KR100191396B1 - A process for preparing liquid fertilizer using by-product from animals - Google Patents
A process for preparing liquid fertilizer using by-product from animals Download PDFInfo
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- KR100191396B1 KR100191396B1 KR1019960047863A KR19960047863A KR100191396B1 KR 100191396 B1 KR100191396 B1 KR 100191396B1 KR 1019960047863 A KR1019960047863 A KR 1019960047863A KR 19960047863 A KR19960047863 A KR 19960047863A KR 100191396 B1 KR100191396 B1 KR 100191396B1
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 49
- 241001465754 Metazoa Species 0.000 title claims abstract description 39
- 239000007788 liquid Substances 0.000 title claims abstract description 31
- 239000006227 byproduct Substances 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 108010019160 Pancreatin Proteins 0.000 claims abstract description 10
- 229940055695 pancreatin Drugs 0.000 claims abstract description 10
- 238000001914 filtration Methods 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 4
- 230000000996 additive effect Effects 0.000 claims abstract description 3
- 238000001816 cooling Methods 0.000 claims abstract description 3
- 210000004209 hair Anatomy 0.000 claims description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 210000004369 blood Anatomy 0.000 claims description 7
- 239000008280 blood Substances 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 210000002615 epidermis Anatomy 0.000 claims description 3
- 150000001413 amino acids Chemical class 0.000 abstract description 14
- 239000002994 raw material Substances 0.000 abstract description 8
- 239000002689 soil Substances 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 238000010521 absorption reaction Methods 0.000 abstract description 4
- 235000013399 edible fruits Nutrition 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 230000020477 pH reduction Effects 0.000 abstract description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 108090000790 Enzymes Proteins 0.000 description 6
- 102000004190 Enzymes Human genes 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
- 239000003513 alkali Substances 0.000 description 6
- 229940088598 enzyme Drugs 0.000 description 6
- 239000011591 potassium Substances 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 235000018102 proteins Nutrition 0.000 description 5
- 108090000623 proteins and genes Proteins 0.000 description 5
- 102000004169 proteins and genes Human genes 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 210000000282 nail Anatomy 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 125000001477 organic nitrogen group Chemical group 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- 102000004142 Trypsin Human genes 0.000 description 1
- 108090000631 Trypsin Proteins 0.000 description 1
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 210000000078 claw Anatomy 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- -1 epidermis Substances 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 210000003284 horn Anatomy 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000005078 molybdenum compound Substances 0.000 description 1
- 150000002752 molybdenum compounds Chemical class 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- 210000000496 pancreas Anatomy 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F1/00—Fertilisers made from animal corpses, or parts thereof
- C05F1/005—Fertilisers made from animal corpses, or parts thereof from meat-wastes or from other wastes of animal origin, e.g. skins, hair, hoofs, feathers, blood
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F1/00—Fertilisers made from animal corpses, or parts thereof
- C05F1/007—Fertilisers made from animal corpses, or parts thereof from derived products of animal origin or their wastes, e.g. leather, dairy products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/40—Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G1/00—Mixtures of fertilisers belonging individually to different subclasses of C05
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
본 발명은 물 100 중량부를 반응기에 넣고 동물로부터 얻어진 부산물을 물 100 중량부에 대하여 20 내지 30 중량부를 투입하는 단계; 반응기의 온도를 80 내지 90℃까지 승온하고 여기에 알칼리 화합물 4 내지 5 중량부를 첨가하여 반응기의 온도를 95 내지 98℃로 유지하면서 교반 하에 반응시키는 단계; 반응기의 온도를 50 내지 60℃까지 냉각한 후, 판크레아틴 0.1 내지 0.3 중량부를 투입하여 반응시킨 후 1차 여과하는 단계; 및 통상의 비료용 첨가제를 첨가하여 2차 여과하는 단계로 이루어진 동물로부터 얻어진 부산물을 이용한 액체 비료의 제조방법에 관한 것이다.In the present invention, 100 parts by weight of water is added to a reactor, and 20 to 30 parts by weight of a by-product obtained from an animal is added to 100 parts by weight of water. Raising the temperature of the reactor to 80 to 90 占 폚, adding 4 to 5 parts by weight of an alkaline compound thereto, and maintaining the temperature of the reactor at 95 to 98 占 폚 while stirring; Cooling the reactor to a temperature of 50 to 60 ° C, adding 0.1 to 0.3 parts by weight of pancreatin to react, and then performing primary filtration; And a step of secondary filtration by adding a conventional additive for fertilizer to a process for producing a liquid fertilizer using a by-product obtained from an animal.
