JP2000300681A - Minus ion generation accessory - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an accessory which is good in style because of the existence as an accessory, moves freely to induce the static electricity by friction in the case of contact with the skin, is capable of supplying ions to the body surface by a semiconductor effect and is capable of effectively generating ions by using the UV rays of sunshine and improving the therapeutic effect as well. SOLUTION: A chain 12 made of noble metals is formed by suitably arraying, side by side, noble metal pieces 10 formed with outer peripheral surfaces by lining up metals 14 having a plus potential and titanium as metal having a minus potential or their respective oxides, nitrides or carbides 13 and noble metal pieces 10 formed by ion plating the noble metals with the titanium or their respective oxides, nitrides, carbides, for example, titanium dioxide (TiO2) 13 or further coating the same with silicon resin films and linking these pieces together with a thread 11.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a negative ion-generating accessory which can be used as a jewelry item such as a necklace or a bracelet to promote health maintenance and activation.

[0002]

2. Description of the Related Art As health-related accessories such as improving blood circulation and correcting shoulder stiffness, there are some which emit magnetism as a weak energy or far infrared rays.
Japanese Patent Application Laid-Open No. 2-295830 discloses a bioion-adjusting adhesive body in which a metal having a positive potential and a metal having a negative potential are provided on an adhesive layer of an adhesive material to form an adhesive body.

[0003] The metal structure having an ion generating function enables an effective ion generation. The effect of negative ions and the generation of a local minute current cause the electrical stimulation applied to the diameter hole to the neuron. To the autonomic nervous system, and to promote the biological function of the sympathetic and parasympathetic nerves, for example, to increase the blood flow by expanding the capillaries of the affected part to promote the recovery of the function of the living body.

[0004]

In the case of such an adhesive, it is fixed to the skin, and it is difficult to obtain an effective potential difference between a positive potential and a negative potential, and the ion generating function is good. is not. In addition, the effect is only exerted to a limited extent at the place where the patch is pasted, and if an attempt is made to expand the treatment area, a large patch is required, which hinders free movement of the body, The appearance is also bad.

An object of the present invention is to solve the above-mentioned disadvantages of the prior art and to wear it as an accessory so that the appearance is good. When it comes into contact with the skin, it freely moves to generate static electricity due to friction. It is an object of the present invention to provide a negative ion generating accessory which can supply ions to a body surface by a semiconductor action, can generate ions more effectively by using ultraviolet rays of sunlight, and has a high therapeutic effect.

[0006] To achieve the above object, the present invention provides a first method.
A precious metal chain formed by arranging a precious metal piece in which an outer peripheral surface is formed by arranging a metal having a positive potential and titanium as a metal having a negative potential or their respective oxides, nitrides, and carbides with a string, Second, titanium or their respective oxides are added to the noble metal,
Noble metal pieces were ion-plated with nitride and carbide, and further coated with a silicone resin film, and tied with beads to form a noble metal chain. Third, a metal having a positive potential and a negative Noble metal pieces having an outer peripheral surface formed by arranging titanium or their respective oxides, nitrides, and carbides as a metal having a potential, and titanium or their respective oxides on the noble metal,
Noble metal chains were formed by ion-plating nitrides and carbides, and further arranging precious metal pieces coated with a silicone resin coating as appropriate and connecting them with beads to form a noble metal chain. Fourth, the threads formed precious metal pieces. The gist of the present invention is that it is made of a different kind of noble metal from the noble metal to be made.

[0007] About 60 to 70% of the human body is in the body as a body fluid (water), and an electrolyte and a non-electrolyte are dissolved in the body fluid. There are positive ions and negative ions in the electrolyte, and these ions are present with a balance. When the balance is lost, various illnesses and diseases are easily caused.

[0008] It is said that the difference in the distribution of ions surrounding cells is closely related to nerve cells, and is said to greatly affect the recovery of the health of the whole body and the deterioration of diseases.
These positive and negative ions exist through the cell membrane, and the permeability of the membrane differs depending on the magnitude of the positive and negative bipolar electric potentials. Ions move organically throughout the body based on certain laws, which are greatly affected by the intensity and distribution of ion electrons in the internal and external environments of the body.

According to the first aspect of the present invention, a noble metal piece formed by connecting beads with a string to form a noble metal chain forms an outer peripheral surface by arranging a metal having a positive potential and a metal having a negative potential. The potential difference generates negative ions from the anode side, which irritates the skin. That is, one or two of Au, Pt, and Ag are used as a typical metal having a positive potential, and titanium, which is a typical metal having a negative potential, or an oxide or nitride thereof is used. By combining with a substance or carbide, amplification of negative ions can be promoted. The precious metal chain is worn as a precious metal accessory such as a necklace, bracelet, ring, etc., which is always in contact with the skin and wrapped in negative ions.

In addition, the precious metal pieces are connected by a thread and can rotate freely. In a necklace, a bracelet, or the like, the precious metal chain itself moves according to the movement of the body. The rolling rotation of the pieces constituting such a chain and the movement of the whole chain act synergistically to generate static electricity due to friction with the skin, which amplifies the generation of negative ions from the anode side due to the potential difference. And make it even more effective.

In general, a fatigue state causes an increase in lactic acid value, an increase in positive ions is observed, and the ion balance in the body is lost. According to the present invention, the imbalance of the ion balance is forcibly adjusted from the outside by giving the stimulation of the negative ions. (Improvement of abnormal body surface potential by negative potential effect)

There is also an effect of removing pain by improving blood flow fluctuation (1 / f).

