KR100367275B1 - 포스파이트를 포함하는 중합체 조성물 - Google Patents
포스파이트를 포함하는 중합체 조성물 Download PDFInfo
- Publication number
- KR100367275B1 KR100367275B1 KR1019940017560A KR19940017560A KR100367275B1 KR 100367275 B1 KR100367275 B1 KR 100367275B1 KR 1019940017560 A KR1019940017560 A KR 1019940017560A KR 19940017560 A KR19940017560 A KR 19940017560A KR 100367275 B1 KR100367275 B1 KR 100367275B1
- Authority
- KR
- South Korea
- Prior art keywords
- butyl
- propane diol
- phosphite
- bis
- styrene
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 40
- 229920000642 polymer Polymers 0.000 title claims description 40
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 title claims description 31
- 229910052799 carbon Inorganic materials 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 239000004952 Polyamide Substances 0.000 claims description 11
- 229920002647 polyamide Polymers 0.000 claims description 11
- 229920000098 polyolefin Polymers 0.000 claims description 9
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 229920000515 polycarbonate Polymers 0.000 claims description 7
- 239000004417 polycarbonate Substances 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 229920001955 polyphenylene ether Polymers 0.000 claims description 6
- 239000004793 Polystyrene Substances 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 5
- 229920000578 graft copolymer Polymers 0.000 claims description 5
- 229920002223 polystyrene Polymers 0.000 claims description 5
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 239000005060 rubber Substances 0.000 claims description 3
- 125000004437 phosphorous atom Chemical group 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 229920001601 polyetherimide Polymers 0.000 claims 1
- 229920001291 polyvinyl halide Polymers 0.000 claims 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 abstract description 18
- 229920001169 thermoplastic Polymers 0.000 abstract description 5
- 230000000087 stabilizing effect Effects 0.000 abstract description 2
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
- -1 hydrogen radicals Chemical class 0.000 description 64
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 52
- 229920001577 copolymer Polymers 0.000 description 22
- 239000004743 Polypropylene Substances 0.000 description 14
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 13
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- 239000005977 Ethylene Substances 0.000 description 12
- 229920001155 polypropylene Polymers 0.000 description 12
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 10
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
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- 229920000573 polyethylene Polymers 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 150000002009 diols Chemical class 0.000 description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
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- 238000006243 chemical reaction Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
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- 238000004519 manufacturing process Methods 0.000 description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
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- 239000000178 monomer Substances 0.000 description 3
- 229940117969 neopentyl glycol Drugs 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
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- 230000006641 stabilisation Effects 0.000 description 3
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- 150000005846 sugar alcohols Polymers 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 3
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- OQGLREGMROLUAQ-UHFFFAOYSA-N 2,2,4,4-tetramethylpentane-1,3-diol Chemical compound CC(C)(C)C(O)C(C)(C)CO OQGLREGMROLUAQ-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- XQESJWNDTICJHW-UHFFFAOYSA-N 2-[(2-hydroxy-5-methyl-3-nonylphenyl)methyl]-4-methyl-6-nonylphenol Chemical compound CCCCCCCCCC1=CC(C)=CC(CC=2C(=C(CCCCCCCCC)C=C(C)C=2)O)=C1O XQESJWNDTICJHW-UHFFFAOYSA-N 0.000 description 2
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- AZIVKLIKTWLEET-UHFFFAOYSA-N 4-butyl-4-ethyl-2,2,6,6-tetramethylheptane-3,5-diol Chemical compound CCCCC(CC)(C(O)C(C)(C)C)C(O)C(C)(C)C AZIVKLIKTWLEET-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/527—Cyclic esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65742—Esters of oxyacids of phosphorus non-condensed with carbocyclic rings or heterocyclic rings or ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
본 발명은 개선된 안정성을 나타내는 네오알킬 포스파이트에 관한 것이다. 본 포스파이트는 입체 장애되었으며, 열가소성 조성물을 안정화시키는데 유용하다.
Description
본 발명은 포스파이트에 관한 것이며, 보다 상세하게는 네오-알킬 포스파이트, 그의 제조방법 및 그에 의해 안정화된 중합체 조성물에 관한 것이다.
유기 포스파이트는 중합체 및 다른 유기 물질용의 공지된 열산화 안정제이다. 그러나, 이러한 포스파이트는 구조적 결함으로 인해 전형적으로 하나 이상의 하기 문제점을 갖는다: (a) 포스파이트는 알콜로 분해되어, -OH 그룹을 이용한 수소의 베타-제거를 통해 H2O(물)를 생성시키며, 이렇게 생성된 H2O는 포스파이트를 추가로 분해시킬 수 있다고 생각되며, (b)포스파이트는 수분(이는 산소 원자와 인 원자 사이의 결합(O-P결합을 공격한다)에 노출되었을 때 가수분해에 의해 불안정하게 되고; (c) 포스파이트는 표준 중합체 공정 조건하에서 포스파이트 안정화된 중합체 조성물로부터 휘발되는 250℃ 미만의 비점을 갖는 알콜분해 생성물, 예를 들어 저분자량 디올, 예를 들어 1,3-프로판 디올(비점 213℃), 2,2-디메틸-1,3-프로판 디올(비점 206℃), 2,2-디에틸-1,3-프로판 디올(비점 240℃), 및 2-메틸, 2-프로필-1,3-프로판 디올(비점 234℃)과 같은 분해 생성물로 분해된다. 최종적으로,유기 포스파이트의 제조공정에서는 알콜자 PCl3의 직접 반응으로부터 포스파이트를 제조할 수 있는 것이 바람직하지만, 베타-수소가 알콜중에 존재하는 경우, 바람직하지 못한 알킬클로라이드가 형성될 가능성이 크다.
PCl3를 사용하며 네오글리콜로 부터 유도된 네오-알킬 포스파이트는 공지되어 있다(본원에 참고로 인용된 데버(Dever)등의 미합중국 특허 제 3,711,302 호 참조). 이들 네오-알킬 포스파이트는 β-수소를 갖지 않으며, 단지 수소 라디칼만을 갖는 α -탄소상에 입체 벌크가 부족하므로 포스파이트는 가수분해에 불안정하기 쉽고, 휘발성 분해 생성물로 될 수 있다.
따라서, 베타-수소를 거의 갖지 않으며(바람직하게는 베타-수소를 전혀 갖지 않음) α-탄소상에 입체 벌크를 갖는 포스파이트를 제공하는 것이 바람직하다.
본 발명은, (a) 베타-탄소상에 수소를 거의 갖지 않으며, 바람직하게는 베타-탄소상에 수소를 전혀 갖지 않으며, (b) 하나 이상의 알파-탄소상에 입체 벌크를 갖는 유기 포스파이트 에스테르를 제공한다. 본 포스파이트는 중합체 조성물에서 열산화 안정제로 사용되기에 적합하다.
본 포스파이트는 하기 일반식을 갖는 것들을 포함한다:
상기 식에서, 각각의 R1은 C1-C10알킬 라디칼로 이루어진 그룹 중에서 독립적으로 선택되고, 각각의 R2는 수소 및 C3-C20라디칼로 이루어진 그룹중에서 독립적으로 신택되나, 단 하나 이상의 R2는 이들이 결합된 α -탄소에 입체 벌크를 제공하는 C1-C20알킬 라디칼이며, R3는 6개 이상의 탄소원자를 갖는 탄화수소 라디칼이다.
바람직하게는 포스파이트는 촉매, HCl 수용체 및 용매의 부재하에 네오글리콜과 PCl3를 반응시켜, 하기 일반식의 중간 생성물을 생성시킨 후, HO-R3(여기에서, R3는 상기 정의된 바와 같다)와 반응시킴으로써 수득된다.
상기 식에서, R1및 R2는 상기 정의된 바와 같다.