본 발명의 방법에 따라 제조된 동물로부터 얻어지는 부산물을 이용한 액체 비료는 유기질 원료를 사용한 아미노산이 풍부한 액체 비료로서, 작물에 의한 직접 흡수가 용이하여 농작물과 과수의 성장을 촉진하고, 이 액체 비료를 사용할 경우 재배된 과실의 맛과 생상이 우수하고 농작물의 연작도 가능하며, 특히 냉해에 대하여 강력한 효과를 발휘할 뿐만 아니라, 화학비료에 의한 토양 산성화 문제 또한 방지할 수 있다.The liquid fertilizer using the byproducts obtained from the animal produced according to the method of the present invention is an amino acid-rich liquid fertilizer using an organic raw material and facilitates the direct absorption by crops to promote the growth of crops and fruit trees. It is possible to produce a fruit having a good taste and a good appearance and to produce a crop, and in particular it can exert a powerful effect against cold weather, and also can prevent a problem of soil acidification by chemical fertilizer.
Description
[발명의 명칭][Title of the Invention]
동물로부터 얻어진 부산물을 이용한 액체 비료의 제조방법Method for producing liquid fertilizer using by-products obtained from animals
[발명의 상세한 설명]DETAILED DESCRIPTION OF THE INVENTION [
[발명의 목적][Object of the invention]
본 발명의 목적은 동물로부터 얻어진 부산물을 이용하여 아미노산이 풍부하고 토양의 산성화를 유발하지 않는 유기질 액체 비료를 제조하는 방법을 제공하는 것이다.It is an object of the present invention to provide a method for producing an organic liquid fertilizer which is rich in amino acids and does not cause acidification of the soil using by-products obtained from animals.
[발명이 속하는 기술분야 및 그 분야의 종래기술][TECHNICAL FIELD OF THE INVENTION AND RELATED ART OF THE SAME]
본발명은 동물로부터 얻어진 부산물을 이용한 액체 비료의 제조방법에 관한 것으로, 더욱 상세하게는 동물로부터 얻어지는 부산물을 고온에서 알칼리 분해하고 효소처리하여 식물이 직접 흡수할 수 있는 아미노산을 다량 함유하는 유기질 액체 비료를 제조하는 방법에 관한 것이다.The present invention relates to a method for producing a liquid fertilizer using a by-product obtained from an animal, and more particularly to a method for producing an organic liquid fertilizer containing a large amount of amino acids that can be directly absorbed by a plant by alkali- And a method for producing the same.
종래에는 무기질 화학비료인 질소비료와 인산비료 및 칼륨비료를 물에 용해하여 액체 비료로서 작물에 살포하였다. 상기한 무기질 화학비료는 무기질이므로 작물에 살포할 경우 일부 소량만이 흡수되고 나머지는 용탈이 되었으며, 특히 토양을 산성화하는 문제점이 있어왔다.Conventionally, nitrogen fertilizer, phosphoric fertilizer and potassium fertilizer, which are mineral chemical fertilizers, are dissolved in water and sprayed on the crops as liquid fertilizer. Since the inorganic fertilizer described above is inorganic, only a small amount of the inorganic fertilizer is absorbed and the remaining is leached when sprayed on crops. Especially, there has been a problem of acidifying the soil.
