KR100622438B1 - 3,3-디메틸부탄올의 산화에 의한3,3-디메틸부티르알데히드의 제조방법 - Google Patents

3,3-디메틸부탄올의 산화에 의한3,3-디메틸부티르알데히드의 제조방법 Download PDF

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Publication number
KR100622438B1
KR100622438B1 KR1020067000262A KR20067000262A KR100622438B1 KR 100622438 B1 KR100622438 B1 KR 100622438B1 KR 1020067000262 A KR1020067000262 A KR 1020067000262A KR 20067000262 A KR20067000262 A KR 20067000262A KR 100622438 B1 KR100622438 B1 KR 100622438B1
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South Korea
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dimethylbutanol
dimethylbutyraldehyde
oxidation
metal oxide
oxidizing agent
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KR20060010871A (ko
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인드라 프라카쉬
데이비드 제이 아거
알란 알 카트리즈키
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더 뉴트라스위트 컴퍼니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/298—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with manganese derivatives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020067000262A 1997-08-06 1998-08-04 3,3-디메틸부탄올의 산화에 의한3,3-디메틸부티르알데히드의 제조방법 Expired - Fee Related KR100622438B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/907,048 US5856584A (en) 1997-08-06 1997-08-06 Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol
US08/907,048 1997-08-06

Related Parent Applications (1)

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KR1020007001153A Division KR100585332B1 (ko) 1997-08-06 1998-08-04 3,3-디메틸부탄올의 산화에 의한3,3-디메틸부티르알데히드의 제조방법

Publications (2)

Publication Number Publication Date
KR20060010871A KR20060010871A (ko) 2006-02-02
KR100622438B1 true KR100622438B1 (ko) 2006-09-19

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KR1020067000262A Expired - Fee Related KR100622438B1 (ko) 1997-08-06 1998-08-04 3,3-디메틸부탄올의 산화에 의한3,3-디메틸부티르알데히드의 제조방법
KR1020007001153A Expired - Fee Related KR100585332B1 (ko) 1997-08-06 1998-08-04 3,3-디메틸부탄올의 산화에 의한3,3-디메틸부티르알데히드의 제조방법

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US (1) US5856584A (enExample)
EP (2) EP1186591B1 (enExample)
JP (3) JP2001525384A (enExample)
KR (2) KR100622438B1 (enExample)
CN (2) CN1238320C (enExample)
AR (1) AR016582A1 (enExample)
AT (1) ATE252532T1 (enExample)
AU (1) AU749936B2 (enExample)
BR (1) BR9811854B1 (enExample)
CA (2) CA2299637C (enExample)
DE (2) DE69819164T2 (enExample)
ES (2) ES2205563T3 (enExample)
HU (1) HUP0003631A3 (enExample)
IL (1) IL134374A0 (enExample)
PE (1) PE96699A1 (enExample)
UY (1) UY25126A1 (enExample)
WO (1) WO1999029646A1 (enExample)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5856584A (en) * 1997-08-06 1999-01-05 The Nutrasweet Company Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol
US6573409B1 (en) * 1999-07-02 2003-06-03 The Nutrasweet Company Process for the preparation of 3,3-dimethylbutanal
EP1103537B1 (de) * 1999-11-19 2003-05-14 Ciba SC Holding AG Verfahren zur selektiven Oxidation von Alkoholen unter Verwendung leicht abtrennbarer Nitroxylradikale
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
WO2004067484A2 (en) * 2003-01-30 2004-08-12 The Nutrasweet Company Bromine free tempo based catalyst system for oxidation of primary and secondary alcohols using naoci as an oxidant.
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US20050038310A1 (en) 2003-07-15 2005-02-17 Lorkovic Ivan M. Hydrocarbon synthesis
US6825384B1 (en) * 2004-01-29 2004-11-30 The Nutrasweet Company Bromine free TEMPO based catalyst system for oxidation of primary and secondary alcohols using NaOCl as an oxidant
DE602005023413D1 (de) * 2004-02-26 2010-10-21 Nutrasweet Property Holdings I Katalysatorsystem zur aeoroben oxidation von primären und sekundären alkoholen
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
JP2006182764A (ja) * 2004-12-03 2006-07-13 Daiso Co Ltd 第１級または第２級アルコールの新規酸化方法
DE102005030728A1 (de) * 2005-07-01 2007-01-04 Lanxess Deutschland Gmbh Verfahren zur Ruthenium-katalysierten Oxidation von Alkoholen mit Hypochlorit
EA015515B1 (ru) 2006-02-03 2011-08-30 ДжиАрТи, ИНК. Непрерывный способ превращения природного газа в жидкие углеводороды
ZA200807230B (en) 2006-02-03 2009-11-25 Grt Inc Separation of light gases from halogens
WO2008148113A1 (en) 2007-05-24 2008-12-04 Grt, Inc. Zone reactor incorporating reversible hydrogen halide capture and release
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
SG192538A1 (en) 2008-07-18 2013-08-30 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
CN101508632B (zh) * 2009-03-25 2012-06-13 东南大学 多相催化氧化制备3,3-二甲基丁醛的方法
CN102030667A (zh) * 2009-09-30 2011-04-27 昆明全新生物制药有限公司 一种4-(n,n-二烷胺基)丁醛缩二醇的制备方法
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
CN102241573B (zh) * 2010-05-10 2014-06-11 陕西天汉生物科技有限公司 一种3,3-二甲基丁醛的制备方法
CN101962327A (zh) * 2010-08-30 2011-02-02 海门慧聚药业有限公司 4-(n,n-二甲氨基)-丁醛缩二甲醇的合成新工艺
CN102030668B (zh) * 2010-10-24 2013-10-30 绍兴文理学院 二甲胺丁缩醛的制备方法
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
CN104119212B (zh) * 2013-04-27 2016-03-02 中国科学院大连化学物理研究所 一种催化氧化3,3-二甲基-1-丁醇制备3,3-二甲基-1-丁醛的方法
JP6155832B2 (ja) * 2013-05-16 2017-07-05 セイコーエプソン株式会社 センサー素子、電子機器、および移動体
CN104649874A (zh) * 2013-11-15 2015-05-27 中国科学院大连化学物理研究所 3,3-二甲基-1-丁醇脱氢制3,3-二甲基-1-丁醛的方法
EP3212601B1 (en) * 2014-10-30 2019-12-04 Organofuel Sweden AB A mild catalytic reduction of c-o bonds and c=o bonds using a recyclable catalyst system

