JPWO2020080122A1 - 印刷物の製造方法 - Google Patents
印刷物の製造方法 Download PDFInfo
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- JPWO2020080122A1 JPWO2020080122A1 JP2020526463A JP2020526463A JPWO2020080122A1 JP WO2020080122 A1 JPWO2020080122 A1 JP WO2020080122A1 JP 2020526463 A JP2020526463 A JP 2020526463A JP 2020526463 A JP2020526463 A JP 2020526463A JP WO2020080122 A1 JPWO2020080122 A1 JP WO2020080122A1
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- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- NHKJPPKXDNZFBJ-UHFFFAOYSA-N phenyllithium Chemical compound [Li]C1=CC=CC=C1 NHKJPPKXDNZFBJ-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229940110337 pigment blue 1 Drugs 0.000 description 1
- 229940104573 pigment red 5 Drugs 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- XIQGQTYUPQAUBV-UHFFFAOYSA-N prop-2-enoic acid;prop-1-en-2-ylbenzene;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1.CC(=C)C1=CC=CC=C1 XIQGQTYUPQAUBV-UHFFFAOYSA-N 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- ARENMZZMCSLORU-UHFFFAOYSA-N propan-2-yl naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)OC(C)C)=CC=CC2=C1 ARENMZZMCSLORU-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 125000005930 sec-butyloxycarbonyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(OC(*)=O)C([H])([H])[H] 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 1
- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 1
- 235000019250 sodium sorbate Nutrition 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- XNRNJIIJLOFJEK-UHFFFAOYSA-N sodium;1-oxidopyridine-2-thione Chemical compound [Na+].[O-]N1C=CC=CC1=S XNRNJIIJLOFJEK-UHFFFAOYSA-N 0.000 description 1
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical group C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 229920005792 styrene-acrylic resin Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical class O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- QZQIWEZRSIPYCU-UHFFFAOYSA-N trithiole Chemical group S1SC=CS1 QZQIWEZRSIPYCU-UHFFFAOYSA-N 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PGOLTJPQCISRTO-UHFFFAOYSA-N vinyllithium Chemical compound [Li]C=C PGOLTJPQCISRTO-UHFFFAOYSA-N 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 