다르게는, 또 다른 반응 공정 및 단계를 사용하여 목적하는 생성물을 수득할 수도 있다. 본원에 참고로 인용된 헤켄블라이크너(Heckenbleikner)등의 미합중국 특허 제 3,056,823호에 기술된 것과 같은 에스테르 교환 방법이 또한 사용될 수도 있다. 포스파이트는 예를들어, 알칼리 촉매(예를 들어 알칼리금속, 알칼리 토금속또는 금속 알콜레이트)의 존재하에 가열함으로써 하기 일반식의 디올과 트리페닐포스파이트를 반응시켜 제조할 수 있다:
상기 반응은 본질적으로 지방족 그룹이 트리아릴 포스파이트중의 하나 이상의 아릴 그룹을 대체하는 치환반응으로서 진행된다. 지방족 알콜과 트리아릴 포스파이트의 비는 그에 맞게 선택한다. 그러므로, 1몰의 지방족 디올을 사용하여 최초의 포스파이트로 부터 2몰의 아릴 라디칼을 대체하면서 2몰의 페놀을 유리시킨다. 반응온도는 폭넓게 변할 수도 있으나, 일반적으로 약 120° 내지 150℃이다.
실제로, 바람직하게는 가열하기 전에 2가 알콜, 트리페닐 포스파이트 에스테르 및 촉매를 임의의 바람직한 순서로 함께 혼합시킬 수 있다. 예를 들어 환류 응축기에서 아릴 성분들의 지방족 성분으로의 대체가 목적하는 상태에 도달할 때까지 상기 물질들을 함께 가열한다. 이는 혼합물의 비점과 같은 관찰가능한 특성이 더이상 변하지 않음으로써 결정할 수 있다. 필요한 가열시간은 보통 2 내지 5시간이다. 이어서 가열을 중지한다. 반응도중 유리된 페놀 또는 다른 아릴하이드록시 화합물 뿐만 이니라 임의의 미반응 지방족 디올을 진공중에서 증류 제거하며, 생성된 포스파이트 트리에스테르를 중류 잔류물로 부터 회수하고, 통상의 수단에 의해 정제한다.
R3는 포스파이트 잔기를 함유할 수 있다.
상기 제시된 바와 같이, 적합한 디올은 하기 일반식을 갖는 것들이다:
상기식에서, 각각의 R1은 C1-C10알킬 라디칼로 이루어진 그룹중에서 독립적으로 선택되는 것이 바람직하며, 각각의 R2는 수소 및 C3-C20알킬 라디칼로 이루어진 그룹중에서 독립적으로 선택되나, 단, 하나 이상의 R2는 C3-C20(바람직하게는 C4-C6) 알킬 라디칼이다. 본원에 기술된 바와 같이, α-탄소는 산소원자에 직접 결합한 것이며, β-탄소는 산소원자로 부터 2번째 탄소에 위치한 것이며, 따라서 β -탄소는 α -탄소에 결합한 것이며, α -탄소는 산소원자에 결합한 것이다. 예시 목적으로, 하기 구조식
의 포스파이트는 베타 탄소에 결합한 수소를 갖지 않으며, 이에 상응하는 하기 구조식
의 디올은 베타-탄소에 결합한 수소를 갖지 않는다:
바람직하게는 본 발명의 포스파이트는 각각의 베타-탄소에 결합한 수소를 하나 이하 가지며, 바람직하게는 전체 포스파이트에서 그러한 베타-수소를 총 2개 이하 가지며, 더욱 바람직하게는 이러한 베타-수소를 하나 이하 가지며, 가장 바람직하게는 베타-탄소에 결합한 수소를 갖지 않는다. 본 발명에서 이용할 수 있는 네오 유형의 글리콜은 베타, 베타 디알킬 치환기를 가지며, 탄화수소 라디칼인 하나 이상의 R2를 가져서, α-탄소에 입체 벌크를 제공한다. 구체적인 네오-글리콜은 베타-탄소에 결합한 수소를 갖지 않는 다음과 같은 것들을 포함한다:
2,2-디메틸-1-t-부틸-1,3-프로판 디올,
2,2-디메틸-1,3-디-t-부틸 프로판 디올,
2-에틸-2-부틸-1-t-부틸-1,3-프로판 디올,
2-에틸-2-부틸-1,3-디-t-부틸-1,3-프로판 디올,
2,2-디메틸-1-t-부틸-1,3-프로판 디올,
2,2-디에틸-1-t-부틸-1,3-프로판 디올,
2,2-디프로필-1-t-부틸-1,3-프로판 디올,
2,2-디부틸-1-t-부틸-1,3-프로판 디올,
2,2-디펜틸-1-t-부틸-1,3-프로판 디올,
2,2-디헥실-1-t-부틸-1,3-프로판 디올,
2-메틸-2-에틸-1-t-부틸-1,3-프로판 디올,
2-메틸-2-프로필-1-t-부틸-1,3-프로판 디올,
2-메틸-2-부틸-1-t-부틸-1,3-프로판 디올,
2-메틸-2-펜틸-1-t-부틸-1,3-프로판 디올,
2-메틸-2-헥실-1-t-부틸-1,3-프로판 디올,
2-에틸-2-프로필-1-t-부틸-1,3-프로판 디올,
2-에틸-2-부틸-1-t-부틸-1,3-프로판 디올,
2-에틸-2-펜틸-1-t-부틸-1,3-프로판 디올,
2-에틸-2-헥실-1-t-부틸-1,3-프로판 디올,
2-프로필-2-부틸-1-t-부틸-1,3-프로판 디올,
2-프로필-2-펜틸-1-t-부틸-1,3-프로판 디올,
2-프로필-2-헥실-1-t-부틸-1,3-프로판 디올,
2-부틸-2-펜틸-1-t-부틸 -1,3-프로판 디올,
2-부틸-2-헥실-1-t-부틸-1,3-프로판 디올,
2-펜틸-2-헥실-1-t-부틸-1,3-프로판 디올,
2,2-디메틸-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2,2-디에틸-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2,2-디프로필-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2,2-디부틸-1-t-부틸 -3-t-부틸-1,3-프로판 디올,
2,2-디펜틸-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2,2-디헥실-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-메틸-2-에틸-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-메틸-2-프로필-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-메틸-2-부틸-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-메틸-2-펜틸-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-메틸-2-헥실-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-에틸-2-프로필-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-에틸-2-부틸-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-에틸-2-펜틸-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-에틸-2-헥실-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-프로필-2-부틸-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-프로필-2-펜틸-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-프로필-2-헥실-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-부틸-2-펜틸-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-부틸-2-헥실-1-t-부틸-3-t-부틸-1,3-프로판 디올,
2-펜틸-2-헥실-1-t-부틸-3-t-부틸-1,3-프로판 디올.
상기에서 나타난 바와 같이, 하나 이상의 R2는 바람직하게는 3급 알킬이고, 하기 일반식으로 나타낼 수 있다:
상기 식에서, 각각의 R4는 독립적으로 C1-C10알킬 라디칼로 이루어진 그룹중에서 독립적으로 선택되고, 바람직하게는 각각의 R4는 메틸 그룹이다.
하나의 베타-수소를 갖는 네오디올은 하나 이상의 R2가 하기 일반식을 갖는 것들을 포함한다:
상기 식에서, R4는 상기 정의된 바와 같다.
하나의 베타-수소를 갖는 구체적인 네오디올은 다음과 같다
2,2-디메틸-1-(2-프로필 )-1,3-프로판 디올,
2,2-디에틸-1-(2-프로필)-1,3-프로판 디올,
2,2-디프로필-1-(2-프로필)-1,3-프로판 디올,
2,2-디부틸-1-(2-프로필)-1,3-프로판 디올,
2,2-디펜틸-1-(2-프로필)-1,3-프로판 디올,
2,2-디헥실-1-(2-프로필)-1,3-프로판 디올,
2-메틸-2-에틸-1-(2-프로필)-1,3-프로판 디올,
2-메틸-2-프로필-1-(2-프로필)-1,3-프로판 디올,
2-메틸-2-부틸-1-(2-프로필)-1,3-프로판 디올,
2-메틸-2-펜틸-1-(2-프로필)-1,3-프로판 디올,
2-메틸-2-헥실-1-(2-프로필)-1,3-프로판 디올,
2-에틸-2-프로필-1-(2-프로필)-1,3-프로판 디올,
2-에틸-2-부틸-1-(2-프로필)-1,3-프로판 디올,
2-에틸-2-펜틸-1-(2-프로필)-1,3-프로판 디올,
2-에틸-2-헥실-1-(2-프로필)-1,3-프로판 디올,
2-프로필-2-부틸-1-(2-프로필)-1,3-프로판 디올,
2-프로필-2-펜틸-1-(2-프로필)-1,3-프로판 디올,
2-프로필-2-헥실-1-(2-프로필)-1,3-프로판 디올,
2-부틸-2-펜틸-1-(2-프로필)-1,3-프로판 디올,
2-부틸-2-헥실-1-(2-프로필)-1,3-프로판 디올,
2-펜틸-2-헥실-1-(2-프로필)-1.3-프로판 디올.