Further, titanium or their respective oxides,
When (2) titanium oxide (TiO ₂ ) is used among nitrides and carbides, generation of negative ions due to the photocatalytic reaction effect can be expected.

(2) The photocatalytic reaction by titanium oxide (TiO ₂ ) is as follows. When light is absorbed by titanium oxide, two carriers, electrons (e ⁻ ) and holes (h ⁺ ), are formed. In a general substance, both recombine immediately. Each of the photocatalysts will survive for a while, leading to the generation of negative ions.

According to the second aspect of the present invention, generation of negative ions is promoted by a semiconductor action. Precious metal pieces are precious metal with titanium or their respective oxides,
Ion-plated nitrides and carbides, and further coated them with a silicon resin coating, combine titanium, which is a metal with a negative potential, or their respective oxides, nitrides, and carbides with a silicon resin coating In this case, as shown in FIG.
-The semiconductor effect is exhibited as a type semiconductor thin film.

FIG. 5 shows the normal skin potential, and FIG. 6 shows the pathological skin potential. In the figure, 1 is a nerve, 2 is a stratum corneum, 3 is an epidermis, 4 is a basement membrane, and 5 is a dermis.

When a precious metal piece exhibiting a semiconductor effect as the P-type semiconductor thin film is brought into contact with a pathological skin, as shown in FIG. 7, the skin comes into contact with a metal having a negative potential. Is removed, and only a negative potential flows.

Similar to the operation of the first aspect, by applying a negative ion stimulus, the ion balance is forcibly adjusted from the outside. (Improvement of abnormal body surface potential by negative potential effect) In addition, there is also an analgesic effect by improvement of blood flow fluctuation (1 / f).

Moreover, as in the operation of the first aspect, the precious metal pieces are connected by a thread and can rotate freely. In a necklace, a bracelet, or the like, the precious metal chain itself moves according to the movement of the body. The rolling rotation of the pieces constituting such a chain and the movement of the whole chain act synergistically to generate static electricity due to friction with the skin, which amplifies the generation of negative ions from the anode side due to the potential difference. And make it even more effective.

Further, coating with a silicon resin film has an effect of preventing metal allergy and the like.

According to the third aspect of the present invention, the noble metal piece having the function of the first aspect and the noble metal piece having the action of the second aspect are combined, and the negative ions can be effectively formed by both the functions. Can be encouraged.

According to the fourth aspect of the present invention, in addition to the above-described operation, the yarn is made of a noble metal different from the noble metal forming the noble metal piece, so that the yarn is formed between the two and the yarn. A potential difference is also generated between the noble metal and titanium or their respective oxides, nitrides, and carbides, and the generation of negative ions from the anode side due to the potential difference is amplified.

[0023]

Embodiments of the present invention will be described below in detail with reference to the drawings. FIG. 1 is a partial front view showing one embodiment of the negative ion generating accessory of the present invention, FIG. 2 is a front view of the entire same as above, FIG. 3 is a front view of a precious metal piece, and the accessory is a necklace or a bracelet. .

In the figure, reference numeral 10 denotes a noble metal piece, which is tied to a rosary with a thread 11 to form a chain 12. This noble metal piece 10 has a surface of a metal 14 having a positive potential and a metal having a negative potential. An outer peripheral surface was formed by arranging the surfaces of titanium dioxide (TiO ₂ ) 13 which is an oxide of Ti. The metal 14 having a positive potential is selected from one or two of Au, Pt, Ag or alloys thereof.

The production of the precious metal piece 10 is performed according to the following steps. For example, a hollow cylindrical body 20 is formed of a gold (Au) alloy as shown in FIG. 8, and this is coated with titanium dioxide (TiO ₂ ) 13 by ion plating. Ion plating evaporates a substance to be plated in a plasma under reduced pressure, ionizes a part of the substance, accelerates it by applying an electric field to it, deposits it on an object to be plated with a large energy, and adheres to the substrate. This is a technique for improving According to this ion plating, a compound that cannot be formed by wet plating is produced, the adhesion between the base metal and the coating is good, the processing temperature is low, the dimensional accuracy of the base material is not impaired, and there is no harmful substance, so there is no pollution. There is a feature that there is.

As described above, the entire surface (both the inner and outer surfaces) is covered with the coating layer of titanium dioxide (TiO ₂ ) 13 by ion plating. [FIG. 9 (a)] Next, as shown in FIG. 9 (b), the coating layer of titanium dioxide 13 is removed by polishing with a diamond bite. In this removed portion, a gold (Au) alloy surface, which is a precious metal material, is exposed. This exposed portion is a portion of the metal 14 having a positive potential.

A lid 16 made of a gold (Au) alloy is fitted to the open end face by caulking to form a closed hollow body. The lid 16 is also a portion of the metal 14 having a positive potential.
The cover 16 is provided with a hole in the center thereof through which the thread 11 passes.

The precious metal piece 10 having the outer peripheral surface formed by arranging the metal 14 having a positive potential and the titanium dioxide 13 as the metal having the negative potential is obtained as described above. The small pieces 17 made of no gold (Au) alloy are alternately arranged with the pieces 10
And connect them in a rosary to form a chain 12. The thread 11 is made of a noble metal, for example, a platinum (Pt) alloy. Chain 12
A clasp 18 is provided at the end of the.

FIG. 10 shows a schematic diagram of the noble metal piece 10 thus formed.