230000016776 visual perception Effects 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000009279 wet oxidation reaction Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- FYGDTMLNYKFZSV-BYLHFPJWSA-N β-1,4-galactotrioside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-BYLHFPJWSA-N 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Coloring (AREA)
- Ink Jet (AREA)
Abstract
Description
測定装置:TVE−25形粘度計(社製、TVE−25 L)
校正用標準液:JS20
測定温度:32℃
回転速度:10〜100rpm
注入量:1200μL
測定装置:自動表面張力計(協和界面科学(株)社製、CBVP−Z型)
測定温度:25℃
測定子:白金プレート
(i)顔料を顔料分散剤と共に、後述する分散方法で水性媒体(C)中に分散させる方法
(ii)顔料の表面に分散性付与基(親水性官能基および/またはその塩)を直接またはアルキル基、アルキルエーテル基またはアリール基等を介して間接的に結合させた自己分散型顔料を水性媒体(C)に分散および/または溶解させる方法が挙げられる。
前記顔料分散剤は、前記色材(B)として顔料を使用する場合に、好適に使用することができる。
(1)ポリマー(G)の酸価を予め、JIS試験方法K 0070−1992に基づく酸価測定方法により測定する。具体的には、テトラヒドロフランにポリマー(G)0.5gを溶解させ、フェノールフタレインを指示薬として、0.1M水酸化カリウムアルコール溶液で滴定し酸価を求める。
(2)水50mlに対して、ポリマー(G)を1g添加後、得られた酸価を100%中和するだけの0.1mol/L水酸化カリウム水溶液を加え、100%中和とする。
(3)100%中和させた液を、25℃の温度下で、2時間超音波洗浄器(株式会社エスエヌディ超音波洗浄器US−102、38kHz自励発振)中で超音波を照射させた後24時間室温で放置する。
ゲル・パーミエーション・クロマトグラフィー(GPC)法により、下記の条件で測定した。
測定装置:高速GPC装置(東ソー株式会社製「HLC−8220GPC」)
カラム:東ソー株式会社製の下記のカラムを直列に接続して使用した。
「TSKgel G4000」(7.8mmI.D.×30cm)×1本
「TSKgel G3000」(7.8mmI.D.×30cm)×1本
「TSKgel G2000」(7.8mmI.D.×30cm)×1本
検出器:RI(示差屈折計)
カラム温度:40℃
溶離液:テトラヒドロフラン
流速:1.0mL/分
注入量:100μL(試料濃度0.4質量%のテトラヒドロフラン溶液)
標準試料:下記の標準ポリスチレンを用いて検量線を作成した。
(標準ポリスチレン)
東ソー株式会社製「TSKgel 標準ポリスチレン A−500」
東ソー株式会社製「TSKgel 標準ポリスチレン A−1000」
東ソー株式会社製「TSKgel 標準ポリスチレン A−2500」
東ソー株式会社製「TSKgel 標準ポリスチレン A−5000」
東ソー株式会社製「TSKgel 標準ポリスチレン F−1」
東ソー株式会社製「TSKgel 標準ポリスチレン F−2」
東ソー株式会社製「TSKgel 標準ポリスチレン F−4」
東ソー株式会社製「TSKgel 標準ポリスチレン F−10」
東ソー株式会社製「TSKgel 標準ポリスチレン F−20」
東ソー株式会社製「TSKgel 標準ポリスチレン F−40」
東ソー株式会社製「TSKgel 標準ポリスチレン F−80」
東ソー株式会社製「TSKgel 標準ポリスチレン F−128」
東ソー株式会社製「TSKgel 標準ポリスチレン F−288」
東ソー株式会社製「TSKgel 標準ポリスチレン F−550」
芳香環または複素環を有するモノマーのポリマーブロックとは、具体的には、スチレン系モノマー等の芳香族環を有するモノマーや、ビニルピリジン系モノマー等の複素環を有するモノマーを単独重合または共重合して得たホモポリマーまたはコポリマーのポリマーブロックである。
前記ポリマーブロックA3におけるアニオン性基は、例えば、カルボキシル基、スルホン酸基または燐酸基等があげられる。なかでも、カルボキシル基がその調製やモノマー品種の豊富さ入手し易さから好ましい。また2つのカルボキシル基が分子内または分子間において脱水縮合した酸無水基となっていてもよい。
第一のモノマーと重合を開始させる重合開始剤とを、それぞれチューブリアクターP1及びP2(図1中7及び8)から、複数の液体を混合可能な流路を備えるT字型マイクロミキサーM1(図1中1)に導入し、T字型マイクロミキサーM1内で、第一のモノマーをリビングアニオン重合し第一の重合体を形成する(工程1)。