[발명이 이루고자 하는 기술적과제][Technical Problem]
본 발명은 상기한 바와 같은 종래의 무기질 액체 화학비료의 문제점을 해결하고 그 효과를 개선하기 위하여 예의 연구한 결과, 일반적으로 폐기물로서 처리되는 동물의 털, 표피, 혈액 및 제각분(손톱, 발톱, 뿔)과 같은 동물로부터 얻어지는 부산물을 비료의 유기질 원료로 이용할 수 있도록 하여 이를 작물의 비료로서 사용하였을 때 농작물과 과수의 성장을 촉진하고 과일의 맛과 색상이 우수하며 농작물의 연작도 가능하게 되었고, 특히 냉해에 대하여 강력한 효과를 발휘하게 됨을 발견하여 본 발명을 완성하게 되었다.The present invention has been made in order to solve the problems of the conventional mineral liquid chemical fertilizer as described above and to improve the effect thereof. As a result, it has been found that, in general, Horns) can be used as organic fertilizer for fertilizer. When this fertilizer is used as a fertilizer for crops, it promotes the growth of crops and fruit trees, has excellent taste and color of fruits, The present invention has been completed.
[발명의 구성 및 작용][Structure and operation of the invention]
본 발명은 물 100 중량부를 반응기에 넣고 동물로부터 얻어진 부산물을 물 100 중량부에 대하여 20 내지 30 중량부를 투입하는 단계; 반응기의 온도를 80 내지 90℃까지 승온하고 여기에 알칼리 화합물 4 내지 5 중량부를 첨가하여 반응기의 온도를 95 내지 98℃로 유지하면서 교반 하에 반응시키는 단계; 반응기의 온도를 50 내지 60℃까지 냉각한 후, 판크레아틴 0.1 내지 0.3 중량부를 투입하여 반응시킨 후 1차 여과하는 단계; 및 통상의 비료용 첨가제를 첨가하여 2차 여과하는 단계로 이루어진 동물로부터 얻어진 부산물을 이용한 액체 비료의 제조방법인 것이다.In the present invention, 100 parts by weight of water is added to a reactor, and 20 to 30 parts by weight of a by-product obtained from an animal is added to 100 parts by weight of water. Raising the temperature of the reactor to 80 to 90 占 폚, adding 4 to 5 parts by weight of an alkaline compound thereto, and maintaining the temperature of the reactor at 95 to 98 占 폚 while stirring; Cooling the reactor to a temperature of 50 to 60 ° C, adding 0.1 to 0.3 parts by weight of pancreatin to react, and then performing primary filtration; And a step of secondary filtration by adding an ordinary additive for fertilizer to the liquid fertilizer.
이하, 본 발명을 더욱 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail.
동물로부터 얻어지는 부산물은 몇몇을 제외하고는 대체로 폐기되는데, 본 발명에서는 이러한 동물로부터 얻어지는 부산물을 유기질 원료로 사용하였다.By-products obtained from animals are generally discarded except for a few. In the present invention, by-products obtained from such animals are used as organic raw materials.
본 발명에 있어서, 동물로부터 얻어지는 부산물이란 동물에서 얻어지는 동물성 단백질을 다량 함유하는, 예를 들면 털, 표피(수구레), 혈액 및, 손톱, 발톱 또는 뿔 등의 제각분을 일컫는다. 일예로, 동물의 털은 고농도의 단백질로서, 약 74%가 단백질로 구성되어 있다.In the present invention, a by-product obtained from an animal refers to a product containing a large amount of animal protein obtained from an animal, such as hair, epidermis, blood and nail, nail, claw or horn. For example, an animal's hair is a high concentration protein, and about 74% is composed of protein.
본 발명에 있어서는 단백질을 다량 함유하는 동물로부터 얻어지는 부산물을 액체 비료의 유기질 원료로서 사용하며, 이 원료는 알칼리에 의해 가수분해되고 효소처리하여 액체 비료로서 제조된다.In the present invention, a byproduct obtained from an animal containing a large amount of protein is used as an organic raw material for a liquid fertilizer, and this raw material is hydrolyzed by an alkali and subjected to an enzyme treatment to produce a liquid fertilizer.
