JPWO2015087694A1 - Redox potential generator using alkoxytitanic acid / phosphoric acid compound - Google Patents

Abstract

In the absence of water and in the presence or absence of mineral acid, phosphoric acid or alkyl phosphate ester is added to the alcoholic solution of alkoxytitanic acid to initiate chain transfer polymerization, and the polymerization product solution is glued. An oxidation-reduction potential generating material coated or impregnated with a linear alkoxytitanic acid / phosphoric acid polymer solution obtained by stopping polymerization before becoming cloudy.

Description

  The present invention uses a material impregnated and coated with an alkoxytitanic acid / phosphoric linear polymer compound to generate an oxidation-reduction potential that can give a living body immune activity from the outside and cure diseases that cannot be cured by internal immune control. Regarding materials.

  Alkoxy titanic acid / phosphoric acid compounds are considered to be compounds in which a linear polymer of alkoxy titanic acid and phosphoric acid or phosphoric acid ester form a complex, and various forms have been known so far. Yes.

  Among these, as the linear alkoxytitanic acid / phosphoric acid compound, a hydrochloric acid-containing type produced in the presence of hydrochloric acid described in Patent Document 1, hydrochloric acid that the inventors have invented and filed earlier There is a hydrochloric acid-free type manufactured under the condition that does not use.

Patent Document 1 has the following description about the obtained hydrochloric acid-containing alkoxytitanic acid / phosphoric acid compound.
"Non-light to ultraviolet catalyst, phosphoric acid titania film forming agent, peroxyphosphoric acid titania film forming agent, intramolecular self-activator, burnt and seizure release agent, PVC cross-linked titania, surface polarity conversion agent, Acid-resistant titanium film-forming agent, electromagnetic wave protective agent, superconducting agent, antistatic agent for fibers, yarns and plastics, antiwear agent, heat resistance, glittering agent, dry lubricant, rust inhibitor, heat resistance glitter Surface treatment agent, lipophilic paint film forming agent, hydrophilic paint film forming agent, surface treatment agent imparting high lipophilicity / hydrophilicity, moss remover, moss preventive, bactericides, antibacterial agents, fungicides, anti antifungal agents, molded titanium San'ito or film, deodorants, NO _X -SO _X fixed catalyst, for ceramic capacitors barium titanate synthesized agents, insolubilization of soluble chelating agent in water (fixing) agents, chelating agents, water-based transesterification catalysts, CO _{2, 2} O decomposition catalyst, binding adhesive particulate titania, polysaccharides hydrolysis catalyst, wood preservative termiticide, pesticides, fish drugs, antifouling dividing fouling (self-cleaning), UV heat ray protective agent, deterioration or It can be used as a white surface restoration agent, and can be used not only for coating methods but also for spinning and film formation, and can be used for additives, synthetic reagents, etc. "([0001], [0043], [0050]).

  In this way, alkoxytitanic acid and phosphate compounds have a wide variety of properties and functions, and expectations for various functional products have been suggested. However, regarding the mechanism of action, pharmacological properties, and specific effects, It was not revealed. Therefore, the pharmacological efficacy and action are shown below.

  The inventor was administered 79 antibiotics for nosocomial infection (in one month), during which GOT / GPT was 200/100 at maximum, normal after one month, and more normal than liver function (echo picture). It was. (Data available) Thereafter, sinus lymphoma occurred, and GOT / GPT was 40/30 or less normal and anti-liver function was normal while anticancer drug was administered 8 times for 6 months.

  One month after discharge, liver function (echo, etc.) was normal even when GOT / GPT reached 800/400. Turned out. The patient had numbness and pain in the shoulders and legs before administration of the anticancer drug, and was normal in surgical diagnosis. Minofit 45 (antidote), a drug that lowers GOT / GPT, was administered for about 1 year, but it decreased to 300/200 of severe cirrhosis, but increased when stopped. Appetite was normal. Occasionally, I got information that I could get pain when I applied a non-woven fabric using yarn containing nano particles (10-100 nano), and I tried using Rainbow's Rainbow Sheet. Although it became light, GOT / GPT did not fall. Therefore, it is considered that the linear phosphoric acid and titanic acid of the present invention have a diameter of 1 nanometer and phosphoric acid is grafted on the titanic acid linear polymer. Ion is considered to be worth the particle size x 4th power, and compared to the known granular product (granular titania and all nanoparticles are 10 nanometers or more), it is thought that there is a surprising activity, the inflamed part (shoulder , Underwear that is in contact with the waist), 3 parts each impregnated with titanic acid, 0.1% of the phosphoric acid polymer IT-P6 and 1.0% of PT6 are used for the part, and the minofit 45 is not injected for 10 days. After traveling home, GOT / GPT fell to 25/15 and has been stable for three years now. (Monthly data available)

  As a result of examination with medical personnel in the references, allergies due to immune abnormalities are caused by aberrant internal reactions that cause rapid inflammation of internal inflammation, which causes atopic / hay fever and collagen disease pain. Although steroids and the like are administered, they are temporary and do not reach full cure, but when external immunity is lowered, internal immune responses are suppressed. In other words, it was found that when the strong immunity from the outside was raised, the function of raising the immunity in the body's immune system was stopped, and new medical theories and methods were built one after another.

  Furthermore, the activity of the technology for including nanoparticles in the known granular titania, Rainbow, and other fibrous polymers is 4 to 100 nanometers, and the generation of negative ions due to the potential between the particles is extremely small. In the case of phosphoric acid linear polymers, redox potentials are alternately formed between the titanium and phosphorus atoms, and are linked to each other. Therefore, the same as the principle of Nihon Trim's other reduced water manufacturing method and Rainbow's electric PDP multi-dome. It has been proved that the positive / negative potential is repeatedly accelerated and moved, and this reacts with moisture to form intense negative and positive ions. , When the electrical products are more active than forcing negative ions and positive ions to form and touch the skin (the polymer surface), the body's moisture and air It is thought that it reacts with the water in it to generate negative ions and positive ions, and also acts on the cell composition of the body, significantly improving the immunological activity of living bodies (animals, plants) shown in the Examples, Oxidation, aging, fatigue, deterioration, pathogenesis, inflammation → swelling (pus) → tumor → cancer The part that leads to cancer is strongly oxidized and reduced, and aging, deterioration, and dead cells are regenerated and repaired like iPS universal cells It has been proven to be. Furthermore, it was found that the oxidized odorant was reduced, the reduced odorant was oxidatively decomposed, deodorized, swelling and pus were repeated, and it was found to be decomposed and eliminated by the oxidation-reduction potential. It has become clear from the outside that there is no side effect.

  Strong negative ions and positive ions are produced in the body as shown in Rainbow products, products using nanoparticles, known titania, pharmacological action of Nihon Trim's reduced water, and CTS's hydrating water. The mechanism is the same as the mechanism that leads to fatigue recovery and disease healing by reducing the peroxide radicals (caused by fatigue, oxidatively deteriorated foods, stress, etc.). Negative ions / plus ions cannot be created, and an expensive device that generates negative ions and positive ions with strong electric power is necessary, which is not always applied to the body and cannot be cured by drugs such as drug allergic inflammation. Simply impregnate the underwear with 0.001-2%, preferably 0.1-1% aqueous solution of the disease, not from the inside, without using electricity or expensive products. Strongly modulate immune (negative ion activity / positive ions activity) method from only the technical present invention came to find that the absence. Known titania is not active without light, it falls off, has a short life, and expensive cloth products such as Rainbow are lost when discarded, but this product is extremely low priced, and is a normal clothing It can be used as if it were renewed, and its activity does not change at all even after repeated washing. Furthermore, if you put torn underwear, towels, socks, etc. in a net, close them in an animal room, they can be reused as a powerful negative ion / positive ion generator for deodorant, antibacterial, heel effect, and life effect.

  In addition, it is effective in preventing the oxidation of plants and fresh foods (meat, fruits, etc.) and activating weak cells, and has a powerful negative ion in the repellent effect of small animals that gather in carcasses and septics like ants and cockroaches. It turns out that it shows efficacy, and sore throats, leg cramps, allergies, etc. are instantly cured because the strong negative ions and positive ions act on the lymph nodes, and the redox potential is at the site where immune control comes. Has been found to be an action that can be brought back to normal control in order to repeat the supply by the required amount, and suddenly promote blood flow. Forced treatment devices cause excessive effects (side effects) in order to supply pharmacological effects and potential effects to the affected areas and sites that require redox, forcibly and unilaterally (oxidation or reduction only). This titania In order to supply the necessary amount of oxidation-reduction potential necessary for the site from the outside at an ultra-high speed, unnecessary cell sites are not damaged (side effects) and are equivalent to universal cell iPS. It has been found that (LED) provides 100% power efficiency compared to 50-60% potential efficiency, and the present invention could be constructed.

International Publication No. 2010/140501

  An object of the present invention is to find a function and property of an alkoxytitanic acid / phosphoric acid linear polymer compound that has not been known so far, and to provide a product that effectively uses it.

  More specifically, as its function, negative ions and positive ions generated from a conventionally known particulate titanium phosphate compound of 10 nm to several hundreds of nm are due to an oxidation-reduction potential generated between molecules or particles. In the alkoxy titanic acid / phosphoric acid linear polymer compound used in the invention, the redox potential generated between the titanium and phosphorus atoms constituting the linear polymer chain is efficiently negative by moving the linear polymer chain. It is presumed that ions and positive ions are generated, and the method of electrically generating negative ions and positive ions is superior to that of a blue light emitting diode (LED) that has only 50 to 60% power efficiency. At the same time, strong negative ions and positive ions can be generated with 100% efficiency without any special energy source.

  In this way, the alkoxy titanic acid / phosphoric acid linear polymer compound generates strong negative ions and positive ions, so that the above-mentioned effects can be exerted. Based on this knowledge, an object of the present invention is to provide a redox potential generating material that uses various base materials and can solve new problems.

  That is, the present invention starts chain transfer polymerization by adding phosphoric acid or alkyl phosphate ester to an alcoholic solution of alkoxytitanic acid in the absence of water and in the presence or absence of mineral acid, The present invention relates to a redox potential generating material coated or impregnated with a solution of a linear alkoxytitanic acid / phosphoric acid polymer obtained by stopping polymerization before becoming glued and becoming cloudy.

