JPWO2020003169A5 - - Google Patents
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- JPWO2020003169A5 JPWO2020003169A5 JP2020573036A JP2020573036A JPWO2020003169A5 JP WO2020003169 A5 JPWO2020003169 A5 JP WO2020003169A5 JP 2020573036 A JP2020573036 A JP 2020573036A JP 2020573036 A JP2020573036 A JP 2020573036A JP WO2020003169 A5 JPWO2020003169 A5 JP WO2020003169A5
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- 239000003085 diluting agent Substances 0.000 claims description 24
- 239000011347 resin Substances 0.000 claims description 24
- 229920005989 resin Polymers 0.000 claims description 24
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 20
- JOYRKODLDBILNP-UHFFFAOYSA-N ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 16
- 150000002009 diols Chemical class 0.000 claims description 13
- 230000002378 acidificating Effects 0.000 claims description 12
- 125000000524 functional group Chemical group 0.000 claims description 12
- 239000003211 photoinitiator Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 4
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 239000004417 polycarbonate Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 238000002835 absorbance Methods 0.000 claims description 2
- 239000006096 absorbing agent Substances 0.000 claims description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M carbamate Chemical group NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 230000001143 conditioned Effects 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002504 physiological saline solution Substances 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000011528 polyamide (building material) Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
Description
上記の特許出願において引用された全ての参考文献、特許文献又は特許出願は、一貫した形でその全文が参照により本明細書に組み込まれる。組み込まれた参照文献の一部と本出願との間に不一致又は矛盾がある場合、前述の記載における情報が優先するものとする。以下に例示的実施形態を示す。
［項目１］
歯科矯正物品であって、
３０～７０重量％（両端の値を含む）の少なくとも１つのウレタン成分と、
２５～７０重量％（両端の値を含む）の、少なくとも１つの単官能性（メタ）アクリレートモノマーを含む反応性希釈剤と、
少なくとも１つの、酸性官能基を有するエチレン性不飽和成分と、を含むフリーラジカル重合性樹脂の反応生成物を含む硬化組成物を含み、
前記フリーラジカル重合性樹脂が、３５重量％以下の、水に対して高い親和性を有する反応性希釈剤を含む、歯科矯正物品。
［項目２］
水に対して高い親和性を有する前記反応性希釈剤が、１．５未満、又は１未満のｌｏｇ Ｐを有する、項目１に記載の歯科矯正物品。
［項目３］
前記反応性希釈剤が、２、２．５、３、又は３．５を超えるｌｏｇ Ｐを有する少なくとも１つの単官能性（メタ）アクリレートモノマーを含む、項目１又は２に記載の歯科矯正物品。
［項目４］
水に対して高い親和性を有する前記反応性希釈剤が、２、２．５、３、又は３．５を超えるｌｏｇ Ｐを有する前記単官能性（メタ）アクリレートモノマーよりも少ない量で存在する、項目３に記載の歯科矯正物品。
［項目５］
前記重合性樹脂が、水に対して高い親和性を有する反応性希釈剤を、前記反応性希釈剤の５０、４５、３０、又は２５重量％以下の濃度で含む、項目１～４のいずれか一項に記載の歯科矯正物品。
［項目６］
前記反応性希釈剤が、前記ウレタン成分の分子量より小さい分子量を有する単官能性（メタ）アクリレートモノマーを含む、項目１～５のいずれか一項に記載の歯科矯正物品。
［項目７］
前記反応性希釈剤が、４００ｇ／モル未満の分子量を有する単官能性（メタ）アクリレートモノマーを含む、項目１～６のいずれか一項に記載の歯科矯正物品。
［項目８］
前記反応性希釈剤が、単官能性（メタ）アクリレートモノマーの混合物を含む、項目１～７のいずれか一項に記載の歯科矯正物品。
［項目９］
前記反応性希釈剤が、前記フリーラジカル重合性樹脂の１～３０重量％の量の少なくとも１つの多官能性反応性希釈剤を含む、項目１～８のいずれか一項に記載の歯科矯正物品。
［項目１０］
反応性希釈剤が、少なくとも２５、３０、３５、４０、４５、又は５０℃のＴｇを有する少なくとも１つの単官能性（メタ）アクリレートモノマーを含む、項目１～９のいずれか一項に記載の歯科矯正物品。
［項目１１］
酸性官能基を有する前記エチレン性不飽和成分が、前記フリーラジカル重合性樹脂の少なくとも０．５、１、１．５、２、２．５、３、３．５、４、３．５、又は５重量％の量で存在する、項目１～１０のいずれか一項に記載の歯科矯正物品。
［項目１２］