なお、このとき反応調整剤の種類や使用量により、前記一般式(3)におけるnの数をコントロールすることが可能である。
次に、反応調整剤を使用して成長末端の反応性を調整した後、前記アニオン性基に再生可能な保護基を有する(メタ)アクリレートを含むモノマーを前記第二のモノマーとして反応させポリマーブロックを得る。
前記ポリマーブロック(A2)とポリマーブロック(A3)のモル比A2:A3を、ポリマーブロック(A2)を構成する芳香環または複素環を有するモル数と、(A3)を構成するアニオン性基のモル数のモル比で表した場合は100:7.5〜100:400が好ましい。
本発明のインクは、前記色材(B)が顔料である場合、顔料を高濃度で含有する水性顔料分散体を製造し、前記水性媒体(C)と、前記バインダー樹脂(A)や界面活性剤(E)、必要に応じてその他の添加剤とを混合することによって製造することができる。
(1)分散樹脂及び水を含有する混合物に、顔料を添加した後、攪拌分散装置を用いて顔料を前記混合物中に分散させることにより水性顔料分散体を調製する方法。
(2)顔料及び分散樹脂を2本ロールやミキサー等の混練機を用いて混練し、得られた混練物を、水、および必要に応じて水と混和する有機溶剤を添加し、攪拌分散装置を用いて水性顔料分散体を調製する方法。
(3)メチルエチルケトン、テトラヒドロフラン等のような水と相溶性を有する有機溶剤中に分散樹脂を溶解して得られた溶液に顔料を添加した後、攪拌分散装置を用いて顔料を有機溶液中に分散させ、次いで水性媒体を用いて転相乳化させた後、前記有機溶剤を留去し水性顔料分散体を調製する方法。
一般的に、布帛とは綿などの繊維からなる糸を縦方向と横方向に交互に織ることで作られる織物を意味する。本発明のインクは一般的な意味での布帛だけでなく、不織布や編物などの繊維で構成される媒体に好適である。素材は綿、絹、羊毛、麻、ナイロン、ポリエステル、ポリウレタン、レーヨン等の任意の天然繊維や合成繊維からなる布帛や、これらが混紡された布帛を用いることができる。
BuLiのヘキサン溶液と、スチレンを予めテトラヒドロフランに溶解したスチレン溶液とを図1に示すチューブリアクターP1及びP2から、T字型マイクロミキサーM1に導入し、リビングアニオン重合させることによって重合体を得た。
(BuLi/スチレン/α−メチルスチレン/tert−ブチルメタクリレート)=1.0/12.0/1.3/8.1であった。
ゲル・パーミエーション・クロマトグラフィー(GPC)法により、下記の条件で測定した。
カラム:東ソー株式会社製の下記のカラムを直列に接続して使用した。
「TSKgel G4000」(7.8mmI.D.×30cm)×1本
「TSKgel G3000」(7.8mmI.D.×30cm)×1本
「TSKgel G2000」(7.8mmI.D.×30cm)×1本
検出器:RI(示差屈折計)
カラム温度:40℃
溶離液:テトラヒドロフラン(THF)
流速:1.0mL/分
注入量:100μL(試料濃度0.4質量%のTHF溶液)
標準試料:下記の標準ポリスチレンを用いて検量線を作成した。
東ソー株式会社製「TSKgel 標準ポリスチレン A−500」
東ソー株式会社製「TSKgel 標準ポリスチレン A−1000」
東ソー株式会社製「TSKgel 標準ポリスチレン A−2500」
東ソー株式会社製「TSKgel 標準ポリスチレン A−5000」
東ソー株式会社製「TSKgel 標準ポリスチレン F−1」
東ソー株式会社製「TSKgel 標準ポリスチレン F−2」
東ソー株式会社製「TSKgel 標準ポリスチレン F−4」
東ソー株式会社製「TSKgel 標準ポリスチレン F−10」
東ソー株式会社製「TSKgel 標準ポリスチレン F−20」
東ソー株式会社製「TSKgel 標準ポリスチレン F−40」
東ソー株式会社製「TSKgel 標準ポリスチレン F−80」
東ソー株式会社製「TSKgel 標準ポリスチレン F−128」
東ソー株式会社製「TSKgel 標準ポリスチレン F−288」
東ソー株式会社製「TSKgel 標準ポリスチレン F−550」
JIS試験方法K 0070−1992に準拠して測定した。THFに試料0.5gを溶解させ、フェノールフタレインを指示薬として、0.1M水酸化カリウムアルコール溶液で滴定することにより求めた。
顔料としてFastogen Super Magenta RY(DIC株式会社製、C.I.Pigment Red 122)を150質量部、前記分散樹脂(P−1)を30質量部、トリエチレングリコールを150質量部、34質量%水酸化カリウム水溶液11.5質量部を、1.0Lのインテンシブミキサー(日本アイリッヒ株式会社)に仕込み、ローター周速2.94m/s、パン周速1m/sで、60分間混練した。
前記水性顔料分散体(A1)30質量部、バインダー樹脂として後述のウレタン樹脂組成物(不揮発分23%質量%)7質量部、サーフィノール440(EVONIK製、アセチレン系界面活性剤)1質量部、グリセリンを25質量部、トリエチレングリコールを1質量部、3−メチル−1,5−ペンタンジオール1質量部、防腐剤としてACTICIDE B−20(ソー・ジャパン(株)製)0.2質量部、イオン交換水34.8質量部を混合することによって水性インクを得た。前記水性インクの25℃での粘度は10mPa・s、表面張力は34mN/mであった。