The standard electrode potential of a metal includes a metal having a positive potential and a metal having a negative potential, and the electrochemical series of these metals is known as the galvanic series. The genetic sequence is known as the galvanic sequence. As a metal having a low potential from a metal having a high potential, TiO
^{_{2 / TiO 2 2+ + 2.18V,}} Au / Au 1+ +1.7
V, Au / Au ³⁺ +1.498 V, Pt / Pt ²⁺ +1.
2 V, Pd / Pd ²⁺ +0.987 V, Rh / Rh ³⁺ +
0.8 V, Ag / Ag ¹⁺ +0.799 V, Hg / Hg ¹⁺
_{+ 0.789V, MoO 2 / MoO 2} 2- + 0.66V,
Cu / Cu ²⁺ +0.377 V, Ti ³⁺ / TiO ²⁺ +0.
1 V, Fe / Fe ¹⁺ -0.036 V, WO ₃ / W-0.
09V, Mo / Mo1 ⁺ -0.2V, Ni / Ni1 ⁺ -0.
^{25V, Ga / Ga 1+ -0.45V,} TiO 2 / Ti-
0.85 V, W / WO ₄ ^2- -1.05 V, Zr / Zr ⁴⁺
-1.53V, Ti / Ti2 ⁺ -1.628V, Al / A
There is l1 ⁺ -1.662V.

The accessory of the present invention is practically Au, Pt, and A, excluding metals that show a strong sensitizing reaction and metals that are toxic to living organisms, because they come into direct contact with the body.
g and Ti are preferred.

As a typical metal having a positive potential,
Amplification of negative ions by using one of Au, Pt, and Ag in combination with Ti, which is a typical metal having a negative potential, or at least one of oxides, nitrides, and carbides thereof. It can encourage outbreaks.

As a second embodiment of the present invention, the outer peripheral surface of the precious metal piece 10 was further coated with a silicon (Si) resin film 19. In this case, the silicon resin is deposited by plasma.

In the second embodiment, the generation of negative ions is promoted by the action of a semiconductor, and titanium dioxide 13 which is a metal having a negative potential and silicon resin film 19 are combined with silicon resin film 19 to form P- The semiconductor effect is exerted as a thin semiconductor film. In this case, the presence of the metal 14 having a positive potential need not contribute to the generation of negative ions.

Further, as a third embodiment, the noble metal piece 10 of the first embodiment and the noble metal piece 10 coated with the silicone resin film 19 of the second embodiment are arranged side by side and connected by beads 11 to form a chain 12. It may be formed. Arrange one by one for one
Place every other or every few.

In the above-described embodiment, the example in which the precious metal piece 10 and the small piece 17 including the lid 16 are made of a gold alloy has been described. However, in another embodiment, the precious metal piece 10 and the small piece 17 are made of platinum (P
t) It can also be made of another noble metal alloy such as an alloy.

When made of a platinum (Pt) alloy, the yarn 11 is made of a gold alloy.

In place of the titanium dioxide 13, another titanium compound such as titanium (Ti) or titanium carbide (TiC) or titanium nitride (TiN) may be deposited by ion plating.

In the case of titanium dioxide 13, a precious metal piece
10 is black or blue, but titanium (Ti)
Etc. can be white or any other color.

As still another embodiment, a precious metal piece
Instead of 10, as shown in FIG. 11, it is also possible to use a titanium dioxide 13 core coated with a silicon resin film 19.

[0041]

As described above, the negative ion generating accessory of the present invention has a good appearance to be worn because it exists as an accessory, and furthermore, when it comes into contact with the skin, it freely moves to cause friction. Ions can be generated more effectively by inducing static electricity, and the therapeutic effect is high.

The negative ion effect of the accessory of the present invention is effective for neutralizing and purifying oxidization in the body, relaxing and recovering from fatigue, promoting health and preventing disease.

[Brief description of the drawings]

FIG. 1 shows a negative ion generating accessory 1 of the present invention.
It is a partial front view showing an embodiment.

FIG. 2 shows one of the negative ion generating accessories of the present invention.
FIG. 1 is an overall front view showing an embodiment.

FIG. 3 is a front view of a precious metal piece of the negative ion generating accessory of the present invention.

FIG. 4 is an explanatory view of a negative ion generating accessory of the present invention as a semiconductor.

FIG. 5 is an explanatory diagram showing a normal skin potential.

FIG. 6 is an explanatory diagram showing a skin potential in a pathological state.

FIG. 7 is an explanatory diagram of a semiconductor effect of the accessory for generating negative ions according to the present invention.

FIG. 8 is a perspective view of a hollow cylindrical body constituting a precious metal piece of the negative ion generating accessory of the present invention.

FIG. 9 is an explanatory view showing a process of manufacturing a precious metal piece of the negative ion generating accessory of the present invention.

FIG. 10 is an explanatory view showing the operation of a precious metal piece of the accessory for generating negative ions according to the present invention.

FIG. 11 is an explanatory view showing the operation of another example of the noble metal piece of the accessory for generating negative ions according to the present invention.

[Explanation of symbols]

DESCRIPTION OF SYMBOLS 1 ... Nerve 2 ... Surface stratum corneum 3 ... Epidermis 4 ... Basement membrane 5 ... Dermis 10 ... Precious metal piece 11 ... Thread 12 ... Chain 13 ... Titanium dioxide 14 ... Metal with positive potential 16 ... Lid 17 ... Precious metal Small piece 18… clasp 19… silicone resin coating 20… hollow cylinder

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[Procedure amendment]

[Submission date] January 28, 2000 (2000.1.2
8)

[Procedure amendment 1]

[Document name to be amended] Statement

[Correction target item name] Full text

[Correction method] Change

[Correction contents]

[Document Name] Statement

[Title of the Invention] Negative ion generating accessories

[Claims]

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a negative ion-generating accessory which can be used as a jewelry item such as a necklace or a bracelet to promote health maintenance and activation.