일반식 -O-R3의 잔기는 또다른 포스파이트 잔기일 수 있거나 하기 일반식의알콜을 포함하는 일반식 H-O-R3의 알콜로 부터 유도될 수 있다:
상기 식에서, 각각의 R5는 수소 및 탄화수소 라디칼로 이루어진 그룹중에서 독립적으로 선택되고, 바람직하게는 2개 이상의 R5그룹은 C1-C10알킬 라디칼이고, 더욱 바람직하게는 2개 이상의 R5그룹은 t-부틸 그룹이고, 바람직하게는 R5그룹중의 탄소 원자의 합은 6이상이고, 더욱 바람직하게는 산소에 인접한 2개의 R5그룹은 각각 알킬 그룹이다.
본 발명의 포스파이트는 R3가 포스파이트 잔기를 함유한 디포스파이트일 수도 있다. 적합한 디포스파이트는 하기 일반식을 갖는 것들을 포함한다:
상기 식에서. 각각의 포스파이트 잔기의 R1및 R2는 상기 정의된 바와 같고, R6는 베타-탄소에 결합한 수소를 바람직하게는 거의 갖지 않고, 더욱 바람직하게는 전혀 갖지 않는 2가 탄화수소 라디칼이다. 잔기 -O-R6-O-는 일반식 HO-R6-OH의디올로부터 유도될 수 있다.
적합한 R6구조는 하기 일반식들을 포함한다:
상기 식에서, 각각의 R7은 C1-C6알킬 라디칼중에서 독립적으로 선택되고. R8은 C1-C20, 바람직하게는 C1-C6의 2가 탄화수소 라디칼이다.
적합한 포스파이트는 하기 구조식들을 갖는 것들을 포함한다:
바람직하게는 각각의 R1은 메틸이다.
구체적인 구조식의 예는 다음과 같다:
포스파이트는 열산화 분해로부터 중합체를 안정화시키는데 유용하다. 적합한 중합체 조성물은 폴리올레핀(폴리프로필렌, 폴리에틸렌, 폴리부텐, 폴리(2-메틸펜텐)), 폴리카보네이트, 폴리에스테르(PET, PBT, PCTG), 폴리아미드, 폴리우레탄, 고무 개질제, 그라프트 공중합체(MBS, ABS, MB, ASA) 및 폴리스티렌을 포함한다.
본 발명은 또한 상기 기술된 하나 이상의 포스파이트를 효과량
포함하는 안정화된 중합체 조성물이다. 본 발명의 포스파이트의 양은 본 발명의 포스파이트를 함유한 중합체 조성물이 본 발명의 포스파이트를 포함하지 않은 유사한 중합체 조성물과 비교하여 그의 물성 또는 색상특성에 있어서 개선된 안정성을 나타낼 때 "효과량"으로 간주된다. 그러나. 대부분의 중합체 조성물에서, 포스파이트는 수지 100 중량부당 약 0.01 내지 약 2 중량부(phr)의 양으로 존재하는 것이 바람직할 것이다. 약 0.01 내지 약 1phr의 양이 더욱 바람직하지만, 대부분의 조성물은 약 0.025phr 이상을 함유한다. 중합체 조성물은 불포화 폴리에스테르, 페놀류, 에폭시, 우레탄, 피복수지 및 가교결합성 라텍스를 포함하여 본래 열경화성일 수도 있다.
중합체는 또한 당해 분야에 공지된 임의의 열가소성 물질일 수도 있으며, 예를 들면 폴리에스테르, 폴리우레탄, 폴리알킬렌 테레프탈레이트, 폴리설폰, 폴리이미드, 폴리페닐렌 에테르, 스티렌계 중합체, 폴리카보네이트, 아크릴계 중합체, 폴리아미드, 폴리아세탈, 할라이드 함유 중합체, 및 폴리올레핀 단독중합체 및 공중합체이다. 상이한 중합체들의 혼합물, 예를 들어 폴리페닐렌 에테르/스티렌계 수지 블렌드, 폴리비닐클로라이드/ABS 또는 다른 충격성 개질된 중합체, 예를 들어 메타크릴로니트릴 및 알파메틸스티렌 함유 ABS, 및 폴리에스테르/ABS 또는 폴리카보네이트/ABS 및 폴리에스테르 + 몇가지 다른 충격성 개질제가 또한 사용될 수도 있다. 상기 충합체들은 시판중이거나, 또는 당해 분야에 공지된 수단에 의해 제조될 수도 있다. 그러나, 본 발명의 포스파이트는, 열가소성 중합체가 종종 과도한 온도에서가공되고/되거나 사용되기 때문에, 열가소성 중합체, 예를 들어 폴리올레핀, 폴리카보네이트, 폴리에스테르, 폴리페닐렌 에테르 및 스티렌계 증합체에 특히 유용하다.
모노올레핀과 디올레핀의 중합체(예를 들어 폴리프로필렌, 폴리이소부틸렌, 폴리부텐-1, 폴리메틸펜텐-1, 폴리이소프렌 또는 폴리부타디엔) 뿐만 아니라 사이클로올레핀의 중합체(예를 들어 사이클로펜텐 또는 노르보넨), 폴리에틸렌(임의로 가교결합할 수 있음)(예를 들어 고밀도 폴리에틸렌(HDPE), 저밀도 폴리에틸렌(LDPE) 및 선형 저밀도 폴리에틸렌(LLDPE))이 사용될 수도 있다. 상기 중합체들의 혼합물, 예를 들어 폴리프로필렌과 폴리이소부틸렌의 혼합물, 폴리프로필렌과 폴리에틸렌의 혼합물(예를 들어, PP/HDPE, PP/LDPE) 및 상이한 유형의 폴리에틸렌의 혼합물(예를 들어 LDPE/HDPE)이 또한 사용될 수 있다. 또한 모노올레핀과 디올레핀 서로간의 또는 다른 비닐 단량체와의 공중합체 예를 들어, 에틸렌/프로필렌, LLDPE 및 LLDPE와 LDPE의 혼합물, 프로필렌/부텐-1, 에틸렌/헥센, 에틸렌/에틸펜텐, 에틸렌/헵텐, 에틸렌/옥텐, 프로필렌/이소부틸렌, 에틸렌/부탄-1, 프로필렌/부타디엔, 이소부틸렌, 이소프렌, 에틸렌/알킬 아크릴레이트, 에틸렌/알킬 메타크릴레이트, 에틸렌/비닐 아세테이트(EVA) 또는 에틸렌/아크릴산 공중합체(EAA) 및 이들의 염(이오노머) 및 에틸렌과 프로필렌 및 디엔(예를 들어, 헥사디엔, 디사이클로펜타디엔 또는 에틸리덴-노르보넨)의 삼원혼성중합체; 뿐만 아니라 이들 공중합체의 혼합물 및 이들과 상기 언급한 중합체와의 혼합물, 예를 들어 폴리프로필렌/에틸렌 프로필렌-공중합체, LDPE/EVA, LDPE,/EAA, LLDPE/EVA 및LLDPE/EAA 도 유용하다.
