KR100671584B1 - 하이드로퍼옥사이드 분해 방법 - Google Patents
하이드로퍼옥사이드 분해 방법 Download PDFInfo
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- KR100671584B1 KR100671584B1 KR1020017012733A KR20017012733A KR100671584B1 KR 100671584 B1 KR100671584 B1 KR 100671584B1 KR 1020017012733 A KR1020017012733 A KR 1020017012733A KR 20017012733 A KR20017012733 A KR 20017012733A KR 100671584 B1 KR100671584 B1 KR 100671584B1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/881—Molybdenum and iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (10)
- 큐멘 하이드로퍼옥사이드로부터 페놀 및 아세톤을 제조하는 방법으로서,큐멘 하이드로퍼옥사이드를, 400℃ 이상의 온도에서 IVB족 금속 옥사이드 공급원을 VIB족 금속의 옥시 음이온의 공급원으로 하소시킴으로써 제조한 고체 산 촉매와 접촉시키는 단계를 포함하는 방법.
- 제 1 항에 있어서,온도가 600℃ 이상인 방법.
- 제 1 항에 있어서,온도가 700 내지 850℃인 방법.
- 제 1 항에 있어서,IVB족 금속 옥사이드가 지르코니아 및 티타니아로부터 선택되는 방법.
- 제 1 항에 있어서,VIB족 금속 옥시 음이온이 크롬, 몰리브덴 및 텅스텐의 옥시 음이온들로부터 선택되는 방법.
- 제 1 항에 있어서,고체 산 촉매가 원소주기율표의 IB족, VIIB족 및 VIII족으로부터 선택된 금속을 추가로 함유하는 방법.
- 제 6 항에 있어서,금속이 철, 망간, 구리 또는 이들의 조합인 방법.
- 제 1 항에 있어서,접촉단계가 20 내지 150℃의 온도 및 대기압 내지 1,000psig의 압력에서 수행되는 방법.
- 제 1 항에 있어서,접촉단계가 40 내지 120℃의 온도 및 대기압 내지 400psig의 압력에서 수행되는 방법.
- 삭제
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/275,749 US6169215B1 (en) | 1999-03-25 | 1999-03-25 | Production of phenol |
US09/275,749 | 1999-03-25 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20010113776A KR20010113776A (ko) | 2001-12-28 |
KR100671584B1 true KR100671584B1 (ko) | 2007-01-18 |
Family
ID=23053640
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020017012733A KR100671584B1 (ko) | 1999-03-25 | 2000-03-23 | 하이드로퍼옥사이드 분해 방법 |
Country Status (11)
Country | Link |
---|---|
US (1) | US6169215B1 (ko) |
EP (1) | EP1169284B1 (ko) |
KR (1) | KR100671584B1 (ko) |
CN (1) | CN1211323C (ko) |
AT (1) | ATE295341T1 (ko) |
BR (1) | BR0010867A (ko) |
DE (1) | DE60020103T2 (ko) |
ES (1) | ES2240085T3 (ko) |
MX (1) | MXPA01009722A (ko) |
TW (1) | TWI292338B (ko) |
WO (2) | WO2000058250A1 (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101327086B1 (ko) * | 2008-10-10 | 2013-11-07 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 페놀 생산 방법 |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6297406B1 (en) * | 1999-08-03 | 2001-10-02 | Mobil Oil Corporation | Production of phenol |
US6441251B1 (en) | 2001-09-04 | 2002-08-27 | Exxonmobil Chemical Patents Inc. | Production of phenol |
US6984761B2 (en) * | 2002-12-16 | 2006-01-10 | Exxonmobil Chemical Patents Inc. | Co-production of phenol, acetone, α-methylstyrene and propylene oxide, and catalyst therefor |
US7491855B2 (en) * | 2003-06-04 | 2009-02-17 | Sabic Innovative Plastics Ip B.V. | Integrated process for the production of bisphenol A from cumene hydroperoxide |
US7154010B2 (en) * | 2003-06-04 | 2006-12-26 | General Electric Company | Integrated process for the production of bisphenol A from cumene hydroperoxide |
TWI376361B (en) * | 2004-08-13 | 2012-11-11 | Exxonmobil Chem Patents Inc | Process for producing phenol and methyl ethyl ketone |
US7326815B2 (en) * | 2005-12-27 | 2008-02-05 | Exxonmobil Chemical Patents Inc. | Selective oxidation of alkylbenzenes |
WO2007137020A2 (en) * | 2006-05-16 | 2007-11-29 | Shell Oil Company | Method for decomposing di(phenylalkyl)peroxides to produce hydroxybenzenes and phenylalkenes using solid catalysts |
US8026398B2 (en) * | 2006-05-16 | 2011-09-27 | Narayana Mysore | Catalysts comprising a combination of oxidized metals and a method for cleaving phenylalkyl hydroperoxides using the catalysts |
US7417003B2 (en) * | 2006-12-29 | 2008-08-26 | Uop Llc | Solid acid catalyst and process for decomposition of cumene hydroperoxide |
EP2178813B8 (en) * | 2007-08-22 | 2011-06-22 | ExxonMobil Chemical Patents Inc. | Process for producing sec-butylbenzene |
EP2098498A1 (en) | 2008-03-04 | 2009-09-09 | ExxonMobil Chemical Patents Inc. | Selective oligomerization of isobutene |
KR20110016964A (ko) * | 2008-08-26 | 2011-02-18 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 알킬벤젠 하이드로퍼옥사이드의 제조방법 |
US8440864B2 (en) * | 2008-10-10 | 2013-05-14 | Exxonmobil Chemical Patents Inc. | Process for producing sec-butylbenzene |
