulement pour pneumatique
FR3090656A3 (fr) 2018-12-21 2020-06-26 Michelin & Cie Bande de roulement pour pneumatique
FR3090659A3 (fr) 2018-12-21 2020-06-26 Michelin & Cie Bande de roulement pour pneumatique
CN112029017A (zh) * 2019-06-03 2020-12-04 中国石油天然气股份有限公司 一种桥联茂稀土金属化合物及其在烯烃共聚合中的应用
CN112029020A (zh) * 2019-06-03 2020-12-04 中国石油天然气股份有限公司 一种长链α-烯烃聚合催化剂组合物及聚合方法
FR3104597B1 (fr) 2019-12-16 2021-11-12 Michelin & Cie Composition de caoutchouc
FR3104585B1 (fr) 2019-12-17 2021-12-03 Michelin & Cie Système catalytique à base d’un métallocène et d’un diorganomagnésien
FR3104595B1 (fr) 2019-12-17 2021-11-12 Michelin & Cie Pneumatique avec une bande de roulement comportant des elements de renforcement
FR3104586B1 (fr) 2019-12-17 2021-12-03 Michelin & Cie Composé diorganomagnésien asymétrique pour système catalytique
FR3104584B1 (fr) 2019-12-17 2021-12-03 Michelin & Cie Composé diorganomagnésien asymétrique
FR3108117B1 (fr) 2020-03-10 2022-03-25 Michelin & Cie Procédé de fabrication d’une composition de caoutchouc.
FR3111352B1 (fr) 2020-06-11 2023-02-10 Michelin & Cie Composition de caoutchouc presentant une resistance aux agressions amelioree
FR3113906B1 (fr) 2020-09-04 2022-08-05 Michelin & Cie Composition de caoutchouc a base d’elastomere dienique fortement sature
FR3113905B1 (fr) 2020-09-04 2022-08-05 Michelin & Cie Composition de caoutchouc a base d’elastomere dienique fortement sature
FR3116277A1 (fr) 2020-11-19 2022-05-20 Compagnie Generale Des Etablissements Michelin Copolymères fonctionnels amine à blocs éthyléniques et diéniques
FR3116276B1 (fr) 2020-11-19 2023-11-10 Michelin & Cie Diorganomagnésien ayant une chaîne diénique ou oléfinique et fonctionnelle amine
FR3116538B1 (fr) 2020-11-24 2022-11-25 Michelin & Cie Co-catalyseur comprenant plusieurs liaisons carbone magnésium
FR3116535B1 (fr) 2020-11-24 2022-11-25 Michelin & Cie Polymères téléchéliques à base d’éthylène et de 1,3-diène
FR3116540B1 (fr) 2020-11-24 2023-11-03 Michelin & Cie Système catalytique à base d’un métallocène de terre rare et d’un co-catalyseur ayant plusieurs liaisons carbone magnésium.
FR3116539B1 (fr) 2020-11-24 2022-11-25 Michelin & Cie Système catalytique à base d’un métallocène de terre rare et d’un co-catalyseur ayant plusieurs liaisons carbone magnésium.
FR3117404B1 (fr) 2020-12-16 2024-02-16 Michelin & Cie Stratifié élastomère présentant une excellente adhésion entre une couche diénique fortement saturé réticulé et une couche diénique vulcanisé
FR3118042B1 (fr) 2020-12-21 2023-07-21 Michelin & Cie systèmes catalytiques supportés pour la synthèse de polyoléfines semi-cristallines
FR3118048B1 (fr) 2020-12-22 2023-01-13 Michelin & Cie Composition de caoutchouc comprenant une poudrette de caoutchouc
FR3118046B1 (fr) 2020-12-23 2022-12-30 Michelin & Cie Composition de caoutchouc comprenant un élastomère diénique fortement saturé
FR3118047B1 (fr) 2020-12-23 2022-12-30 Michelin & Cie Composition de caoutchouc comprenant un élastomère diénique fortement saturé
FR3118045B1 (fr) 2020-12-23 2022-12-30 Michelin & Cie Composition de caoutchouc
FR3118044B1 (fr) 2020-12-23 2022-12-30 Michelin & Cie Composition de caoutchouc
FR3123654B1 (fr) 2021-06-07 2023-04-28 Michelin & Cie Composition de caoutchouc base d’élastomère fortement saturé et de compolymère de butadiene-styrene
FR3123655B1 (fr) 2021-06-07 2023-04-28 Michelin & Cie Bande transporteuse comprenant une composition à base d’élastomère fortement saturé
FR3123920B1 (fr) 2021-06-15 2023-04-28 Michelin & Cie Composition de caoutchouc a base de copolymere contenant des unites ethylene et des unites dieniques, et de polyethylene
FR3123919B1 (fr) 2021-06-15 2023-04-28 Michelin & Cie Composition de caoutchouc a base de copolymere contenant des unites ethylene et des unites dieniques, et de polyethylene
FR3124514B1 (fr) 2021-06-25 2023-06-02 Michelin & Cie Composition de caoutchouc presentant une resistance aux agressions amelioree