열가소성 중합체는 또한 스티렌계 중합체, 예를 들어 폴리스티렌, 폴리-(p-메틸스티렌), 폴리-(α-메틸스티렌), 스티렌 또는 α -메틸스티렌과 디엔 또는 아크릴계 유도체의 공중합체, 예를 들어 스티렌/부타디엔 스티렌/아크릴로니트릴, 스티렌/알킬 메타크릴레이트, 스티렌/말레산 무수물, 스티렌/부타디엔/에틸 아크릴레이트, 스티렌/아크릴로니트릴/메틸아크릴레이트, 스티렌 공중합체와 또다른 중합체 (예를 들어 폴리아크릴레이트)의 고충격강도 혼합물, 디엔 중합체 또는 에틸렌/프로필렌/디엔 삼원혼성중합체: 및 스티렌의 블록 공중합체, 예를 들어 스티렌/부타디엔/스티렌, 스티렌/이소프렌/스티렌, 스티렌/에틸렌/부틸렌/스티렌 또는 스티렌/에틸렌/프로필렌 스티렌을 포함할 수도 있다. 스티렌계 중합체는 추가적으로 또는 선택적으로 스티렌 또는 알파-메틸스티렌의 그라프트 공중합체, 예를 들어 폴리부타디엔상의 스티렌, 폴리부타디엔-스티렌상의 스티렌 또는 폴리부타디엔-아크릴로니트릴상의 스티렌; 폴리부타디엔상의 스티렌 및 아크릴로니트릴(또는 메타크릴로니트릴) 및 이들의 공중합체; 폴리부타디엔상의 스티렌 및 말레산 무수물 또는 말레이미드; 폴리부타디엔상의 스티렌, 아크릴로니트릴 및 말레산 무수물 또는 말레이미드; 폴리부타디엔상의 스티렌, 아크릴로니트릴 및 메틸 메타크릴레이트, 폴리부타디엔상의 스티렌 및 알킬 아크릴레이트 또는 메타크릴레이트, 에틸렌/프로필렌/디엔 삼원혼성중합체상의 스티렌 및 아크릴로니트릴, 폴리아크릴레이트 또는 폴리메타크릴레이트상의 스티렌 및 아크릴로니트릴, 아크릴레이트/부타디엔 공중합체상의 스티렌 및 아크릴로니트릴 뿐만 아니라 상기 언급한 스티렌계공중합체와의 혼합물을 포함할 수 있다.
니트릴 중합체도 또한 본 발명의 중합체 조성물에 유용하다. 니트릴 중합체로는 아크릴로니트릴 및 그의 유사체의 단독중합체 및 공중합체, 예를 들어 폴리메타크릴로니트릴, 폴리아크릴로니트릴, 아크릴로니트릴/부타디엔 중합체, 아크릴로니트릴/알킬 아크릴레이트 중합체, 아크릴로니트릴/알킬 메타크릴레이트/부타디엔 중합체 및 스티렌계와 관련하여 상기 언급한 다양한 ABS 조성물이 있다.
아크릴산, 예를 들어 아크릴산, 메타크릴산, 메틸 메타크릴산 및 에타크릴산, 및 이들의 에스테르를 기재로 하는 중합체들도 또한 사용될 수 있다. 이러한 중합체는 폴리메틸메타크릴레이트, 및 아크릴로니트릴 유형의 단량체의 전부 또는 일부가 아크릴산 에스테르 또는 아크릴산 아미드로 치환된 ABS형 그라프트 공중합체를 포함한다. 다른 아크릴형 단량체, 예를 들어 아크롤레인, 메타크롤레인, 아크릴아미드 및 메타크릴아미드를 포함하는 중합체도 또한 사용될 수 있다.
할로겐-함유 중합체도 또한 유용할 수 있다. 이들 중합체로는 수지, 예를 들어 폴리클로로프렌, 에피클로로히드린 단독중합체 및 공중합체, 폴리비닐 클로라이드, 폴리비닐 브로마이드, 폴리비닐 플루오라이드, 폴리비닐리덴 클로라이드, 염화 폴리에틸렌, 염화 폴리프로필렌, 플루오르화 폴리비닐리덴, 브롬화 폴리에틸렌, 염화고무, 비닐 클로라이드 비닐 아세테이트 공중합체, 비닐 클로라이드-에틸렌 공중합체, 비닐 클로라이드-프로필렌 공중합체, 비닐 클로라이드-스티렌 공중합체, 비닐 클로라이드-이소부틸렌 공중합체, 비닐 클로라이드-비닐리덴 클로라이드 공중합체, 비닐 클로라이드-스티렌-말레산 무수물 삼원혼성중합체, 비닐 클로라이드-스티렌-아크릴로니트릴 공중합체, 비닐 클로라이드-부타디엔 공중합체, 비닐 클로라이드 이소프렌 공중합체, 비닐 클로라이드-염화 프로필렌 공중합체, 비닐 클로라이드-비닐리덴 클로라이드-비닐 아세테이트 삼원혼성중합체, 비닐 클로라이드-아크릴산 에스테르 공중합체, 비닐 클로라이드-말레산 에스테르 공중합체, 비닐 클로라이드-메타크릴산에스테르 공중합체, 비닐 클로라이드-아크릴로니트릴 공중합체 및 내부적으로 가소화된(internally platicized) 폴리비닐 클로라이드가 있다.
다른 유용한 열가소성 중합체로는 환상 에테르의 단독중합체 및 공중합체 예를 들어 폴리알킬렌 글리콜, 폴리에틸렌 옥사이드, 폴리프로필렌 옥사이드 또는 이들과 비스-글리시딜 에테르와의 공중합체; 및 폴리아세탈, 예를 들어 폴리옥시메틸렌 및 공단량체로서 에틸렌 옥사이드를 함유하는 폴리옥시메틸렌; 열가소성 폴리우레탄으로 개질된 폴리아세탈, 아크릴레이트 또는 메타크릴로니트릴을 함유하는 ABS; 폴리페닐렌 옥사이드 및 설파이드, 및 폴리페닐렌 옥사이드와 폴리스티렌 또는 폴리아미드의 혼합물; 폴리카보네이트 및 폴리에스테르-카보네이트; 폴리설폰, 폴리에테르설폰 및 폴리에테르케톤; 및 디카복실산 및 디올 및/또는 하이드록시카복실산 또는 상응하는 락톤으로부터 유도되는 폴리에스테르, 예를 들어 폴리에틸렌 테레프탈레이트, 폴리부틸렌 테레프탈레이트, 폴리-1,4-디메틸올-사이클로헥산 테레프탈레이트, 폴리-2(2,2,4(4-하이드록시페닐)-프로판) 테레프탈레이트 및 폴리하이드록시벤조에이트 뿐만 아니라 하이드록실 말단기를 갖는 폴리에테르로부터 유도된 블록 코폴리에테르에스테르가 있다.
디아민 및 디카복실산 및/또는 아미노카복실산 또는 상응하는 락탐으로부터유도되는 폴리아미드 및 코폴리아미드, 예를 들어 폴리아미드 4, 폴리아미드 6, 폴리아미드 6/6, 6/10, 6/9, 6/12 및 4/6, 폴리아미드 11, 폴리아미드 12, 및 m-크실렌, 디아민 및 아디프산의 축합 반응에 의해 수득한 방향족 폴리아미드; 헥사메틸렌 디아민 및 이소프탈산 또는/및 테레프탈산으로부터 제조된 폴리아미드 및 임의로 탄성중합체, 예를 들어 폴리-2,4,4-트리메틸헥사메틸렌 테레프탈아미드 또는 폴리-m-페닐렌 이소프탈아미드가 개질제로 사용될 수 있다. 또한, 상기 언급한 폴리아미드와 폴리올레핀, 올레핀 공중합체, 이오노머 또한 화학결합하거나 그라프트화된 탄성중합체와의 공중합체; 또는 상기한 폴리아미드와 폴리에테르, 예를 들어 폴리에틸렌 글리콜, 폴리프로필렌 글리폴 또는 폴리테트라메틸렌 글리콜과의 공중합체, 및 EPDM 또는 ABS로 개질된 폴리아미드 또는 코폴리아미드가 사용될 수도 있다.
