JPWO2017043575A1 - 合わせガラス用中間膜及び合わせガラス - Google Patents
合わせガラス用中間膜及び合わせガラス Download PDFInfo
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- JPWO2017043575A1 JPWO2017043575A1 JP2016558413A JP2016558413A JPWO2017043575A1 JP WO2017043575 A1 JPWO2017043575 A1 JP WO2017043575A1 JP 2016558413 A JP2016558413 A JP 2016558413A JP 2016558413 A JP2016558413 A JP 2016558413A JP WO2017043575 A1 JPWO2017043575 A1 JP WO2017043575A1
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- Prior art keywords
- layer
- laminated glass
- acetal resin
- polyvinyl acetal
- content
- Prior art date
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- 239000005340 laminated glass Substances 0.000 title claims abstract description 274
- 239000011229 interlayer Substances 0.000 title claims abstract description 138
- 239000010410 layer Substances 0.000 claims abstract description 399
- 239000011354 acetal resin Substances 0.000 claims abstract description 232
- 229920006324 polyoxymethylene Polymers 0.000 claims abstract description 232
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 232
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims abstract description 229
- 239000004014 plasticizer Substances 0.000 claims abstract description 140
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 89
- 239000011521 glass Substances 0.000 claims description 60
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 238000009413 insulation Methods 0.000 abstract description 47
- 238000005452 bending Methods 0.000 abstract description 42
- 229910052727 yttrium Inorganic materials 0.000 abstract description 4
- 239000002245 particle Substances 0.000 description 82
- 230000001965 increasing effect Effects 0.000 description 59
- 239000003795 chemical substances by application Substances 0.000 description 51
- 239000003963 antioxidant agent Substances 0.000 description 30
- -1 alkali metal salt Chemical class 0.000 description 27
- 230000003078 antioxidant effect Effects 0.000 description 24
- 238000004519 manufacturing process Methods 0.000 description 23
- 238000006359 acetalization reaction Methods 0.000 description 20
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 19
- 229910001930 tungsten oxide Inorganic materials 0.000 description 19
- 230000021736 acetylation Effects 0.000 description 18
- 238000006640 acetylation reaction Methods 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- 230000009477 glass transition Effects 0.000 description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