FR3129399B1 (fr) 2021-11-22 2023-11-10 Michelin & Cie Composition de caoutchouc
FR3129396B1 (fr) 2021-11-22 2023-11-10 Michelin & Cie Composition de caoutchouc
FR3129397B1 (fr) 2021-11-22 2023-11-10 Michelin & Cie Composition de caoutchouc
FR3129398B1 (fr) 2021-11-22 2025-05-23 Michelin & Cie Composition de caoutchouc
FR3129401B1 (fr) 2021-11-22 2023-11-10 Michelin & Cie Composition de caoutchouc
FR3129400B1 (fr) 2021-11-22 2023-11-10 Michelin & Cie Composition de caoutchouc
FR3130281B1 (fr) 2021-12-10 2025-07-25 Michelin & Cie Composition de caoutchouc antivibratoire
FR3130807B1 (fr) 2021-12-16 2025-08-29 Michelin & Cie Composition de caoutchouc comprenant un élastomère diénique fortement saturé
FR3135722B1 (fr) 2022-05-17 2024-04-19 Michelin & Cie Composition de caoutchouc a base d’un elastomere fortement sature et d’un plastifiant liquide
FR3135723B1 (fr) 2022-05-17 2024-04-19 Michelin & Cie Composition de caoutchouc a base d’un elastomere fortement sature et d’un plastifiant liquide polaire
FR3136473A1 (fr) 2022-06-14 2023-12-15 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc comprenant un élastomère diénique fortement saturé
FR3136768B1 (fr) 2022-06-20 2024-05-31 Michelin & Cie Composition de caoutchouc diénique comportant une microsilice.
FR3136771B1 (fr) 2022-06-21 2024-05-10 Michelin & Cie Composition de caoutchouc comprenant un élastomère diénique fortement saturé
FR3143032A1 (fr) 2022-12-08 2024-06-14 Compagnie Generale Des Etablissements Michelin Composite pour article de caoutchouc
FR3143035B1 (fr) 2022-12-08 2024-11-29 Michelin & Cie Composition de caoutchouc
FR3143033B1 (fr) 2022-12-12 2024-11-29 Michelin & Cie Pneumatique pour véhicule portant de lourdes charges
FR3143034B1 (fr) 2022-12-13 2025-05-02 Michelin & Cie Composition de caoutchouc
FR3143613B1 (fr) 2022-12-15 2024-11-15 Michelin & Cie Composition de caoutchouc comprenant un élastomère diénique fortement saturé
FR3143612B1 (fr) 2022-12-15 2024-11-15 Michelin & Cie Composition de caoutchouc comprenant un élastomère diénique fortement saturé
FR3144145A1 (fr) 2022-12-21 2024-06-28 Compagnie Generale Des Etablissements Michelin Compositions elastomeriques comprenant un noir de carbone de pyrolyse
FR3145756A1 (fr) 2023-02-09 2024-08-16 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc a base d’elastomere dienique fortement sature et d’un derive d’imidazole
FR3145755B1 (fr) 2023-02-09 2025-02-07 Michelin & Cie Composition de caoutchouc a base d’elastomere dienique fortement sature et d’une resine renforçante
FR3148030A1 (fr) 2023-04-24 2024-10-25 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc
FR3148429B1 (fr) 2023-05-04 2025-05-02 Michelin & Cie Composition de caoutchouc
FR3148598A1 (fr) 2023-05-10 2024-11-15 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc
FR3149322B1 (fr) 2023-05-31 2025-05-02 Michelin & Cie Composition de caoutchouc comprenant un élastomère diénique fortement saturé
FR3149614B1 (fr) 2023-06-09 2025-05-02 Michelin & Cie Composition de caoutchouc antivibratoire
FR3149613B1 (fr) 2023-06-09 2025-05-02 Michelin & Cie Composition de caoutchouc antivibratoire
FR3156448B1 (fr) 2023-12-12 2025-10-31 Michelin & Cie Composition de caoutchouc a base d’elastomere dienique fortement sature
FR3159971A1 (fr) 2024-03-05 2025-09-12 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc comprenant un elastomere dienique fortement sature
FR3160409A1 (fr) 2024-03-21 2025-09-26 Compagnie Generale Des Etablissements Michelin Système catalytique comprenant un métallocène pour la synthèse de polyéthylène et de copolymère d’éthylène et de 1,3-diène.
FR3160408A1 (fr) 2024-03-21 2025-09-26 Compagnie Generale Des Etablissements Michelin Procédé de préparation d’un polyéthylène ou d’un copolymère d’éthylène et de 1,3-diène.
FR3161910A1 (fr) 2024-05-02 2025-11-07 Compagnie Generale Des Etablissements Michelin Membrane échangeuse d’anions et son procédé d’obtention.