酸性官能基を有する前記エチレン性不飽和成分が、前記フリーラジカル重合性樹脂の３５、３０、２５、２０、１５、又は１０重量％以下の量で存在する、項目１～９のいずれか一項に記載の歯科矯正物品。
［項目１３］
酸性官能基を有する前記エチレン性不飽和成分が、少なくとも３０、３５、４０、４５、５０、５５、６０、６５、７０、７５、８０、８５、９０、９５、１００℃のＴｇを有する、項目１～１２のいずれか一項に記載の歯科矯正物品。
［項目１４］
酸性官能基を有する前記エチレン性不飽和成分が、２０、１５、１０、５、０、－５、－１０、又は－１５℃未満のＴｇを有する、項目１～１２のいずれか一項に記載の歯科矯正物品。
［項目１５］
酸性官能基当たりの酸性官能基を有するエチレン性不飽和成分の当量を、カルバメート官能基当たりの前記ウレタン成分の当量で割ったものが、６、５、４、３、又は２未満である、項目１～１２のいずれか一項に記載の歯科矯正物品。
［項目１６］
前記ウレタン成分が、アルキル、ポリアルキレン、ポリアルキレンオキシド、アリール、ポリカーボネート、ポリエステル、ポリアミド、及びこれらの組み合わせから選択される連結基を含む、項目１～１５のいずれか一項に記載の歯科矯正物品。
［項目１７］
前記ウレタン成分が、ポリカーボネートジオール若しくはポリエステルジオールから選択されるジオール又はポリアルキレンオキシド又はこれらの組み合わせから誘導される重合単位を含むウレタン（メタ）アクリレートポリマーである、項目１～１６のいずれか一項に記載の歯科矯正物品。
［項目１８］
前記ジオールが、少なくとも７５０、８００、８５０、９００、９５０、又は１０００ｇ／モルのＭｎを有する、項目１７に記載の歯科矯正物品。
［項目１９］
前記ウレタン（メタ）アクリレートポリマーが、２，０００ｇ／モル～５０，０００ｇ／モルの分子量（Ｍｗ）を有する、項目１７又は１８に記載の歯科矯正物品。
［項目２０］
前記ウレタン（メタ）アクリレートポリマーが、ポリカーボネートジオール、ポリエステルジオール、又はポリアルキレンオキシドジオールから選択される少なくとも１つのジオールに由来する、項目１７～１９のいずれか一項に記載の歯科矯正物品。
［項目２１］
前記重合性樹脂が、１０重量％を超える、そのホモポリマーが６０、６５、７０、７５、８０、８５、又は９０℃のＴｇを有する単官能性（メタ）アクリレートモノマーを含む、項目１～２０のいずれか一項に記載の歯科矯正物品。
［項目２２］
前記重合性樹脂が、１０重量％超の、少なくとも３．５のｌｏｇ Ｐを有する単官能性（メタ）アクリレートモノマーを含む、項目１～２１のいずれか一項に記載の歯科矯正物品。
［項目２３］
前記重合性樹脂が、２５℃未満のＴｇを有する単官能性（メタ）アクリレートモノマーを２５、２０、１５、１０、又は５重量％未満の量で含む、項目１～２２のいずれか一項に記載の歯科矯正物品。
［項目２４］
前記重合性樹脂が、２５℃未満のＴｇを有する単官能性（メタ）アクリレートモノマーを含まない、項目１～２３のいずれか一項に記載の歯科矯正物品。
［項目２５］
前記組成物が、前記重合性組成物の総重量に基づいて、０．１～５重量％の光開始剤を含み、前記光開始剤が、単一の光開始剤を含むか、又は第１の光開始剤と、熱開始剤若しくは第１の光開始剤とは異なる波長範囲で十分な吸光度を有する光開始剤から選択される第２のフリーラジカル開始剤と、を含む、項目１～２４のいずれか一項に記載の歯科矯正物品。
［項目２６］
前記重合性組成物が、紫外線吸収剤を更に含む、項目１～２５のいずれか一項に記載の歯科矯正物品。
［項目２７］
前記歯科矯正物品が、５％のエタノールの水溶液中に０．１重量％未満の抽出物を含む、項目１～２６のいずれか一項に記載の歯科矯正物品。
［項目２８］
前記硬化組成物が、３７℃の温度で２４時間、ｐＨ７．４を有するリン酸緩衝生理食塩水中でのコンディショニング後に、ＡＳＴＭ Ｄ６３８－１４に従って測定したときに、１５％以上の破断点伸び及び少なくとも１０ＭＰａの降伏点引張強度を示す、項目１～２７のいずれか一項に記載の歯科矯正物品。
［項目２９］
前記硬化光重合性組成物重合組成物が、２０～２５℃で４８時間脱イオン水中でのコンディショニング後に、２％のひずみで動的機械分析に従って測定したときに、少なくとも１００ＭＰａの３点曲げ弾性率を示す、項目１～２８のいずれか一項に記載の歯科矯正物品。
［項目３０］
歯科矯正物品であって、
３０～７０重量％（両端の値を含む）の少なくとも１つのウレタン成分と、
２５～７０重量％（両端の値を含む）の、少なくとも１つの単官能性（メタ）アクリレートモノマーを含む反応性希釈剤と、を含むフリーラジカル重合性樹脂の反応生成物を含む硬化組成物を含み、
前記重合性樹脂が、３５重量％以下の、水に対して高い親和性を有する反応性希釈剤を含む、歯科矯正物品。
［項目３１］
前記重合性樹脂が、項目２～２９のいずれか一項に従って更に特徴付けられる、項目３０に記載の歯科矯正物品。
［項目３２］
前記ウレタン成分が、ポリエーテルジオールから誘導され、前記重合性組成物が、２５℃未満のＴｇを有する単官能性（メタ）アクリレートモノマーを含まない、項目３０に記載の歯科矯正物品。
［項目３３］
前記重合性樹脂が、項目２～２２及び２４～２９のいずれか一項に従って更に特徴付けられる、項目３２に記載の歯科矯正物品。
［項目３４］
前記歯科矯正物品が、歯科矯正トレイアライナ物品である、項目１～３３のいずれか一項に記載の歯科矯正物品。
［項目３５］
重合性組成物であって、
３０～７０重量％（両端の値を含む）の少なくとも１つのウレタン成分と、
２５～７０重量％（両端の値を含む）の、少なくとも１つの単官能性（メタ）アクリレートモノマーを含む反応性希釈剤と、
任意に、少なくとも１つの、酸性官能基を有するエチレン性不飽和成分と、を含み、
重合性樹脂が、５０重量％以下の、水に対して高い親和性を有する反応性希釈剤を含む、重合性組成物。
［項目３６］
前記重合性樹脂が、項目２～３３のいずれか一項に従って更に特徴付けられる、項目３５に記載の光重合性組成物。
All references, patent documents or patent applications cited in the above patent applications are incorporated herein by reference in their entirety in a consistent manner. In the event of any discrepancy or inconsistency between a portion of the incorporated references and this application, the information in the above description shall prevail. An exemplary embodiment is shown below.