  Hereinafter, the oxidation-reduction potential generating material of one embodiment of the present invention will be described. In this embodiment, chain transfer polymerization is initiated by adding phosphoric acid or an alkyl phosphate ester to an alcoholic solution of alkoxytitanic acid in the absence of water and in the presence or absence of a mineral acid, particularly hydrochloric acid, Regarding a redox potential generating material composed of a material coated or impregnated with a solution of a linear alkoxytitanic acid / phosphoric acid polymer obtained by stopping polymerization before the polymerization solution is further glued and further clouded, In the oxidation-reduction potential generating material of this embodiment, yellow phosphorus / red phosphorus is oxidized / reduced between the phosphorus atoms of phosphoric acid grafted on the titanic acid linear chain and the titanium atoms of titanic acid, and oxidized. / Reduction potential is chain-transferred to generate strong negative ions and positive ions, and the positive ions reduce the peroxidation sites, and the bacterial sites of inflammation and swelling are decomposed with negative ions It is inferred.

  Examples of the linear alkoxytitanic acid / phosphoric acid polymer used in the present embodiment include a hydrochloric acid-containing type produced in the presence of hydrochloric acid described in Patent Document 1, and the present inventors have invented the invention. Preferred is a hydrochloric acid-free type (Japanese Patent Application No. 2012-170990 specification) manufactured under the condition that no hydrochloric acid is applied.

The linear alkoxytitanic acid / phosphoric acid polymer described in Patent Document 1 is
(1) Pure alkoxy titanic acid monomer in a system in which excess alcohol without adding water and hydrochloric acid coexist, the excess alcohol and hydrochloric acid are 1/1 in hydrochloric acid type with respect to the alkoxy titanic acid monomer. In addition to coexisting from 2 moles to 2 moles (“valence mole” means the number of moles of hydrochloric acid reacted with 1 mole of tetravalent alkoxytitanic acid), a protective function was formed. Following the process of synthesizing the alkoxy titanate monomer,
(2) A dilution step in which water is added to the alkoxytitanic acid monomer to perform dilution hydration reaction depending on the polymerization concentration, or methanol is added and diluted without adding water,
(3) after the dilution step, adding a chain transfer catalyst containing an ion exchange resin, and polymerizing from a low molecular weight polymer to a transparent gelation point;
(4) a step of dehydrochlorinating a polymer polymerized with a chain transfer polymerization catalyst with an ion exchange resin;
(5) After the ion exchange polymerization, phosphoric acid or trimethyl phosphoric acid is added to form a complex.

（式中、Ｒはアルキル基）
で表される繰り返し単位、またはチタン酸水和保護基にリン酸が錯塩として安定して配位している単位を持つものと考えられる。このチタン原子とリン酸のリン原子の間で黄リン／赤リンが連鎖変換され、連鎖移動する酸化還元電位により、マイナスイオンとプラスイオンを発生させる電気装置（レインボー社のＰＤＰドームや（株）日本トリムの水素水発生装置）にも近似する強力なマイナスイオンとプラスイオンが発生するものと考えられる。Its structural formula is an estimate, but the formula:

(Wherein R is an alkyl group)
Or a unit in which phosphoric acid is stably coordinated as a complex salt to the titanic acid hydrate protecting group. Electric devices that generate negative ions and positive ions by the redox potential of chain transfer between yellow and red phosphorus between the titanium atom and the phosphorus atom of phosphoric acid (PDP Dome and Rainbow Co., Ltd.) It is thought that strong negative ions and positive ions that are similar to those of Nippon Trim's hydrogen water generator are generated.

In addition, the hydrochloric acid-free linear alkoxytitanic acid / phosphoric acid polymer, which was invented by the present inventors and manufactured under the conditions without using hydrochloric acid, is in the absence of water and mineral acid. In addition, phosphoric acid or trimethyl phosphate is added to an alcoholic solution of alkoxytitanic acid to start chain transfer polymerization, and before the polymerization product liquid is glued and further clouded, for example, the viscosity of the polymerization product solution is 1.0 × It can be obtained by stopping the polymerization when it reaches 10 ⁴ cP.

（式中、Ｒはアルキル基）
で表される繰り返し単位、またはチタン酸水和保護基にリン酸が錯塩として安定して配位している単位を持ち、安定化するものと考えられる。Hydrochloric acid-free type linear alkoxytitanic acid / phosphoric acid polymer obtained by this production method is polymerized under conditions where water is not present, and when the obtained polymer is diluted in water,

(Wherein R is an alkyl group)
Or a unit in which phosphoric acid is stably coordinated as a complex salt to the titanate hydrate protecting group.

  As the alkoxy titanic acid used in this embodiment, tetraalkoxy titanic acid is preferable. For example, one or more of tetramethoxy titanic acid, tetraethoxy titanic acid, tetraisopropoxy titanic acid, and tetrabutoxy titanic acid are preferable. Above all, in terms of synthesis stability, high concentration, cost, etc. Tetraisopropoxytitanic acid is particularly preferred because it is advantageous and has excellent stability at a high concentration.

  As alcohol which melt | dissolves alkoxy titanic acid, a lower alcohol is preferable, for example, 1 type (s) or 2 or more types, such as methanol, ethyl alcohol, butanol, isopropanol, are mentioned. Among these, isopropanol is particularly preferable because it is advantageous in that the concentration of the polymerization product can be increased and the chain transfer polymerization is stably advanced.

  The concentration of the alkoxy titanic acid in the alcohol solution is preferably 0.2% by mass or more and 50% by mass or less from the viewpoint of easy stirring during polymerization. In particular, the range of 1.0 to 10% by mass is preferable from the viewpoint of good productivity and uniform polymerization reactivity.

  To initiate the chain transfer polymerization of alkoxy titanic acid, phosphoric acid or alkyl phosphate ester is added in the absence of water and mineral acid. The amount of phosphoric acid or alkyl phosphate ester added per mole of alkoxytitanic acid (tetravalent) and the polymerization concentration are controlled by the target phosphorylation rate to control negative ion strength and positive ion strength, and from the viewpoint of polymerization degree, etc. May be selected as appropriate. Specifically, it will be described later.

  Examples of the alkyl phosphate ester include trimethyl phosphate, triethyl phosphate, tributyl phosphate, triisopropyl phosphate, and the like. Particularly, the phosphorylation reaction rate and the chain transfer polymerization initiation ability are good. -Trimethyl phosphoric acid is preferable because the phosphoric acid polymer is excellent in storage stability.

In order to linearize the alkoxytitanic acid / phosphoric acid polymer used in the present embodiment, it is important to stop the polymerization “before the polymerization product solution is glued and further clouded”. The polymerization product solution becomes cloudy because the degree of polymerization increases and the viscosity increases as chain transfer polymerization proceeds, and uniform stirring becomes difficult (glue). Therefore, it is necessary to add phosphoric acid or alkyl phosphate ester. If the polymerization is not stopped by stopping, the reaction between the phosphoric acid or the alkyl phosphate ester and the generated alkoxy titanic acid / phosphoric acid polymer proceeds, and the alkoxy titanic acid / phosphoric acid polymer causes a crosslinking reaction, This is probably because a three-dimensional network structure is partially formed. As a result, it becomes difficult to dissolve in water and becomes cloudy. The standard of the upper limit of the viscosity that can be uniformly stirred (before gelatinization) is 1.0 × 10 ⁴ cP.

  The timing for stopping the polymerization before the polymerization product liquid becomes cloudy depends on the polymerization conditions (for example, whether there is uniform stirring or when addition of phosphoric acid or alkyl phosphate is stopped). Since it changes variously, it is possible to confirm that the polymerization solution does not become cloudy and cloudy by conducting a pilot experiment in advance and grasping the relationship between the polymerization conditions and the clouding and clouding point. For example, in a system in which tetraisopropyl titanic acid is diluted with isopropanol and then added with phosphoric acid or alkyl phosphate ester diluted with isopropanol, polymerization of phosphoric acid or alkyl phosphate ester is performed while stirring is performed. When the addition is stopped and the polymerization is stopped, the resulting polymer increases the viscosity but does not cause cloudiness (crosslinking).

For example, the time point when the polymerization is stopped is preferably a time point when the viscosity of the polymerization product solution becomes 1.0 × 10 ⁴ cP, but the polymerization may be stopped before that. However, it is not preferable that the stop timing is too early because productivity, that is, the phosphorylation rate cannot be increased. Therefore, it is desirable to stop the polymerization when the polymerization solution has a viscosity of 1.0 × 10 ³ cP to 1.0 × 10 ⁴ cP.

（Ｒはメチル基、エチル基、ブチル基またはイソプロピル基、ＩＰＡはイソプロパノール、Ｐはリン酸、ｎは２〜１０００の整数）It is considered that the estimated reaction formula in the method for producing a linear alkoxytitanic acid / phosphoric acid polymer proceeds in the following two stages.

(R is methyl group, ethyl group, butyl group or isopropyl group, IPA is isopropanol, P is phosphoric acid, and n is an integer of 2 to 1000)

A measure of the timing for stopping the polymerization is the time when the viscosity of the polymerization product solution reaches 1.0 × 10 ⁴ cP, but the timing for stopping the polymerization can also be judged from other qualitative or quantitative viewpoints. For example, important polymerization conditions that affect the time when the polymerization product liquid becomes cloudy after gelatinization include the addition method of phosphoric acid or alkyl phosphate ester, polymerization temperature, stirring efficiency, and the like. In the following, in relation to these conditions, the timing for stopping the polymerization before the polymerization product liquid becomes glued and the stirring becomes uneven and becomes cloudy will be described. As described above, even if the polymerization product liquid becomes glued and the stirring becomes uneven, when the polymerization is stopped by stopping the injection of phosphoric acid or alkyl phosphate ester, the resulting polymer increases the viscosity but becomes cloudy ( (Crosslinking) is not performed, so the timing for stopping the polymerization can be controlled.

(1) Method of adding phosphoric acid or alkyl phosphate ester Addition of phosphoric acid or alkyl phosphate ester includes continuous addition, sequential addition, and batch addition. Among these, the continuous addition method is preferred, because the reaction proceeds uniformly, and when phosphoric acid comes into contact with the polymerized polymer inhomogeneously, it becomes an ultra-polymer or branched / crosslinked polymer, which causes white turbidity. It is possible to easily find the gelled cloudiness point and to uniformly promote the polymerization. In particular, the most preferable reaction for using a phosphoric acid ratio of 30% or more with respect to the weight of alkyl titanic acid is to rotate the continuous emulsifier to 1000 to 10,000 rpm, This is a method of proportionally injecting liquid.