- 150000003839 salts Chemical class 0.000 description 15
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
- 238000002834 transmittance Methods 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- 229910044991 metal oxide Inorganic materials 0.000 description 10
- 150000004706 metal oxides Chemical class 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 9
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N pentanal Chemical compound CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 9
- 239000002344 surface layer Substances 0.000 description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000005357 flat glass Substances 0.000 description 7
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 7
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000011777 magnesium Chemical class 0.000 description 6
- 150000007524 organic acids Chemical class 0.000 description 6
- 230000035515 penetration Effects 0.000 description 6
- 239000011787 zinc oxide Substances 0.000 description 6
- FRQDZJMEHSJOPU-UHFFFAOYSA-N Triethylene glycol bis(2-ethylhexanoate) Chemical compound CCCCC(CC)C(=O)OCCOCCOCCOC(=O)C(CC)CCCC FRQDZJMEHSJOPU-UHFFFAOYSA-N 0.000 description 5
- 150000001299 aldehydes Chemical class 0.000 description 5
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 230000035484 reaction time Effects 0.000 description 5
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical group [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 5
- JEYLQCXBYFQJRO-UHFFFAOYSA-N 2-[2-[2-(2-ethylbutanoyloxy)ethoxy]ethoxy]ethyl 2-ethylbutanoate Chemical compound CCC(CC)C(=O)OCCOCCOCCOC(=O)C(CC)CC JEYLQCXBYFQJRO-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002895 organic esters Chemical class 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 3
- IYXGSMUGOJNHAZ-UHFFFAOYSA-N Ethyl malonate Chemical group CCOC(=O)CC(=O)OCC IYXGSMUGOJNHAZ-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 3
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical group OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 238000004049 embossing Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- LKKPNUDVOYAOBB-UHFFFAOYSA-N naphthalocyanine Chemical class N1C(N=C2C3=CC4=CC=CC=C4C=C3C(N=C3C4=CC5=CC=CC=C5C=C4C(=N4)N3)=N2)=C(C=C2C(C=CC=C2)=C2)C2=C1N=C1C2=CC3=CC=CC=C3C=C2C4=N1 LKKPNUDVOYAOBB-UHFFFAOYSA-N 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 239000002530 phenolic antioxidant Substances 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 239000011342 resin composition Substances 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- OXQGTIUCKGYOAA-UHFFFAOYSA-N 2-Ethylbutanoic acid Chemical compound CCC(CC)C(O)=O OXQGTIUCKGYOAA-UHFFFAOYSA-N 0.000 description 2
