KR100266112B1 - Abs그라프트공중합체를제조하기위한,그라프팅,상전환및가교결합반응을조절할수있는다단계벌크공정 - Google Patents

Abs그라프트공중합체를제조하기위한,그라프팅,상전환및가교결합반응을조절할수있는다단계벌크공정 Download PDF

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Publication number
KR100266112B1
KR100266112B1 KR1019940033407A KR19940033407A KR100266112B1 KR 100266112 B1 KR100266112 B1 KR 100266112B1 KR 1019940033407 A KR1019940033407 A KR 1019940033407A KR 19940033407 A KR19940033407 A KR 19940033407A KR 100266112 B1 KR100266112 B1 KR 100266112B1
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South Korea
Prior art keywords
reactor
polymerization product
rubber
polymerization
monomer
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Expired - Fee Related
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KR1019940033407A
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English (en)
Korean (ko)
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KR950018101A (ko
Inventor
첸-윤쉐
로버트코치
존에드워드페이스
그레고리리안프린스
Original Assignee
제이 엘. 차스킨, 버나드 스나이더, 아더엠. 킹
제너럴 일렉트릭 캄파니
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Publication of KR950018101A publication Critical patent/KR950018101A/ko
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Publication of KR100266112B1 publication Critical patent/KR100266112B1/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1862—Stationary reactors having moving elements inside placed in series
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00168—Controlling or regulating processes controlling the viscosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00184—Controlling or regulating processes controlling the weight of reactants in the reactor vessel

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
KR1019940033407A 1993-12-10 1994-12-09 Abs그라프트공중합체를제조하기위한,그라프팅,상전환및가교결합반응을조절할수있는다단계벌크공정 Expired - Fee Related KR100266112B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US8/165,766 1993-12-10
US08/165,766 US5414045A (en) 1993-12-10 1993-12-10 Grafting, phase-inversion and cross-linking controlled multi-stage bulk process for making ABS graft copolymers
US08/165,766 1993-12-10

Publications (2)

Publication Number Publication Date
KR950018101A KR950018101A (ko) 1995-07-22
KR100266112B1 true KR100266112B1 (ko) 2000-09-15

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940033407A Expired - Fee Related KR100266112B1 (ko) 1993-12-10 1994-12-09 Abs그라프트공중합체를제조하기위한,그라프팅,상전환및가교결합반응을조절할수있는다단계벌크공정

Country Status (9)

Country Link
US (2) US5414045A (cg-RX-API-DMAC7.html)
EP (1) EP0657479B1 (cg-RX-API-DMAC7.html)
JP (1) JP2971351B2 (cg-RX-API-DMAC7.html)
KR (1) KR100266112B1 (cg-RX-API-DMAC7.html)
CN (1) CN1052015C (cg-RX-API-DMAC7.html)
CA (1) CA2137581A1 (cg-RX-API-DMAC7.html)
DE (1) DE69416497T2 (cg-RX-API-DMAC7.html)
ES (1) ES2127357T3 (cg-RX-API-DMAC7.html)
TW (1) TW267174B (cg-RX-API-DMAC7.html)

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KR20020043764A (ko) * 2000-12-04 2002-06-12 성재갑 내충격성이 우수한 아크릴로니트릴-부타디엔-스티렌계수지의 연속 제조 방법
KR20020048628A (ko) * 2000-12-18 2002-06-24 안복현 열가소성 니트릴계 공중합체 및 그 제조방법
KR100708991B1 (ko) 2005-05-19 2007-04-18 주식회사 엘지화학 아크릴로니트릴-부타디엔-스티렌 라텍스의 제조방법
KR100896208B1 (ko) 2007-11-29 2009-05-12 제일모직주식회사 저광택 고무 변성 수지의 연속 제조 방법