[Item 1]
It ’s an orthodontic item,
With at least one urethane component of 30-70% by weight (including the values at both ends),
Reactive diluents comprising at least one monofunctional (meth) acrylate monomer of 25-70% by weight (including values at both ends).
A cured composition comprising a reaction product of a free radically polymerizable resin comprising at least one ethylenically unsaturated component having an acidic functional group.
An orthodontic article containing 35% by weight or less of the free radically polymerizable resin and a reactive diluent having a high affinity for water.
[Item 2]
The orthodontic article according to item 1, wherein the reactive diluent having a high affinity for water has a log P of less than 1.5 or less than 1.
[Item 3]
The orthodontic article of item 1 or 2, wherein the reactive diluent comprises at least one monofunctional (meth) acrylate monomer having a log P greater than 2, 2.5, 3, or 3.5.
[Item 4]
The reactive diluent having a high affinity for water is present in a smaller amount than the monofunctional (meth) acrylate monomer having a log P greater than 2, 2.5, 3, or 3.5. , The orthodontic article according to item 3.
[Item 5]
Any of items 1 to 4, wherein the polymerizable resin contains a reactive diluent having a high affinity for water at a concentration of 50, 45, 30, or 25% by weight or less of the reactive diluent. The orthodontic article described in paragraph 1.
[Item 6]
The orthodontic article according to any one of items 1 to 5, wherein the reactive diluent contains a monofunctional (meth) acrylate monomer having a molecular weight smaller than the molecular weight of the urethane component.
[Item 7]
The orthodontic article according to any one of items 1 to 6, wherein the reactive diluent contains a monofunctional (meth) acrylate monomer having a molecular weight of less than 400 g / mol.
[Item 8]
The orthodontic article according to any one of items 1 to 7, wherein the reactive diluent contains a mixture of monofunctional (meth) acrylate monomers.
[Item 9]
The orthodontic article according to any one of items 1 to 8, wherein the reactive diluent comprises at least one polyfunctional reactive diluent in an amount of 1 to 30% by weight of the free radically polymerizable resin. ..
[Item 10]
The item according to any one of items 1 to 9, wherein the reactive diluent comprises at least one monofunctional (meth) acrylate monomer having a Tg of at least 25, 30, 35, 40, 45, or 50 ° C. Orthodontic articles.
[Item 11]
The ethylenically unsaturated component having an acidic functional group is at least 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 3.5, or the free radically polymerizable resin of the free radically polymerizable resin. The orthodontic article according to any one of items 1 to 10, which is present in an amount of 5% by weight.
[Item 12]
Item 1 of item 1 to 9, wherein the ethylenically unsaturated component having an acidic functional group is present in an amount of 35, 30, 25, 20, 15, or 10% by weight or less of the free radically polymerizable resin. Orthodontic articles described in.
[Item 13]
The item, wherein the ethylenically unsaturated component having an acidic functional group has a Tg of at least 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 100 ° C. The orthodontic article according to any one of 1 to 12.
[Item 14]
Item 6. Orthodontic articles.
[Item 15]
Item that the equivalent of the ethylenically unsaturated component having an acidic functional group per acidic functional group divided by the equivalent of the urethane component per carbamate functional group is 6, 5, 4, 3, or less than 2. The orthodontic article according to any one of 1 to 12.
[Item 16]
The orthodontic article according to any one of items 1 to 15, wherein the urethane component comprises an alkyl, a polyalkylene, a polyalkylene oxide, an aryl, a polycarbonate, a polyester, a polyamide, and a linking group selected from a combination thereof. ..
[Item 17]
Item 1 to any one of items 1 to 16, wherein the urethane component is a urethane (meth) acrylate polymer containing a diol selected from a polycarbonate diol or a polyester diol, a polyalkylene oxide, or a polymerization unit derived from a combination thereof. The listed orthodontic article.
[Item 18]
The orthodontic article according to item 17, wherein the diol has at least 750, 800, 850, 900, 950, or 1000 g / mol of Mn.
[Item 19]
The orthodontic article according to item 17 or 18, wherein the urethane (meth) acrylate polymer has a molecular weight (Mw) of 2,000 g / mol to 50,000 g / mol.
[Item 20]
The orthodontic article according to any one of items 17 to 19, wherein the urethane (meth) acrylate polymer is derived from at least one diol selected from a polycarbonate diol, a polyester diol, or a polyalkylene oxide diol.