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5066739A (en) * 1990-07-30 1991-11-19 Phillips Petroleum Company Olefin polymerization with cyclopentadienyl lanthanidealkyl of hydride in presence of hydrogen
WO1994009044A1 (fr) * 1992-10-08 1994-04-28 Ecp-Enichem Polymeres France S.A. Catalyseurs et procede de preparation de catalyseurs utilisables pour la polymerisation de l'ethylene
JPH08245711A (ja) * 1995-03-10 1996-09-24 Showa Denko Kk 新規ランタニド錯体及びこれを用いた不飽和カルボン酸エステル重合体並びにポリオレフィンの製造方法
KR20000022454A (ko) * 1996-07-05 2000-04-25 빌프리더 하이더 고융점 폴리올레핀의 제조 방법
KR100317589B1 (ko) * 1993-10-08 2002-04-24 그래햄 이. 테일러 쇄 전이제를 사용한 신디오탁틱 비닐리덴 방향족중합체의제조방법

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
US4801666A (en) * 1985-03-25 1989-01-31 Northwestern University Olefin and cycloalkene polymerization with organolanthanide catalysts
US4716257A (en) 1985-03-25 1987-12-29 Northwestern University Organolanthanide catalysts
US5109085A (en) * 1990-08-27 1992-04-28 Phillips Petroleum Company Olefin polymerization process
FR2681870B1 (fr) * 1991-10-01 1994-02-11 Ecp Enichem Polymeres France Sa Catalyseurs et procede de preparation de catalyseurs utilisables pour la polymerisation de l'ethylene.
JPH0641232A (ja) * 1992-07-22 1994-02-15 Idemitsu Kosan Co Ltd 重合用触媒、それを用いた重合体の製造方法及び触媒成分の製造方法
JPH06256419A (ja) * 1993-03-09 1994-09-13 Showa Denko Kk エチレン系重合体の製造方法
JPH07304829A (ja) * 1994-05-09 1995-11-21 Mitsubishi Chem Corp 重合体の製造法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5066739A (en) * 1990-07-30 1991-11-19 Phillips Petroleum Company Olefin polymerization with cyclopentadienyl lanthanidealkyl of hydride in presence of hydrogen
WO1994009044A1 (fr) * 1992-10-08 1994-04-28 Ecp-Enichem Polymeres France S.A. Catalyseurs et procede de preparation de catalyseurs utilisables pour la polymerisation de l'ethylene
KR100317589B1 (ko) * 1993-10-08 2002-04-24 그래햄 이. 테일러 쇄 전이제를 사용한 신디오탁틱 비닐리덴 방향족중합체의제조방법
JPH08245711A (ja) * 1995-03-10 1996-09-24 Showa Denko Kk 新規ランタニド錯体及びこれを用いた不飽和カルボン酸エステル重合体並びにポリオレフィンの製造方法
KR20000022454A (ko) * 1996-07-05 2000-04-25 빌프리더 하이더 고융점 폴리올레핀의 제조 방법