[0002]

2. Description of the Related Art As health-related accessories such as improving blood circulation and correcting shoulder stiffness, there are some which emit magnetism as a weak energy or far infrared rays.
Japanese Patent Application Laid-Open No. 2-295830 discloses a bioion-adjusting adhesive body in which a metal having a positive potential and a metal having a negative potential are provided on an adhesive layer of an adhesive material to form an adhesive body.

[0003] The metal structure having an ion generating function enables an effective ion generation. The effect of negative ions and the generation of a local minute current cause the electrical stimulation applied to the diameter hole to the neuron. To the autonomic nervous system, and to promote the biological function of the sympathetic and parasympathetic nerves, for example, to increase the blood flow by expanding the capillaries of the affected part to promote the recovery of the function of the living body.

[0004]

In the case of such an adhesive, it is fixed to the skin, and it is difficult to obtain an effective potential difference between a positive potential and a negative potential, and the ion generating function is good. is not. In addition, the effect is only exerted to a limited extent at the place where the patch is pasted, and if an attempt is made to expand the treatment area, a large patch is required, which hinders free movement of the body, The appearance is also bad.

An object of the present invention is to solve the above-mentioned disadvantages of the prior art and to wear it as an accessory so that the appearance is good. When it comes into contact with the skin, it freely moves to generate static electricity due to friction. It is an object of the present invention to provide a negative ion generating accessory which can supply ions to a body surface by a semiconductor action, can generate ions more effectively by using ultraviolet rays of sunlight, and has a high therapeutic effect.

[0006] To achieve the above object, the present invention provides a first method.
A precious metal piece in which a metal having a positive potential and titanium as a metal having a negative potential or their respective oxides, nitrides, and carbides are arranged to form an outer peripheral surface, and further coated with a silicon resin film. Secondly, the noble metal chain is formed by arranging the noble metals with a string and forming a noble metal chain. Second, the yarn is made of a noble metal different from the noble metal forming the noble metal piece.

[0007] About 60 to 70% of the human body is in the body as a body fluid (water), and an electrolyte and a non-electrolyte are dissolved in the body fluid. There are positive ions and negative ions in the electrolyte, and these ions are present with a balance. When the balance is lost, various illnesses and diseases are easily caused.

[0008] It is said that the difference in the distribution of ions surrounding cells is closely related to nerve cells, and is said to greatly affect the recovery of the health of the whole body and the deterioration of diseases.
These positive and negative ions exist through the cell membrane, and the permeability of the membrane differs depending on the magnitude of the positive and negative bipolar electric potentials. Ions move organically throughout the body based on certain laws, which are greatly affected by the intensity and distribution of ion electrons in the internal and external environments of the body.

According to the first aspect of the present invention, a noble metal piece formed by connecting beads with a string to form a noble metal chain forms an outer peripheral surface by arranging a metal having a positive potential and a metal having a negative potential. The potential difference generates negative ions from the anode side, which irritates the skin. That is, one or two of Au, Pt, and Ag are used as a typical metal having a positive potential, and titanium, which is a typical metal having a negative potential, or an oxide or nitride thereof is used. By combining with a substance or carbide, amplification of negative ions can be promoted. The precious metal chain is worn as a precious metal accessory such as a necklace, bracelet, ring, etc., which is always in contact with the skin and wrapped in negative ions.

In addition, the precious metal pieces are connected by a thread and can rotate freely. In a necklace, a bracelet, or the like, the precious metal chain itself moves according to the movement of the body. The rolling rotation of the pieces constituting such a chain and the movement of the whole chain act synergistically to generate static electricity due to friction with the skin, which amplifies the generation of negative ions from the anode side due to the potential difference. And make it even more effective.

In general, a fatigue state causes an increase in lactic acid value, an increase in positive ions is observed, and the ion balance in the body is lost. According to the present invention, the imbalance of the ion balance is forcibly adjusted from the outside by giving the stimulation of the negative ions. (Improvement of abnormal body surface potential by negative potential effect)

There is also an effect of removing pain by improving blood flow fluctuation (1 / f).

Further, titanium or their respective oxides,
When (2) titanium oxide (TiO ₂ ) is used among nitrides and carbides, generation of negative ions due to the photocatalytic reaction effect can be expected.

(2) The photocatalytic reaction by titanium oxide (TiO ₂ ) is as follows. When light is absorbed by titanium oxide, two carriers, electrons (e ⁻ ) and holes (h ⁺ ), are formed. In a general substance, both recombine immediately. Each of the photocatalysts will survive for a while, leading to the generation of negative ions.

Further, according to the present invention, generation of negative ions is promoted by a semiconductor action. The noble metal piece is made by ion-plating noble metal with titanium or their oxides, nitrides, and carbides, and coating it with a silicon resin film. When the silicon resin film is combined with the silicon resin film, the silicon resin film becomes P-
It exhibits a semiconductor effect as a thin semiconductor film.

FIG. 5 shows the normal skin potential, and FIG. 6 shows the pathological skin potential. In the figure, 1 is a nerve, 2 is a stratum corneum, 3 is an epidermis, 4 is a basement membrane, and 5 is a dermis.

When a precious metal piece exhibiting a semiconductor effect as the P-type semiconductor thin film is brought into contact with a pathological skin, as shown in FIG. 7, the skin comes into contact with a metal having a negative potential. Is removed, and only a negative potential flows.

Further, by giving a negative ion stimulus, the ion balance is forcibly adjusted from the outside. (Improvement of abnormal body surface potential by negative potential effect) In addition, there is also an analgesic effect by improvement of blood flow fluctuation (1 / f).