温度計、窒素ガス導入管、攪拌器を備えた窒素置換された容器中で、1,6−ヘキサンジオールとメチルカーボネートとを反応して得られるポリカーボネートポリオール(数平均分子量2000)500質量部、2,2―ジメチロールプロピオン酸37.7質量部及びメチルエチルケトン 420質量部を加え、均一に混合した。次いで、トリレンジイソシアネート92.4質量部を加えた後、ジブチル錫ジラウレート0.1質量部を加え、80℃で7時間反応させることによって、重量平均分子量が40000のポリウレタン(PUD−1)(酸価35mgKOH/g)の有機溶剤溶液を得た。その後、50℃まで冷却し、トリエチルアミン29.8質量部及び水2069質量部を加え、減圧下、40℃〜60℃の温度下でメチルエチルケトンを除去し、水を加えて濃度調節を行うことによって、前記ウレタン樹脂(PUD−1)が水性媒体中に分散された不揮発分23質量%のウレタン樹脂組成物を得た。
ゲル・パーミエーション・クロマトグラフィー(GPC)法により、前述の条件で測定した。
JIS試験方法K 0070−1992に準拠し前述の条件により求めた。
前記ウレタン樹脂(PUD−1)のガラス転移温度は、DSCを用いて測定した。
測定装置:TVE−25形粘度計(社製、TVE−25 L)
校正用標準液:JS20
測定温度:32℃
回転速度:10〜100rpm
注入量:1200μL
インクの静的表面張力は、ウィルへルミ法を適用した自動表面張力計を用い、下記条件にて測定した。
測定装置:自動表面張力計(協和界面科学(株)社製、CBVP−Z型)
測定温度:25℃
測定子:白金プレート
インクの液滴サイズを表1に記載の値に変更したこと以外は、実施例1と同様の方法で印刷物を得た。
前記方法で得られた印刷物のインク濃度(OD値)をX−Rite(エックスライト(株)製分光濃度計・色彩計)を用いて測定し、布帛上でのインク濃度を評価した。
前記方法で得られた印刷物をスキャナーで読み取り、画像解析ソフト「ImageJ」にてインクが塗布されていない部分を算出し、画質評価をおこなった。
△:印刷物のインクが塗布されていない部分の割合が5%以上10%未満
×:印刷物のインクが塗布されていない部分の割合が10%以上
前記方法で得られた印刷物について、JIS L 0844:2005のA−2法に準拠して、試験した後、JIS L 0801:2004の変退色用グレースケールを用いた視感法の判定基準にしたがって、1級〜5級で等級を判定した。なお、等級は、1級が最も退色が大きく、5級に近づくほど退色が少ないと評価した。
前記方法で得られた印刷物について、JIS L 0849:2004に準拠して、学振型摩擦堅牢度試験機を使用して、乾式及び湿式の試験を行った後、JIS L 0801:2004の変退色用グレースケールを用いた視感法の判定基準にしたがって、1級〜 5級で等級を判定した。なお、等級は、1級が最も退色が大きく、5級に近づくほど退色が少ない。
2:T字型マイクロミキサーM2
3:T字型マイクロミキサーM3
4:チューブリアクターR1
5:チューブリアクターR2
6:チューブリアクターR3
7:プレクーリングの為のチューブリアクターP1
8:プレクーリングの為のチューブリアクターP2
9:プレクーリングの為のチューブリアクターP3
10:プレクーリングの為のチューブリアクターP4
Claims (3)
- インクジェット記録方式で布帛にインクを印刷することにより印刷物を得る印刷工程を備え、前記印刷工程において、インクジェットヘッドのインク吐出口と前記布帛との最短距離が2mm以上であり、前記インクジェットヘッドから吐出されるインク液滴1個のサイズが10〜50plの範囲であることを特徴とする印刷物の製造方法。
- 前記インクが、前記インクの全量に対してバインダー樹脂(A)を1〜15質量%含有するものである請求項1に記載の印刷物の製造方法。
- 前記インクが、粘度20mPa・s以下で、かつ、表面張力20mN/m〜40mN/mの範囲である請求項1または2に記載の印刷物の製造方法。
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Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000110084A (ja) * | 1998-10-05 | 2000-04-18 | Canon Inc | インクジェット染色用布帛処理剤、インクジェット染色用布帛処理液、インクジェット染色用布帛、捺染方法及び捺染物 |
JP2003096342A (ja) * | 2001-09-19 | 2003-04-03 | Fuji Shikiso Kk | インクジェット印刷用水系インク組成物 |
JP2003213164A (ja) * | 2002-01-18 | 2003-07-30 | Fuji Shikiso Kk | インクジェット印刷用水系顔料インク組成物 |