단백질을 가수분해하면 아미노산으로 되므로 본 발명에 따라 동물로부터 얻어지는 부산물을 분해하여 제조되는 유기 액체 비료는 다량의 아미노산을 함유하게 된다.The hydrolysis of the protein results in an amino acid. Therefore, the organic liquid fertilizer produced by decomposing by-products obtained from an animal according to the present invention contains a large amount of amino acid.
상기한 바와 같이, 본 발명에 따라 제조되는 액체 비료는 비료에 필수적으로 요구되는 17종의 아미노산을 고루 함유한다.As described above, the liquid fertilizer produced according to the present invention contains 17 kinds of amino acids which are essential for fertilizer.
화학비료는 분해되어 질산태 질소로 변하여 질산이 되며 질산이 분해되어 암모니아가 되고 다시 암모니아는 아미노산이 되어 작물이 흡수하게 되므로 비료의 손실이 크고 작물에 의한 흡수가 지연되며 토양의 산성화를 유발하지만, 본 발명에 따른 주성분이 단백질인 동물성 부산물을 분해하여 제조되는 액체 비료는 아미노산으로 이루어져 있으므로 작물에 의한 직접 흡수가 용이하다.The chemical fertilizer decomposes and becomes nitrate nitrogen, becomes nitric acid, decomposes nitric acid to become ammonia, and ammonia becomes amino acid again and absorbs crops, so the loss of fertilizer is large, the absorption by the crop is delayed and causes the acidification of the soil, Since the liquid fertilizer produced by decomposing the animal by-products of which the main component is a protein according to the present invention is made of amino acid, direct absorption by the crop is easy.
본 발명에 따라 동물로부터 얻어진 부산물을 원료로 하는 액체 비료는 다음과 같이 제조된다. 먼저 물을 반응기에 투입하여 온도를 80 내지 85℃로 가열한다. 가열된 물에 동물로부터 얻어진 부산물을 물 100 중량부에 대하여 20 내지 30 중량부를 첨가하고 온도를 다시 약 90℃까지 승온한다. 여기에 알칼리를 4 내지 5 중량부 첨가하고, 반응기의 온도를 95 내지 98℃로 유지하면서 교반 하에 가수분해한다. 얻어진 용액의 온도를 50 내지 60℃까지 낮춘 다음, 여기에 동물의 췌장 효소인 판크레아틴 0.1 내지 0.3 중량부를 첨가하여 교반 하에 24시간 동안 숙성한다. 숙성된 액체를 1차 여과한다. 상기에서 얻어진 여과액에 비료에 통상적으로 첨가되는 질소, 인산, 칼륨, 붕소 및 몰리브덴 화합물을 첨가하고 2차 여과하여 액체 비료를 제조한다.A liquid fertilizer using a by-product obtained from an animal according to the present invention as a raw material is prepared as follows. First, water is introduced into the reactor and the temperature is heated to 80 to 85 캜. 20 to 30 parts by weight of a by-product obtained from an animal is added to heated water in 100 parts by weight of water, and the temperature is further raised to about 90 캜. 4 to 5 parts by weight of alkali is added thereto, and hydrolysis is carried out with stirring while maintaining the temperature of the reactor at 95 to 98 占 폚. The temperature of the obtained solution is lowered to 50 to 60 DEG C and 0.1 to 0.3 parts by weight of pancreatin, which is an animal pancreatic enzyme, is added thereto and aged for 24 hours under stirring. Primary filtration of the aged liquid. To the filtrate obtained above is added a nitrogen, phosphoric acid, potassium, boron and molybdenum compound which is usually added to the fertilizer, followed by secondary filtration to prepare a liquid fertilizer.