더욱 바람직한 것은 폴리올레핀, 폴리알킬렌 테레프탈레이트, 폴리페닐렌 에테르 및 스티렌계 수지, 및 이들의 혼합물이고, 특히 바람직한 것은 폴리에틸렌, 폴리프로필렌, 폴리에틸렌 테레프탈레이트, 폴리페닐렌 에테르 단독중합체 및 공중합체, 폴리스티렌, 고충격성 폴리스티렌, 폴리카보네이트 및 ABS형 그라프트 공중합체 및 이들의 혼합물이다.
본 발명의 생성된 안정화된 중합체 조성물은 또한 임의로 하기와 같은 다양한 통상의 첨가제를 함유할 수도 있다:
1. 산화 방지제
1.1 알킬화 모노페놀, 예를 들어 2,6-디-t-부틸-4-메틸페논, 2-t-부틸-4,6-디메틸페놀, 2,6-디-t-부틸-4-에틸페놀, 2,6-디-t-부틸-4-n-부틸페놀, 2,6-디-t-부틸-4--이소부틸페놀, 2,6-디사이클로펜틸-4-메틸페놀, 2-(알파-메틸사이클로헥실)-4,6-디메틸페놀, 2,6-디-옥타데실-4-메틸페놀, 2,4,6-트리사이클로헥실페놀, 2,6-디-t-부틸-4-메톡시메틸페놀.
1.2 알킬화 하이드로퀴논, 예를 들어, 2,6-디-t-부틸-4-메톡시페놀, 2,5-디-t-부틸-하이드로퀴논, 2,5-디-t-아밀-하이드로퀴논, 2,6-디페닐-4-옥타데실옥시페놀.
1.3 하이드록시화 티오디페닐 에테르, 예를 들어 2,2'-티오-비스-(6-t-부틸-4-메틸페놀), 2,2'-티오-비스-(4-옥틸페놀), 4,4'-티오-비스-(6-t-부틸-3-메틸페놀), 4,4'-티오-비스-(6-t-부틸-2-메틸페놀).
1.4 알킬리덴-비스페놀, 예를 들어, 2,2'-메틸렌-비스-(6-t-부틸-4-메틸페놀), 2,2'-메틸렌-비스-(6-t-부틸-4-에틸페놀), 2,2'-메틸렌-비스-(4-메틸-6-(알파-메틸사이클로헥실)페놀), 2,2'-메틸렌-비스-(4-메틸-6-사이클로헥실페놀), 2,2'-메틸렌-비스-(6-노닐-4-메틸페놀), 2,2'-메틸렌-비스-(6-노닐-4-메틸페놀), 2,2'-메틸렌-비스-(6-(알파-메틸벤질)-4-노닐페놀), 2,2'-메틸렌-비스-(6-(알파, 알파-디메틸벤질)-4-노닐-페놀). 2,2'-메틸렌-비스-(4,6-디-t-부틸페놀). 2,2'-에틸렌-비스-(6-t-부틸-4-이소부틸페놀), 4,4'-메틸렌-비스-2,6-디-t-부틸페놀). 4,4'-메틸렌-비스-(6-t-부틸-2-메틸페놀), 1,1-비스-(5-t-부틸-4-하이드록시-2-메틸페놀)부탄, 2,6-디-(3-t-부틸-5-메틸-2-하이드록시벤질)-4-메틸페놀, 1,1,3-트리스-(5-t-부틸-4-하이드록시-2-메틸페닐)부탄,1,1-비스-(5-t-부틸-4-하이드록시-2-메틸페닐)-3-도데실-머캅토부탄, 에틸렌글리콜-비스-(3,3-비스-(3'-t-부틸-4'-하이드록시페닐)부티레이트)-디-(3-t-부틸-4-하이드록시-5-메틸페닐)-디사이클로펜타디엔, 디-(2-(3'-t-부틸-2'-하이드록시-5'-메틸-벤질 )-6-t-부틸-4-메틸페닐)테레프탈레이트.
1.5 벤질 화합물, 예를 들어 1,3,5-트리스-(3,5-디-t-부틸-4--하이드록시벤질)-2,4,6-트리메틸벤젠, 비스-(3,5-디-t-부틸-4-하이드록시벤질)설파이드. 이소옥틸 3,5-디-t-부틸-4-하이드록시벤질-머캅토-아세테이트, 비스-(4-t-부틸-3-하이드록시-2,6-디메틸벤질)디티올-테레프탈레이트, 1,3,5-트리스-(3,5-디-t-부틸-4-하이드록시벤질)이소시아누레이트, 1,3,5-트리스-(4-t-부틸-3-하이드록시-2,6-디메틸벤질)이소시아누레이트, 디옥타데실 3,5-디-t-부틸-4-하이드록시벤질-포스포네이트, 모노에틸 3,5-디-t-부틸-4-하이드록시벤질포스포네이트의 칼슘 염, 1,3,5-트리스- (3,5-디사이클로헥실-4-하이드록시벤질)이소시아누레이트.
1.6 아실아미노페놀, 예를 들어 4-하이드록시-라우르산 아닐리드, 4-하이드록시-스테아르산 아닐리드, 2,4-비스-옥틸머캅토-6-(3,5-t-부틸-4-하이드록시아닐리노)-s-트리아진, 옥틸 -N-(3,5-디-t-부틸-4-하이드록시페닐)-카바메이트.
1.7 베타-(3,5-디-t-부틸-4-하이드록시페놀)-프로피온산과 일가 또는 다가 알콜(예를 들어 메탄올, 디에틸렌글리콜, 옥타데카놀, 트리에틸렌글리콜, 1,6-헥산디올, 펜타-에리트리톨, 네오펜틸글리콜, 트리스-하이드록시에틸 이소시아누레이트, 티오디에틸렌글리콜, 디-하이드록시에틸 옥살산 디아미드)의 에스테르.
1.8 베타-(5-t-부틸-4-하이드록시-3-메틸페닐)-프로피온산과 일가 또는 다가알콜(예를 들어 메탄올, 디에틸렌글리콜, 옥타데카놀, 트리에틸렌글리콜, 1,6-헥산디올, 펜타에리트리톨, 네오펜틸글리콜, 트리스-하이드록시에틸 이소시아누레이트, 티디에틸렌글리콜, 디하이드록시에틸 옥살산 디아미드)의 에스테르.
1.9 베타-(5-t-부틸-4-하이드록시-3-메틸페닐)프로피온산과 일가 또는 다가 알콜(예를 들어 메탄올, 디에틸렌 글리콜, 옥타데카놀, 트리에틸렌 글리콜, 1,6-헥산디올, 펜타에리트리톨, 네오펜틸 글리콜, 트리스(하이드록시에틸) 이소시아누레이트, 티오디에틸렌 글리콜, N,N-비스(하이드록시에틸) 옥살산 디아미드)의 에스테르.
1.10 베타-(3,5-디-t-부틸-4-하이드록시페놀)-프로피온산의 아미드, 예를 들어, N,N'-디-(3,5-디-t-부틸-4-하이드록시페닐프로피오닐)-헥사메틸렌-디아민, N,N'-디-(3,5-디-t-부틸-4-하이드록시페닐프로피오닐)트리메틸렌디아민, N,N'-디-(3,5-디-t-부틸-4-하이드록시페닐프로피오닐)-하이드라진.
2. UV 흡수제 및 광 안정제
2.1 2-(2'-하이드록시페닐)-벤조트리아졸, 예를 들어 5'-메틸-, 3',5'-디-t-부틸-, 5'-t-부틸-, 5'-(1,1,3,3-테트라메틸부틸)-, 5-클로로-3',5'-디-t-부틸-, 5-클로로-3'-t-부틸-5'-메틸-, 3'-s-부틸-5'-t-부틸-, 4'-옥톡시 , 3',5'-디-t-아밀-3',5'-비스-(알파,알파-디메틸벤질) 유도체.
2.2 2-하이드록시-벤조페논, 예를 들면 4-하이드록시-4-데톡시-, 4-옥톡시, 4-데실옥시-, 4-도데실옥시-, 4-벤질옥시, 4,2',4'-트리하이드록시- 및 2'-하이드록시-4,4'-디메톡시 유도체.