JP2007522285A (ja) * | 2004-01-21 | 2007-08-09 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 架橋済みポリウレタンを含有するインクジェットインキ |
JP2008223193A (ja) * | 2007-03-15 | 2008-09-25 | Seiko Epson Corp | インクジェット捺染用前処理剤、前記前処理剤によって処理した布帛、及びインクジェット捺染方法 |
JP2010070886A (ja) * | 2008-09-22 | 2010-04-02 | Konica Minolta Ij Technologies Inc | インクジェット記録方法 |
WO2011027560A1 (ja) * | 2009-09-02 | 2011-03-10 | 株式会社ミマキエンジニアリング | インクジェットプリンタ、及び印刷方法 |
JP2014159114A (ja) * | 2013-02-19 | 2014-09-04 | Fujifilm Corp | インクジェット記録方法及びインクジェット記録装置 |
JP2014163021A (ja) * | 2013-02-27 | 2014-09-08 | Seiko Epson Corp | 顔料捺染インクジェット記録方法 |
WO2015115614A1 (ja) * | 2014-01-30 | 2015-08-06 | コニカミノルタ株式会社 | インクジェットインクおよびインクジェット記録方法 |
JP2015182237A (ja) * | 2014-03-20 | 2015-10-22 | セーレン株式会社 | インクジェット記録方法 |
-
2019
- 2019-10-03 JP JP2020526463A patent/JP6886601B2/ja active Active
- 2019-10-03 WO PCT/JP2019/039099 patent/WO2020080122A1/ja active Application Filing
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000110084A (ja) * | 1998-10-05 | 2000-04-18 | Canon Inc | インクジェット染色用布帛処理剤、インクジェット染色用布帛処理液、インクジェット染色用布帛、捺染方法及び捺染物 |
JP2003096342A (ja) * | 2001-09-19 | 2003-04-03 | Fuji Shikiso Kk | インクジェット印刷用水系インク組成物 |
JP2003213164A (ja) * | 2002-01-18 | 2003-07-30 | Fuji Shikiso Kk | インクジェット印刷用水系顔料インク組成物 |
JP2007522285A (ja) * | 2004-01-21 | 2007-08-09 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 架橋済みポリウレタンを含有するインクジェットインキ |
JP2008223193A (ja) * | 2007-03-15 | 2008-09-25 | Seiko Epson Corp | インクジェット捺染用前処理剤、前記前処理剤によって処理した布帛、及びインクジェット捺染方法 |
JP2010070886A (ja) * | 2008-09-22 | 2010-04-02 | Konica Minolta Ij Technologies Inc | インクジェット記録方法 |
WO2011027560A1 (ja) * | 2009-09-02 | 2011-03-10 | 株式会社ミマキエンジニアリング | インクジェットプリンタ、及び印刷方法 |
JP2014159114A (ja) * | 2013-02-19 | 2014-09-04 | Fujifilm Corp | インクジェット記録方法及びインクジェット記録装置 |
JP2014163021A (ja) * | 2013-02-27 | 2014-09-08 | Seiko Epson Corp | 顔料捺染インクジェット記録方法 |
WO2015115614A1 (ja) * | 2014-01-30 | 2015-08-06 | コニカミノルタ株式会社 | インクジェットインクおよびインクジェット記録方法 |
JP2015182237A (ja) * | 2014-03-20 | 2015-10-22 | セーレン株式会社 | インクジェット記録方法 |
Non-Patent Citations (1)
Title |
---|
電子写真学会誌, vol. 第37巻、第2号, JPN6020049201, 1998, pages 149 - 155, ISSN: 0004477948 * |
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