- YJGHMLJGPSVSLF-UHFFFAOYSA-N 2-[2-(2-octanoyloxyethoxy)ethoxy]ethyl octanoate Chemical compound CCCCCCCC(=O)OCCOCCOCCOC(=O)CCCCCCC YJGHMLJGPSVSLF-UHFFFAOYSA-N 0.000 description 2
- PQJZHMCWDKOPQG-UHFFFAOYSA-N 2-anilino-2-oxoacetic acid Chemical group OC(=O)C(=O)NC1=CC=CC=C1 PQJZHMCWDKOPQG-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001278 adipic acid derivatives Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- IHTSDBYPAZEUOP-UHFFFAOYSA-N bis(2-butoxyethyl) hexanedioate Chemical group CCCCOCCOC(=O)CCCCC(=O)OCCOCCCC IHTSDBYPAZEUOP-UHFFFAOYSA-N 0.000 description 2
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 2
- 229910052792 caesium Inorganic materials 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229910003437 indium oxide Inorganic materials 0.000 description 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 2
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- 239000012488 sample solution Substances 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- KJYSXRBJOSZLEL-UHFFFAOYSA-N (2,4-ditert-butylphenyl) 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 KJYSXRBJOSZLEL-UHFFFAOYSA-N 0.000 description 1
- QFMZQPDHXULLKC-UHFFFAOYSA-N 1,2-bis(diphenylphosphino)ethane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)CCP(C=1C=CC=CC=1)C1=CC=CC=C1 QFMZQPDHXULLKC-UHFFFAOYSA-N 0.000 description 1
- KZVBBTZJMSWGTK-UHFFFAOYSA-N 1-[2-(2-butoxyethoxy)ethoxy]butane Chemical compound CCCCOCCOCCOCCCC KZVBBTZJMSWGTK-UHFFFAOYSA-N 0.000 description 1
- KNQFGKYCUMPAHP-UHFFFAOYSA-N 1-[3-(benzotriazol-2-yl)-5-pentylphenyl]pentan-2-ol Chemical compound CCCCCC1=CC(CC(O)CCC)=CC(N2N=C3C=CC=CC3=N2)=C1 KNQFGKYCUMPAHP-UHFFFAOYSA-N 0.000 description 1
- DLZBUNUDESZERL-UHFFFAOYSA-N 1-o-heptyl 6-o-nonyl hexanedioate Chemical compound CCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCC DLZBUNUDESZERL-UHFFFAOYSA-N 0.000 description 1
- XCTNDJAFNBCVOM-UHFFFAOYSA-N 1h-imidazo[4,5-b]pyridin-2-ylmethanamine Chemical compound C1=CC=C2NC(CN)=NC2=N1 XCTNDJAFNBCVOM-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 1