(1-1) When addition of phosphoric acid or alkyl phosphate is continuous or sequential addition:
The timing for stopping the polymerization in this case is preferably the time when the addition amount is 0.05 mol or more and less than 2 mol with respect to 1 mol (tetravalent) of alkoxytitanic acid in the case of phosphoric acid, more preferably The addition amount with respect to 1 mol (tetravalent) of alkoxy titanic acid is 0.1 to 1.7 mol. In the case of an alkyl phosphate ester, the addition amount is preferably 0.05 mol or more and less than 2 mol with respect to 1 mol (tetravalent) of alkoxytitanic acid, and more preferably the addition amount is 0.1 to 0. This is the point when it reached 9 moles. As the polymerization temperature, it is desirable to employ a temperature not lower than the precipitation of alkoxy titanic acid, 5 ° C. or higher when the polymerization concentration is 10% by mass, preferably 30 ° C. or lower, and 20 ° C. or lower when the polymerization rate is not controlled. When the polymerization temperature becomes high, the polymerization reaction rate becomes too fast, and it may be difficult to grasp the time point when the polymerization product liquid becomes glued and cloudy. Further, it is desirable to proceed the polymerization with stirring, and as the stirring speed, for example, when the rotation diameter of the stirring blade is 50 mm, it is preferable to select 500 rpm or more, preferably 1000 rpm or more. In addition, when using phosphoric acid, it is preferable to dilute and add with alcohol (isopropanol, methanol, etc.) from the point which controls reaction easily. If the alkyl phosphate ester is added excessively, it will act as a solvent after the polymerization product solution has become turbid and cloudy, thereby reducing the viscosity of the polymerization product solution.

(1-2) When adding alkyl phosphate ester all at once:
In this case, in addition to the addition amount of the alkyl phosphate ester, the polymerization temperature and the polymerization time, and further the stirring speed are important in determining when to stop the polymerization. When phosphoric acid is used, the reaction rate is fast, so continuous addition is most preferable instead of batch addition.

  In the case of batch addition, 0.05 to 2 mol is preferable, and 0.05 to 1.9 mol is more preferable for alkyl phosphate ester (trimethyl phosphoric acid) with respect to 1 mol (tetravalent) of alkoxytitanic acid. When the amount added is increased, the time for gelation and cloudiness tends to increase. The polymerization temperature is preferably selected in the range of 10 to 40 ° C. The polymerization temperature is closely related to the polymerization time (manufacturing time), and as the polymerization temperature increases, the time for white turbidity tends to increase, so it is desirable to select appropriately from the viewpoint of efficiency. The stirring speed is preferably selected at 1000 rpm or more when the stirring blade has a rotation diameter of 50 mm. If the alkyl phosphate ester is added excessively, it will act as a solvent after the polymerization product solution has become turbid and cloudy, thereby reducing the viscosity of the polymerization product solution.

  A specific example of the batch addition is, for example, in the range of 20 ° C. to 35 ° C. which is a preferable polymerization temperature when 0.25 mol of alkyl phosphate ester is added in one batch to 1 mol (tetravalent) of alkoxytitanic acid. When the polymerization is carried out, the polymerization product liquid often becomes cloudy and cloudy after about 20 to 40 hours, but the polymerization is stopped before that.

  In addition, even when the batch addition amount of the alkyl phosphate ester is the same, the polymerization is promoted when the polymerization temperature is increased to 45 ° C. or higher, and a heterogeneous reaction system is easily formed. Since the mixture often becomes cloudy and cloudy, it is cooled before that and diluted with water or alcohol to stop the polymerization.

  The alkoxytitanic acid / phosphoric acid polymer produced by this production method is a linear polymer and is almost infinitely soluble in various inorganic solvents and organic solvents. Therefore, various prescriptions adapted to various uses are possible, and the application range is greatly expanded.

  Although it does not specifically limit as a solvent as a solvent, For example, in addition to inorganic solvents, such as water and tetramethylsilane, Alcohols, such as methyl alcohol, ethyl alcohol, butanol, isopropanol, and phenol; Esters, such as ethyl acetate and butyl acetate Ketones such as acetone and methyl ethyl ketone; ethers such as tetrahydrofuran; aldehydes such as furfural; hydrocarbon compounds such as xylene; one or two organic solvents such as dimethylformamide (DMF) and dimethyl sulfide (DMS); More than species. Among these, water, alcohols, ketones, and esters are preferable from the viewpoint of excellent solubility, safety, coating environment safety, and the like, and infinitely soluble water and alcohols are particularly preferable. The resulting polymer concentration after being diluted with a solvent is preferably 0.0002 to 2% by mass.

  A chlorine-free alkoxytitanic acid / phosphoric acid polymer has a higher negative ion / positive ion generation effect. In order to make it chlorine-free, mineral acid, especially chlorine compounds such as hydrogen chloride and chlorine are not used for polymerization (production). The obtained alkoxy titanic acid / phosphoric acid polymer not only has a high negative ion / positive ion generation effect, but also can solve problems such as corrosion and rust generation, which are adversely affected by chlorine atoms. Furthermore, the coating speed and density of the coated film after application are increased, and it is possible to form a transparent and glossy alkoxy titanic acid / phosphoric acid polymer film with a surface hardness (pencil hardness) of 9H or more in a short time. There is also an advantage of becoming.

  Chlorine-free alkoxy titanic acid / phosphoric acid polymer is obtained by removing excess ion exchange resin from alkoxy titanic acid / phosphoric acid polymer (Patent Document 1) synthesized using hydrochloric acid or ion exchange resin developed by the present inventors. When used, it can also be obtained by removing free (desorbed by polymerization) chlorine, but the bonded chlorine atoms cannot be completely removed. When bound chlorine exists, it decomposes itself or decomposes by ultraviolet rays or visible light, and releases chlorine. From the viewpoint of the presence or absence of bound chlorine, the chlorine-free alkoxy titanic acid / phosphoric acid polymer used in this embodiment is designated as a new chemical substance by the Ministry of Health, Labor and Welfare, the Ministry of the Environment, and the Ministry of Science and Technology's Ministry of Science and Technology's three ministries' examination committee, Certification application is in progress. Test manufacturing, test construction, and test processing must comply with the GLP Law and strictly follow safety and health management. When using test processed products that are applied to the human body, strictly observe the use of the test in consultation with a doctor. Also, strictly observe the approval of the Ministry of Health, Labor and Welfare when officially selling products.

  The oxidation-reduction potential generating material of this embodiment can be produced by applying or impregnating various base materials. In addition, it is possible to coat the pelletized plastic and mold the coated product to obtain various forms of oxidation-reduction potential generating materials. Further, for example, a long fiber can be provided by spinning, and a mesh-like cloth / film can be formed by curing.

  As a base material, natural materials such as cotton, linen and leather; fibers, yarns, hollow fibers using synthetic materials such as polyester, polyvinyl chloride, polypropylene, nylon, polyimide, polyvinylidene chloride, polyacetal, polyurethane, polyacryl, etc. In addition to intermediate materials and molded products such as woven fabric, non-woven fabric, knitted fabric, paper, film, board, etc., natural wood, materials processed from paper, etc. can also be used, and trees, cuttings, next trees, fruits, It can also be used for storing vegetables, cut flowers, paddy rice, etc., and maintaining the freshness of transplants.

  A coating method, an impregnation method, etc. are not specifically limited, Generally a well-known method is employable.

  The adhesion amount or impregnation amount of the alkoxy titanic acid / phosphoric acid polymer varies depending on the type of the substrate, the intended effect, the activity strength of the alkoxy titanic acid / phosphoric acid polymer, etc. 0.0001 mg or more per 10 cm square, 0.001 to 0.5 mg for the hydrochloric acid type, and 0.0001 to 0.05 mg for the hydrochloric acid free type are preferable from the viewpoint of cost and effect.

  When applying, it is essential to use a spray gun and an air mask in combination because it is a new chemical substance. When impregnating cloth, paper, or wood, the hydrochloric acid type is preferably 10% to 0.0001% and the non-hydrochloric acid type is preferably 2% to 0.00001% with respect to the dry matter weight.

  The oxidation-reduction potential generating material of this embodiment can be produced in various forms by impregnating or coating a base material made of various materials such as plastic, metal, ceramics, glass, natural or synthetic fiber. For example, it can be used in the form of cloth, underwear, socks, shoes, wallpaper, flooring, wallboard, ceiling board, air filter, follow fiber, artificial flower, film, processed wood product, plant, etc. of various sizes and thicknesses.

  The oxidation-reduction potential generating material according to the present embodiment causes strong negative ions and positive ions to act on water molecules to generate a redox activity effect even in the absence of light. Non-medical effects such as repellent effect, freshness maintenance effect, growth promotion effect in agriculture field, sterilization effect, gasoline vehicle fuel efficiency improvement effect, cooling and heating effect, appropriate temperature / temperature keeping / constant temperature effect, power efficiency improvement effect, new power generation system creation effect Since it has a system effect, it can be effectively used for these applications.

  In addition, diseases caused by peroxide radicals due to abnormal increase or decrease in immunity, that is, anti-inflammatory analgesic effect, hematoma disappearance effect, dizziness disappearance effect, komakaeri disappearance effect, capillary hemangioma disappearance effect, hay fever and Atopic symptom improvement effect, tinnitus improvement effect, drug allergic rhinitis disappearance effect, colon polyp disappearance effect, senile gastric wall atrophy disappearance effect, senile skin tumor spot disappearance effect, tendonitis inflammation treatment effect, blister and herpes treatment effect, physiological irregularity improvement effect Prostate hypertrophy prevention effect, tonsillitis pain relieving effect, headache relieving effect, elimination of benign tumors in sinus, blood vessel regeneration effect, emphysema regeneration effect, thyroid / breast / prostate cancer improvement effect, disappearance of benign lymphoma Since therapeutic effects such as an effect and an auxiliary effect of administration of an anticancer agent for malignant lymphoma are also obtained, it can be effectively used for these pharmaceutical applications.

  Furthermore, the oxidation-reduction potential generating material of this embodiment is also a magnetic substance, and can be expected to be effective for various treatments using magnetic force.