2.3 치환 및 비치환된 벤조산의 에스테르, 예를 들어 폐닐 살리실레이트, 4-t-부틸페닐-살리실레이트, 옥틸페닐 살리실레이트, 디벤조일레조르시놀, 비스-(4-t-부틸벤조일)-레조르시놀, 벤조일레조르시놀, 2.4-디-t-부틸-페닐-3,5-디-t-부틸-4-하이드록시벤조에이트 및 헥사데실-3,5-디-t-부틸-4-하이드록시벤조에이트.
2.4 아크릴레이트, 예를 들면 알파-시아노-베타, 베타-디페닐아크릴산-에틸 에스테르 또는 이소옥틸 에스테르, 알파-카보메톡시-신남산 메틸 에스테르, 알파-시아노-베타-메틸-p-메톡시-신남산 메틸 에스테르 또는 부틸 에스테르, 알파-카보메톡시-p-메톡시-신남산 메틸 에스테르, N-(베타-카보메톡시-베타-시아노-비닐)-2-메틸-인돌린.
2.5 니켈 화합물, 예를 들어 2,2'-티오-비스(4-(1,1,1,3-테트라메틸부틸)페놀)의 니켈 착화합물, 예를 들어 임의로 추가의 리간드(예: n-부틸아민, 트리에탄올아민 또는 N-사이클로헥실디에탄올아민)를 갖는 1:1 또는 1:2 착화합물, 니켈 디부틸디티오카바메이트, 4-하이드록시-3,5-디-t-부틸벤질포스폰산 모노알킬 에스테르(예: 메틸, 에틸 또는 부틸 에스테르)의 니켈 염, 케톡심(예: 2-하이드록시-4-메틸-페닐 운데실 케톡심)의 니켈 착화합물, 임의로 추가의 리간드를 갖는 1-페닐-4-라우로일-5-하이드록시-피라졸의 니켈 착화합물.
2.6 입체장애 아민, 예를 들어 비스(2,2,6,6-테트라메틸피페리딜)세바케이트, 비스(1,2,2,6,6-펜타메틸피페리딜)세바케이트, n-부틸-3,5-디-t-부틸-4-하이드록시벤질 말론산 비스(1,2,2,6,6-펜타메틸피페리딜)에스테르, 1-하이드록시에틸-2,2,6,6-테트라메틸-4-하이드록시-피페리딘과 숙신산의 축합 생성물, N,N'-(2,2,6,6-테트라메틸피페리딜)헥사메틸렌디아민과 4-t-옥틸아미노-2,6-디클로로-1,3,5-s-트리아진의 축합 생성물, 트리스-(2,2,6,6-테트라메틸피페리틸)니트릴로트리아세테이트, 테트라키스-(2,2,6,6-테트라메틸-4-피페리딜 )-1,2,3,4-부탄-테트라-카본산, 1,1'-(1,2-에탄디일)-비스-(3,3,5,5-테트라메틸피페라지논). 이러한 아민으로는 장애 아민으로부터 유도된 하이드록실아민, 예를 들어 디(1-하이드록시-2,2,6,6-테트라메틸피페리딘-4-일)세바케이트; 1-하이드록시-2,2,6,6-테트라메틸-4-벤족시피페리딘; 1-하이드록시-2,2,6,6-테트라메틸-4-(3,5-디-t-부틸-4-하이드록시 하이드로신나모일옥시)-피페리딘; 및 N-(1-하이드록시-2,2,6,6-테트라메틸피페리딘-4-일)-ε-카프로락탐.
2.7 옥살산 디아미드, 예를 들어 4,4'-디옥틸옥시옥사닐리드, 2,2'-디-옥틸옥시-5',5'-디-t-부틸옥사닐리드, 2,2'-디-도데실옥시-5',5'-디-t-부틸옥사닐리드, 2-에톡시-2'-에틸옥사닐리드, N,N'-비스(3-디메틸아미노프로필)옥살아미드, 2-에톡시-5-t-부틸-2'-에틸옥사닐리드 및 이들과 2-에톡시-2'-에틸-5,4-디-t-부틸옥사닐리드의 혼합물 및 오르토- 및 파라-메톡시-뿐만 아니라 o- 및 p-에톡시-이치환된 옥사닐리드의 혼합물.
3. 금속 탈활성제, 예를 들어 N,N'-디페닐옥살산 디아미드, N-살리실알-N'-살릴실로일히드라진, N,N'-비스-살릴실로일히드라진, N,N'-비스-(3,5-디-t-부틸-4-하이드로페닐프로피오닐)-히드라진, 살리실로일아미노-1,2,4-트리아졸, 비스-벤질리덴-옥살산 디히드라지드.
4. 포스파이트 및 포스포나이트, 예를 들어 트리페닐 포스파이트, 디페닐알킬 포스파이트, 페닐디알킬 포스파이트, 트리스(노닐페닐)포스파이트, 트리라우릴 포스파이트, 트리옥타데실 포스파이트, 디스테아릴펜타에리트리톨 디포스파이트, 트리스(2,4-디-t-부틸페닐)포스파이트, 디이소데실펜타에리트리톨 디포스파이트, 비스(2,4-디-t-부틸페닐)펜타에리트리톨 디포스파이트, 트리스테아릴 소르비톨 트리포스파이트, 및 테트라키스(2,4-디-t-부틸페닐)4,4'-비페닐렌 디포스포나이트.
5. 과산화물 소거제, 예를 들어 베타티오디프로피온산의 에스테르, 예를 들어 라우릴, 스페아릴, 미리스틸 또는 트리데실 에스테르, 머캅토벤즈이미다졸, 또는 2-머캅토벤즈이미다졸의 아연 염, 아연-디부틸디티오카바메이트, 디옥타데실디설파이드, 펜타에리트리톨테트라키스-(베타-도데실머갑토)프로피오네이트.
6. 폴리아미드 안정제. 예를 들어 요오다이드 및/또는 인 화합물과의 구리 염 및 2가 망간의 염.
7. 염기성 보조-안정제, 예를 들어 멜라민, 폴리비닐피롤리돈, 디시안디아미드, 트리알릴 시아누레이트, 우레아 유도체, 히드라진 유도체, 아민, 폴리아미드, 폴리우레탄, 고급 지방산의 알칼리 금속 염 및 알칼리 토금속 및, 예를 들어 Ca 스테아레이트, 칼슘 스테아로일 락테이트, 칼슘 락테이트, Zn 스테아레이트, Mg 스테아레이트, Na 리시놀리에이트 및 K 팔미테이트, 안티몬 피로카테콜레이트 또는 아연 피로카테콜레이트.
8. 핵 생성제(nucleating agent), 예를 들어 4-t-부틸벤조산, 아디프산, 디페닐아세트산.
9. 충진제 및 보강제, 예를 들어 탄산칼슘, 실리케이트, 유리 섬유, 석면,활석, 카올린, 운모, 황산바륨, 금속 산화물, 금속 수산화물, 카본블랙 및 흑연.
10. 본 발명은 아미녹시 프로파노에이트 유도체, 예를 들어 메틸-3-(N,N-디벤질아미녹시)프로파노에이트; 에틸-3-(N,N-디벤질아미녹시)프로파노에이트; 1,6-헥사메틸렌-비스(3-N,N-디벤질아미녹시)프로파노에이트; 메틸-(2-(메틸)-3-N,N-디벤질아미녹시)프로파노에이트); 옥타데실-3-(N,N-디벤질아미녹시)프로파노산; 테트라키스(N,N-디벤질아미녹시)에틸 카보닐옥시메틸)메탄; 옥타데실-3-(N,N-디에틸아미녹시)프로파노에이트; 3-(N,N-디벤질아미녹시)프로파노산 칼륨 염; 및 1,6-헥사메틸렌, 비스(3-(N-알릴-N-도데실 아미녹시)프로파노에이트)와 함께 사용될 수 있다.