- CKQNDABUGIXFCL-UHFFFAOYSA-N 2-(2-octanoyloxyethoxy)ethyl octanoate Chemical compound CCCCCCCC(=O)OCCOCCOC(=O)CCCCCCC CKQNDABUGIXFCL-UHFFFAOYSA-N 0.000 description 1
- LHPPDQUVECZQSW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O LHPPDQUVECZQSW-UHFFFAOYSA-N 0.000 description 1
- UNNGUFMVYQJGTD-UHFFFAOYSA-N 2-Ethylbutanal Chemical compound CCC(CC)C=O UNNGUFMVYQJGTD-UHFFFAOYSA-N 0.000 description 1
- GCDUWJFWXVRGSM-UHFFFAOYSA-N 2-[2-(2-heptanoyloxyethoxy)ethoxy]ethyl heptanoate Chemical compound CCCCCCC(=O)OCCOCCOCCOC(=O)CCCCCC GCDUWJFWXVRGSM-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- SSKNCQWPZQCABD-UHFFFAOYSA-N 2-[2-[2-(2-heptanoyloxyethoxy)ethoxy]ethoxy]ethyl heptanoate Chemical compound CCCCCCC(=O)OCCOCCOCCOCCOC(=O)CCCCCC SSKNCQWPZQCABD-UHFFFAOYSA-N 0.000 description 1
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 description 1
- VWSWIUTWLQJWQH-UHFFFAOYSA-N 2-butyl-6-[(3-butyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CCCCC1=CC(C)=CC(CC=2C(=C(CCCC)C=C(C)C=2)O)=C1O VWSWIUTWLQJWQH-UHFFFAOYSA-N 0.000 description 1
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Images
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- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
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Abstract
Description
上記第1の層は、ポリビニルアセタール樹脂(以下、ポリビニルアセタール樹脂(1)と記載することがある)を含む。上記第2の層は、ポリビニルアセタール樹脂(以下、ポリビニルアセタール樹脂(2)と記載することがある)を含む。上記第3の層は、ポリビニルアセタール樹脂(以下、ポリビニルアセタール樹脂(3)と記載することがある)を含む。上記ポリビニルアセタール樹脂(1)と上記ポリビニルアセタール樹脂(2)と上記ポリビニルアセタール樹脂(3)とは、同一であってもよく、異なっていてもよいが、遮音性がより一層高くなることから、上記ポリビニルアセタール樹脂(1)は、上記ポリビニルアセタール樹脂(2)及び上記ポリビニルアセタール樹脂(3)と異なっていることが好ましい。上記ポリビニルアセタール樹脂(1)、上記ポリビニルアセタール樹脂(2)及び上記ポリビニルアセタール樹脂(3)はそれぞれ、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記第1の層は、可塑剤(以下、可塑剤(1)と記載することがある)を含む。上記第2の層は、可塑剤(以下、可塑剤(2)と記載することがある)を含む。上記第3の層は、可塑剤(以下、可塑剤(3)と記載することがある)を含む。ポリビニルアセタール樹脂と可塑剤との併用により、ポリビニルアセタール樹脂と可塑剤とを含む層の合わせガラス部材又は他の層に対する接着力が適度に高くなる。上記可塑剤は特に限定されない。上記可塑剤(1)と上記可塑剤(2)と上記可塑剤(3)とは同一であってもよく、異なっていてもよい。上記可塑剤(1)、上記可塑剤(2)及び上記可塑剤(3)はそれぞれ、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記第1の層はシリカ粒子を含むことが好ましい。シリカ粒子の使用により、遮音性を低下させず、剛性がより一層高くなり、更に各層間接着力も高くなる。上記シリカ粒子は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記中間膜は、遮熱性化合物を含むことが好ましい。上記第1の層は、遮熱性化合物を含むことが好ましい。上記第2の層は、遮熱性化合物を含むことが好ましい。上記第3の層は、遮熱性化合物を含むことが好ましい。上記遮熱性化合物は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記中間膜は、フタロシアニン化合物、ナフタロシアニン化合物及びアントラシアニン化合物の内の少なくとも1種の成分Xを含むことが好ましい。上記第1の層は、上記成分Xを含むことが好ましい。