Moreover, as in the operation of the first aspect, the precious metal pieces are connected by a thread and can rotate freely. In a necklace, a bracelet, or the like, the precious metal chain itself moves according to the movement of the body. The rolling rotation of the pieces constituting such a chain and the movement of the whole chain act synergistically to generate static electricity due to friction with the skin, which amplifies the generation of negative ions from the anode side due to the potential difference. And make it even more effective.

Further, coating with a silicon resin film has an effect of preventing metal allergy and the like.

According to the second aspect of the present invention, in addition to the above operation, the yarn is made of a noble metal different from the noble metal forming the noble metal piece, so that the yarn is formed between them and the yarn. A potential difference is also generated between the noble metal and titanium or their respective oxides, nitrides, and carbides, and the generation of negative ions from the anode side due to the potential difference is amplified.

[0022]

Embodiments of the present invention will be described below in detail with reference to the drawings. FIG. 1 is a partial front view showing one embodiment of the negative ion generating accessory of the present invention, FIG. 2 is a front view of the entire same as above, FIG. 3 is a front view of a precious metal piece, and the accessory is a necklace or a bracelet. .

In the figure, reference numeral 10 denotes a precious metal piece, which is tied to a rosary with a thread 11 to form a chain 12. The precious metal piece 10 is formed of a surface of a metal 14 having a positive potential and a metal having a negative potential. An outer peripheral surface was formed by arranging the surfaces of titanium dioxide (TiO ₂ ) 13 which is an oxide of Ti. The metal 14 having a positive potential is selected from one or two of Au, Pt, Ag or alloys thereof.

The production of the precious metal piece 10 is performed in the following steps. For example, a hollow cylindrical body 20 is formed of a gold (Au) alloy as shown in FIG. 8, and this is coated with titanium dioxide (TiO ₂ ) 13 by ion plating. Ion plating evaporates a substance to be plated in a plasma under reduced pressure, ionizes a part of the substance, accelerates it by applying an electric field to it, deposits it on an object to be plated with a large energy, and adheres to the substrate. This is a technique for improving According to this ion plating, a compound that cannot be formed by wet plating is produced, the adhesion between the base metal and the coating is good, the processing temperature is low, the dimensional accuracy of the base material is not impaired, and there is no harmful substance, so there is no pollution. There is a feature that there is.

As described above, the entire surface (both inner and outer peripheral surfaces) is covered with the coating layer of titanium dioxide (TiO ₂ ) 13 by ion plating. [FIG. 9 (a)] Next, as shown in FIG. 9 (b), the coating layer of titanium dioxide 13 is removed by polishing with a diamond bite. The gold (Au) alloy surface, which is a precious metal material, is exposed in this removed portion. This exposed portion is a portion of the metal 14 having a positive potential.

A lid 16 made of a gold (Au) alloy is fitted to the open end face by caulking to form a closed hollow body. The lid 16 is also a portion of the metal 14 having a positive potential.
The cover 16 is provided with a hole in the center thereof through which the thread 11 passes.

As described above, a precious metal piece 10 having an outer peripheral surface formed by arranging the metal 14 having a positive potential and the titanium dioxide 13 as the metal having a negative potential is obtained. The small pieces 17 made of no gold (Au) alloy are alternately arranged with the pieces 10
And connect them in a rosary to form a chain 12. The thread 11 is made of a noble metal, for example, a platinum (Pt) alloy. Chain 12
A clasp 18 is provided at the end of the.

FIG. 10 shows a schematic diagram of the noble metal piece 10 thus formed.

The standard electrode potential of a metal includes a metal having a positive potential and a metal having a negative potential, and the electrochemical series of these metals is known as the galvanic series. The genetic sequence is known as the galvanic sequence. As a metal having a low potential from a metal having a high potential, TiO
^{_{2 / TiO 2 2+ + 2.18V,}} Au / Au 1+ +1.7
V, Au / Au ³⁺ +1.498 V, Pt / Pt ²⁺ +1.
2 V, Pd / Pd ²⁺ +0.987 V, Rh / Rh ³⁺ +
0.8 V, Ag / Ag ¹⁺ +0.799 V, Hg / Hg ¹⁺
_{+ 0.789V, MoO 2 / MoO 2} 2- + 0.66V,
Cu / Cu ²⁺ +0.377 V, Ti ³⁺ / TiO ²⁺ +0.
1 V, Fe / Fe ¹⁺ -0.036 V, WO ₃ / W-0.
09V, Mo / Mo1 ⁺ -0.2V, Ni / Ni1 ⁺ -0.
^{25V, Ga / Ga 1+ -0.45V,} TiO 2 / Ti-
0.85 V, W / WO ₄ ^2- -1.05 V, Zr / Zr ⁴⁺
-1.53V, Ti / Ti2 ⁺ -1.628V, Al / A
There is l1 ⁺ -1.662V.

The accessory of the present invention is practically made of Au, Pt, and A, excluding metals that show a strong sensitizing reaction or metals that are toxic to living organisms, because they come into direct contact with the body.
g and Ti are preferred.

As a typical metal having a positive potential,
Amplification of negative ions by using one of Au, Pt, and Ag in combination with Ti, which is a typical metal having a negative potential, or at least one of oxides, nitrides, and carbides thereof. It can encourage outbreaks.

Further, the outer peripheral surface of the precious metal piece 10 was coated with a silicon (Si) resin film 19. In this case, the silicon resin is deposited by plasma.