  As described above, according to the oxidation-reduction potential generating material of the present embodiment, the generated negative ions and positive ions act on moisture generated in the air and on the surface of the living body, and in the case of a living body, it is strongly negative depending on the symptom in the living body. Ion or positive ions are taken in, fatigue, inflammation, swelling, hematoma, aging, deterioration, purulent cells, reducing action by positive ions at sites oxidized radicals, negative ions and positive ions are immune system and lymph nodes It exerts excellent external medical effects in a very wide range of fields by accelerating blood flow, reducing and purifying blood, and sterilizing bacteria in the inflamed and swollen pus with negative ions. It is thought to do. Since most medical treatments are internal medical methods including iPS universal cell therapy, and have many problems such as genetic problems, side effects, and treatment costs, the technology of this embodiment is epoch-making. It can be said.

  More specifically, for example, various deodorizing effects, repellent effects of various organisms, freshness maintenance effects, growth promotion effects in the agricultural field, sterilization effects, gasoline fuel economy improvement effects, cooling and heating effects, redox water production effects , Non-medical effects such as power generation / charging effect (power efficiency improvement effect, creation of new power generation system), anti-inflammatory analgesic effect, hematoma disappearance effect, dizziness disappearance effect, komakaeri disappearance effect, capillary hemangioma disappearance effect, pollen Symptom and atopy symptom improvement effect, tinnitus improvement effect, drug allergic joint / muscle anti-inflammatory effect, rhinitis disappearance effect, colon polyp disappearance effect, senile gastric wall atrophy disappearance effect, senile skin tumor spot disappearance effect, fracture treatment promotion effect, colon Hematoma healing effect, nose rash disappearance effect, headache disappearance effect, sore throat inflammation extinction effect, headache improvement disappearance effect, emphysema repair effect, thyroid gland, mammary gland, prostate Improvement effect, benign lymphoma elimination effect, malignant lymphoma anticancer agent administration, anticancer agent auxiliary effect using a low concentration of 0.3% or less for the previous week (if the impregnation concentration is 1.0% wt ratio or more, the anticancer agent has cell activity It is thought that the action of weakening and eliminating high cancer cells by attack is reduced and repaired, so that it needs to be used in consultation with a doctor.).

  In particular, it is effective for the fundamental treatment of various allergic diseases for which coping therapy is the mainstream, as well as for the extinction and analgesia of collagen diseases and rheumatism, which are regarded as intractable diseases, and the disappearance of various tumors.

  The present invention is not limited to the above embodiment. The above-described embodiment is included in the invention having the following configuration.

  (1) In the absence of water and in the presence or absence of mineral acid, phosphoric acid or alkyl phosphate ester is added to the alcoholic solution of alkoxytitanic acid to initiate chain transfer polymerization, An oxidation-reduction potential generating material coated or impregnated with a solution of a linear alkoxytitanic acid / phosphoric acid polymer obtained by stopping the polymerization before conversion and further clouding.

(2) The oxidation-reduction potential generating material according to (1), wherein the timing for stopping the polymerization is when the viscosity of the polymerization product reaches 1.0 × 10 ⁴ cP.

  (3) The oxidation-reduction potential generating material according to (1) or (2), wherein the alkoxytitanic acid is tetramethoxytitanic acid, tetraethoxytitanic acid, tetrabutoxytitanic acid or tetraisopropoxytitanic acid.

  (4) The redox potential generating material according to any one of (1) to (3), wherein the alcohol solution is at least one solution selected from the group consisting of methanol, ethanol, butanol, and isopropanol.

  (5) The oxidation-reduction potential generating material according to any one of (1) to (4), wherein the alkyl phosphate ester is trimethyl phosphate, triethyl phosphate, tributyl phosphate, or triisopropyl phosphate.

  (6) After the solution of the linear alkoxytitanic acid / phosphoric acid polymer to be coated or impregnated stops the polymerization, the concentration of the produced polymer is immediately increased using water, an organic solvent, or a mixed solvent of water and an organic solvent. The redox potential generating material according to any one of (1) to (5), which is a diluted solution diluted to 0.0002 to 2% by mass.

  (7) For deodorization, for repelling organisms, for maintaining freshness, for promoting growth in the agricultural field, for sterilization, for improving fuel economy of gasoline vehicles, for cooling and heating, for producing redox water, for power generation and charging ( The redox potential generating material according to any one of (1) to (6), which is used for improving power efficiency and creating a new power generation system.

  (8) For normalization of GOT / GTP value due to drug allergic myositis, anti-inflammatory analgesic, hematoma disappearance, dizziness disappearance, vertigo disappearance, capillary hemangioma disappearance, hay fever improvement, atopic symptom improvement , Tinnitus improvement, drug allergic rhinitis disappearance, nasal rash (benign tumor) disappearance, collagenous rheumatic treatment, colon polyp disappearance, senile gastric wall atrophy disappearance, senile skin tumor spot disappearance, Tendinitis treatment, blister and herpes treatment, improvement of menstrual irregularity, prevention of prostatic hypertrophy, tonsillitis pain relief, headache relief, disappearance of sinus benign tumor, revascularization, emphysema repair, thyroid / breast / prostate cancer The redox potential generating material according to any one of (1) to (6), which is used for improving effect or lymphoma disappearance assistant (used together for 1 week before administration of anticancer agent), improving power efficiency, creating a new power generation system, and the like.

  Next, the present invention will be specifically described with reference to production examples, examples and test examples.

Production Example 1 (Production of hydrochloric acid type tetraisopropoxytitanic acid / phosphoric acid polymer)
Monomer described in Example 2 of Patent Document 1 (monomer obtained by adding 2 mol of hydrochloric acid to 1 mol of TIPT in a 10% by mass methanol solution of tetraisopropoxytitanic acid (sometimes abbreviated as “TIPT”)) The tetraisopropoxy titanic acid / phosphoric acid polymer obtained by reacting 6% by mass of phosphoric acid with respect to the monomer mass at 30 ° C. or lower was used. Hereinafter, this hydrochloric acid type tetrapropoxy titanic acid / phosphoric acid polymer solution is referred to as PT6.

  In addition, the monomers described in Example 2 of Patent Document 1 are as follows. That is, the monomer (A) synthesized in Example 1 of Patent Document 1 (A) (TIPT-MC4 10 / TMT-MC4 10 / POT-OC4 10) 10% equivalent solution 1 mol (4 mol of hydrochloric acid, etc.) Mole number), 85% phosphoric acid and trimethyl phosphate (trimethyl phosphate ester) are added to the chain transfer polymerization catalyst (chelating agent) and polymerized to gradually become viscous, with a clear gelation point or maximum viscosity ( Viscosity increased, became thicker, did not become agglomerated, and when it was further added, the concentration reached the point where the viscosity began to decrease), and a 2 mol hydrochloric acid (1/2 mole of titanium) monomer (B) (TIPT-MC2 10 / TMT-MC2 10 / POT-OC2 10) was similarly subjected to chain transfer polymerization, and the concentration of the catalyst reaching the gelation point was measured. In addition, the rotation speed at the time of reaction was performed at 10 m / min or more, and the rotation speed was adjusted by the dropping speed and the cooling efficiency.

  When 1 mol of titanic acid has 4 mol of HCl (equal molar value), the polymerization does not reach a high molecular weight, terminates at a low molecular weight, does not reach the point of gelation, and phosphoric acid and trimethyl phosphate are solvents. It is thought that the viscosity decreases because of becoming. The addition of a large excess of the phosphoric acid compound does not produce a cloudy chelate precipitate, demonstrating the stability of the protecting group.

Production Example 2 (Manufacture of hydrochloric acid-free tetraisopropoxytitanic acid / phosphoric acid polymer)
While maintaining a 4% by mass isopropanol solution of tetraisopropoxytitanic acid at 20 ± 1 ° C., an 8.5% isopropanol solution until phosphoric acid was 6% by mass with respect to the amount of tetraisopropoxytitanic acid was continuously added. The polymerization was started by dropping, and the dropping was continued over 30 minutes while stirring at a stirring speed of 1000 ± 10 rpm. The dropping amount of phosphoric acid (the ratio by weight of phosphoric acid to the weight of tetraisopropoxytitanic acid) was tetra The polymerization was stopped when the mass of isopropoxytitanic acid reached 6%. The liquid temperature of the polymerization product liquid was maintained at 20 ± 5 ° C. The viscosity of the polymerization product liquid at that time was 1 × 10 ³ cP. Hereinafter, this hydrochloric acid-free tetraisopropoxytitanic acid / phosphoric acid polymer solution is referred to as IT-P6.

Comparative production example 1 (particulate titania having a large particle size)
A commercial product of nitric acid-based particles having a diameter of 10 to 200 nm (STS-01 manufactured by Ishihara Sangyo Co., Ltd., concentration 30% by mass, trade name) was diluted in water and used as a 2% solution. Hereinafter, this titanic acid nitric acid condensation polymer solution is referred to as STS01.

Example 1
PT6 produced in Production Example 1 was diluted with pure water to prepare 2 L of a diluted liquid having a concentration of 1.0% by mass.

  Subsequent dry matter of the substrate 1 was soaked in this diluted solution for 10 minutes and then taken out and squeezed until it became about twice the weight of the substrate. Next, the sample was naturally dried in a room (about 25 ° C.) for 6 days to prepare Test Sample 1 (PT6 adhesion amount: 1.0 mass%). In order to obtain the impregnated dry product efficiently and uniformly in high quality, it is more preferable to use a commercial laundry dryer having a spray inscribed.

Base material 1: 200 mm × 200 mm non-woven fabric (thickness 5 mm, polyester 100%, 10 g)

Example 2
IT-P6 produced in Production Example 2 was diluted with pure water to prepare 2 L of a diluted liquid having a concentration of 0.1% by mass.

  Next, the substrate 2 was dipped in the dried material of the next substrate 10 for 10 minutes, and then taken out until it became about twice the weight of the substrate. Next, the sample was naturally dried in a room (about 25 ° C.) for 6 days to prepare Test Sample 2 (IT6 adhesion amount of 0.1% by mass).

Base material 2: 200 mm × 200 mm non-woven fabric (thickness 5 mm, polyester 100%, 10 g)

Comparative Example 1
STS01 produced in Comparative Production Example 1 was diluted with pure water to prepare 2 L of a diluted liquid 2 L having a concentration of 2% by mass.

  The dried material of the substrate 1 was dipped in this diluted solution for 10 minutes and then taken out and squeezed until it became about twice the weight of the substrate. Next, the sample was naturally dried in a room (about 25 ° C.) for 6 days to prepare a test sample 3 (attached amount of STS01 of 2 mass%).