본 발명에서 원료로 사용되는 동물의 털로는 모든 종류의 동물의 털을 사용할 수 있는데, 예를들면 사람의 모발, 우모, 계모 등이 있다. 동물의 털은 바람직하게는 5% 이하의 물을 함유하는 것을 사용하고, 표피는 1㎝ 이하로 분쇄하여 사용하며, 제각분은 0.5mm 이하로 분쇄하여 사용한다. 동물의 혈액은 초산을 첨가하여 pH 4 내지 5로 보관된 상태의 것을 사용한다.The animal hair used as a raw material in the present invention may be any kind of animal hair, for example, human hair, female hair, and stepmother. An animal hair preferably contains 5% or less of water, and the skin is ground to 1 cm or less, and the crushed powder is ground to 0.5 mm or less. The blood of the animal is stored at pH 4 to 5 by adding acetic acid.
본 발명에 따르면, 반응기에 투입된 동물성 부산물은 먼저 고온에서 알칼리에 의해 가수분해되는데, 사용가능한 알칼리 화합물은 바람직하게는 수산화나트륨 또는 수산화칼륨이다. 알칼리 화합물에 의해 가수분해하여 얻어진 원료 용액은 다시 판크레아틴으로 재차 분해된다. 판크레아틴은 온혈 동물의 췌장에서 분비되는 효소 혼합물로서, 아밀라제, 트립신, 리파제 등의 효소를 함유한다. 본 발명에서는 판크레아틴으로, 예를들면 돼지로부터 얻어진 것을 사용할 수 있다.According to the present invention, the animal by-products introduced into the reactor are first hydrolyzed by alkali at a high temperature, and the alkali compounds which can be used are preferably sodium hydroxide or potassium hydroxide. The raw material solution obtained by hydrolysis with an alkali compound is decomposed again with pancreatin. Pancreatin is a mixture of enzymes secreted from the pancreas of warm-blooded animals and contains enzymes such as amylase, trypsin, and lipase. In the present invention, pancreatin, for example, obtained from pigs, may be used.
판크레아틴을 0.1중량부 이하로 사용하면 목적하는 효소 작용을 충분히 발휘할 수 없으며, 0.3 중량부 이상을 사용하는 경우에는 효소의 낭비를 초래하게 된다. 본 발명의 바람직한 한 구현에 있어서, 상기한 바와 같이 알칼리에 의해 가수분해되고 판크레아틴으로 효소처리된 동물의 털은 그 자체만으로 54.8%의 아미노산과 2.05%의 유기태 질소 및 1.5%의 칼륨 등을 함유한다.When the pancreatin is used in an amount of 0.1 part by weight or less, the desired enzyme action can not be sufficiently exerted, and when 0.3 parts by weight or more is used, waste of the enzyme is caused. In one preferred embodiment of the present invention, as described above, the hair of an animal hydrolyzed by alkali and enzymatically treated with pancreatin itself contains 54.8% of amino acid, 2.05% of organic nitrogen and 1.5% of potassium do.
본 발명에서는 상기한 성분 이외에 비료를 제조하는데 통상적으로 사용되는 보조 첨가제와 비료의 필수 요소인 질소, 인 칼륨 등을 일반적인 화합물 형태 또는 원소 형태로서 첨가할 수 있다. 상기한 바와 같이 제조된 본 발명에 따른 액체 비료는 17종의 아미노산을 고루 함유할 뿐만 아니라, 혈액에 있어서는 철분을 함유하는 액체 비료를 제조할 수 있다. 또한, 본 발명에 따른 액체 비료는 아미노산 이외에도 비료의 필수 성분인 질소, 인, 칼륨, 붕소, 몰리브덴 등을 다량 함유하는 양질의 비료인 것이다.In the present invention, in addition to the above-mentioned components, auxiliary additives commonly used for producing fertilizers and nitrogen, phosphorus and the like which are essential elements of fertilizer can be added in general compound form or element form. The liquid fertilizer according to the present invention prepared as described above not only contains 17 kinds of amino acids evenly, but also can produce liquid fertilizer containing iron in the blood. In addition, the liquid fertilizer according to the present invention is a fertilizer containing a large amount of nitrogen, phosphorus, potassium, boron, molybdenum and the like which are essential ingredients of fertilizer in addition to amino acid.