上記第2の層は、上記成分Xを含むことが好ましい。上記第3の層は、上記成分Xを含むことが好ましい。上記成分Xは遮熱性化合物である。上記成分Xは、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記中間膜は、遮熱粒子を含むことが好ましい。上記第1の層は、上記遮熱粒子を含むことが好ましい。上記第2の層は、上記遮熱粒子を含むことが好ましい。上記第3の層は、上記遮熱粒子を含むことが好ましい。上記遮熱粒子は遮熱性化合物である。遮熱粒子の使用により、赤外線(熱線)を効果的に遮断できる。上記遮熱粒子は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記中間膜は、アルカリ金属塩、アルカリ土類金属塩及びMg塩の内の少なくとも1種の金属塩(以下、金属塩Mと記載することがある)を含むことが好ましい。上記第1の層は、上記金属塩Mを含むことが好ましい。上記第2の層は、上記金属塩Mを含むことが好ましい。上記第3の層は、上記金属塩Mを含むことが好ましい。上記金属塩Mの使用により、中間膜と合わせガラス部材との接着性又は中間膜における各層間の接着性を制御することが容易になる。上記金属塩Mは、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記中間膜は、紫外線遮蔽剤を含むことが好ましい。上記第1の層は、紫外線遮蔽剤を含むことが好ましい。上記第2の層は、紫外線遮蔽剤を含むことが好ましい。上記第3の層は、紫外線遮蔽剤を含むことが好ましい。紫外線遮蔽剤の使用により、中間膜及び合わせガラスが長期間使用されても、可視光線透過率がより一層低下し難くなる。上記紫外線遮蔽剤は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記中間膜は、酸化防止剤を含むことが好ましい。上記第1の層は、酸化防止剤を含むことが好ましい。上記第2の層は、酸化防止剤を含むことが好ましい。上記第3の層は、酸化防止剤を含むことが好ましい。上記酸化防止剤は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記第1の層、上記第2の層及び上記第3の層はそれぞれ、必要に応じて、ケイ素、アルミニウム又はチタンを含むカップリング剤、分散剤、界面活性剤、難燃剤、帯電防止剤、顔料、染料、接着力調整剤、耐湿剤、蛍光増白剤及び赤外線吸収剤等の添加剤を含んでいてもよい。これらの添加剤は、1種のみが用いられてもよく、2種以上が併用されてもよい。
合わせガラスの曲げ剛性を高める観点から、中間膜の25℃での等価剛性は2.4MPa以上である。合わせガラスの曲げ剛性をより一層高める観点からは、中間膜の25℃での等価剛性は好ましくは3MPa以上、より好ましくは4MPa以上、更に好ましくは5MPa以上、特に好ましくは9MPa以上である。中間膜の25℃での等価剛性は好ましくは30MPa以下、より好ましくは20MPa以下である。
図2は、図1に示す合わせガラス用中間膜を用いた合わせガラスの一例を模式的に示す断面図である。
下記の表1に示すポリビニルアセタール樹脂を用いた。用いたポリビニルアセタール樹脂では全て、アセタール化に、炭素数4のn−ブチルアルデヒドが用いられている。ポリビニルアセタール樹脂に関しては、アセタール化度(ブチラール化度)、アセチル化度及び水酸基の含有率はJIS K6728「ポリビニルブチラール試験方法」に準拠した方法により測定した。なお、ASTM D1396−92により測定した場合も、JIS K6728「ポリビニルブチラール試験方法」に準拠した方法と同様の数値を示した。
トリエチレングリコールジ−2−エチルヘキサノエート(3GO)
Tinuvin326(2−(2’−ヒドロキシ−3’−t−ブチル−5−メチルフェニル)−5−クロロベンゾトリアゾール、BASF社製「Tinuvin326」)
BHT(2,6−ジ−t−ブチル−p−クレゾール)
(実施例1)
第1の層を形成するための組成物の作製:
下記の表1に示す種類のポリビニルアセタール樹脂100重量部と、可塑剤(3GO)60重量部と、紫外線遮蔽剤(Tinuvin326)0.2重量部と、酸化防止剤(BHT)0.2重量部とを混合し、第1の層を形成するための組成物を得た。
下記の表1に示す種類のポリビニルアセタール樹脂100重量部と、可塑剤(3GO)34重量部と、紫外線遮蔽剤(Tinuvin326)0.2重量部と、酸化防止剤(BHT)0.2重量部とを混合し、第2の層及び第3の層を形成するための組成物を得た。
第1の層を形成するための組成物と、第2の層及び第3の層を形成するための組成物とを、共押出機を用いて共押出しすることにより、第2の層(厚み340μm)/第1の層(厚み100μm)/第3の層(厚み340μm)の積層構造を有する中間膜(厚み780μm)を作製した。
洗浄及び乾燥した2つのガラス板(クリアフロートガラス、縦25cm×横10cm×厚み0.7mm)を用意した。この2つのガラス板の間に、得られた中間膜を挟み込み、積層体を得た。得られた積層体をゴムバック内に入れ、2660Pa(20torr)の真空度で20分間脱気した。その後、脱気したままで積層体をオートクレーブ中で更に90℃で30分間保持しつつ、真空プレスした。このようにして予備圧着された積層体を、オートクレーブ中で135℃、圧力1.2MPa(12kg/cm2)の条件で20分間圧着を行い、合わせガラスAを得た。