The generation of negative ions is promoted by the action of a semiconductor, and the silicon resin film 19 is formed into a P-type semiconductor thin film by combining titanium dioxide 13 which is a metal having a negative potential and the silicon resin film 19 to form a semiconductor effect. It was made to show. In this case, the presence of the metal 14 having a positive potential need not contribute to the generation of negative ions.

In the above-described embodiment, the example in which the precious metal piece 10 and the small piece 17 including the lid 16 are made of a gold alloy has been described. However, in another embodiment, the precious metal piece 10 and the small piece 17 are made of platinum (P).
t) It can also be made of another noble metal alloy such as an alloy.

When made of a platinum (Pt) alloy, the yarn 11 is made of a gold alloy.

Instead of titanium dioxide 13, another titanium compound such as titanium (Ti) or titanium carbide (TiC) or titanium nitride (TiN) may be deposited by ion plating.

In the case of titanium dioxide 13, a precious metal piece
10 is black or blue, but titanium (Ti)
Etc. can be white or any other color.

As still another embodiment, a precious metal piece
Instead of 10, as shown in FIG. 11, it is also possible to use a titanium dioxide 13 core coated with a silicon resin film 19.

[0039]

As described above, the negative ion generating accessory of the present invention has a good appearance to be worn because it exists as an accessory, and furthermore, when it comes into contact with the skin, it freely moves to cause friction. Ions can be generated more effectively by inducing static electricity, and the therapeutic effect is high.

The negative ion effect of the accessory of the present invention is effective for neutralizing and purifying oxidization in the body, relaxing and recovering from fatigue, promoting health and preventing disease.

[Brief description of the drawings]

FIG. 1 shows a negative ion generating accessory 1 of the present invention.
It is a partial front view showing an embodiment.

FIG. 2 shows one of the negative ion generating accessories of the present invention.
FIG. 1 is an overall front view showing an embodiment.

FIG. 3 is a front view of a precious metal piece of the negative ion generating accessory of the present invention.

FIG. 4 is an explanatory view of a negative ion generating accessory of the present invention as a semiconductor.

FIG. 5 is an explanatory diagram showing a normal skin potential.

FIG. 6 is an explanatory diagram showing a skin potential in a pathological state.

FIG. 7 is an explanatory diagram of a semiconductor effect of the accessory for generating negative ions according to the present invention.

FIG. 8 is a perspective view of a hollow cylindrical body constituting a precious metal piece of the negative ion generating accessory of the present invention.

FIG. 9 is an explanatory view showing a process of manufacturing a precious metal piece of the negative ion generating accessory of the present invention.

FIG. 10 is an explanatory view showing the operation of a precious metal piece of the accessory for generating negative ions according to the present invention.

FIG. 11 is an explanatory view showing the operation of another example of the noble metal piece of the accessory for generating negative ions according to the present invention.

[Description of Signs] 1 ... nerve 2 ... superficial stratum corneum 3 ... epidermis 4 ... basement membrane 5 ... dermis 10 ... precious metal piece 11 ... thread 12 ... chain 13 ... titanium dioxide 14 ... metal with a positive potential 16 ... lid 17… Small piece made of precious metal 18… Clasp 19… Silicon resin coating 20… Hollow cylinder

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[Submission date] August 10, 2000 (2008.1.
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[Title of the Invention] Negative ion generating accessories

[Claims]

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a negative ion-generating accessory which can be used as a jewelry item such as a necklace or a bracelet to promote health maintenance and activation.

[0002]

2. Description of the Related Art As health-related accessories such as improving blood circulation and correcting shoulder stiffness, there are some which emit magnetism as a weak energy or far infrared rays.
Japanese Patent Application Laid-Open No. 2-295830 discloses a bioion-adjusting adhesive body in which a metal having a positive potential and a metal having a negative potential are provided on an adhesive layer of an adhesive material to form an adhesive body.

[0003] The metal structure having an ion generating function enables an effective ion generation. The effect of negative ions and the generation of a local minute current cause the electrical stimulation applied to the diameter hole to the neuron. To the autonomic nervous system, and to promote the biological function of the sympathetic and parasympathetic nerves, for example, to increase the blood flow by expanding the capillaries of the affected part to promote the recovery of the function of the living body.

[0004]

In the case of such an adhesive, it is fixed to the skin, and it is difficult to obtain an effective potential difference between a positive potential and a negative potential, and the ion generating function is good. is not. In addition, the effect is only exerted to a limited extent at the place where the patch is pasted, and if an attempt is made to expand the treatment area, a large patch is required, which hinders free movement of the body, The appearance is also bad.

An object of the present invention is to solve the above-mentioned disadvantages of the prior art and to wear it as an accessory so that the appearance is good. When it comes into contact with the skin, it freely moves to generate static electricity due to friction. It is an object of the present invention to provide a negative ion generating accessory which can supply ions to a body surface by a semiconductor action, can generate ions more effectively by using ultraviolet rays of sunlight, and has a high therapeutic effect.

[0006] To achieve the above object, the present invention provides a first method.
In addition, a precious metal piece in which a metal having a positive potential and titanium as a metal having a negative potential or their respective oxides, nitrides, and carbides are arranged to form an outer peripheral surface is appropriately arranged, and tied together with a string to form a noble metal. Secondly, the necklace and the noble metal chain were formed so that the piece itself could freely rotate, and secondly, the thread was made of a different kind of noble metal from the noble metal forming the noble metal piece. Is what you do.

[0007] About 60 to 70% of the human body is in the body as a body fluid (water), and an electrolyte and a non-electrolyte are dissolved in the body fluid. There are positive ions and negative ions in the electrolyte, and these ions are present with a balance. When the balance is lost, various illnesses and diseases are easily caused.