[실시예][Example]
이하, 본 발명을 실시예에 의하여 더욱 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail with reference to the following examples.
[실시예 1][Example 1]
물 1000ℓ를 반응기에 넣고 85℃까지 가열한 후, 수분이 5% 이하인 동물의 털 250㎏을 서서히 투입하였다. 동물의 털을 모두 첨가한 후, 온도를 90℃까지 승온하였다. 여기에 수산화칼륨 45㎏을 첨가한 후, 반응기의 온도를 98℃로 유지하면서 6시간동안 반응시켰다. 반응조 교반기는 1분에 60회전할 수 있도록 조작하였고, 반응조의 압력은 0.5㎏/㎥이었다.1000 L of water was added to the reactor, heated to 85 캜, and 250 kg of hair of an animal having moisture of 5% or less was slowly added thereto. After all of the animal hair was added, the temperature was raised to 90 캜. 45 kg of potassium hydroxide was added thereto, and the reaction was carried out for 6 hours while maintaining the temperature of the reactor at 98 占 폚. Reactor The stirrer was operated to rotate at 60 revolutions per minute, and the pressure of the reaction tank was 0.5 kg / m3.
투입된 동물의 털이 완전히 가수분해되어 액체가 될 때까지 반응시킨 후, 온도를 57℃로 낮추고 여기에 판크레아틴 3㎏을 투입하여 온도를 55℃로 유지하면서 24시간 동안 숙성시켰다. 숙성시에는 분당 60회의 교반을 유지하였다.After the horses of the injected animals were completely hydrolyzed and reacted until a liquid was obtained, the temperature was lowered to 57 ° C, 3 kg of pancreatin was added thereto, and aged for 24 hours while maintaining the temperature at 55 ° C. During aging, stirring was maintained at 60 times per minute.
24시간 동안 숙성시킨 액체를 기공크기가 100μ인 여과기를 사용하여 여과하였다.The liquid aged for 24 hours was filtered using a filter having a pore size of 100 mu.
얻어진 여과액은 ㎏당 유기태 질소 2.05%, 칼륨(K2O) 1.5% 및 아미노산 54.8%를 함유하였다. 상기 여과액에 질소, 인산, KCl, H3BO3및 Na2MoO42H2O를 첨가하고, 30℃에서 2시간 동안 교반한 후, 기공크기가 20μ인 여과기로 여과하여 액체 비료를 제조하였다.The obtained filtrate contained 2.05% of organic nitrogen per kg, 1.5% of potassium (K 2 O) and 54.8% of amino acid. Nitrogen, phosphoric acid, KCl, H 3 BO 3 and Na 2 MoO 4 2H 2 O were added to the filtrate, stirred at 30 ° C for 2 hours, and then filtered with a filter having a pore size of 20μ to prepare a liquid fertilizer .
여과된 액체 비료는 그 조성중에 질소 6%, 인산 3%, 칼륨 4%, 붕소 0.05%, 몰리브덴 0.0005%를 함유하였다.The filtered liquid fertilizer contained 6% nitrogen, 3% phosphoric acid, 4% potassium, 0.05% boron and 0.0005% molybdenum in its composition.
[실시예 2 내지 4][Examples 2 to 4]
동물의 털 대신 동물로부터 얻어진 제각분, 표피 및 혈액을 원료로 한 것을 제외하고, 실시예 1과 동일한 방법으로 액체 비료를 제조하여 각각을 실시예 2 내지 4로 하였다.A liquid fertilizer was prepared in the same manner as in Example 1, except that the animal's hair was replaced with a sacrificed powder, epidermis, and blood obtained from an animal.
상기에서, 동물의 제각분은 0.5mm 이하로 미분하였고, 표피는 1cm 이하로 절단하여 사용하였으며, 동물의 혈액은 초산으로 pH를 4 내지 5로 조절하여 사용하였다.In the above, animals were divided into less than 0.5 mm and the cuticle was cut to 1 cm or less, and the blood of the animal was used with acetic acid adjusted to a pH of 4 to 5.