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US5552494A (en) * 1993-12-27 1996-09-03 Mitsui Toatsu Chemicals, Inc. Quality control method for ABS-based resin and molding of the ABS-based resin
DE19527579A1 (de) * 1995-07-28 1997-01-30 Basf Ag Transparente spannungsrißbeständige Formmassen mit einem verbesserten Zähigkeits-Steifigkeits-Verhältnis
US6391965B1 (en) 1996-05-31 2002-05-21 Mitsui Chemicals, Inc. Production process of ABS resin, ABS resin, and ABS-polycarbonate resin composition making use of the same
JP2001509189A (ja) * 1997-01-24 2001-07-10 ザ ダウ ケミカル カンパニー 非常にグラフトされたゴムを含むポリマー
US6949607B2 (en) * 2000-12-27 2005-09-27 Techno Polymer Co., Ltd. Thermoplastic resin composition and its molded articles
US6784253B2 (en) * 2001-07-24 2004-08-31 General Electric Company Enhanced polymerization process
CN101104666B (zh) * 2001-07-24 2013-03-20 沙伯基础创新塑料知识产权有限公司 改进的聚合方法
KR100441799B1 (ko) * 2001-10-25 2004-07-27 주식회사 엘지화학 고무강화 열가소성 수지의 제조방법
US7799855B2 (en) * 2001-11-12 2010-09-21 Sabic Innovative Plastics Ip B.V. Flame retardant thermoplastic polycarbonate compositions, use and method thereof
KR100568772B1 (ko) * 2003-10-07 2006-04-07 주식회사 엘지화학 고충격 및 고광택을 갖는 아크릴로니트릴-부타디엔-스티렌 수지 제조방법
US7223804B2 (en) * 2003-12-30 2007-05-29 General Electric Company Polycarbonate composition
US20060004154A1 (en) * 2004-07-02 2006-01-05 Derudder James L Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US20090023871A9 (en) * 2004-08-05 2009-01-22 General Electric Company Flame retardant thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US20060030647A1 (en) * 2004-08-05 2006-02-09 Thomas Ebeling Flame retardant thermoplastic polycarbonate compositions, use, and method of manufacture thereof
US7365125B2 (en) * 2004-08-16 2008-04-29 General Electric Company Polycarbonate compositions, articles, and method of manufacture
KR100671135B1 (ko) * 2004-09-08 2007-01-17 주식회사 엘지화학 고충격 고광택 고무변성 스티렌계 공중합 수지의 제조방법
US20060142486A1 (en) * 2004-12-23 2006-06-29 Derudder James L Thermoplastic polycarbonate compositions, articles made therefrom and method of manufacture
US7432327B2 (en) * 2004-12-30 2008-10-07 Sabic Innovative Plastics Ip B.V. Transparent polymeric compositions comprising polysiloxane-polycarbonate copolymer, articles made therefrom and methods of making same
US7498401B2 (en) * 2005-03-03 2009-03-03 Sabic Innovative Plastics Ip B.V. Thermoplastic polycarbonate compositions, articles made therefrom and method of manufacture
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CN100358944C (zh) * 2005-06-03 2008-01-02 中化国际余杭高分子材料研发设计有限公司 一种光感好易塑性苯乙烯系树脂组合物
US20070060716A1 (en) * 2005-09-13 2007-03-15 Bala Ambravaneswaran Fatigue resistant thermoplastic composition, method of making, and articles formed therefrom
US20070072961A1 (en) * 2005-09-28 2007-03-29 General Electric Company Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US20070072960A1 (en) * 2005-09-28 2007-03-29 General Electric Company Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US7544745B2 (en) * 2005-10-25 2009-06-09 Sabic Innovative Plastics Ip B.V. Flame retardant thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US7649051B2 (en) 2005-10-25 2010-01-19 Sabic Innovative Plastics Ip B.V. Flame retardant thermoplastic polycarbonate compositions
US20070135569A1 (en) * 2005-12-14 2007-06-14 General Electric Company Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US7488774B2 (en) * 2005-12-21 2009-02-10 Fina Technology, Inc. Reactor system for the production of high impact polystyrene
EP1996632A4 (en) * 2006-03-20 2010-06-02 Fina Technology REACTOR SYSTEM FOR IMPACT POLYSTYRENE PRODUCTION
US8674007B2 (en) 2006-07-12 2014-03-18 Sabic Innovative Plastics Ip B.V. Flame retardant and scratch resistant thermoplastic polycarbonate compositions
US8871865B2 (en) * 2006-08-01 2014-10-28 Sabic Global Technologies B.V. Flame retardant thermoplastic polycarbonate compositions
US8030400B2 (en) * 2006-08-01 2011-10-04 Sabic Innovative Plastics Ip B.V. Thermoplastic polycarbonate compositions with improved chemical and scratch resistance
KR100837092B1 (ko) * 2006-08-16 2008-06-12 제일모직주식회사 투명 고무변성 스티렌계 수지 및 그의 연속 괴상중합제조방법
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CN1986635B (zh) * 2006-12-21 2010-05-19 中化国际（苏州）新材料研发有限公司 一种采用连续本体法制备挤出级丙烯腈-丁二烯-苯乙烯接枝共聚物的方法
US8222351B2 (en) * 2007-02-12 2012-07-17 Sabic Innovative Plastics Ip B.V. Low gloss polycarbonate compositions
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JP5581320B2 (ja) * 2008-07-10 2014-08-27 サビック・イノベーティブ・プラスチックス・アイピー・ベスローテン・フェンノートシャップ 結合層組成物
CN102051034B (zh) * 2009-10-30 2013-04-17 上海普利特复合材料股份有限公司 一种低光泽、高耐热聚碳酸酯组合物
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KR20020043764A (ko) * 2000-12-04 2002-06-12 성재갑 내충격성이 우수한 아크릴로니트릴-부타디엔-스티렌계수지의 연속 제조 방법
KR20020048628A (ko) * 2000-12-18 2002-06-24 안복현 열가소성 니트릴계 공중합체 및 그 제조방법
KR100708991B1 (ko) 2005-05-19 2007-04-18 주식회사 엘지화학 아크릴로니트릴-부타디엔-스티렌 라텍스의 제조방법
KR100896208B1 (ko) 2007-11-29 2009-05-12 제일모직주식회사 저광택 고무 변성 수지의 연속 제조 방법

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Publication number Publication date
US5414045A (en) 1995-05-09
DE69416497T2 (de) 1999-09-02
CN1052015C (zh) 2000-05-03
EP0657479A1 (en) 1995-06-14
TW267174B (cg-RX-API-DMAC7.html) 1996-01-01
CA2137581A1 (en) 1995-06-11
ES2127357T3 (es) 1999-04-16
CN1106827A (zh) 1995-08-16
DE69416497D1 (de) 1999-03-25
EP0657479B1 (en) 1999-02-10
JP2971351B2 (ja) 1999-11-02
KR950018101A (ko) 1995-07-22
JPH07233204A (ja) 1995-09-05
US5569709A (en) 1996-10-29

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