[0008] It is said that the difference in the distribution of ions surrounding cells is closely related to nerve cells, and is said to greatly affect the recovery of the health of the whole body and the deterioration of diseases.
These positive and negative ions exist through the cell membrane, and the permeability of the membrane differs depending on the magnitude of the positive and negative bipolar electric potentials. Ions move organically throughout the body based on certain laws, which are greatly affected by the intensity and distribution of ion electrons in the internal and external environments of the body.

According to the first aspect of the present invention, a noble metal piece formed by connecting beads with a string to form a noble metal chain forms an outer peripheral surface by arranging a metal having a positive potential and a metal having a negative potential. The potential difference generates negative ions from the anode side, which irritates the skin. That is, one or two of Au, Pt, and Ag are used as a typical metal having a positive potential, and titanium, which is a typical metal having a negative potential, or an oxide or nitride thereof is used. By combining with a substance or carbide, amplification of negative ions can be promoted. The precious metal chain is worn as a precious metal accessory such as a necklace, bracelet, ring, etc., which is always in contact with the skin and wrapped in negative ions.

In addition, the precious metal pieces are connected by a thread and can rotate freely. In a necklace, a bracelet, or the like, the precious metal chain itself moves according to the movement of the body. The rolling rotation of the pieces constituting such a chain and the movement of the whole chain act synergistically to generate static electricity due to friction with the skin, which amplifies the generation of negative ions from the anode side due to the potential difference. And make it even more effective.

In general, a fatigue state causes an increase in lactic acid value, an increase in positive ions is observed, and the ion balance in the body is lost. According to the present invention, the imbalance of the ion balance is forcibly adjusted from the outside by giving the stimulation of the negative ions. (Improvement of abnormal body surface potential by negative potential effect)

There is also an effect of removing pain by improving blood flow fluctuation (1 / f).

Further, titanium or their respective oxides,
Among nitrides and carbides, (di) titanium oxide (TiO ₂ )
When is used, generation of negative ions due to the photocatalytic reaction effect can be expected.

(2) The photocatalytic reaction by titanium oxide (TiO ₂ ) is as follows. When light is absorbed by titanium oxide, electrons (e ⁻ ) and holes (h ⁺ )
One carrier is formed, and in a general substance, both recombine immediately, but in the case of the (di) titanium oxide photocatalyst, each of them survives for a while, leading to the generation of negative ions.

FIG. 4 shows normal skin potentials, and FIG. 5 shows pathological skin potentials. In the figure, 1 is a nerve, 2 is a stratum corneum, 3 is an epidermis, 4 is a basement membrane, and 5 is a dermis.

Further, by giving a negative ion stimulus, the ion balance is forcibly adjusted from the outside. (Improvement of abnormal body surface potential by negative potential effect) In addition, there is also an analgesic effect by improvement of blood flow fluctuation (1 / f).

According to the second aspect of the present invention, in addition to the above operation, the yarn is made of a noble metal different from the noble metal forming the noble metal piece, so that the yarn is formed between the two and the yarn. A potential difference is also generated between the noble metal and titanium or their respective oxides, nitrides, and carbides, and the generation of negative ions from the anode side due to the potential difference is amplified.

[0018]

Embodiments of the present invention will be described below in detail with reference to the drawings. FIG. 1 is a partial front view showing one embodiment of the negative ion generating accessory of the present invention, FIG. 2 is a front view of the entire same as above, FIG. 3 is a front view of a precious metal piece, and the accessory is a necklace or a bracelet. .

In the figure, reference numeral 10 denotes a noble metal piece, which is tied to a rosary with a thread 11 to form a chain 12. This noble metal piece 10 has a surface of a metal 14 having a positive potential and a metal having a negative potential. The outer peripheral surface was formed by arranging the surfaces of titanium dioxide (TiO ₂ ) 13 which is an oxide of Ti. The metal 14 having a positive potential is selected from one or two of Au, Pt, Ag or alloys thereof.

The production of the precious metal piece 10 is performed in the following steps. For example, as shown in FIG. 6, a hollow cylindrical body 20 is formed of a gold (Au) alloy, and this is coated with titanium dioxide (TiO ₂ ) 13 by ion plating. Ion plating evaporates a substance to be plated in a plasma under reduced pressure, ionizes a part of the substance, accelerates it by applying an electric field to it, deposits it on an object to be plated with a large energy, and adheres to the substrate. This is a technique for improving According to this ion plating, a compound that cannot be formed by wet plating is produced, the adhesion between the base metal and the coating is good, the processing temperature is low, the dimensional accuracy of the base material is not impaired, and there is no harmful substance, so there is no pollution. There is a feature that there is.

As described above, the entire surface (both inner and outer peripheral surfaces) is covered with the coating layer of titanium dioxide (TiO ₂ ) 13 by ion plating. [FIG. 7 (a)] Then, as shown in FIG. 7 (b), the coating layer of titanium dioxide 13 is removed by polishing with a diamond cutting tool. In this removed portion, a gold (Au) alloy surface, which is a precious metal material, is exposed. This exposed portion is a portion of the metal 14 having a positive potential.

Further, a lid 16 made of a gold (Au) alloy is fitted to the open end face by caulking to form a closed hollow body. The lid 16 is also a portion of the metal 14 having a positive potential.
The cover 16 is provided with a hole in the center thereof through which the thread 11 passes.

