KR100268539B1 - 올레핀의 중합 및 공중합 방법,및 이를 위한 촉매 - Google Patents

올레핀의 중합 및 공중합 방법,및 이를 위한 촉매 Download PDF

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Publication number
KR100268539B1
KR100268539B1 KR1019930000870A KR930000870A KR100268539B1 KR 100268539 B1 KR100268539 B1 KR 100268539B1 KR 1019930000870 A KR1019930000870 A KR 1019930000870A KR 930000870 A KR930000870 A KR 930000870A KR 100268539 B1 KR100268539 B1 KR 100268539B1
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KR
South Korea
Prior art keywords
group
compound
formula
cocatalyst
metallocene
Prior art date
Application number
KR1019930000870A
Other languages
English (en)
Korean (ko)
Other versions
KR930016446A (ko
Inventor
안드레아스빈터
폴커돌레
발터스팔레크
Original Assignee
테르가울 발렌틴
훽스트 악티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6450335&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR100268539(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 테르가울 발렌틴, 훽스트 악티엔게젤샤프트 filed Critical 테르가울 발렌틴
Publication of KR930016446A publication Critical patent/KR930016446A/ko
Application granted granted Critical
Publication of KR100268539B1 publication Critical patent/KR100268539B1/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1019930000870A 1992-01-27 1993-01-25 올레핀의 중합 및 공중합 방법,및 이를 위한 촉매 KR100268539B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP4202163.40 1992-01-27
DE4202163 1992-01-27
DEP4202163.4 1992-01-27

Publications (2)

Publication Number Publication Date
KR930016446A KR930016446A (ko) 1993-08-26
KR100268539B1 true KR100268539B1 (ko) 2000-10-16

Family

ID=6450335

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930000870A KR100268539B1 (ko) 1992-01-27 1993-01-25 올레핀의 중합 및 공중합 방법,및 이를 위한 촉매

Country Status (11)

Country Link
US (1) US5985784A (US06818585-20041116-C00001.png)
EP (1) EP0553757B1 (US06818585-20041116-C00001.png)
JP (1) JP3459272B2 (US06818585-20041116-C00001.png)
KR (1) KR100268539B1 (US06818585-20041116-C00001.png)
AT (1) ATE143384T1 (US06818585-20041116-C00001.png)
AU (1) AU669684B2 (US06818585-20041116-C00001.png)
CA (1) CA2088114A1 (US06818585-20041116-C00001.png)
DE (1) DE59303908D1 (US06818585-20041116-C00001.png)
ES (1) ES2093287T3 (US06818585-20041116-C00001.png)
TW (1) TW304963B (US06818585-20041116-C00001.png)
ZA (1) ZA93548B (US06818585-20041116-C00001.png)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022035132A1 (ko) * 2020-08-12 2022-02-17 주식회사 엘지화학 메탈로센 담지 촉매의 제조 방법, 메탈로센 담지 촉매 및 이를 이용한 폴리올레핀의 제조 방법

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06100614A (ja) * 1992-08-06 1994-04-12 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびこれを用いるオレフィンの重合方法
TW298593B (US06818585-20041116-C00001.png) * 1993-02-12 1997-02-21 Hoechst Ag
US6211109B1 (en) * 1995-07-18 2001-04-03 Fina Technology, Inc. Process for treating silica with alumoxane
US6818585B2 (en) 1998-12-30 2004-11-16 Univation Technologies, Llc Catalyst compounds, catalyst systems thereof and their use in a polymerization process
US6034192A (en) * 1998-12-30 2000-03-07 Univation Technologies, Llc Germanium bridged metallocenes producing polymers with increased melt strength
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6444765B1 (en) * 2000-06-14 2002-09-03 Equistar Chemicals, Lp Olefin polymerization process for producing broad MWD polymers
WO2003014166A1 (en) * 2001-08-07 2003-02-20 Denki Kagaku Kogyo Kabushiki Kaisha Process for producing polymer
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
KR101113341B1 (ko) 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
JP2006509898A (ja) 2002-12-16 2006-03-23 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング アルミノキサンを少量含む担持触媒組成物の製造
JP5695419B2 (ja) 2007-08-29 2015-04-08 アルベマール・コーポレーシヨン ジアルキルアルミニウム陽イオンの前駆剤から生じるアルミノキサン触媒活性剤、同物質の製造方法、ならびにオレフィンの触媒および重合におけるその用途
BRPI0703586B1 (pt) 2007-10-19 2018-02-06 Braskem S.A Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0459264A2 (en) * 1990-05-24 1991-12-04 MITSUI TOATSU CHEMICALS, Inc. Method for preparing syndiotactic poly (alpha-olefin)
US5122491A (en) * 1987-04-20 1992-06-16 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin

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US3709853A (en) * 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
DE3443087A1 (de) 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
JP2538588B2 (ja) * 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
DE3726067A1 (de) 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
DE3742934A1 (de) 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
DE3743321A1 (de) * 1987-12-21 1989-06-29 Hoechst Ag 1-olefinpolymerwachs und verfahren zu seiner herstellung
DE3907965A1 (de) * 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
CA2027145C (en) * 1989-10-10 2002-12-10 Michael J. Elder Metallocene catalysts with lewis acids and aluminum alkyls
US5369196A (en) * 1990-11-30 1994-11-29 Idemitsu Kosan Co., Ltd. Production process of olefin based polymers
EP0516458B2 (en) * 1991-05-31 2007-12-19 Mitsui Chemicals, Inc. Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization
US5308817A (en) * 1992-05-18 1994-05-03 Fina Technology, Inc. Metallocene catalyst component with good catalyst efficiency after aging
US5498582A (en) * 1993-12-06 1996-03-12 Mobil Oil Corporation Supported metallocene catalysts for the production of polyolefins

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5122491A (en) * 1987-04-20 1992-06-16 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
EP0459264A2 (en) * 1990-05-24 1991-12-04 MITSUI TOATSU CHEMICALS, Inc. Method for preparing syndiotactic poly (alpha-olefin)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022035132A1 (ko) * 2020-08-12 2022-02-17 주식회사 엘지화학 메탈로센 담지 촉매의 제조 방법, 메탈로센 담지 촉매 및 이를 이용한 폴리올레핀의 제조 방법

Also Published As

Publication number Publication date
EP0553757B1 (de) 1996-09-25
JP3459272B2 (ja) 2003-10-20
ATE143384T1 (de) 1996-10-15
ZA93548B (en) 1993-08-05
JPH06122706A (ja) 1994-05-06
ES2093287T3 (es) 1996-12-16
AU3199693A (en) 1993-07-29
US5985784A (en) 1999-11-16
TW304963B (US06818585-20041116-C00001.png) 1997-05-11
KR930016446A (ko) 1993-08-26
CA2088114A1 (en) 1993-07-28
AU669684B2 (en) 1996-06-20
DE59303908D1 (de) 1996-10-31
EP0553757A1 (de) 1993-08-04

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