[Item 21]
Items 1-20, wherein the polymerizable resin comprises more than 10% by weight, the homopolymer comprising a monofunctional (meth) acrylate monomer having a Tg of 60, 65, 70, 75, 80, 85, or 90 ° C. The orthodontic article according to any one of the above.
[Item 22]
The orthodontic article according to any one of items 1 to 21, wherein the polymerizable resin contains a monofunctional (meth) acrylate monomer having a log P of at least 3.5, which is more than 10% by weight.
[Item 23]
Item 1 to any one of items 1 to 22, wherein the polymerizable resin contains a monofunctional (meth) acrylate monomer having a Tg of less than 25 ° C. in an amount of 25, 20, 15, 10, or less than 5% by weight. The orthodontic article described.
[Item 24]
The orthodontic article according to any one of items 1 to 23, wherein the polymerizable resin does not contain a monofunctional (meth) acrylate monomer having a Tg of less than 25 ° C.
[Item 25]
The composition comprises 0.1-5% by weight of the photoinitiator based on the total weight of the polymerizable composition and the photoinitiator comprises a single photoinitiator or a first. 1-24, comprising the photoinitiator of 1 and a second free radical initiator selected from photoinitiators having sufficient absorbance in a wavelength range different from that of the thermal initiator or the first photoinitiator. The orthodontic article according to any one of the above.
[Item 26]
The orthodontic article according to any one of items 1 to 25, wherein the polymerizable composition further contains an ultraviolet absorber.
[Item 27]
The orthodontic article according to any one of items 1 to 26, wherein the orthodontic article contains less than 0.1% by weight of an extract in a 5% aqueous solution of ethanol.
[Item 28]
When the cured composition was conditioned in a phosphate buffered physiological saline solution having a pH of 7.4 at a temperature of 37 ° C. for 24 hours and then measured according to ASTM D638-14, it had a breaking point elongation of 15% or more and at least 10 MPa. The orthodontic article according to any one of items 1 to 27, which indicates the yield point tensile strength of.
[Item 29]
Cured Photopolymerizable Composition When the polymerized composition is conditioned in deionized water at 20-25 ° C. for 48 hours and then measured by dynamic mechanical analysis at a strain of 2%, it has a three-point flexural modulus of at least 100 MPa. The orthodontic article according to any one of items 1 to 28.
[Item 30]
It ’s an orthodontic item,
With at least one urethane component of 30-70% by weight (including the values at both ends),
A cured composition comprising a reactive diluent comprising at least one monofunctional (meth) acrylate monomer of 25-70% by weight (including values at both ends) and a reaction product of a free radically polymerizable resin comprising. Including,
An orthodontic article containing 35% by weight or less of the polymerizable resin and a reactive diluent having a high affinity for water.
[Item 31]
30. The orthodontic article of item 30, wherein the polymerizable resin is further characterized according to any one of items 2-29.
[Item 32]
The orthodontic article according to item 30, wherein the urethane component is derived from a polyether diol, and the polymerizable composition does not contain a monofunctional (meth) acrylate monomer having a Tg of less than 25 ° C.
[Item 33]
32. The orthodontic article of item 32, wherein the polymerizable resin is further characterized according to any one of items 2-22 and 24-29.
[Item 34]
The orthodontic article according to any one of items 1 to 33, wherein the orthodontic article is an orthodontic tray aligner article.
[Item 35]
It is a polymerizable composition and
With at least one urethane component of 30-70% by weight (including the values at both ends),
Reactive diluents comprising at least one monofunctional (meth) acrylate monomer of 25-70% by weight (including values at both ends).
Optionally, it comprises at least one ethylenically unsaturated component having an acidic functional group.
A polymerizable composition comprising a reactive diluent in which the polymerizable resin has a high affinity for water in an amount of 50% by weight or less.
[Item 36]
35. The photopolymerizable composition of item 35, wherein the polymerizable resin is further characterized according to any one of items 2-33.
Claims (15)
３０～７０重量％（両端の値を含む）の少なくとも１つのウレタン成分と、
２５～７０重量％（両端の値を含む）の、少なくとも１つの単官能性（メタ）アクリレートモノマーを含む反応性希釈剤と、
少なくとも１つの、酸性官能基を有するエチレン性不飽和成分と、を含むフリーラジカル重合性樹脂の反応生成物を含む硬化組成物を含み、
前記フリーラジカル重合性樹脂が、３５重量％以下の、水に対して高い親和性を有する反応性希釈剤を含む、歯科矯正物品。 It ’s an orthodontic item,
With at least one urethane component of 30-70% by weight (including the values at both ends),
A reactive diluent comprising at least one monofunctional (meth) acrylate monomer of 25-70% by weight (including values at both ends).
A cured composition comprising a reaction product of a free radically polymerizable resin comprising at least one ethylenically unsaturated component having an acidic functional group.
An orthodontic article containing 35% by weight or less of the free radically polymerizable resin and a reactive diluent having a high affinity for water.