Comparative Example 2
A non-woven fabric (thickness 5 mm × A4 size, Rainbow PDP cloth (trade name)) prepared using a yarn obtained by spinning nano platinum particles and nano diamond particles in polyester was used as test sample 4.

  Further, the redox potential generating material of the present invention is used for deodorization, organism repellent, freshness maintenance, growth promotion in the agricultural field, sterilization, gasoline vehicle fuel economy improvement, cooling / warming, power efficiency It can be used for improvement and for new power generation systems.

  In addition, the redox potential generating material of the present invention is used for normalization of GOT / GTP value due to drug allergic myositis, anti-inflammatory analgesic, hematoma disappearance, dizziness disappearance, komakaeri disappearance, capillary hemangioma For elimination, hay fever improvement, atopy symptoms improvement, tinnitus improvement, drug allergic rhinitis elimination, nasal discharge (benign tumor) elimination, collagenous rheumatism treatment, colon polyps elimination, senile gastric wall atrophy For disappearance, for senile cutaneous spots, tendonitis treatment, blister and herpes treatment, menstrual irregularity, prevention of prostatic hypertrophy, tonsillitis pain relief, headache relief, disappearance of sinus benign tumor, revascularization, emphysema Adjuvants that are used in combination for only one week prior to administration of anticancer drugs for malignant lymphoma using restoration, thyroid / mammary gland / prostate cancer improvement effects, or disappearance of benign lymphoma, and optimal concentration of 0.1% or less Doctor Should be performed in consultation) it can be used for such.

Test example 1
(Positive ion activity test) (under visible light)
Four beakers containing 100 ml of 0.5 mass% hydrogen peroxide solution (A) were added to test sample 1 (PT6), test sample 2 (IT-P6), test sample 3 (STS01) and test sample 4 (PDP). The time until hydrogen peroxide (A) was completely decomposed was examined by oxidation-reduction titration analysis while the cloth was floated in a beaker, covered with a food wrap film, and stirred with a magnetic stirrer at 10 V / m.

  Similarly, using the aqueous hypochlorous acid solution (B), the time until the hypochlorous acid (B) was completely decomposed was examined by oxidation-reduction titration analysis.

(Negative ion activity test) (under visible light)
Moreover, using sodium bicarbonate aqueous solution (C), the time when (C) was completely decomposed and became sodium carbonate (pH 8) was measured with a pH meter manufactured by Horiba.

  As a result, in test sample 1 (PT6), hydrogen peroxide (A) was 2.4 hours, hypochlorous acid (B) was 2.0 hours, sodium bicarbonate (C) was 2.5 hours, test sample 2 (IT -P6) for 2 hours for hydrogen peroxide (A), 1.5 hours for hypochlorous acid (B), 3 hours for sodium bicarbonate (C), 200% for hydrogen peroxide (A) in test sample 3 (STS01). Time, 180 hours for hypochlorous acid (B), 25 hours for sodium bicarbonate (C), 24.0 hours for hydrogen peroxide (A) for test sample 4 (PDP cloth), 20 hours for hypochlorous acid (B) 0.0 hours and 25.0 hours for sodium bicarbonate (C).

  From this result, generation of strong negative ions and positive ions can be estimated for test sample 1 (PT6) and test sample 2 (IT-P6). This occurs because the redox potential is linked between the titanium atom and the phosphoric acid atom, and the positive ion potential is transferred to hydrogen peroxide (A) (hypochlorous acid (B)) to form hydrogen peroxide (A). It is presumed that (hypochlorous acid (B)) is reduced and decomposed, and the negative ion potential is transferred to sodium bicarbonate (C) to decompose bicarbonate ions.

Test example 2 (sweat deodorization test 1)
Test samples 1, 2, 3 and test sample 4 were affixed to the back of a man (73 years old) for 1 hour in midsummer to soak up sweat and body odor. After that, the sample was left on a desk in the room while sweat was soaked, and the smell was smelled every day, and the change in odor was examined (10 days). No abnormalities such as fogging were observed in any of the test samples on the subject's skin.

  As a result, test sample 1 (PT6) does not emit an odor (sour rot odor generated by decomposition of the sweat component by Moraxella bacteria) for 10 days, and test sample 2 (IT-P6) is at the end of the test (after 10 days). But no odor was emitted. On the other hand, test sample 3 (STS01) had a bad odor after one day, and test sample 4 (PDP cloth) had a bad odor after one day.

  Furthermore, after the test was completed, when exposed to sunlight for 1 hour, Test Samples 1 and 2 gave a buttery aromatic odor (which is considered to be an odor when the fats and oils are completely decomposed). In test sample 3, the odor once disappeared, but a bad odor was emitted again one day later. Test sample 4 did not wash away sweat odor. The subject had a body temperature of 33 ° C. ± 0.5 ° C. before this test, but increased to 36.5 ° C. ± 0.2 ° C. two months after the start of the test. It is thought that immunity improved.

Test example 3 (deodorant activity maintenance test: washing)
After the test for deodorizing sweat in Test Example 2, each test sample was washed with a household alkaline detergent and dried outdoors in the sun. After drying, the sweat deodorization test of Test Example 2 (one cycle for 14 days) was conducted to observe whether the effect was maintained. When this cycle was performed 16 times (8 months), the effect was not changed in test samples 1 and 2, but in test sample 3, the activity disappeared in the first cycle. For test sample 4, the sweat odor did not disappear after 2 cycles unless washed.

Test Example 4 (Odor Mitigation Test: Bacterial Liquid Absorption Method)
According to JIS L 1902 (2008), growth inhibition of Moraxella bacteria (causative bacteria of sweat odor) was examined by a bacterial liquid absorption method.

The test sample was produced as follows.
Test sample A (IT-P6):
A sample in which IT-P6 produced in Production Example 2 was diluted with pure water and impregnated with a 0.1% by weight diluted solution on a 100 mm × 100 mm × 5 mm thick polyester non-woven fabric (attachment amount of IT-P6 0. 1% by mass)
Test sample B (PDP cloth):
Nonwoven fabric (5mm thick x A4 size, Rainbow PDP cloth (trade name)) made by spinning yarns containing nanoplatinum and nanodiamond particles in polyester

The test method is as follows.
It carried out according to JIS L 1902 (2008).

  As a result, the number of cells decreased to 20 after 10 minutes in the test sample A, but as many as 2200 cells remained even after 20 hours in the test sample B.

Test example 5 (ant repellent test)
Test sample 1 (PT6), test sample 2 (IT-P6), test sample 4 (PDP cloth) and control test sample (untreated non-woven fabric) are each cut into 10 cm squares and placed side by side on dry ground. In the center, 1 g of Aritol (Sumitomo Chemical Gardening Co., Ltd.) was placed and left.

  As a result, after 1 hour, countless ants gathered in the control test sample, and 23 ants were on the non-woven fabric of test sample 4, but ants gathered in test samples 1 and 2. None (zero). Ants and cockroaches have the property of gathering in dead bodies and septics of organisms, gathering in negative ion activities that have lost their livelihood, and in particular, have the property of sensing and avoiding animals and humans that have positive ion activity (liveness). It is considered that the strong negative ion activity that has occurred is concentrated, and in particular, positive ions are avoided. As a result of applying penetration to screen doors and sashes, placing allitol on the indoor side and conducting intrusion tests, it was found that there was no intrusion from the treated part, which was a new technology for building materials and construction.

Test Example 6 (cockroach repellent test)
Test Sample 1 (PT6), Test Sample 2 (IT-P6), Test Sample 4 (PDP cloth) and Control Test Sample (untreated non-woven fabric) are placed side by side, and the positions are set daily at the four corners between the kitchen plates in a general house. They were placed in order, and a cockroach capture device ("Gokuburi Hoi Hoi (registered trademark) mini" manufactured by Earth Pharmaceutical Co., Ltd.) was placed in the middle of the plates and allowed to stand overnight.The total captured between April and August was measured.

  As a result, 7 animals were captured in the control test sample and 3 animals were captured in the test sample 4, but zero were present in the test samples 1 and 2. The mechanism of repelling is considered to be the same as in Test Example 5. As a result of testing five houses each of the sash and door gaps, the housing applied to the floor of the closet and sink storage area, and the house not treated at all, no one cockroach was found in the treated house for one year. In untreated houses, 5 to 10 animals have been confirmed per building.

Test Example 7 (Strawberry freshness maintenance test)
Test sample 1 (PT6), test sample 2 (IT-P6), test sample 4 (PDP cloth) and control test sample (untreated non-woven fabric) were each cut into 10 cm squares and spread on the bottom of a plastic container for strawberries. Next, six strawberries ("Sahonoka") were arranged in a row, covered, and left in the room for 3 days.

  As a result, white spots were generated in all six of the control test samples, white spots were generated in three of the test samples 4, but zero in the test samples 1 and 2.

Test Example 8 (Fresh Freshness Maintenance Test)
Test Example 8-A
Test sample 1 (PT6), test sample 2 (IT-P6), test sample 4 (PDP cloth) and control test sample (untreated non-woven fabric) are each cut into 10 cm squares, and 6 daffodil cut flowers are bundled and wrapped around the bottom. It was. The narcissus bouquet was put in a vase (with 200 ml of water) and left in the room for one week. When fruits and cut flowers are separated from the living body, they lose their livelihood (immunity in animals) rapidly, and the freshness decreases due to auto-oxidation (digestion). It is thought that the freshness was maintained because the antibacterial action by negative ions and the positive ions were reduced to suppress auto-oxidation.

  As a result, all six petals were discolored in the control test sample, and one petal was discolored in test sample 4, but none of the six petals were discolored in test samples 1 and 2.

Test Example 8-B
After the treatment of spraying 0.001% solution of IT-P6 on the stems of mini roses, air-dry and confirm that it is dry, cut the cut with scissors (sealing the cut with IT-P6 will absorb water Hindered and counterproductive), and put this mini rose in a 50cc vase. Compared to the case of mini roses that were not treated with IT-P6, the results of a comparison of freshness courses showed that, even if treated, it survived even after 3 weeks, and even after the petals fell, new buds germinated and white roots were produced. It was. In the case of untreated, it withered in 3 to 4 days.

Test Example 8-C
Prepare cedar cuttings, 10 samples of paper towels impregnated with IT-P6 and dried around 10 cm below the branches, and 10 untreated samples without IT-P6. As a result of planting in (Home Wide Sales) and holding for 3 months (May-July), 50% died without treatment, and only 5-10 rooted roots grew sideways. In the treated one, a paper towel made of pulp was spread out, rooted in a cylindrical shape of 3 to 4 cmφ, the roots were innumerable, and new shoots were spread from 13 to 5 cm. Even if this seedling did not dig a hole with mulberry, it was possible to easily plant a seedling by sticking a bar-shaped burring bar into the soil, putting it into the soil, and stepping on it with a foot.