得られた中間膜を縦30cm×横2.5cmの大きさに切断した。次に、JIS R3208に準拠したグリーンガラス(縦30cm×横2.5cm×厚さ2mm)2枚の間に、中間膜を挟み込み、積層体を得た。この積層体をゴムバック内に入れ、2.6kPaの真空度で20分間脱気した後、脱気したままオーブン内に移し、更に90℃で30分間保持して真空プレスし、積層体を予備圧着した。オートクレーブ中で135℃及び圧力1.2MPaの条件で、予備圧着された積層体を20分間圧着し、合わせガラスBを得た。
第1の層を形成するための組成物と第2の層及び第3の層を形成するための組成物とに用いるポリビニルアセタール樹脂及び可塑剤の種類と配合量とを下記の表1,2に示すように設定したこと、並びに第1の層、第2の層及び第3の層の厚みを下記の表1,2に示すように設定したこと以外は実施例1と同様にして、中間膜及び合わせガラスを得た。また、実施例2〜12及び比較例1〜10では、実施例1と同じ種類の紫外線遮蔽剤及び酸化防止剤を、実施例1と同様の配合量(ポリビニルアセタール樹脂100重量部に対して0.2重量部)で配合した。
(1)合わせガラス用中間膜中のポリビニルアセタール樹脂100重量部に対する、合わせガラス用中間膜中の可塑剤の含有量Yの測定
合わせガラス用中間膜を縦0.5cm、横5cmに切断し、上記第2の層、上記第1の層、及び、上記第3の層が積層された3層構造の場合は、上記合わせガラス用中間膜を、23±2℃、湿度25±5%の環境下に、12時間放置した後、上記第2の層を上記第1の層から剥離し、次いで、上記第3の層を上記第1の層から剥離する。剥離された上記第1の層の重量を分析用電子天びん(エー・アンド・デイ社製GH−200)を用いて測定し、剥離された上記第1の層の重量をX1(mg)とする。剥離された上記第1の層を、ガスクロマトグラフ(島津製作所社製GC−2014)を用いて、上記第1の層中のポリビニルアセタール樹脂及び可塑剤の合計に占めるポリビニルアセタール樹脂の含有率(R1)、及び、上記第1の層中のポリビニルアセタール樹脂及び可塑剤の合計に占める可塑剤の含有率(P1)を測定した。なお、上記R1は上記第1の層中のポリビニルアセタール樹脂の含有量を、上記第1の層中のポリビニルアセタール樹脂及び可塑剤の合計の含有量で除算することにより算出し、上記P1は上記第1の層中の可塑剤の含有量を、上記第1の層中のポリビニルアセタール樹脂及び可塑剤の合計の含有量で除算することにより算出した。同様にして、上記第2の層の重量X2(mg)、上記第2の層中のポリビニルアセタール樹脂及び可塑剤の合計に占めるポリビニルアセタール樹脂の含有率(R2)、及び、上記第2の層中のポリビニルアセタール樹脂及び可塑剤の合計に占める可塑剤の含有率(P2)を測定した。同様にして、上記第3の層の重量X3(mg)、上記第3の層中のポリビニルアセタール樹脂及び可塑剤の合計に占めるポリビニルアセタール樹脂の含有率(R3)、及び、上記第3の層中のポリビニルアセタール樹脂及び可塑剤の合計に占める可塑剤の含有率(P3)を測定した。更に、上記第1の層中のポリビニルアセタール樹脂の含有量をX1(mg)×R1、上記第2の層中のポリビニルアセタール樹脂の含有量をX2(mg)×R2、及び、上記第3の層中のポリビニルアセタール樹脂の含有量をX3(mg)×R3として算出し、上記合わせガラス用中間膜中のポリビニルアセタール樹脂の含有量をX1(mg)×R1+X2(mg)×R2+X3(mg)×R3とした。同様にして、上記第1の層中の可塑剤の含有量をX1(mg)×P1、上記第2の層中の可塑剤の含有量をX2(mg)×P2、及び、上記第3の層中の可塑剤の含有量をX3(mg)×P3として算出し、上記合わせガラス用中間膜中の可塑剤の含有量をX1(mg)×P1+X2(mg)×P2+X3(mg)×P3とした。この結果から、上記合わせガラス用中間膜中のポリビニルアセタール樹脂100重量部に対する、上記合わせガラス用中間膜中の可塑剤の含有量Yを、[{X1(mg)×P1+X2(mg)×P2+X3(mg)×P3}/{X1(mg)×R1+X2(mg)×R2+X3(mg)×R3}]により算出した。尚、第1の層の中に占めるポリビニルアセタール樹脂の含有率(R1)、および、可塑剤の含有率(P1)は以下の方法でGC測定により求めた。剥離して得た膜から0.05gを精秤し、メタノールとクロロホルムを重量比1:1で混合した溶媒4mlに溶解させた。混合溶液0.1mlをメタノール/クロロホルムの1:1混合溶媒1.9mlで希釈した。希釈後の溶液を0.2μmのシリンジフィルターでろ過し、GC測定用溶液とした。GC測定条件は以下の通りに設定した。注入口温度は280℃とし、カラムはHP−5(0.32mmΦ×30m×0.25μm、アジレント・テクノロジー社製)を使用し、カラム温度は80℃で1分間保持した後、20℃/分で昇温し、320℃で30秒間保持で設定した。キャリアガスはヘリウムで流量を2.0ml/分とし、スプリット比は1:10とした。サンプル溶液の注入量は2μlとし、検出器は水素炎イオン化検出器(FID)を使用し、検出器の温度は320℃とした。同日に事前に作成しておいた可塑剤の検量線を用いて、サンプル溶液中の可塑剤の含有率(P1)を算出した。また、ポリビニルアセタール樹脂の含有率(R1)は1−P1により算出した。中間膜中に含まれる他の添加物の含有率もR1に含まれるが、ごく微量であるため無視してもよい。同様にして、第2の層及び第3の層についても実施した。