11. 다른 첨가제, 예를 들어 가소제, 윤활제, 유화제, 안료, 형광증백제, 방염제, 대전방지제, 발포제 및 티오상승제, 예를 들어 디라우릴티오디프로피오네이트 또는 디스테아릴티오디프로피오네이트.
중합체 입자를 본 발명의 포스파이트만으로 또는 중합체 물질의 안정화를 위한 다른 안정제와 함께 본 발명의 포스파이트로 피복할 수 있다. 입자들은 구형일 수 있으며, 본원에 참고로 인용된 갈리(P. Galli) 및 할록크(J.C. Halock)의 문헌[The Reactor Granule-A Unique Technology for the Production of a New Generation of Polymer Blends, Society of Plastics Engineers, Polyolefin III International Conference February 24-27, 1991] 및 페드라제쓰(Pedrazzeth) 등의 미합중국 특허 제 4708979 호[발명의 명칭 Process for the Stabilization of Spherically Polymerized Polyolefins](허여일: 1987. 11. 24)에 기술된 "반응기과립 기술(Reactor Granule Technology)"과 같은 공정에 의해 제조될 수 있다. 지지된 지글러-나타(Ziegler-Natta) 촉매제에 의해 입자를 제조할 수 있다. 적합한 상업적인 공정은 상표명 Spheripol, Addipol 및 Spherilene 으로 공지되어 있다.
올레핀 중합체는 임의로 지지체, 예를 들어 MgCl2상의 지글러-나타 촉매, 임의로 실리카 또는 다른 물질상에 지지된 크롬 염 및 이들의 착화합물의 존재하에 올레핀의 중합에 의해 제조될 수도 있다. 이들은 또한 금속, 전형적으로 Ti 또는 Zr의 사이클로펜타디엔 착화합물을 기재로 하는 촉매를 사용하여 제조될 수도 있다.
본 발명의 포스파이트는 제품으로 제조하기 전에 또는 제조도중에 어느 때라도 중합체에 첨가할 수 있으며, 당해 분야에 공지된 다양한 수단에 의해, 예를 들어 예비혼합하거나 제조장치에 직접 공급하여 중합체와 혼합될 수도 있다.
폴리프로필렌 조성물은 지지체상에서 운반될 수도 있는 지글러촉매(즉, MgCl2상의 TiCl3)와 같은 잔류 촉매를 포함할 수도 있다. 다른 안정제도 또한 조성물에 혼입될 수 있다.
실시예
하기 실시예들은 폴리프로필렌내에서 본 발명의 포스파이트의 열산화 안정화 능력을 예시한다. 실시예 A와 B 및 1과 2에서 조성물은 600ppm의 포스파이트, 500ppm의 페놀계 산화방지제(시바-가이기(Ciba-Geigy)에서 시판중인 Irganox 1010), 500ppm의 칼슘 스테아레이트를 함유하는 폴리프로필렌이다. 실시예 A는 시판중인 포스파이트이다.
실시예 A와 1 및 2에서 YI 값은 제 5 회 압출후 폴리프로필렌 조성물의 황색도 지수이고, △YI 는 제 1 회 압출에서 제 5 회 압출까지의 황색도 지수의 변화이고; MF는 제 5회 압출후 230℉ 에서의 용융유동 지수이고; △MF 는 제 1 회 압출에서 제 5 회 압출까지의 용융 유동 지수의 변화이다. 조성물의 압출 공정은 다음과 같다:
장치: 2단계 스크류(3:1 압축비) 및 2:1의 매독스(Maddox) 혼합요소, 및 개시 및 퍼지 사이클도중 블렌드 #1에 설정된 스크류 RPM 100, 배압 1000PSI를 갖는 1" 킬리온(killion) 압출기. 성분들을 30분동안 터뷸라 블렌더(Turbula Blender)를 사용하여 혼합하였다. 액상 첨가제를 칭량하여 소량의 수지에 가하고, 웨어링 블렌더(Waring Blender)를 사용하여 대략 1핀트의 수지에 가하여 혼합하였다. 첨가제와 수지의 혼합물을 나머지 수지에 가하고, 30분 동안 터뷸라 블렌더에 넣었다. 압출기의 온도 변화: 후방 200℃, 중간: 240℃, 전방: 258℃, 다이 260℃, 실제 원료(stock) 온도=262℃. HS는 60℃/75% 상대 습도에서 매일 포스파이트의 50%가 손실됨을 시험하여 측정한 중합체에서의 포스파이트 조성물의 가수분해 안정성이고; UV는 자외선에 노출되었을 때의 황변도이고, "P"는 황변하지 않았음을 나타내고, "F"는 황변하였음을 나타낸다. 가수분해 안정성은 x 탄소상에서 벌크를 필요로 하고, 최소의 β 탄화수소를 필요로 한다. 실시예 A, B 및 C는 비교예이다. 실시예1 내지 7은 본 발명을 예시한다.
P-7에 대한 P-4 및 P-8에 대한 P-3의 개선된 가수분해 안정성에 주목해야 한다. I168은 트리(2,4-디-t-부틸페닐)포스파이트이다.
Claims (1)
- (a) 폴리올레핀, 폴리에스테르, 폴리카보네이트, 고무 재질된 그라프트 공중합체, 폴리아미드, 폴리에테르이미드, 폴리페닐렌 에테르, 폴리비닐할라이드, 폴리스티렌 및 폴리우레탄으로 이루어진 그룹 중에서 선택된 중합체, 및(b) 일반식의포스파이트를 중합체 100중량부당 0.01 내지 2중량부로 포함하는중합체 조성물:상기 식에서,각각의 R1은 C1-C10알킬 라디칼로 이루어진 그룹중에서 독립적으로 선택되고,각각의 R2는 수소 및 C3-C20알킬 라디칼로 이루어진 그룹중에서 독립적으로 선택되나, 단, 하나 이상의 R2는 알킬 라디칼이고,R3는 6개 이상의 탄소원자를 갖는 탄화수소 라디칼이나,단, 상기 포스파이트는 인 원자에 결합된 산소원자에 대해 β-탄소원자에 직접 결합된 수소원자를 갖지 않는다.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US9611393A | 1993-07-22 | 1993-07-22 | |
US8/096,113 | 1993-07-22 | ||
US08/096,113 | 1993-07-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR950003307A KR950003307A (ko) | 1995-02-16 |
KR100367275B1 true KR100367275B1 (ko) | 2003-04-23 |
Family
ID=22255426
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019940017560A KR100367275B1 (ko) | 1993-07-22 | 1994-07-21 | 포스파이트를 포함하는 중합체 조성물 |
Country Status (6)
Country | Link |
---|---|
US (1) | US5464889A (ko) |
EP (1) | EP0635512B1 (ko) |
JP (1) | JP3605145B2 (ko) |
KR (1) | KR100367275B1 (ko) |
DE (1) | DE69423147T2 (ko) |
ES (1) | ES2142379T3 (ko) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0779294A1 (de) * | 1995-12-15 | 1997-06-18 | Hoechst Aktiengesellschaft | Halogenfreie cyclische Phosphorsäureester und Verfahren zu ihrer Herstellung |
ES2154111B1 (es) * | 1996-09-25 | 2001-10-16 | Witco Vinyl Additives Gmbh | Bisfosfitos monomeros y oligomeros como estabilizadores del poli(cloruro de vinilo). |
US5969015A (en) * | 1996-09-25 | 1999-10-19 | Witco Vinyl Additives Gmbh | Monomeric and oligomeric bisphosphites as stabilisers for polyvinyl chloride |
KR100431062B1 (ko) * | 1997-03-12 | 2004-07-27 | 제일모직주식회사 | 비자성 1성분 흑색 토너 입자의 제조방법 |
KR100347315B1 (ko) * | 1997-12-22 | 2003-02-19 | 제일모직주식회사 | 비자성 일성분 흑색 토너의 제조방법 |
US6369157B1 (en) | 2000-01-21 | 2002-04-09 | Cyclics Corporation | Blend material including macrocyclic polyester oligomers and processes for polymerizing the same |
US6420047B2 (en) | 2000-01-21 | 2002-07-16 | Cyclics Corporation | Macrocyclic polyester oligomers and processes for polymerizing the same |
AU2001288663A1 (en) | 2000-09-01 | 2002-03-13 | Cyclics Corporation | Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters |
US6436548B1 (en) | 2000-09-12 | 2002-08-20 | Cyclics Corporation | Species modification in macrocyclic polyester oligomers, and compositions prepared thereby |
US6420048B1 (en) | 2001-06-05 | 2002-07-16 | Cyclics Corporation | High molecular weight copolyesters from macrocyclic oligoesters and cyclic esters |
ATE396184T1 (de) | 2001-06-27 | 2008-06-15 | Cyclics Corp | Formgebende verarbeitung von makrozyklischen oligoestern |
US6436549B1 (en) | 2001-07-16 | 2002-08-20 | Cyclics Corporation | Block copolymers from macrocyclic oligoesters and dihydroxyl-functionalized polymers |
US20050009967A1 (en) * | 2003-06-12 | 2005-01-13 | Hayder Zahalka | Phosphite stabilizers and methods to preparation and polymer composition thereof |
WO2010080285A2 (en) * | 2008-12-18 | 2010-07-15 | Dow Global Technologies Inc. | Stabilizers for polymers containing aliphatically-bound bromine |
US8816211B2 (en) | 2011-02-14 | 2014-08-26 | Eastman Kodak Company | Articles with photocurable and photocured compositions |