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| JP2024009850A JP2024038487A (en) | 2018-06-29 | 2024-01-26 | Orthodontic articles comprising cured free-radically polymerizable composition with improved strength in aqueous environment |
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| US201862692456P | 2018-06-29 | 2018-06-29 | |
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| US201862769421P | 2018-11-19 | 2018-11-19 | |
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| US201862769305P | 2018-11-19 | 2018-11-19 | |
| US201862769434P | 2018-11-19 | 2018-11-19 | |
| US201862769081P | 2018-11-19 | 2018-11-19 | |
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| US201962850658P | 2019-05-21 | 2019-05-21 | |
| US62/850,658 | 2019-05-21 | ||
| PCT/IB2019/055413 WO2020003169A1 (en) | 2018-06-29 | 2019-06-26 | Orthodontic articles comprising cured free-radically polymerizable composition with improved strength in aqueous environment |
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11141919B2 (en) | 2015-12-09 | 2021-10-12 | Holo, Inc. | Multi-material stereolithographic three dimensional printing |
| US11904031B2 (en) * | 2017-11-22 | 2024-02-20 | 3M Innovative Properties Company | Orthodontic articles comprising polymerized composition comprising at least two free-radical initiators |
| US20230131633A1 (en) * | 2020-03-26 | 2023-04-27 | Mitsui Chemicals, Inc. | Photocurable composition, three-dimensional modeling product, and dental product |
| CN116472175A (en) * | 2020-09-03 | 2023-07-21 | 巴斯夫欧洲公司 | Reactive polyurethane elastomers |
| WO2022106998A1 (en) | 2020-11-20 | 2022-05-27 | 3M Innovative Properties Company | Articles, methods and compositions comprising polymerizable dicarbonyl polymers |
| KR102499004B1 (en) * | 2021-03-22 | 2023-02-14 | 오스템임플란트 주식회사 | Photocurable resin composition and molded article prepared therefrom |
| CN113185645A (en) * | 2021-04-23 | 2021-07-30 | 东莞理工学院 | Photosensitive resin for 3D printing based on DLP type photocuring and preparation method thereof |
| EP4334402A1 (en) | 2021-05-07 | 2024-03-13 | 3D Systems, Inc. | Additives for build materials and associated printed 3d articles |
| US11998415B2 (en) * | 2021-11-08 | 2024-06-04 | Sprintray, Inc. | System and method of forming a custom bleaching tray with trench and material reservoirs |
| DE102022110896A1 (en) * | 2022-05-03 | 2023-11-09 | Kulzer Gmbh | Radiation-curable composition for use in rapid prototyping or rapid manufacturing processes |
| WO2024044330A1 (en) * | 2022-08-24 | 2024-02-29 | Pac-Dent, Inc. | Photocurable materials for the production of dental prostheses and devices |
| DE102022123995A1 (en) | 2022-09-19 | 2024-03-21 | Amann Girrbach Ag | Light-curable mixture of substances |
Family Cites Families (132)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3429722A (en) | 1965-07-12 | 1969-02-25 | Carborundum Co | Boron nitride fiber manufacture |
| US3795524A (en) | 1971-03-01 | 1974-03-05 | Minnesota Mining & Mfg | Aluminum borate and aluminum borosilicate articles |
| GB1428673A (en) | 1972-06-02 | 1976-03-17 | Amalgamated Dental Co Ltd | Orthodontics |
| JPS5224965B2 (en) | 1972-06-28 | 1977-07-05 | ||
| US4047965A (en) | 1976-05-04 | 1977-09-13 | Minnesota Mining And Manufacturing Company | Non-frangible alumina-silica fibers |
| FR2431514A1 (en) | 1978-07-19 | 1980-02-15 | Poudres & Explosifs Ste Nale | NOVEL UNSATURATED POLY (CARBONATES-URETHANNES) AND THEIR APPLICATIONS TO PHOTORETICULATION |
| US4264752A (en) | 1979-08-08 | 1981-04-28 | Union Carbide Corporation | Radiation-curable acrylated urethane polycarbonate compositions |
| US4591626A (en) | 1983-10-24 | 1986-05-27 | Hitachi Chemical Company, Ltd. | Polymers of tricyclo[5.2.1.02,6 ]deca-8-yl (meth)acrylate |
| JPS6121117A (en) * | 1984-07-10 | 1986-01-29 | Yokohama Rubber Co Ltd:The | Photosetting resin composition |
| US4642126A (en) | 1985-02-11 | 1987-02-10 | Norton Company | Coated abrasives with rapidly curable adhesives and controllable curvature |
| US4652274A (en) | 1985-08-07 | 1987-03-24 | Minnesota Mining And Manufacturing Company | Coated abrasive product having radiation curable binder |
| JPH0653647B2 (en) | 1986-04-18 | 1994-07-20 | 而至歯科工業株式会社 | Dental restoration composition |
| US5185299A (en) | 1987-06-05 | 1993-02-09 | Minnesota Mining And Manufacturing Company | Microcrystalline alumina-based ceramic articles |
| US4954462A (en) | 1987-06-05 | 1990-09-04 | Minnesota Mining And Manufacturing Company | Microcrystalline alumina-based ceramic articles |