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3146493A1 (de) * 1981-11-24 1983-06-01 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von reinem neohexanol
ES535014A0 (es) * 1983-08-11 1985-08-01 Monsanto Co Un procedimiento para preparar derivados de piridina sustituidos en las posiciones 2 y 6
CA2006355A1 (en) * 1988-12-23 1990-06-23 Philip M. Sher 7-oxabicycloheptyl substituted heterocyclic amide prostaglandin analogs useful in the treatment of thrombotic and vasospastic disease
JPH0832647B2 (ja) * 1989-01-27 1996-03-29 大阪有機化学工業株式会社 １級アルコールからアルデヒドの製造法
NZ232897A (en) * 1989-04-03 1992-12-23 Squibb & Sons Inc Interphenylene 7-oxabicycloheptyl substituted heterocyclic amide prostaglandin analogues, preparation and pharmaceutical compositions thereof
JP3039025B2 (ja) * 1991-07-19 2000-05-08 吉富製薬株式会社 置換アセトアルデヒドの製造方法
JPH05310632A (ja) * 1992-04-28 1993-11-22 Sumitomo Chem Co Ltd ｍ−フェノキシベンズアルデヒドの製造方法
JP3626520B2 (ja) * 1994-12-26 2005-03-09 株式会社クラレ ３−置換−３−メチルブタナールの製造方法
US5631366A (en) * 1995-01-12 1997-05-20 Hoffmann-La Roche Inc. Process for making 3-formylcephem derivatives
JPH08198795A (ja) * 1995-01-20 1996-08-06 Kuraray Co Ltd セネシオンアルデヒドの製造方法
JPH08198893A (ja) * 1995-01-27 1996-08-06 Nippon Kayaku Co Ltd １４α−ヒドロキシ−４−アンドロステン−３，６，１７−トリオンの製造法
US5821374A (en) * 1995-11-21 1998-10-13 Hoffmann-La Roche Inc. Process for the oxidation of alcohols
US5856584A (en) * 1997-08-06 1999-01-05 The Nutrasweet Company Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol

Also Published As

Publication number Publication date
EP1186591B1 (en) 2005-11-02
DE69832209D1 (de) 2005-12-08
CN1286790C (zh) 2006-11-29
DE69819164T2 (de) 2004-07-22
CA2486890A1 (en) 1999-06-17
CN1266419A (zh) 2000-09-13
DE69832209T2 (de) 2006-07-27
DE69819164D1 (de) 2003-11-27
WO1999029646A1 (en) 1999-06-17
JP2012102113A (ja) 2012-05-31
AU749936B2 (en) 2002-07-04
ES2246978T3 (es) 2006-03-01
EP1186591A2 (en) 2002-03-13
CN1238320C (zh) 2006-01-25
AR016582A1 (es) 2001-07-25
ATE252532T1 (de) 2003-11-15
CA2299637C (en) 2005-10-11
KR20060010871A (ko) 2006-02-02
JP2010031021A (ja) 2010-02-12
US5856584A (en) 1999-01-05
PE96699A1 (es) 1999-09-29
BR9811854B1 (pt) 2009-08-11
KR100585332B1 (ko) 2006-05-30
BR9811854A (pt) 2000-08-15
CA2299637A1 (en) 1999-06-17
AU9773898A (en) 1999-06-28
JP2001525384A (ja) 2001-12-11
EP1186591A3 (en) 2002-03-20
IL134374A0 (en) 2001-04-30
EP1003703B1 (en) 2003-10-22
KR20010022562A (ko) 2001-03-26
CN1515533A (zh) 2004-07-28
UY25126A1 (es) 1998-08-31
ES2205563T3 (es) 2004-05-01
HUP0003631A2 (hu) 2001-05-28
CA2486890C (en) 2009-03-31
EP1003703A1 (en) 2000-05-31
HUP0003631A3 (en) 2001-08-28

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