Test Example 9 (Cow Growth Promotion Test)
Test sample 2 (IT-P6), test sample 4 (PDP cloth) and control test sample (untreated non-woven fabric) were sewn together as necessary to form a 1 m × 1 m sheet. These sheets were attached with six strings to the back of three calves (weight 60 ± 1 kg) 2 months old. Three sheets were prepared for each test sample, replaced every three days, washed and reused. All calves were bulls, and the average body temperature before the test was 38.0 ± 0.5 ° C., but at the end of the test, the average body temperature was 39.0 ± 5 ° C. in sample 2, and in sample 4, The average body temperature was 38.5 ± 0.5 ° C. This difference in body temperature is considered to indicate a difference in immunity.

  After 6 months, the weight of the calf fitted with the control test sample averaged 205 kg, test sample 4 was 230 kg, and test sample 2 was 310 kg.

Test Example 10 (Red-head disease and rust disease occurrence prevention test in acupuncture)
IT-P6 before the bud emerges on the trunk of a 35-year-old cocoon (variety: berry A. One branch is called branch A and the other branch is called branch B) with the trunk branching into two from the root. A 0.1% by mass aqueous solution of IT-P6 was sprayed over the entire shaft connected to the fruit bunches of the branch A at the time of pollination. A vinyl sheet was hung on the side of the branch B that was not sprayed, and a weir was provided on the side of the sprayed branch A so as not to flow into the fruit bunch.

  As a result, no red star disease and rust disease occurred on the branch A on the sprayed side, and the tufts of cocoons grew large, and the total weight of the ten tufts was 8.9 kg. On the other hand, branch B which was not sprayed and covered with a vinyl sheet developed red star disease and rust disease and was poor in growth, and the total weight of 10 tresses was only 3.5 kg.

  As with animals, negative ions and positive ions improve living ability (immunity), making it difficult for bacteria to attack diseases and pests, activating sap (blood in animals) and improving tree power Conceivable.

Test Example 11 (Eradication test for Klebsiella pneumoniae)
The following test was carried out using a positive pressure controlled sterile room used by a patient (59-year-old male) who had been treated with an anticancer drug and had a white blood cell count of zero. The test was repeated three times and an average value was taken.

Test example 11A
An air purifier (Plasma Cluster 7000 type manufactured by Sharp Corporation) was placed in this positive pressure controlled sterile room aseptic room. When the change in the number of Klebsiella pneumoniae in the air in the positive pressure-controlled sterile room was examined, the number of bacteria, which was initially 22,000, became 20 or less after 3 hours. However, the bacteria attached to pillows and sheets could not be reduced to 20 or less unless it took 21 hours or longer.

Test example 11B
The ceiling, wall, floor, window, and bedding in the positive pressure aseptic room were all sprayed with a 0.1% by weight diluted solution of IT-P6 prepared in Example 2 and held overnight, and then positive pressure control was performed. As a result of examining changes in the number of Klebsiella pneumoniae in the air in the aseptic room, the number of Klebsiella pneumoniae, which was initially 22,000, became 20 or less in four hours, and bedding such as pillows and sheets were also available. The bacterial count became zero in 1 hour.

  In the plasma cluster, the ability to kill bacteria attached to walls and fabrics is extremely low. On the contrary, the bacteria attached to the coated part impregnated with the specific titania of the present invention are sterilized and proliferated at the same time. It is thought that nobody was gone.

Test Example 12 (Fuel Economy Improvement Test)
Toyota Motor ("Noah": displacement 2000 cc, nominal fuel consumption: 15 km / L) was run 500 km x 3 times, and the average fuel consumption was determined to be 14.7 km / L.

  Next, IT-P6 produced in Production Example 2 was impregnated with a diluted solution diluted with pure water to a concentration of 0.1% by mass and replaced with a dehydrated and dried air filter. When the fuel consumption was calculated, it was improved by about 4 km / L to 18.9 km / L.

  The redox potential generated by linking the moisture contained in the air sucked into the engine between titanium and phosphorus atoms strongly negatively ionizes the sucked moisture, improving the oxidation and combustion efficiency, resulting in gasoline This is considered to be efficiently decomposed.

Test Example 13 (Magnetic force generation test)
Four each of test sample 2 (IT-P6), test sample 4 (PDP cloth), and control test sample (untreated non-woven fabric) were stacked, and 10 iron nails having a length of 2 m were sown thereon. The stacked test samples were then tilted slowly until they were vertical, and the presence or absence of nail dropping was observed.

  As a result, the test sample 4 and the control test sample all dropped, but the test sample 2 did not fall at all.

Test Example 14 (Anti-inflammatory test: Rheumatoid Explosive Collagen Disease)
Test sample 2 was applied to the knee joint of a patient (female: 69 years old) who had been suffering from Rheumatoid Collagenosis for 30 years and had been given an anti-inflammatory agent (loxoprofen sodium) orally and percutaneously, and fixed with a supporter did. When this state was continued for 12 hours (administration of the anti-inflammatory agent was stopped), the pain and swelling subsided. After removing the test sample and leaving it for 3 days, the test sample 2 was affixed again for 6 hours a day, so that neither pain nor swelling occurred. Continuously, test sample 1 (PT6) and test sample 2 (IT-P6) were used alternately for 12 hours a day, and were washed and used alternately. As a result, pain was swollen even without using loxonin for one year. Didn't happen either. In addition, in subjects, the average body temperature before starting this test was 32.8 ± 0.2 ° C., but it became possible to maintain 36.5 ± 0.5 ° C. or more after 2 months. .

Test Example 15 (Hematoma disappearance test)
Test sample 4 was applied to the purple hematoma (about 5 cm × 10 cm) remaining in the left arm of a patient (female: 60 years old) one day after osteoarthritis treatment of the left arm fracture, but there was no change. Therefore, when test sample 2 was applied, the disappearance of the hematoma started around one month and disappeared completely after three months. It is considered that cell damage (swelling, just before the blood is peroxidized to purple in the purple color) was reduced with strong positive ions and regenerated like iPS cell therapy.

  After that, when the test sample 2 was continuously applied for 24 hours a day, the bone at the fracture site joined in about 4 months after the fracture (the average fracture completion period of 60-year-old women is said to be 7 to 8 months) . The recovery rate at this age was said to be 70% at the maximum after one year, but it recovered to 95% (arms straight up).

Test Example 16 (Dizziness disappearance test)
When dizziness occurs in a woman who is dizzy frequently (70 years old), test sample 1 (PT6), test sample 2 (IT-P6), and test sample 4 (PDP cross) are folded in four And wrapped in a turban. It is thought that the strong negative ions and positive ions activate the lymph nodes and the blood flow increases rapidly.

  As a result, it took about 3 hours for the test sample 4 to get dizzy, but the test sample 1 disappeared after 10 minutes and the test sample 2 disappeared after 1 minute.

Test Example 17 (Komurakaeri disappearance test)
For a male (73 years old) who frequently suffers from skin irritation, test sample 1 (PT6), test sample 2 (IT-P6), and test sample 4 (PDP cloth) are calves when he / she suffers I fixed it. This is considered to be due to the same mechanism as in Test Example 16.

  As a result, it took about 2 hours or more for the test sample 4 to relieve the muscle spasms, but the test sample 1 disappeared immediately after 3 minutes and the test sample 2 immediately.

Test Example 18 (Capillary hemangioma disappearance test)
The ankle portion of a commercially available cotton sock was dipped in a 0.1% by weight diluted solution of IT-P6 prepared in Example 2 and dried. Moreover, what sewed the test sample 4 on the same kind of cotton socks was used. This is considered to be due to the same mechanism as in Test Example 15.

  IT6 impregnated socks are worn on the left foot of three men (age: 65, 67, 70) and two women (age: 65, 68 years), and socks with test sample 4 sewn on the right foot ( 12 hours / day), the state of hematoma in the capillaries of both ankles was observed, and in all subjects, hematoma began to disappear from about 1 month at the ankle of the left foot wearing IT-P6 impregnated socks. The subjects disappeared in 3 to 6 months, but there was no change in the ankle of the right foot wearing the socks sewn with test sample 4. From this result, it is considered that arteriosclerosis of the capillaries that have deteriorated due to oxidation (aging) is reduced, regenerated and recovered, and blood flow is restored.

Test Example 19 (hay fever and atopic symptom improvement test)
A commercially available cotton mask (Cosmos drugstore product) was repeatedly immersed in a 0.1% by weight diluted solution of IT-P6 prepared in Example 2 and dried.

  This mask is used for 5 hay fever patients (20-year-old male, 22-year-old male, 28-year-old male, 30-year-old female, 40-year-old female) and 5 atopic patients (18-year-old male, 25-year-old male, 27-year-old male, 20-year-old female). , A 31-year-old woman) and observed the circumstances.

  As a result, 3 patients with hay fever and 1 atopic patient were completely cured in 1 week, and 1 patient with hay fever and 2 patients with atopy were completely cured in 2 weeks. 1 patient and 2 atopy patients) were completely cured.

  This is because in pollinosis and atopic patients, the internal immunity suddenly increases in response to pollen and the skin cells are congested / destroyed, resulting in kayumi and sneezing. Use the redox potential generating material of the present invention. This is thought to be due to the strong negative ion generated from the outside, and the internal immunity rising signal disappears, and the immunity is lowered by the steroid from the inside.

Test Example 20 (Comprehensive negative ion / positive ion activity confirmation test)
Undershirts and pants that were soaked and dried in a 0.1% by weight dilution of IT-P6 prepared in Example 2 for male patients (early 70 years old) who had received anticancer drug treatment after colorectal cancer resection surgery (any (100% cotton) was worn only during the day, the following symptoms were alleviated, improved or disappeared.