得られた合わせガラスAを用意した。図3に模式的に示す試験方法で、曲げ剛性を評価した。測定装置としては、静的3点曲げ試験治具2810を備えたインストロンジャパンカンパニイリミテッド社製の万能材料試験機5966を使用した。測定条件としては、測定温度20±3℃、距離D1は18cm、距離D2は25cmとし、変位速度1mm/分でFの方向に合わせガラスに変形を加え、1.5mmの変位を加えたときの応力を測定し、曲げ剛性を算出した。なお、曲げ剛性は、製造してから1日経過した合わせガラスの曲げ剛性δ(1D)、及び、製造してから20℃の環境下で3カ月保管した合わせガラスの曲げ剛性δ(3M)をそれぞれ測定した。
合わせガラスBをダンピング試験用の振動発生機(振研社製「加振機G21−005D」)により加振し、そこから得られた振動特性を機械インピーダンス測定装置(リオン社製「XG−81」)にて増幅し、振動スペクトルをFFTスペクトラムアナライザー(横河ヒューレッドパッカード社製「FFTアナライザー HP3582A」)により解析した。
○:TL値が35dB以上
×:TL値が35dB未満
1a…第1の表面
1b…第2の表面
2…第2の層
2a…外側の表面
3…第3の層
3a…外側の表面
11…中間膜
11A…中間膜(第1の層)
11a…第1の表面
11b…第2の表面
21…第1の合わせガラス部材
22…第2の合わせガラス部材
31…合わせガラス
Claims (14)
- 3層以上の構造を有し、かつポリビニルアセタール樹脂及び可塑剤を含む合わせガラス用中間膜であり、
ポリビニルアセタール樹脂及び可塑剤を含む第1の層、
前記第1の層の第1の表面に積層され、かつ、ポリビニルアセタール樹脂及び可塑剤を含む第2の層、及び、
前記第1の層の前記第1の表面とは反対の第2の表面に積層され、かつ、ポリビニルアセタール樹脂及び可塑剤を含む第3の層を備え、
前記第1の層中の前記ポリビニルアセタール樹脂の水酸基の含有率は、前記第2の層中の前記ポリビニルアセタール樹脂の水酸基の含有率よりも低く、かつ前記第2の層中の前記ポリビニルアセタール樹脂の水酸基の含有率と前記第1の層中の前記ポリビニルアセタール樹脂の水酸基の含有率との差の絶対値をXAとしたときに、前記絶対値XAが9モル%以上、11モル%以下であり、
前記第1の層中の前記ポリビニルアセタール樹脂の水酸基の含有率は、前記第3の層中の前記ポリビニルアセタール樹脂の水酸基の含有率よりも低く、かつ前記第3の層中の前記ポリビニルアセタール樹脂の水酸基の含有率と前記第1の層中の前記ポリビニルアセタール樹脂の水酸基の含有率との差の絶対値をXBとしたときに、前記絶対値XBが9モル%以上、11モル%以下であり、
前記合わせガラス用中間膜中の前記ポリビニルアセタール樹脂100重量部に対する、前記合わせガラス用中間膜中の前記可塑剤の含有量をYとしたときに、Y≦−1.68XA+56及びY≦−1.68XB+56を満たす、合わせガラス用中間膜。 - 前記第1の層中の前記ポリビニルアセタール樹脂100重量部に対する前記第1の層中の前記可塑剤の含有量は、前記第2の層中の前記ポリビニルアセタール樹脂100重量部に対する前記第2の層中の前記可塑剤の含有量よりも多い、請求項1に記載の合わせガラス用中間膜。
- 前記第1の層中の前記ポリビニルアセタール樹脂100重量部に対する前記第1の層中の前記可塑剤の含有量は、前記第3の層中の前記ポリビニルアセタール樹脂100重量部に対する前記第3の層中の前記可塑剤の含有量よりも多い、請求項1又は2に記載の合わせガラス用中間膜。
- 前記第2の層中の前記ポリビニルアセタール樹脂の水酸基の含有率が32モル%以上である、請求項1〜3のいずれか1項に記載の合わせガラス用中間膜。
- 前記第3の層中の前記ポリビニルアセタール樹脂の水酸基の含有率が32モル%以上である、請求項1〜4のいずれか1項に記載の合わせガラス用中間膜。
- 前記絶対値XAは9.3モル%を超える、請求項1〜5のいずれか1項に記載の合わせガラス用中間膜。
- 前記絶対値XBは9.3モル%を超える、請求項1〜6のいずれか1項に記載の合わせガラス用中間膜。
- 前記第1の層中の前記ポリビニルアセタール樹脂100重量部に対する前記第1の層中の前記可塑剤の含有量が55重量部以上、100重量部以下である、請求項1〜7のいずれか1項に記載の合わせガラス用中間膜。
- 前記第2の層中の前記ポリビニルアセタール樹脂100重量部に対する前記第2の層中の前記可塑剤の含有量、及び、前記第3の層中の前記ポリビニルアセタール樹脂100重量部に対する前記第3の層中の前記可塑剤の含有量が50重量部以下である、請求項1〜8のいずれか1項に記載の合わせガラス用中間膜。
- 前記合わせガラス用中間膜中の前記ポリビニルアセタール樹脂100重量部に対する、前記合わせガラス用中間膜中の前記可塑剤の含有量Yが25重量部以上40重量部以下である、請求項1〜9のいずれか1項に記載の合わせガラス用中間膜。
- 前記第1の層中の前記ポリビニルアセタール樹脂がポリビニルブチラール樹脂であり、
前記第2の層中の前記ポリビニルアセタール樹脂がポリビニルブチラール樹脂であり、
前記第3の層中の前記ポリビニルアセタール樹脂がポリビニルブチラール樹脂である、請求項1〜10のいずれか1項に記載の合わせガラス用中間膜。 - 厚みが2mm未満である第1のガラス板を用いて、前記第1のガラス板と第2のガラス板との間に配置されて、合わせガラスを得るために用いられる、請求項1〜11のいずれか1項に記載の合わせガラス用中間膜。
- 第1の合わせガラス部材と、
第2の合わせガラス部材と、
請求項1〜11のいずれか1項に記載の合わせガラス用中間膜とを備え、
前記第1の合わせガラス部材と前記第2の合わせガラス部材との間に、前記合わせガラス用中間膜が配置されている、合わせガラス。 - 前記第1の合わせガラス部材が第1のガラス板であり、