| CA2024379A1 (en) | 1989-09-01 | 1991-03-02 | Erwin S. Poklacki | Primary coating compositions for optical glass fibers |
| DE59007720D1 (en) | 1989-10-27 | 1994-12-22 | Ciba Geigy Ag | Method for tuning the radiation sensitivity of photopolymerizable compositions. |
| CA2048232A1 (en) | 1990-09-05 | 1992-03-06 | Jerry W. Williams | Energy curable pressure-sensitive compositions |
| EP0506616B1 (en) | 1991-03-27 | 1998-01-21 | Ciba SC Holding AG | Photosensitive acrylate mixture |
| CA2092131A1 (en) * | 1992-03-27 | 1993-09-28 | Victor Kadziela (Nmi) | Low viscosity self-toughening acrylate composition |
| JP3301447B2 (en) | 1992-12-01 | 2002-07-15 | 共栄社化学株式会社 | Urethane / unsaturated organo oligomers and method for producing the same |
| US5780154A (en) | 1994-03-22 | 1998-07-14 | Tokuyama Corporation | Boron nitride fiber and process for production thereof |
| DE69515310T2 (en) | 1994-07-29 | 2000-07-27 | Minnesota Mining & Mfg | ACRYLIC SYRUP WHICH CAN BE CURED TO A CROSSLINKED VISCOELASTIC MATERIAL |
| JPH09504572A (en) * | 1994-11-04 | 1997-05-06 | ザ カー コーポレイション | Radiation curable molding composition |
| JPH08188630A (en) | 1995-01-06 | 1996-07-23 | Daicel Chem Ind Ltd | Photocurable resin composition |
| GB9504995D0 (en) | 1995-03-11 | 1995-04-26 | Zeneca Ltd | Compositions |
| JP3115792B2 (en) | 1995-05-15 | 2000-12-11 | 早川ゴム株式会社 | Active energy ray-curable resin composition, method for producing the same, molded cured product of active energy ray-curable resin |
| US5981621A (en) | 1996-02-29 | 1999-11-09 | Closure Medical Corporation | Monomeric compositions effective as wound closure devices |
| DE19603577C2 (en) | 1996-02-01 | 2003-11-13 | Heraeus Kulzer Gmbh & Co Kg | adhesive |
| EP0802455B1 (en) | 1996-04-15 | 2002-10-16 | Teijin Seiki Co., Ltd. | Use of a photocurable resin composition for the production of a stereolithographed object |
| EP0807853B1 (en) | 1996-05-16 | 2003-10-08 | Teijin Seiki Co., Ltd. | Photocurable resin composition, method of producing photo-cured shaped object, vacuum casting mold, vacuum casting method and urethane acrylate |
| KR100341693B1 (en) | 1996-11-08 | 2002-06-24 | 윌리암 로엘프 드 보에르 | Radiation-curable optical glass fiber coating compositions, coated optical glass fibers, and optical glass fiber assemblies |
| WO1998039374A1 (en) | 1997-03-07 | 1998-09-11 | Dsm N.V. | Radiation-curable composition having high cure speed |
| JPH1111986A (en) | 1997-04-25 | 1999-01-19 | Takeda Chem Ind Ltd | Resin composition for coating optical fiber |
| US6379866B2 (en) | 2000-03-31 | 2002-04-30 | Dsm Desotech Inc | Solid imaging compositions for preparing polypropylene-like articles |
| US6572693B1 (en) | 1999-10-28 | 2003-06-03 | 3M Innovative Properties Company | Aesthetic dental materials |
| US6183593B1 (en) | 1999-12-23 | 2001-02-06 | Closure Medical Corporation | 1,1-disubstituted ethylene adhesive compositions containing polydimethylsiloxane |
| JP2001302744A (en) | 2000-04-26 | 2001-10-31 | Mitsubishi Rayon Co Ltd | Actinic-ray curing composition |
| US6448301B1 (en) | 2000-09-08 | 2002-09-10 | 3M Innovative Properties Company | Crosslinkable polymeric compositions and use thereof |
| US6635690B2 (en) | 2001-06-19 | 2003-10-21 | 3M Innovative Properties Company | Reactive oligomers |
| FR2835828B1 (en) | 2002-02-08 | 2006-07-14 | Ct De Transfert De Technologie | METHOD AND COMPOSITION FOR THE MANUFACTURE OF CERAMIC PIECES BY STEREO-LITHOPHOTOGRAPHY AND DENTAL FIELD APPLICATION |
| US7211368B2 (en) | 2003-01-07 | 2007-05-01 | 3 Birds, Inc. | Stereolithography resins and methods |
| JP2004217809A (en) | 2003-01-16 | 2004-08-05 | Mitsubishi Chemicals Corp | Active energy beam-cured resin sheet |
| JP4526056B2 (en) | 2003-08-26 | 2010-08-18 | 三菱レイヨン株式会社 | Active energy ray-curable composition |
| EP1589040B1 (en) | 2004-03-24 | 2008-09-10 | Nippon Shokubai Co., Ltd. | Method for continuous production of water absorbent resin |
| JP4880248B2 (en) | 2004-05-17 | 2012-02-22 | リンテック株式会社 | Adhesive sheet and decorative adhesive sheet |
| US20050277084A1 (en) | 2004-06-10 | 2005-12-15 | 3M Innovative Properties Company | Orthodontic brace with polymeric arch member |
| JP4682544B2 (en) | 2004-06-17 | 2011-05-11 | 日本ポリウレタン工業株式会社 | RESIN COMPOSITION FOR PHOTOCURABLE COATING AND PROCESS FOR PRODUCING THE SAME |
| US7641828B2 (en) | 2004-10-12 | 2010-01-05 | Align Technology, Inc. | Methods of making orthodontic appliances |
| KR100968670B1 (en) | 2005-03-15 | 2010-07-06 | 쇼와 덴코 가부시키가이샤 | Methacryloyl group-containing aromatic isocyanate compound and production process thereof |
