DE69416497T2 - Mehrstufiges Masse-Polymerisationsverfahren mit kontrollierter Pfropfung, Phasenumkehrung und Vernetzung für die Herstellung von ABS-Pfropfcopolymeren - Google Patents

Mehrstufiges Masse-Polymerisationsverfahren mit kontrollierter Pfropfung, Phasenumkehrung und Vernetzung für die Herstellung von ABS-Pfropfcopolymeren

Info

Publication number
DE69416497T2
DE69416497T2 DE69416497T DE69416497T DE69416497T2 DE 69416497 T2 DE69416497 T2 DE 69416497T2 DE 69416497 T DE69416497 T DE 69416497T DE 69416497 T DE69416497 T DE 69416497T DE 69416497 T2 DE69416497 T2 DE 69416497T2
Authority
DE
Germany
Prior art keywords
crosslinking
production
polymerization process
phase inversion
bulk polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69416497T
Other languages
English (en)
Other versions
DE69416497D1 (de
Inventor
Chen-Youn Sue
Robert Koch
John Edward Pace
Gregory Ryan Prince
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SABIC Global Technologies BV
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Application granted granted Critical
Publication of DE69416497D1 publication Critical patent/DE69416497D1/de
Publication of DE69416497T2 publication Critical patent/DE69416497T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1862—Stationary reactors having moving elements inside placed in series
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00168—Controlling or regulating processes controlling the viscosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00184—Controlling or regulating processes controlling the weight of reactants in the reactor vessel
DE69416497T 1993-12-10 1994-11-21 Mehrstufiges Masse-Polymerisationsverfahren mit kontrollierter Pfropfung, Phasenumkehrung und Vernetzung für die Herstellung von ABS-Pfropfcopolymeren Expired - Fee Related DE69416497T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/165,766 US5414045A (en) 1993-12-10 1993-12-10 Grafting, phase-inversion and cross-linking controlled multi-stage bulk process for making ABS graft copolymers

Publications (2)

Publication Number Publication Date
DE69416497D1 DE69416497D1 (de) 1999-03-25
DE69416497T2 true DE69416497T2 (de) 1999-09-02

Family

ID=22600375

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69416497T Expired - Fee Related DE69416497T2 (de) 1993-12-10 1994-11-21 Mehrstufiges Masse-Polymerisationsverfahren mit kontrollierter Pfropfung, Phasenumkehrung und Vernetzung für die Herstellung von ABS-Pfropfcopolymeren

Country Status (9)

Country Link
US (2) US5414045A (de)
EP (1) EP0657479B1 (de)
JP (1) JP2971351B2 (de)
KR (1) KR100266112B1 (de)
CN (1) CN1052015C (de)
CA (1) CA2137581A1 (de)
DE (1) DE69416497T2 (de)
ES (1) ES2127357T3 (de)
TW (1) TW267174B (de)