Also Published As

Publication number Publication date
CA2321362A1 (fr) 2001-04-12
EP1092731B1 (fr) 2011-12-14
EP1829901B1 (fr) 2016-04-13
CN1205238C (zh) 2005-06-08
BR0004778A (pt) 2001-05-29
ATE537196T1 (de) 2011-12-15
US6569799B1 (en) 2003-05-27
JP2001294607A (ja) 2001-10-23
EP1829901A2 (fr) 2007-09-05
CA2321362C (fr) 2010-06-15
CN1310188A (zh) 2001-08-29
KR20010050962A (ko) 2001-06-25
FR2799468B1 (fr) 2006-04-28
US20030004287A1 (en) 2003-01-02
FR2799468A1 (fr) 2001-04-13
EP1829901A3 (fr) 2007-10-10
US6800705B2 (en) 2004-10-05
EP1092731A1 (fr) 2001-04-18
BR0004778B1 (pt) 2010-11-30
JP4806784B2 (ja) 2011-11-02

Similar Documents

Publication Publication Date Title
KR100722171B1 (ko) 촉매 시스템, 이의 제조방법, 및 에틸렌과 공액 디엔과의공중합체의 제조방법
RU2312870C2 (ru) Сополимеры этилена и бутадиена, каталитическая система и способ их синтеза
US8492573B2 (en) Borohydride metallocene complex of a lanthanide, catalytic system including said complex, polymerization method using same and ethylene/butadiene copolymer obtained using said method
JP6903660B2 (ja) 希土類メタロセンを含む触媒予備形成系
US10934377B2 (en) Preformed catalytic system comprising a rare-earth metallocene
JP6959979B2 (ja) 希土類メタロセンを含む予備形成触媒系
CN102863577B (zh) 乙烯和丁二烯的共聚物
US20120046158A1 (en) Polymerization catalyst compositions containing metallocene complexes and polymers produced by using the same
JP2007501881A5 (enExample)
JP6946322B2 (ja) 希土類メタロセンを含む触媒系
KR100955739B1 (ko) 올레핀 중합체
KR20230129399A (ko) 1,3-디엔과 에틸렌을 기반으로 하는 블럭 중합체의합성
JPS5917724B2 (ja) オレフインの重合および共重合の触媒組成物
CN106795181A (zh) 锆的吡啶络合物、包含所述锆的吡啶络合物的催化体系以及使共轭二烯(共)聚合的工艺
US20070179260A1 (en) Isotactic 3, 4-isoprene-based polymer
US6399727B1 (en) Heteroleptic alkaline-earth metal compounds and methods for carrying out stereoselective anionic polymerization
JP2886906B2 (ja) ポリシクロペンテンおよびその製造方法

Legal Events

Date Code Title Description
PA0109 Patent application

St.27 status event code: A-0-1-A10-A12-nap-PA0109

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

PN2301 Change of applicant

St.27 status event code: A-3-3-R10-R11-asn-PN2301

St.27 status event code: A-3-3-R10-R13-asn-PN2301

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

D13-X000 Search requested

St.27 status event code: A-1-2-D10-D13-srh-X000

PN2301 Change of applicant

St.27 status event code: A-3-3-R10-R11-asn-PN2301

St.27 status event code: A-3-3-R10-R13-asn-PN2301

D14-X000 Search report completed

St.27 status event code: A-1-2-D10-D14-srh-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

Fee payment year number: 1

St.27 status event code: A-2-2-U10-U11-oth-PR1002

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

FPAY Annual fee payment

Payment date: 20100518

Year of fee payment: 4

PR1001 Payment of annual fee

Fee payment year number: 4

St.27 status event code: A-4-4-U10-U11-oth-PR1001

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

Not in force date: 20110522

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

St.27 status event code: A-4-4-U10-U13-oth-PC1903

PC1903 Unpaid annual fee

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20110522

St.27 status event code: N-4-6-H10-H13-oth-PC1903

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000