얻어진 액체 비료에 대하여 아미노산을 분석하고, 그 결과를 표2에 기재하였다.Amino acids were analyzed for the obtained liquid fertilizer, and the results are shown in Table 2.
동물의 혈액을 이용한 실시예 4에서는 철분이 248.43mg/kg이 검출되었다.In Example 4 using blood of animals, 248.43 mg / kg of iron was detected.
[발명의 효과][Effects of the Invention]
본 발명의 방법에 따라 제조된 동물로부터 얻어진 부산물을 이용한 액체 비료는 유기질 원료를 사용한 아미노산이 풍부한 액체 비료로서, 작물에 의한 직접 흡수가 용이하여 농작물과 과수의 성장을 촉진하고, 이 액체 비료를 사용할 경우 재배된 과실의 맛과 색상이 우수하고 농작물의 연작도 가능하며, 특히 냉해에 대하여 강력한 효과를 발휘할 뿐만 아니라, 화학비료에 의한 토양 산성화 문제 또한 방지할 수 있다.The liquid fertilizer using the byproducts obtained from the animal produced according to the method of the present invention is an amino acid-rich liquid fertilizer using an organic raw material and facilitates the direct absorption by the crop to promote the growth of crops and fruit juice. It is possible to produce crops with excellent taste and color and to produce crops. In particular, it not only exerts a powerful effect against cold weather, but also can prevent the problem of soil acidification by chemical fertilizer.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20000063721A (en) * | 2000-08-01 | 2000-11-06 | 신람식 | organic liquid manure |
KR20020006548A (en) * | 2002-01-02 | 2002-01-19 | 김찬홍 | Amino acid liquid fertilizer |
KR100433046B1 (en) * | 2000-10-17 | 2004-05-24 | 이상진 | Reuse method and apparatus for waste water |
KR101255972B1 (en) * | 2012-07-04 | 2013-04-23 | 윤재현 | Method for promoting production of biogas using pancreatin in an anaerobic digestion process |
KR102178329B1 (en) | 2019-11-01 | 2020-11-13 | (주)우리비앤비 | Method of disposing of slaughter by-products |
Families Citing this family (5)
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KR100333091B1 (en) * | 1999-09-13 | 2002-04-22 | 오남순 | Manufacturing Method of Liquid Fertilizer Based on the Hydrolyzed Blood Meal |
KR100407560B1 (en) * | 2000-02-15 | 2003-12-11 | 대한민국(여수대학교 총장) | Method for preparing fertilizer by utilizing oligopeptide salt and/or amino acid salt mixture |
KR20010089928A (en) * | 2000-03-14 | 2001-10-17 | 신용환 | A method for preparing organic solid fertilizer by using bovine hair |
KR100699321B1 (en) * | 2005-10-06 | 2007-03-23 | 장창순 | The manufacturing method of organic fertilizer containing high amino acid content utilizing the animal by-products |
KR102104279B1 (en) | 2018-12-07 | 2020-04-24 | 주식회사 바이오에이엠 | Animal feed additive and manufacturing method thereof |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20000063721A (en) * | 2000-08-01 | 2000-11-06 | 신람식 | organic liquid manure |
KR100433046B1 (en) * | 2000-10-17 | 2004-05-24 | 이상진 | Reuse method and apparatus for waste water |
KR20020006548A (en) * | 2002-01-02 | 2002-01-19 | 김찬홍 | Amino acid liquid fertilizer |
KR101255972B1 (en) * | 2012-07-04 | 2013-04-23 | 윤재현 | Method for promoting production of biogas using pancreatin in an anaerobic digestion process |
WO2014007530A1 (en) * | 2012-07-04 | 2014-01-09 | 한국과학기술원 | Method for promoting production of biogas using pancreatin in anaerobic digestion process |
KR102178329B1 (en) | 2019-11-01 | 2020-11-13 | (주)우리비앤비 | Method of disposing of slaughter by-products |
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