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US5470915A (en) * 1993-06-28 1995-11-28 Miwon Petrochemical Corporation ABS resins having impact resistance and low-gloss properties and processes for preparing them
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DE19527579A1 (de) * 1995-07-28 1997-01-30 Basf Ag Transparente spannungsrißbeständige Formmassen mit einem verbesserten Zähigkeits-Steifigkeits-Verhältnis
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US5959033A (en) * 1997-01-24 1999-09-28 The Dow Chemical Company Polymers containing highly grafted rubbers
KR20020043764A (ko) * 2000-12-04 2002-06-12 성재갑 내충격성이 우수한 아크릴로니트릴-부타디엔-스티렌계수지의 연속 제조 방법
KR20020048628A (ko) * 2000-12-18 2002-06-24 안복현 열가소성 니트릴계 공중합체 및 그 제조방법
US6949607B2 (en) * 2000-12-27 2005-09-27 Techno Polymer Co., Ltd. Thermoplastic resin composition and its molded articles
US6784253B2 (en) * 2001-07-24 2004-08-31 General Electric Company Enhanced polymerization process
CN101104666B (zh) * 2001-07-24 2013-03-20 沙伯基础创新塑料知识产权有限公司 改进的聚合方法
KR100441799B1 (ko) * 2001-10-25 2004-07-27 주식회사 엘지화학 고무강화 열가소성 수지의 제조방법
US7799855B2 (en) * 2001-11-12 2010-09-21 Sabic Innovative Plastics Ip B.V. Flame retardant thermoplastic polycarbonate compositions, use and method thereof
KR100568772B1 (ko) * 2003-10-07 2006-04-07 주식회사 엘지화학 고충격 및 고광택을 갖는 아크릴로니트릴-부타디엔-스티렌 수지 제조방법
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US20060004154A1 (en) * 2004-07-02 2006-01-05 Derudder James L Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US20060030647A1 (en) * 2004-08-05 2006-02-09 Thomas Ebeling Flame retardant thermoplastic polycarbonate compositions, use, and method of manufacture thereof
US20090023871A9 (en) * 2004-08-05 2009-01-22 General Electric Company Flame retardant thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US7365125B2 (en) * 2004-08-16 2008-04-29 General Electric Company Polycarbonate compositions, articles, and method of manufacture
KR100671135B1 (ko) * 2004-09-08 2007-01-17 주식회사 엘지화학 고충격 고광택 고무변성 스티렌계 공중합 수지의 제조방법
US20060142486A1 (en) * 2004-12-23 2006-06-29 Derudder James L Thermoplastic polycarbonate compositions, articles made therefrom and method of manufacture
US7432327B2 (en) * 2004-12-30 2008-10-07 Sabic Innovative Plastics Ip B.V. Transparent polymeric compositions comprising polysiloxane-polycarbonate copolymer, articles made therefrom and methods of making same
US7498401B2 (en) * 2005-03-03 2009-03-03 Sabic Innovative Plastics Ip B.V. Thermoplastic polycarbonate compositions, articles made therefrom and method of manufacture
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KR100708991B1 (ko) 2005-05-19 2007-04-18 주식회사 엘지화학 아크릴로니트릴-부타디엔-스티렌 라텍스의 제조방법
CN100358944C (zh) * 2005-06-03 2008-01-02 中化国际余杭高分子材料研发设计有限公司 一种光感好易塑性苯乙烯系树脂组合物
US20070060716A1 (en) * 2005-09-13 2007-03-15 Bala Ambravaneswaran Fatigue resistant thermoplastic composition, method of making, and articles formed therefrom
US20070072960A1 (en) * 2005-09-28 2007-03-29 General Electric Company Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US20070072961A1 (en) * 2005-09-28 2007-03-29 General Electric Company Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US7649051B2 (en) 2005-10-25 2010-01-19 Sabic Innovative Plastics Ip B.V. Flame retardant thermoplastic polycarbonate compositions
US7544745B2 (en) * 2005-10-25 2009-06-09 Sabic Innovative Plastics Ip B.V. Flame retardant thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US20070135569A1 (en) * 2005-12-14 2007-06-14 General Electric Company Thermoplastic polycarbonate compositions, method of manufacture, and method of use thereof
US7488774B2 (en) 2005-12-21 2009-02-10 Fina Technology, Inc. Reactor system for the production of high impact polystyrene