US20120207935A1 (en) | 2011-02-14 | 2012-08-16 | Deepak Shukla | Photocurable inks and methods of use |
US20120208914A1 (en) | 2011-02-14 | 2012-08-16 | Deepak Shukla | Photoinitiator compositions and uses |
KR20200026516A (ko) * | 2018-09-03 | 2020-03-11 | 현대자동차주식회사 | 조명용 빛몰림 저감 광섬유 및 그 제조방법 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3467733A (en) * | 1965-11-26 | 1969-09-16 | Hooker Chemical Corp | Cyclic esters of phosphorus and a process for the preparation thereof |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3056823A (en) * | 1956-05-31 | 1962-10-02 | Hooker Chemical Corp | Transesterification process for making trialiphatic phosphite esters |
US3281381A (en) * | 1958-06-17 | 1966-10-25 | Hooker Chemical Corp | Reaction products of pentaerythritol and phosphites as vinyl chloride stabilizer |
FR1277898A (fr) * | 1960-01-27 | 1961-12-01 | Weston Chemical Corp | Procédé de préparation d'esters d'acide phosphoreux et phosphites obtenus par ce procédé |
US3149181A (en) * | 1960-04-28 | 1964-09-15 | Union Carbide Corp | Polypropylene stabilized with an astage para-tertiary alkylphenolformaldehyde resin and a phosphorous containing compound |
US3039993A (en) * | 1960-05-10 | 1962-06-19 | Weston Chemical Corp | Polyethylene stabilizers |
US3133043A (en) * | 1960-09-15 | 1964-05-12 | Rosett Chemicals Inc | Composition comprising halogen-containing resin and a diphosphite stabilizer |
US3264247A (en) * | 1962-09-07 | 1966-08-02 | Union Carbide Corp | Pentyl isobutyrate phosphite plastizer-stabilizer |
US3415906A (en) * | 1964-05-29 | 1968-12-10 | Hooker Chemical Corp | Phosphite phospholane and phosphorinane compounds |
US3342767A (en) * | 1964-06-10 | 1967-09-19 | Ferro Corp | Vinyl chloride resins containing cyclic phosphites |
US3305526A (en) * | 1964-07-07 | 1967-02-21 | Weston Chemical Corp | Phenoxy phosphite polymers |
US3305520A (en) * | 1965-04-06 | 1967-02-21 | Bayer Ag | Polycarbonates stabilized by phosphites |
US3457331A (en) * | 1965-10-23 | 1969-07-22 | Weston Chemical Corp | Neo carboxylate tetrol diphosphites |
US3488407A (en) * | 1965-11-26 | 1970-01-06 | Hooker Chemical Corp | Cyclic esters of phosphorus |
US3441633A (en) * | 1965-12-03 | 1969-04-29 | Weston Chemical Corp | Cyclic phosphites |
US3558554A (en) * | 1966-06-09 | 1971-01-26 | Yoshitomi Pharmaceutical | Oxidatively stable polyolefin composition |
US3482002A (en) * | 1966-07-27 | 1969-12-02 | Hooker Chemical Corp | Phosphorus acid-carboxylic acid anhydrides |
US3437720A (en) * | 1966-08-03 | 1969-04-08 | Weston Chemical Corp | Carboxylated hydroxy phosphites |
US3509091A (en) * | 1967-07-20 | 1970-04-28 | Mobay Chemical Corp | Polycarbonates stabilized with cyclic phosphites |
US3646173A (en) * | 1969-05-29 | 1972-02-29 | Hooker Chemical Corp | Process for preparing bisphosphite esters of alkylidene diphenol |
US3714302A (en) * | 1969-07-08 | 1973-01-30 | Borg Warner | Preparation of neoalkyl phenyl phosphite |
US3845168A (en) * | 1970-01-16 | 1974-10-29 | Weston Chemical Corp | Trimethylol propane phosphite |
DE2140207C3 (de) * | 1971-08-11 | 1975-11-27 | Farbenfabriken Bayer Ag, 5090 Leverkusen | Stabilisiertes aromatisches PoIycarbonat |
NL7506988A (nl) * | 1975-06-12 | 1976-12-14 | Akzo Nv | Organische trifosfieten met verbeterde hydrolyti- sche stabiliteit. |
US4755546A (en) * | 1981-05-11 | 1988-07-05 | Borg-Warner Chemicals, Inc. | Stabilized olefin polymers |
US4405739A (en) * | 1981-11-17 | 1983-09-20 | General Electric Company | Polyphenylene ether resins and compositions heat stabilized with phosphite compounds |
US4708979A (en) * | 1985-05-02 | 1987-11-24 | Ciba-Geigy Corporation | Process for the stabilization of spherically polymerized polyolefins |
JPH0621211B2 (ja) * | 1985-08-13 | 1994-03-23 | 旭電化工業株式会社 | 塩化ビニル樹脂組成物 |
US4782170A (en) * | 1986-05-13 | 1988-11-01 | Argus Chemical Corporation | Liquid polyvinyl chloride resin stabilizer systems based on complexes of organic triphosphites with zinc chloride |
US4882374A (en) * | 1989-02-06 | 1989-11-21 | Eastman Kodak Company | Dioxaphosphorinane compounds and polyolefin compositions sabilized therewith |
US4956406A (en) * | 1989-08-03 | 1990-09-11 | Eastman Kodak Company | Bis-cyclic phosphite compounds and polymeric materials stabilized therewith |
-
1994
- 1994-07-05 ES ES94304915T patent/ES2142379T3/es not_active Expired - Lifetime
- 1994-07-05 EP EP94304915A patent/EP0635512B1/en not_active Expired - Lifetime
- 1994-07-05 DE DE69423147T patent/DE69423147T2/de not_active Expired - Fee Related
- 1994-07-20 JP JP16729594A patent/JP3605145B2/ja not_active Expired - Fee Related
- 1994-07-21 KR KR1019940017560A patent/KR100367275B1/ko not_active IP Right Cessation
- 1994-08-03 US US08/285,585 patent/US5464889A/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3467733A (en) * | 1965-11-26 | 1969-09-16 | Hooker Chemical Corp | Cyclic esters of phosphorus and a process for the preparation thereof |
Also Published As
Publication number | Publication date |
---|---|
EP0635512B1 (en) | 2000-03-01 |
JPH07179485A (ja) | 1995-07-18 |
KR950003307A (ko) | 1995-02-16 |
DE69423147T2 (de) | 2000-10-19 |
DE69423147D1 (de) | 2000-04-06 |
EP0635512A1 (en) | 1995-01-25 |
JP3605145B2 (ja) | 2004-12-22 |
ES2142379T3 (es) | 2000-04-16 |
US5464889A (en) | 1995-11-07 |
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