Revascularization:
The blood vessels that had been cured by the infusion of the anticancer drug regenerated after about 6 months.
Disappearance of benign tumors in the sinuses:
The benign tumor that had developed in the sinuses had disappeared after about 6 months.
Disappearance of drug allergic myositis:
In 2010, a patient (70-year-old male) who received 79 antibiotics and 29 antipyretic drugs due to nosocomial infection at the time of caecal surgery was immunized 2 months after discharge and became GOT / GTP 800 / GOT increased to 400 and decreased to 300/200 after administration of Minofit 45, but increased after discontinuation and was worn by the above patient who was unable to heal. / GTP is reduced to 25/15 of normal value in 10 days, and the value is maintained for 3 years.
Regeneration of pulmonary emphysema A 77-year-old man who is using an oxygen cylinder in pulmonary emphysema is testing with a mat mated with 8 pieces of gauze under the mask and impregnated with 0.3% IT-P6. The amount of oxygen used is being drastically reduced. Emphysema is a disease that cannot be cured unless it is an iPS universal cell, but the possibility of repair is born in this titania.

  Similar to Test Examples 15, 18, and 19, drug allergy symptoms are considered to be caused by a rapid rise in internal immunity due to a misidentification of internal immunity unique to allergy even though liver function is normal such as echo. This is probably because the strong external negative ions and positive ions generated by the redox potential generating material can suppress the immune rise caused by the internal.

Test Example 21 (elimination of headache)
When the male patient of Test Example 20 had a headache, the test sample 2 was wrapped around the head in a turban shape, and the pain was cured within 5 minutes. This is considered to be the same mechanism as in Test Examples 16 and 17.

Test Example 22 (pain relief of tonsillitis)
When the male patient of Test Example 20 developed tonsillitis, when the test sample 2 was wrapped around the neck, the pain was instantly cured. This is considered to be the same mechanism as in Test Examples 16 and 17.

Test Example 23 (elimination of tinnitus)
When the male patient of Test Example 20 developed tinnitus, tinnitus subsided within 1 hour when test sample 2 was wrapped around the head in a turban shape. This is considered to be the same mechanism as in Test Examples 16 and 17.

Test Example 24 (Drug allergic rhinitis disappearance test)
When the male patient of Test Example 20 was suffering from drug allergic rhinitis, wearing the test sample Test Example 20 caused the rhinitis to disappear in one month, and the swelling (Hanatake) began to shrink gradually. This is considered to be due to the same mechanism as in Test Examples 19 and 20.

Test Example 25 (Colon polyp disappearance test)
In the male of Test Example 20, a 3 mm polyp was found in the sigmoid colon in the first year after surgery for colorectal cancer, but the polyp disappeared completely after about 1 year by wearing the sample of Test Sample 20 did. This is considered to be due to the same mechanism as in Test Example 20.

Test Example 26 (senile gastric wall atrophy disappearance test)
As a result of conducting Test Examples 24 and 24, the chronic atrophic gastritis completely disappeared after one year. This is considered to be due to the same mechanism as in Test Examples 18 and 20.

Test Example 27 (senile skin tumor spot disappearance test)
About the male patient of the test example 20 who conducted the test of the test examples 20 to 25, in addition to this, the sock of the test example 15, the trousers, and the steteco impregnated with 0.1% by mass of IT-P6 were worn. One year later, the spots on the legs and legs were partially disappeared (70% = 70/100). This is considered to be due to the same mechanism as in Test Examples 18 and 20.

Test Example 28 (Preventing prostate enlargement)
Three male patients (61 years old, 65 years old, 69 years old) who have a PSA value of 8 or more due to prostatic hypertrophy wear UNIQLO cotton pants impregnated with 0.1% by mass of IT-P6 When measured after one month, the PSA values dropped to 3.5, 2.0 and 1.9, respectively, and maintained thereafter.

  The mechanism according to Test Examples 26 and 27 and the disease caused by the decrease in female hormones shown in Test Example 29, which will be described later, are caused by aging, that is, the disease caused by decreased immunity is caused by peroxide radicals as in tumors and cancers. Therefore, it is considered that cells are regenerated (rejuvenated) by giving strong positive ions from the outside and reducing them.

Test Example 29 (improving irregular physiology)
Underwear (pants, slips) impregnated with 0.1% by mass of IT-P6 in three women (50 years old, 55 years old, 49 years old) with irregular menstrual periods (vertigo, heat, poor appetite, insomnia, irregular menstrual periods) As a result of checking the symptoms every 10 days, all were controlled to a normal state in one month. This is considered to be due to the same mechanism as in Test Example 28.

Test Example 30 (Bubble herpes treatment)
A male patient (34 years old) who has been treated with acyclovir, a bacterial herpes agent, twice a month has developed blistering herpes in the yang area for 10 years. Uniqlo cotton pants with 0.1 mass of IT-P6 When four pieces were made to be impregnated with 4% and worn, they were worn every day for 6 months while washing, and no herpes developed during that time. This is considered to be due to the same mechanism as in Test Examples 14, 19, and 20. The mechanism of the onset is similar to shingles and labial herpes, but when the immune system is weakened, the bacteria that inhabit the body start to activate, but until now internal immunity is difficult to cure, and a bactericidal agent is administered. I had to apply it to the affected area.

Test Example 31 (Healing of tendonitis)
For 10 years, a male patient (40 years old) who has developed tendonitis due to handwritten documents, treated gloves with IT-P6 impregnated in 0.1% by mass of gloves with fingertips (manufactured by Uniqlo Co., Ltd.) When I put on, the pain resolved on the first day. Repeated wearing every other week for 1 day showed no pain after 6 months.

  For this reason, if muscles are used harshly without normal recovery due to muscle fatigue, normal cells become inflamed and swollen by peroxide radicals, become hardened (aged), and are stubborn that cannot be cured by drugs, exercise, or massage. It can be seen that such stubborn inflammation could be cured with strong negative ions or positive ions of external immunity.

Test Example 32 (treatment of colorectal hematoma)
Underpants and undershirts impregnated with 0.5% IT-P6 for 90-year-old women and 70-year-old men who were hospitalized for colorectal hematoma, treated with steroids but were not cured, and were sentenced to life expectancy As a result of wearing pajamas and refusing steroids, men stopped bleeding after 3 days and women were discharged after 1 week. By giving external immunity strongly, internal immunity is suppressed, and it is considered as an example of self-healing. Even if steroids and hemostatic agents are used in combination with colonic hematomas, bleeding, swelling, and pus increase when immunity is reduced with steroids, and even if hemostasis is stopped, swelling and pus cannot be repaired. It has been found that there is only an external immunization method that uses a strong redox potential to repair swelling, bleeding, and dead cell pus.

Test Example 33 (Cold healing)
A sample of IT-P6 produced in Example 2 was set on the inside of the mask so as to cover the nose and lips of a 74-year-old man who had a nasal cold and a runny nose and had a slight fever of 37 ° C. Ceased after 30 minutes, and body temperature dropped to 36 ° C. ± 0.5 ° C. after 1 hour. It is thought that the virus was sterilized by strong negative ions, and inflammation was cured by external immunity by strong positive ions.

Test Example 34 (cooling and heating)
A short-sleeved male undergarment (manufactured by Uniqlo Co., Ltd.) was impregnated with an aqueous solution of IT-P6 to a concentration of 0.1% by mass / 100 g to produce the redox potential generating material (treated undergarment) of the present invention. A test was conducted.

(Cooling action)
In a room with a room temperature of 38 ± 0.5 ° C in mid-August, a 74-year-old man (body temperature: 36.5 ° C) is put on untreated underwear and laid on his back on a cotton bedcloth between the bedcloth and underwear. The temperature change was measured with a thermometer equipped with a needle sensor. As a result, the temperature reached 37.0 ° C. after 10 minutes, and the average temperature during the subsequent 10 to 30 minutes was 37.5 ° C.

  On the same day, the same test was conducted with the treatment underwear worn, and after 10 minutes, the temperature fell below 36.5 ° C, and the average temperature for the next 10-30 minutes was 35.5 ° C. there were.

(Warming effect)
In a room with a room temperature of 25 ± 0.5 ° C in mid-November, a 74-year-old man (body temperature: 36.5 ° C) was put on untreated underwear, laid on his back on a cotton mat, and another blanket was hung The temperature change between the mattress and the undergarment was measured with a thermometer equipped with a needle sensor. As a result, the average temperature for 10 to 30 minutes after the start of the test was 36.0 ° C.

  When the same test was conducted on the same day with the treatment underwear worn, the average temperature for 10 to 30 minutes after the start of the test was 37.2 ° C.

  From this test result, in the summer, negative ions and positive ions generated from the redox potential generating material of the present invention evaporate a large amount of moisture in sweat and have a cooling effect due to the heat of evaporation, and in winter, the redox potential of the present invention It is inferred that the negative ions and positive ions generated from the generating material react with a small amount of moisture on the body surface to produce a heat generation effect. This titania, depending on the grade, does not allow water, water permeability, and moisture retention of cloth, carpets, materials, bedding, clothing, and medical materials. It will be a revolution that can create a deodorant effect and a living environment that restores immune system diseases.

Test Example 35 (Recurrent lymphoma treatment)
A CT scan revealed that lymphoma had recurred in two places, the nasal cavity and the abdomen, in a man (74 years old) who became nasal lymphoma and remissioned with anticancer drugs 3 years ago. The rainbow sheet (PDP) was used immediately, but there was no effect.

  The male was then worn with an eight-layer gauze mask impregnated with the following redox potential generating materials 1 and 2 of the present invention alternately on the nose for the entire day (24 hours), and CT and PET were examined one month later. The nasal lymphoma disappeared. The nasal cavity was benign and the abdomen was determined to be malignant. When CT was performed using a Rainbow PDP dome for 3 weeks, it stopped because it became swollen. The rainbow magazine wrote that there were many cases of sarcoma cancer that were completely cured, ameliorated, or prolonged life, but as a result of inquiring about lymphoma, `` Please consult with a doctor about lymphoma and use it. '' Got an answer. Thereafter, antibody two-step R-TEO (R is the meaning of antibody Rituxan, TEO is an acronym for anticancer agent) and antibody two-step R-GDP (R is antibody Rituxan, GDP is anticancer agent) Initials) Entered anticancer drug treatment, put underwear with 0.3% impregnated underpants and undershirt with a thickness of 2 to 2mm in the abdomen. Although it was greatly reduced, the impregnation concentration was further increased to 1.5%, and it became rather large in CT after 1 month (same as PDP dome). Therefore, when 4 courses of treatment instead of the anticancer drug DEVIC method (ordinary prescription without using an antibody) were used without treatment with the titania of the present invention, the swelling was reduced by 80%. By switching to underwear with 0.3% impregnation using the hints of the literature (Rainbow PDP Report 2013, page 6, "International Journal of nano" Dr. Ghosn "Pulmonary tolerance in human myeloid leukemia") After 1 week before therapy, CT was taken 1 month after the end of 6 courses.