As described above, a precious metal piece 10 having an outer peripheral surface formed by arranging the metal 14 having a positive potential and the titanium dioxide 13 as the metal having a negative potential is obtained. A small piece 17 made of no gold (Au) alloy is alternately arranged with the piece 10
And connect them in a rosary to form a chain 12. The thread 11 is made of a noble metal, for example, a platinum (Pt) alloy. Chain 12
A clasp 18 is provided at the end of the.

FIG. 8 shows a schematic diagram of the noble metal piece 10 thus formed.

The standard electrode potential of a metal has a positive potential.
Metal and metals with a negative potential.
The electrochemical series of the genus is known as the galvanic series
You. The genetic sequence is known as the galvanic sequence. High
As a metal having a low potential from a metal having a potential, TiO
₂/ TiO₂ ²⁺+ 2.18V, Au / Au¹⁺+
1.7V, Au / Au³⁺+ 1.498V, Pt / Pt
²⁺+ 1.2V, Pd / Pd²⁺+ 0.987V, Rh
/ Rh³⁺+0.8 V, Ag / Ag¹⁺+0.799
V, Hg / Hg¹⁺+ 0.789V, MoO₂/ Mo
O₂ ^2-+0.66 V, Cu / Cu²⁺+0.377
V, Ti³⁺/ TiO²⁺+ 0.1V, Fe / Fe¹⁺
-0.036V, WO₃/W-0.09V, Mo / M
o¹⁺-0.2V, Ni / Ni¹⁺-0.25V, Ga
/ Ga¹⁺-0.45V, TiO₂/Ti-0.85
V, W / WO ₄ ^2--1.05V, Zr / Zr⁴⁺−
1.53V, Ti / Ti²⁺-1.628V, Al / A
l¹⁺-1.662V.

The accessory of the present invention is practically Au, Pt, and A.
g and Ti are preferred.

As a typical metal having a positive potential,
Amplification of negative ions by using one of Au, Pt, and Ag in combination with Ti, which is a typical metal having a negative potential, or at least one of oxides, nitrides, and carbides thereof. It can encourage outbreaks.

In the above-described embodiment, the example in which the precious metal piece 10 and the small piece 17 including the lid 16 are made of a gold alloy has been described.
t) It can also be made of another noble metal alloy such as an alloy.

When made of a platinum (Pt) alloy, the yarn 11 is made of a gold alloy.

Instead of titanium dioxide 13, another titanium compound such as titanium (Ti) or titanium carbide (TiC) or titanium nitride (TiN) may be deposited by ion plating.

In the case of titanium dioxide 13, a precious metal piece
10 is black or blue, but titanium (Ti)
Etc. can be white or any other color.

[0032]

As described above, the negative ion generating accessory of the present invention has a good appearance to be worn because it exists as an accessory, and furthermore, when it comes into contact with the skin, it freely moves to cause friction. Ions can be generated more effectively by inducing static electricity, and the therapeutic effect is high.

The negative ion effect of the accessory of the present invention is effective for neutralizing and purifying oxidization in the body, relaxing and recovering from fatigue, promoting health and preventing disease.

[Brief description of the drawings]

FIG. 1 shows a negative ion generating accessory 1 of the present invention.
It is a partial front view showing an embodiment.

FIG. 2 shows one of the negative ion generating accessories of the present invention.
FIG. 1 is an overall front view showing an embodiment.

FIG. 3 is a front view of a precious metal piece of the negative ion generating accessory of the present invention.

FIG. 4 is an explanatory diagram showing a normal skin potential.

FIG. 5 is an explanatory diagram showing a skin potential in a pathological state.

FIG. 6 is a perspective view of a hollow cylindrical body constituting a precious metal piece of the negative ion generating accessory of the present invention.

FIG. 7 is an explanatory view showing a manufacturing process of a precious metal piece of the accessory for generating negative ions according to the present invention.

FIG. 8 is an explanatory view showing the operation of a precious metal piece of the accessory for generating negative ions according to the present invention.

[Description of Signs] 1 ... nerve 2 ... superficial stratum corneum 3 ... epidermis 4 ... basement membrane 5 ... dermis 10 ... precious metal piece 11 ... thread 12 ... chain 13 ... titanium dioxide 14 ... metal with a positive potential 16 ... lid 17 ... small piece made of precious metal 18 ... clasp 20 ... hollow cylinder

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 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Shuichi Onodera 3-6-3-208 Toyomakita, Nerima-ku, Tokyo Inside Tiara Co., Ltd. (72) Inventor Masami Saito 2-11-8 Nishishinbashi, Minato-ku, Tokyo No. Japan Medical Beauty F-term (Reference) 3B114 AA06 BB07 BD06 CC07 FA01 FB02 HH09 JA01 4C053 BB23 GG04

Claims (4)

[Claims] 1. A precious metal piece in which an outer peripheral surface is formed by arranging a metal having a positive potential and titanium as a metal having a negative potential or their respective oxides, nitrides, and carbides, and tying them with beads. An anion generating accessory characterized by forming a precious metal chain. 2. A precious metal chain formed by ion-plating titanium or oxides, nitrides, and carbides thereof on a precious metal, and further linking the precious metal pieces coated with a silicon resin film with beads to form a precious metal chain. An anion generating accessory characterized by the following. 3. A noble metal piece in which an outer peripheral surface is formed by arranging a metal having a positive potential and titanium as a metal having a negative potential or their respective oxides, nitrides, and carbides; Each oxide of
A negative ion generating accessory characterized in that a noble metal chain is formed by ion-plating nitrides and carbides, and further arranging precious metal pieces coated with a silicon resin coating as appropriate and connecting the beads with beads. 4. The accessory according to claim 1, wherein the yarn is made of a noble metal of a type different from the noble metal forming the noble metal piece.