前記第1のガラス板の厚みが2mm未満である、請求項13に記載の合わせガラス。
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CN (1) | CN107922261A (ja) |
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WO2011081190A1 (ja) * | 2009-12-28 | 2011-07-07 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
WO2012043817A1 (ja) * | 2010-09-30 | 2012-04-05 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
WO2012091117A1 (ja) * | 2010-12-28 | 2012-07-05 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
JP2013006727A (ja) * | 2011-06-23 | 2013-01-10 | Sekisui Chem Co Ltd | 合わせガラス用中間膜及び合わせガラス |
JP2015516934A (ja) * | 2012-03-09 | 2015-06-18 | ソルティア・インコーポレーテッド | 高剛性中間層及び軽量ラミネート化多層パネル |
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JP2007070200A (ja) | 2005-09-09 | 2007-03-22 | Asahi Glass Co Ltd | 合わせガラス |
WO2011081191A1 (ja) | 2009-12-28 | 2011-07-07 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
WO2012043819A1 (ja) | 2010-09-30 | 2012-04-05 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
CN103282324B (zh) | 2010-12-28 | 2019-09-27 | 积水化学工业株式会社 | 夹层玻璃用中间膜及夹层玻璃 |
US20170100918A1 (en) | 2015-10-09 | 2017-04-13 | Solutia Inc. | High rigidity interlayers and light weight laminated multiple layer panels |
US20170100919A1 (en) | 2015-10-09 | 2017-04-13 | Solutia Inc. | High rigidity interlayers and light weight laminated multiple layer panels |
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JP2010525967A (ja) * | 2007-04-30 | 2010-07-29 | ソリユテイア・インコーポレイテツド | 耐衝撃性ポリマー中間層 |
WO2011081190A1 (ja) * | 2009-12-28 | 2011-07-07 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
WO2012043817A1 (ja) * | 2010-09-30 | 2012-04-05 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
WO2012091117A1 (ja) * | 2010-12-28 | 2012-07-05 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
JP2013006727A (ja) * | 2011-06-23 | 2013-01-10 | Sekisui Chem Co Ltd | 合わせガラス用中間膜及び合わせガラス |
JP2015516934A (ja) * | 2012-03-09 | 2015-06-18 | ソルティア・インコーポレーテッド | 高剛性中間層及び軽量ラミネート化多層パネル |
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KR20180052594A (ko) | 2018-05-18 |
CN107922261A (zh) | 2018-04-17 |
US10981361B2 (en) | 2021-04-20 |
TWI700318B (zh) | 2020-08-01 |
US20180200998A1 (en) | 2018-07-19 |
EP3348531A4 (en) | 2019-05-08 |
WO2017043575A1 (ja) | 2017-03-16 |
TW201718733A (zh) | 2017-06-01 |
MX2018001899A (es) | 2018-06-20 |
EP3348531A1 (en) | 2018-07-18 |
JP6698542B2 (ja) | 2020-05-27 |
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