CN102177126A (zh) | 2008-10-10 | 2011-09-07 | 埃克森美孚化学专利公司 | 制备苯酚和甲乙酮的方法 |
CN102177121B (zh) * | 2008-10-10 | 2015-05-13 | 埃克森美孚化学专利公司 | 生产苯酚的方法 |
WO2010074779A1 (en) | 2008-12-15 | 2010-07-01 | Exxonmobil Chemical Patents Inc. | Oxidation of alkylaromatic compounds |
SG172949A1 (en) | 2009-02-26 | 2011-08-29 | Exxonmobil Chem Patents Inc | Process for producing phenol |
US9321710B2 (en) | 2010-01-25 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
WO2012036824A1 (en) | 2010-09-14 | 2012-03-22 | Exxonmobil Chemical Patents Inc. | Oxidation of alkylbenzenes and cycloalkylbenzenes |
US9388102B2 (en) | 2011-04-19 | 2016-07-12 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
JP5793792B2 (ja) | 2011-04-19 | 2015-10-14 | エクソンモービル ケミカル パテンツ インコーポレイテッド | フェノールの製造方法 |
US9249078B2 (en) | 2011-10-07 | 2016-02-02 | Exxonmobil Chemical Patents Inc. | Mixed metal oxide catalysts and use thereof |
US9815756B2 (en) * | 2016-03-31 | 2017-11-14 | Uop Llc | Methods and apparatuses for phenol fractionation in a single dividing wall column |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4490565A (en) * | 1983-05-06 | 1984-12-25 | Mobil Oil Corporation | Production of phenol |
US4490566A (en) * | 1983-05-06 | 1984-12-25 | Mobil Oil Corporation | Production of phenol |
US4870217A (en) * | 1988-10-24 | 1989-09-26 | Texaco Chemical Company | Method for production of phenol/acetone from cumene hydroperoxide |
US4898995A (en) * | 1988-10-24 | 1990-02-06 | Texaco Chemical Company | Method for production of phenol/acetone from cumene hydroperoxide |
EP0367408A3 (en) * | 1988-10-24 | 1991-06-12 | Texaco Development Corporation | Method for production of phenol/acetone from cumene hydroperoxide |
EP0492807A3 (en) | 1990-12-27 | 1992-08-12 | Texaco Chemical Company | Method for production of phenol/acetone from cumene hydroperoxide |
US5113034A (en) * | 1991-08-05 | 1992-05-12 | Exxon Research And Engineering Company | Dimerization catalyst and process therefor |
US5185480A (en) * | 1992-07-28 | 1993-02-09 | Texaco Chemical Company | Catalytic removal of peroxide contaminants from a methanol-tertiary butyl alcohol recycle stream |
CA2279493A1 (en) * | 1997-02-11 | 1998-08-13 | E.I. Du Pont De Nemours And Company | Hydroperoxide decomposition process |
-
1999
- 1999-03-25 US US09/275,749 patent/US6169215B1/en not_active Expired - Lifetime
-
2000
- 2000-03-02 WO PCT/US2000/005476 patent/WO2000058250A1/en active Application Filing
- 2000-03-23 CN CNB008073244A patent/CN1211323C/zh not_active Expired - Lifetime
- 2000-03-23 MX MXPA01009722A patent/MXPA01009722A/es not_active Application Discontinuation
- 2000-03-23 DE DE60020103T patent/DE60020103T2/de not_active Expired - Lifetime
- 2000-03-23 AT AT00919533T patent/ATE295341T1/de not_active IP Right Cessation
- 2000-03-23 WO PCT/US2000/007596 patent/WO2000056682A1/en active IP Right Grant
- 2000-03-23 ES ES00919533T patent/ES2240085T3/es not_active Expired - Lifetime
- 2000-03-23 TW TW089105337A patent/TWI292338B/zh not_active IP Right Cessation
- 2000-03-23 KR KR1020017012733A patent/KR100671584B1/ko active IP Right Grant
- 2000-03-23 EP EP00919533A patent/EP1169284B1/en not_active Expired - Lifetime
- 2000-03-23 BR BRPI0010867-7A patent/BR0010867A/pt not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101327086B1 (ko) * | 2008-10-10 | 2013-11-07 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 페놀 생산 방법 |
Also Published As
Publication number | Publication date |
---|---|
BR0010867A (pt) | 2007-07-31 |
EP1169284A1 (en) | 2002-01-09 |
TWI292338B (en) | 2008-01-11 |
WO2000058250A1 (en) | 2000-10-05 |
DE60020103T2 (de) | 2006-01-26 |
ES2240085T3 (es) | 2005-10-16 |
DE60020103D1 (de) | 2005-06-16 |
US6169215B1 (en) | 2001-01-02 |
ATE295341T1 (de) | 2005-05-15 |
WO2000056682A1 (en) | 2000-09-28 |
CN1211323C (zh) | 2005-07-20 |
CN1349481A (zh) | 2002-05-15 |
MXPA01009722A (es) | 2002-07-22 |
EP1169284A4 (en) | 2002-11-06 |
EP1169284B1 (en) | 2005-05-11 |
KR20010113776A (ko) | 2001-12-28 |
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