  This anticancer drug treatment method is called the DEVIC method, and it causes acute pneumonia and cystitis as a side effect. As soon as there is an abnormality in the lungs and trachea and wrinkles occur, a mask impregnated with 0.3% for 30 minutes I was able to prevent pneumonia after 6 months of treatment. The other three (65-year-old male, 70-year-old male, 72-year-old male) who were treated in the same way developed pneumonia, two became lung infiltrates and became oxygen masking diseases.

  One month after remission, CT was found, and a new lymphoma was found around the left kidney. As a result of investigating the cause, Goza was in midsummer (thickness 10 mm with a cloth cushion on the back) and was not treated. Because this goza was purchased at home wide (made in China) using only underwear and towels, the smell was bad, and PT6 2% liquid was impregnated with 2% of the weight of goza. I remembered (deodorization treatment). It was considered that the same action as that of rainboardome occurred when 1.5% of IT-P6 was used due to strong redox. After that, after examination and diagnosis with a group of doctors from CT images, blood data (cancer markers, lymphocyte values, etc.), side effect data, and soft part shadow images in the paranasal sinuses, they were used as an adjuvant for anticancer agents. Because of the synergistic effect with titania, which was too effective in this experiment, inflammatory lesions occurred around the left kidney because of inflammation of the basophils. Disappeared and remissioned with 2 cools. In parallel, sinus inflammation and soft swelling was also caused by the regular use of gauze mask impregnated with 0.6% or more of IT-P6, so it was considered a basal tumor (Hanatake). Remission has been found to lead to new treatments for lymphoid cancers and tumors. In conclusion, the titania of the present invention having a strong redox potential repairs peroxidized cells with a reduction potential, but if used excessively and at a high concentration, it becomes an inflammation / tumor of basic lymph, resulting in anti-cancer. It was found that when used at a high concentration in combination with the agent, the cancer cells that are destroyed are repaired / reduced, so that soft inflammatory tumors are increased around the cancer cells. However, in addition to treating lymph cancer, it can be erased with anti-cancer drugs because it causes inflammation, swelling, and tumor caused by basic lymphocytes even after long-term use to cure other diseases. In the human experiment, it is effective that the stage method is effective, and if underwear of 0.3% or less is used before administration of the anticancer drug, it will awaken resistant cancer cells and be effective in the treatment of malignant lymphoma. Proven.

  By the way, the reason why this lymphoma recurred was to suppress drug allergy (as mentioned above) and that the Rainbow PDP dome was effective in prolonging the survival of terminal cancers. I have been using P6 0.1% impregnated for 2 years, but in order to further increase the concentration and thickness (weight), 2% PT6 in 8mm thick band (specific gravity, density is 3 times that of non-woven fabric) And IT-P6 0.3% impregnated wound and used for 24 hours, it is considered that the recurrence from the esophagus to the pancreas, right kidney and liver lymph nodes, similar to the activity of Goza.

  People who suffer from blood cancer (lymphoma, leukemia) should be strictly followed in consultation with a doctor to cure other diseases shown in the examples.

  The concentration used is 0.1% or less for PT6 (hydrochloric acid type) and 0.01% or less for IT-P6 (hydrochloric acid type), and is set as the concentration used for underwear of 1 mm to 2 mm thickness. When used for 10mm blankets, etc., it is safe to use 0.01% or less for PT6 and 0.001% or less for IT-P6. It is necessary to tie-up with a doctor while examining closely.

  Furthermore, inflammation (trial 11/14/22/24/33/31), deodorant antibacterial (2/3/4), benign tumor (15/18/20/25/26/27/28/32), atopy Rather than using it every time for allergies (19/30) and others (16/17/21/23/29), for example, when using it for anti-inflammation, convulsions, etc., we want to adhere strictly to removing it as soon as it disappears.

  Since this titania shows activity equal to or better than that of the electric type, as all electric therapy devices show, “too high the concentration” “increases the thickness and weight of the fabric” “continues to use for a long time” Since it is not known what kind of disease it will cause, it should be strictly observed that it starts with "low concentration" and "short time" and consults with a doctor.

Test Example 36
Polyester non-woven fabric (manufactured by Daiso Sangyo Co., Ltd.), 8mm thickness cut into A4 size, immersed in 0.1% solution of IT-P6, put on dehydrator, twice the weight of dry matter Was dried for two days on a sun, and a sample A was produced. As a comparative example, Rainbow BDP sheet A4 size sample B having a thickness of 8 mm was used. Float 4 test samples in a home bath, select 5 patients each with back pain, shoulder pain, and joint pain, divide into samples A and B, and bath for 30 minutes once a week. As a result of investigating the time and frequency, the following results were obtained.

In the sample A group, one person disappeared in 10 minutes after taking a bath, and two persons disappeared in two times.
In sample B, 1 person disappeared after 4 times and 1 person disappeared after 5 times.
When the test sample was drained and used repeatedly, sample B had an unpleasant odor after 3 days, but sample A did not have a strange odor even after being used 10 times. Even after repeated use, the anti-inflammatory activity did not drop for half a year. Based on these results, we were able to create a new bathing system that can permanently maintain anti-inflammatory activity by positive ions and bactericidal antibacterial activity by negative ions due to a strong oxidation (negative ion) reduction (positive ion) potential. Become.

Test Example 37 (Reduced water test)
A polyester nonwoven fabric made of art chemical with a thickness of 30 mm x width 80 mm x height 100 mm impregnated with 1% IT-P6 per weight and dried at 100 ° C for 5 hours, stainless steel 0.5 mm x width 80 mm x on both sides Sandwiched on a perforated plate with a hole diameter of 1 mmφ and a pitch of 1.5 mm in the part of the plate with a height of 100 mm and an upper part of 30 mm, this was set in a case of an acrylic plate with a width of 80 mm × length of 100 mm, Tap water is injected from the center of the lower part of the case, nozzles for taking out positive ion water and negative ion water are provided on the upper left and right sides, and a terminal for connecting the battery +/- is attached to the upper part of the stainless punching plate. A single battery (National) was connected to this. As a result of continuing to flow Nobeoka city tap water at 6 L / hour with a flow meter, the water exiting from the + pole nozzle had a pH of 6 ± 0.2, and the water exiting from the minus pole nozzle was a pH of 8 ± 0.2. It is assumed that the -potential moves to the + pole and the + potential moves to the minus pole. That is, the water molecules contained in the nonwoven fabric react with the potentials of + and −, and a large amount of potential moves to water, which moves toward each counter electrode and is partially consumed by the counter electrode. Mostly, it passes through a hole in a 1 mm punching plate and moves to each discharge, and −ion water and + ion water are considered to be produced smoothly. The total time consumed for a single battery was 30 days. The commercial product uses a power supply of 100 V, and when this titania is used compared to its power consumption, it is considered that the operation with a slight power is due to the activity of the redox potential of titania. Compared with the power efficiency of light emitting diodes (LEDs) of 50-60%, this method is considered to be able to create an efficiency close to 100%. Without using + and-battery electrodes, using a metal or a synthetic polymer with-and + potentials generates power at 100% efficiency without giving any energy or consuming energy. The system can be created and the purpose that the light emitting diode (LED) is exploring will be completed.

Test Example 38 (charging power generation test)
The result of measuring the time until charging was completed by connecting a portable charger to the electrode of Test Example 37 after making a full call after charging was completed using a mobile phone, docomo, F-07A The average value repeated three times was 8.7 minutes. As a comparative example, the average value of the charging time which was charged with household electricity and repeated three times was 7.5 minutes. Therefore, the power generation function could be confirmed.

Claims (8)

In the absence of water and in the presence or absence of a mineral acid, chain transfer polymerization is initiated by adding phosphoric acid or an alkyl phosphate ester to an alcoholic solution of alkoxytitanic acid, and the polymerization product solution is glued. An oxidation-reduction potential generating material coated or impregnated with a linear alkoxytitanic acid / phosphoric acid polymer solution obtained by stopping polymerization before becoming cloudy. 2. The oxidation-reduction potential generating material according to claim 1, wherein the timing for stopping the polymerization is when the viscosity of the polymerization product reaches 1.0 × 10 ⁴ cP. The redox potential generating material according to claim 1 or 2, wherein the alkoxytitanic acid is tetramethoxytitanic acid, tetraethoxytitanic acid, tetrabutoxytitanic acid or tetraisopropoxytitanic acid. The redox potential generating material according to any one of claims 1 to 3, wherein the alcohol solution is at least one solution selected from the group consisting of methanol, ethanol, butanol and isopropanol. The redox potential generating material according to any one of claims 1 to 4, wherein the alkyl phosphate ester is trimethyl phosphate, triethyl phosphate, tributyl phosphate or triisopropyl phosphate. After the solution of the linear alkoxytitanic acid / phosphoric acid polymer to be coated or impregnated is stopped, the polymer concentration immediately becomes 0.0002 using water, an organic solvent, or a mixed solvent of water and an organic solvent. The oxidation-reduction potential generating material according to any one of claims 1 to 5, wherein the oxidation-reduction potential generating material is a diluted solution diluted to ˜2% by mass. For deodorization, for avoiding organisms, for maintaining freshness, for promoting growth in the agricultural field, for sterilization, for improving the fuel economy of gasoline vehicles, for cooling and heating, for producing redox water, for power generation and charging (increasing power efficiency The redox potential generating material according to any one of claims 1 to 6, which is used for creation of a new power generation system and the like. For normalization of GOT / GTP levels due to drug allergic myositis, anti-inflammatory analgesic, hematoma disappearance, dizziness disappearance, komurakaeri disappearance, capillary angioma disappearance, hay fever improvement, atopy symptoms improvement, tinnitus For improvement, drug allergic rhinitis disappearance, nasal rash (benign tumor) disappearance, collagenous rheumatism treatment, colon polyp disappearance, senile gastric wall atrophy disappearance, senile skin tumor spot disappearance, tendonitis treatment, Blister and herpes treatment, menstrual irregularity improvement, prevention of prostatic hypertrophy, tonsillitis pain relief, headache relief, disappearance of sinus benign tumor, revascularization, emphysema repair, thyroid / breast / prostate cancer improvement effect or The oxidation-reduction potential generating material according to any one of claims 1 to 6, which is used as a lymphoma disappearance assistant (used together for one week before administration of an anticancer agent) or the like.