CA2642953A1 (en) * 2006-03-20 2007-09-27 Fina Technology, Inc. Reactor system for the production of high impact polystyrene
US8674007B2 (en) 2006-07-12 2014-03-18 Sabic Innovative Plastics Ip B.V. Flame retardant and scratch resistant thermoplastic polycarbonate compositions
US8030400B2 (en) * 2006-08-01 2011-10-04 Sabic Innovative Plastics Ip B.V. Thermoplastic polycarbonate compositions with improved chemical and scratch resistance
US8871865B2 (en) * 2006-08-01 2014-10-28 Sabic Global Technologies B.V. Flame retardant thermoplastic polycarbonate compositions
CN101360767B (zh) * 2006-08-16 2012-05-30 第一毛织株式会社 透明的橡胶改性的苯乙烯树脂以及通过连续的本体聚合制备它的方法
EP1903064A1 (de) * 2006-09-20 2008-03-26 Ineos Europe Limited Verfahren zur Herstellung von Polystyrol
CN1986635B (zh) * 2006-12-21 2010-05-19 中化国际（苏州）新材料研发有限公司 一种采用连续本体法制备挤出级丙烯腈-丁二烯-苯乙烯接枝共聚物的方法
US8222350B2 (en) * 2007-02-12 2012-07-17 Sabic Innovative Plastics Ip B.V. Low gloss polycarbonate compositions
US8222351B2 (en) * 2007-02-12 2012-07-17 Sabic Innovative Plastics Ip B.V. Low gloss polycarbonate compositions
US7723428B2 (en) * 2007-07-31 2010-05-25 Sabic Innovative Plastics Ip B.V. Polycarbonate compositions with improved molding capability
KR100896208B1 (ko) 2007-11-29 2009-05-12 제일모직주식회사 저광택 고무 변성 수지의 연속 제조 방법
WO2010006226A1 (en) 2008-07-10 2010-01-14 Sabic Innovative Plastics Ip B.V. Tie layer compositions
CN102051034B (zh) * 2009-10-30 2013-04-17 上海普利特复合材料股份有限公司 一种低光泽、高耐热聚碳酸酯组合物
CN102051042B (zh) * 2009-10-30 2013-04-17 上海普利特复合材料股份有限公司 一种低光泽、耐刮擦尼龙/丙烯腈-丁二烯-苯乙烯树脂共混材料
US20140093712A1 (en) 2012-09-28 2014-04-03 Sabic Innovative Plastics Ip B.V. Polycarbonate ABS Composites with Improved Electromagnetic Shielding Effectiveness
US9790367B2 (en) 2013-01-11 2017-10-17 Sabic Global Technologies B.V. Polycarbonate compositions for reduced splay in combination with sustained or improved impact resistance
US20140206800A1 (en) 2013-01-22 2014-07-24 Sabic Innovative Plastics Ip B.V. Thermoplastic Compositions Containing Nanoscale-Sized Particle Additives For Laser Direct Structuring And Methods For The Manufacture And Use Thereof
KR101811485B1 (ko) 2014-11-28 2017-12-21 주식회사 엘지화학 열가소성 수지 조성물 및 이를 적용한 성형품
KR101946482B1 (ko) 2015-10-22 2019-02-11 주식회사 엘지화학 폴리부타디엔의 제조 장치
KR101960726B1 (ko) 2015-10-22 2019-03-22 주식회사 엘지화학 폴리부타디엔의 제조 방법
CN109096444B (zh) * 2017-06-20 2022-10-04 上海华谊（集团）公司 一种高刚性abs组合物及其制备方法
CN108276528A (zh) * 2017-12-27 2018-07-13 北方华锦化学工业股份有限公司 一种环保型abs树脂及其制备方法
CN114867762A (zh) * 2019-08-30 2022-08-05 英力士苯领集团股份公司 经本体或溶液聚合获得的abs成型材料
CN112452258A (zh) * 2020-11-10 2021-03-09 北京科技大学 一种轻合金半固态浆料复合搅拌高效制备装置
CN113136007A (zh) * 2021-03-26 2021-07-20 林轩 一种易干燥的带孔型abs接支聚合物颗粒的制备方法
TW202330677A (zh) 2021-12-10 2023-08-01 義大利商佛沙里斯股份有限公司 橡膠強化的乙烯芳香族(共)聚合物及其製備方法
WO2023228123A1 (en) 2022-05-25 2023-11-30 Shpp Global Technologies B.V. Anti-drip polycarbonate compositions
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Also Published As

Publication number Publication date
CN1052015C (zh) 2000-05-03
KR100266112B1 (ko) 2000-09-15
JPH07233204A (ja) 1995-09-05
US5569709A (en) 1996-10-29
JP2971351B2 (ja) 1999-11-02
CA2137581A1 (en) 1995-06-11
EP0657479A1 (de) 1995-06-14
KR950018101A (ko) 1995-07-22
TW267174B (de) 1996-01-01
ES2127357T3 (es) 1999-04-16
CN1106827A (zh) 1995-08-16
EP0657479B1 (de) 1999-02-10
US5414045A (en) 1995-05-09
DE69416497D1 (de) 1999-03-25

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Owner name: SABIC INNOVATIVE PLASTICS IP B.V., BERGEN OP Z, NL

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Representative=s name: PATENT- UND RECHTSANWAELTE BARDEHLE, PAGENBERG, DO

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