| US20070031791A1 (en) | 2005-08-03 | 2007-02-08 | 3M Innovative Properties Company | Scanning models for digital orthodontics |
| US7495054B2 (en) | 2005-09-19 | 2009-02-24 | 3M Innovative Properties Company | Curable compositions containing dithiane monomers |
| JP5055764B2 (en) | 2005-12-21 | 2012-10-24 | 住友ベークライト株式会社 | Resin composition and semiconductor device produced using resin composition |
| CN101437692B (en) | 2006-05-08 | 2011-02-02 | 旭化成电子材料株式会社 | Cushioning material for printing |
| JP5068513B2 (en) | 2006-11-21 | 2012-11-07 | 根上工業株式会社 | Unsaturated group-containing urethane resin and active energy ray-curable resin composition containing the same |
| WO2008103494A2 (en) | 2007-02-23 | 2008-08-28 | Dentsply International Inc. | Methods for making dental restorations using two-phase light-curing materials |
| EP2008636A1 (en) | 2007-06-29 | 2008-12-31 | 3M Innovative Properties Company | Dental composition containing a polyfunctional (meth)acrylate comprising urethane, urea or amide groups, method of production and use thereof |
| US20110229838A1 (en) | 2007-10-01 | 2011-09-22 | Kalgutkar Rajdeep S | Orthodontic composition with polymeric fillers |
| US8827697B2 (en) | 2008-04-09 | 2014-09-09 | 3M Innovative Properties Company | Lingual orthodontic appliance with removable section |
| DK2299926T3 (en) | 2008-06-26 | 2020-03-02 | 3M Innovative Properties Co | PROCEDURE FOR PREPARING A TRANSFER TRAY FOR ORTHODONTIC DEVICES |
| JP5224965B2 (en) | 2008-08-04 | 2013-07-03 | 三菱レイヨン株式会社 | Cured resin and key sheet |
| JP2010043194A (en) | 2008-08-13 | 2010-02-25 | Mitsubishi Rayon Co Ltd | Curable composition and optical information-recording medium |
| CN102209708B (en) * | 2008-10-22 | 2015-03-11 | 3M创新有限公司 | Dental composition comprising biphenyl di(meth)acrylate monomer comprising urethane moieties |
| JP5445215B2 (en) | 2009-02-24 | 2014-03-19 | 三菱化学株式会社 | Active energy ray-curable resin composition, cured film and laminate |
| CN102428112B (en) | 2009-05-18 | 2014-01-08 | 爱克发印艺公司 | Polymerizable Polymeric Photoinitiators And Radiation Curable Compositions |
| WO2011143620A2 (en) | 2010-05-13 | 2011-11-17 | Symdent, Inc. | Dental appliance, dental appliance adhesive and related methods and uses |
| EP2603160A2 (en) | 2010-08-11 | 2013-06-19 | 3M Innovative Properties Company | Polymer coated dental articles and method of making the same |
| EP2436510A1 (en) | 2010-10-04 | 2012-04-04 | 3D Systems, Inc. | System and resin for rapid prototyping |
| EP2481390A1 (en) | 2011-01-31 | 2012-08-01 | 3M Innovative Properties Company | Dental composition, method of producing and use thereof |
| CN103370041B (en) | 2011-02-15 | 2016-06-15 | 3M创新有限公司 | Comprise the dental composition of the unsaturated addition-clastogen of ethylenic |
| JP2012184385A (en) | 2011-03-08 | 2012-09-27 | Ube Industries Ltd | Polyurethane compound, composition including the same, and cured product of them |
| KR20120119442A (en) | 2011-04-21 | 2012-10-31 | 동우 화인켐 주식회사 | Pressure-sensitive adhesive composition for optical use |
| EP2581062A3 (en) | 2011-10-12 | 2015-07-22 | Ormco Corporation | Direct manufacture of an orthodontic aligner |
| EP2751618B1 (en) | 2012-04-11 | 2019-05-29 | Ivoclar Vivadent AG | Composite resin composition and use of it, method for producing dental components by means of stereo-lithography |
| WO2014078537A1 (en) | 2012-11-14 | 2014-05-22 | Dentsply International Inc. | Three-dimensional fabricating material systems for producing dental products |
| WO2014077688A1 (en) | 2012-11-16 | 2014-05-22 | Dsm Ip Assets B.V. | D1531 radiation-curable resin composition for wire coating layer formation |
| JP2014114444A (en) | 2012-11-16 | 2014-06-26 | Jsr Corp | Radiation-curable resin composition for forming wire coating layer |
| JP2014116295A (en) | 2012-11-16 | 2014-06-26 | Jsr Corp | Radiation-curable resin composition for forming wire coating layer |
| US10357435B2 (en) | 2012-12-18 | 2019-07-23 | Dentca, Inc. | Photo-curable resin compositions and method of using the same in three-dimensional printing for manufacturing artificial teeth and denture base |
| WO2014098956A1 (en) | 2012-12-18 | 2014-06-26 | Dentca. Inc. | Photo-curable resin compositions and method of using the same in three-dimensional printing for manufacturing artificial teeth and denture base |
| DK2956823T4 (en) | 2013-02-12 | 2019-09-23 | Carbon3D Inc | CONTINUOUS PRINTING WITH LIQUID INTERMEDIATE |
| EP2842980B1 (en) | 2013-08-09 | 2021-05-05 | DSM IP Assets B.V. | Low-viscosity liquid radiation curable dental aligner mold resin compositions for additive manufacturing |
| US9360757B2 (en) | 2013-08-14 | 2016-06-07 | Carbon3D, Inc. | Continuous liquid interphase printing |
| JP2015043793A (en) | 2013-08-27 | 2015-03-12 | ディーダブルエス エス・アール・エル | Method for manufacturing artificial teeth |
| US9580621B2 (en) | 2013-09-09 | 2017-02-28 | Dymax Corporation | High temperature resistance, radiation curable maskant for metal substrates |
| US9096722B2 (en) | 2013-10-18 | 2015-08-04 | Hrl Laboratories, Llc | Method for curing structures using a dual photoinitiator system and a structure made using the same |
| EP2886077A1 (en) | 2013-12-18 | 2015-06-24 | 3M Innovative Properties Company | Method of making a transfer tray |
| US9682018B2 (en) | 2014-03-13 | 2017-06-20 | Steven Sadowsky | Denture tooth and material |
| JP6329281B2 (en) | 2014-06-23 | 2018-05-23 | アルケマ フランス | Urethane acrylate polymer with unique physical properties |
| BR112016029755A2 (en) | 2014-06-23 | 2017-08-22 | Carbon Inc | methods of producing three-dimensional objects from materials having multiple hardening mechanisms |
| US9574039B1 (en) | 2014-07-22 | 2017-02-21 | Full Spectrum Laser | Additive use in photopolymer resin for 3D printing to enhance the appearance of printed parts |
| WO2016071811A1 (en) | 2014-11-04 | 2016-05-12 | Dws S.R.L. | Stereolithographic method and composition |
| CN104765251A (en) | 2014-11-06 | 2015-07-08 | 青岛科技大学 | High-toughness photosensitive resin for 3D printing and preparation method thereof. |
| WO2016094272A1 (en) | 2014-12-09 | 2016-06-16 | 3M Innovative Properties Company | Dental restoration molding techniques |
| US20160167301A1 (en) | 2014-12-12 | 2016-06-16 | Autodesk, Inc. | Polymeric photoinitiators for 3d printing applications |
| JP6451288B2 (en) | 2014-12-17 | 2019-01-16 | コニカミノルタ株式会社 | Model material ink, ink set and method for producing 3D object |
| EP3240496B1 (en) | 2014-12-30 | 2020-09-16 | 3M Innovative Properties Company | Dental appliance providing exposed occlusal surfaces |
| US20180049847A1 (en) | 2015-03-13 | 2018-02-22 | 3M Innovative Properties Company | Orthodontic appliance including arch member |
| US20180014916A1 (en) | 2015-03-13 | 2018-01-18 | 3M Innovative Properties Company | Orthodontic appliance including arch member |
| JP6831333B2 (en) | 2015-04-02 | 2021-02-17 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ | A method for producing it using a polymer-based gravure printing plate and a curable composition having a polyfunctional urethane. |
| WO2016182444A1 (en) | 2015-05-12 | 2016-11-17 | Rijksuniversiteit Groningen | 3d-printable antimicrobial composite resins, methods for manufacturing the same |
| CA2986029C (en) | 2015-05-15 | 2023-05-23 | Dentsply Sirona Inc. | Three-dimensional fabricating method for rapidly producing objects |
| JP6835742B6 (en) | 2015-05-28 | 2021-03-24 | スリーエム イノベイティブ プロパティズ カンパニー | Additional manufacturing method for producing ceramic articles using sol containing nano-sized particles |
| JP6493875B2 (en) | 2015-06-08 | 2019-04-03 | 富士フイルム株式会社 | Method for forming a three-dimensional structure |
| US10492888B2 (en) | 2015-07-07 | 2019-12-03 | Align Technology, Inc. | Dental materials using thermoset polymers |
| JP6574980B2 (en) | 2015-09-01 | 2019-09-18 | Ｋｊケミカルズ株式会社 | Active energy ray-curable resin composition for model materials |
| EP3391871A4 (en) | 2015-12-18 | 2019-08-28 | Kuraray Noritake Dental Inc. | Dental adhesive material kit |
| CN105566916B (en) | 2016-02-23 | 2018-04-06 | 上海应用技术学院 | A kind of quick-setting noctilucence 3D printing light-sensitive emulsion and preparation method thereof |
| JP2017210579A (en) | 2016-05-27 | 2017-11-30 | 凸版印刷株式会社 | Photocurable resin molded body using urethane acrylate |
| WO2017208959A1 (en) | 2016-06-01 | 2017-12-07 | 三菱瓦斯化学株式会社 | Urethane (meth)acrylate, method for producing urethane (meth)acrylate, curable composition, cured product and method for producing cured product |
| US11650498B2 (en) | 2016-06-30 | 2023-05-16 | 3M Innovative Properties Company | Printable compositions including highly viscous components and methods of creating 3D articles therefrom |
| US10941313B2 (en) | 2016-11-21 | 2021-03-09 | 3M Innovative Properties Company | Flexible hardcoat comprising urethane oligomer hydrogen bonded to an acrylic polymer |
| CN110036342A (en) | 2016-12-05 | 2019-07-19 | 阿科玛股份有限公司 | Initiator blend and the Photocurable composition containing such initiator blend that can be used for 3D printing |
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