JPS649334B2 - - Google Patents
Info
- Publication number
- JPS649334B2 JPS649334B2 JP55502142A JP50214280A JPS649334B2 JP S649334 B2 JPS649334 B2 JP S649334B2 JP 55502142 A JP55502142 A JP 55502142A JP 50214280 A JP50214280 A JP 50214280A JP S649334 B2 JPS649334 B2 JP S649334B2
- Authority
- JP
- Japan
- Prior art keywords
- block
- polyamide
- copolymer
- precursor
- poly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002647 polyamide Polymers 0.000 description 45
- 239000004952 Polyamide Substances 0.000 description 43
- 229920002614 Polyether block amide Polymers 0.000 description 39
- 239000002243 precursor Substances 0.000 description 37
- 229920001400 block copolymer Polymers 0.000 description 35
- 229920005604 random copolymer Polymers 0.000 description 30
- 150000003839 salts Chemical class 0.000 description 29
- 238000002844 melting Methods 0.000 description 20
- 230000008018 melting Effects 0.000 description 20
- 239000000203 mixture Substances 0.000 description 19
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 14
- 229920001577 copolymer Polymers 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 229920002302 Nylon 6,6 Polymers 0.000 description 11
- 238000013329 compounding Methods 0.000 description 11
- 229920002292 Nylon 6 Polymers 0.000 description 7
- -1 ether diamines Chemical class 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 238000006068 polycondensation reaction Methods 0.000 description 6
- 238000007056 transamidation reaction Methods 0.000 description 6
- 150000004985 diamines Chemical class 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 230000002411 adverse Effects 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical class NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 125000006832 (C1-C10) alkylene group Chemical group 0.000 description 3
- 125000006835 (C6-C20) arylene group Chemical group 0.000 description 3
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 230000000875 corresponding effect Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical group 0.000 description 2
- VDBXLXRWMYNMHL-UHFFFAOYSA-N decanediamide Chemical compound NC(=O)CCCCCCCCC(N)=O VDBXLXRWMYNMHL-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N 1,3-Dimethylbenzene Natural products CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 1
- ZXOSLNZFVPGYTB-UHFFFAOYSA-N 3-(3-aminopropoxy)propan-1-amine hexanedioic acid Chemical compound C(CCCCC(=O)O)(=O)O.NCCCOCCCN ZXOSLNZFVPGYTB-UHFFFAOYSA-N 0.000 description 1
- VTHRQKSLPFJQHN-UHFFFAOYSA-N 3-[2-(2-cyanoethoxy)ethoxy]propanenitrile Chemical compound N#CCCOCCOCCC#N VTHRQKSLPFJQHN-UHFFFAOYSA-N 0.000 description 1
- UFFRSDWQMJYQNE-UHFFFAOYSA-N 6-azaniumylhexylazanium;hexanedioate Chemical compound [NH3+]CCCCCC[NH3+].[O-]C(=O)CCCCC([O-])=O UFFRSDWQMJYQNE-UHFFFAOYSA-N 0.000 description 1
- COXRPBBNPBCNDM-UHFFFAOYSA-N Dioxamide Natural products C1=C2OCOC2=CC(C=CC(=O)N(CCC=2C=C3OCOC3=CC=2)C)=C1 COXRPBBNPBCNDM-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- FJXWKBZRTWEWBJ-UHFFFAOYSA-N nonanediamide Chemical compound NC(=O)CCCCCCCC(N)=O FJXWKBZRTWEWBJ-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 210000002706 plastid Anatomy 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
Landscapes
- Polyamides (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1980/001098 WO1981000719A1 (en) | 1979-09-06 | 1980-08-25 | Block copolymer of polyetheramide and random copolymer of polyamide and polyetheramide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56501093A JPS56501093A (cs) | 1981-08-06 |
| JPS649334B2 true JPS649334B2 (cs) | 1989-02-17 |
Family
ID=22154510
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55502142A Expired JPS649334B2 (cs) | 1980-08-25 | 1980-08-25 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS649334B2 (cs) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4044071A (en) * | 1976-11-08 | 1977-08-23 | Suntech, Inc. | Single step preparation of block copolymer of polyamides |
| US4130602A (en) * | 1975-03-12 | 1978-12-19 | Sun Ventures, Inc. | Block copolymer of poly(dioxa-amide) and polyamide |
| US4168602A (en) * | 1975-03-11 | 1979-09-25 | Sun Ventures, Inc. | Block copolymer of poly (dioxaarylamide) and polyamide and fibers and fibrous material produced therefrom |
-
1980
- 1980-08-25 JP JP55502142A patent/JPS649334B2/ja not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4168602A (en) * | 1975-03-11 | 1979-09-25 | Sun Ventures, Inc. | Block copolymer of poly (dioxaarylamide) and polyamide and fibers and fibrous material produced therefrom |
| US4130602A (en) * | 1975-03-12 | 1978-12-19 | Sun Ventures, Inc. | Block copolymer of poly(dioxa-amide) and polyamide |
| US4044071A (en) * | 1976-11-08 | 1977-08-23 | Suntech, Inc. | Single step preparation of block copolymer of polyamides |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56501093A (cs) | 1981-08-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH04227633A (ja) | 混合アミンからポリエーテルアミドを製造する方法 | |
| JPH04227632A (ja) | 新規なポリエーテルアミド及びその製法 | |
| KR20020074446A (ko) | 테트라메틸렌 테레프탈아미드 및 헥사메틸렌테레프탈아미드에 기초한 코폴리아미드 | |
| JPS6238370B2 (cs) | ||
| JPH0234633A (ja) | ２９０℃より低い融点を有する結晶化セミ芳香族ポリアミド | |
| US5030710A (en) | Nylon-6 modified with low molecular weight polyethylene glycol diamines | |
| AU663326B2 (en) | Copolyadipamide containing pentamethyleneadipamide units and products prepared therefrom | |
| CA2107386A1 (en) | Poly(etheramide) segmented block copolymers | |
| EP0400827A2 (en) | Grafting of amine functional polymers onto functionalized oxymethylene polymers and the resulting graft polymers thereof | |
| US3627736A (en) | Polyamides from isophorone diamine, hexamethylene diamine, isophthalic acid and terephthalic acid | |
| EP0035551B1 (en) | Block copolymer of polyetheramide and random copolymer of polyamide and polyetheramide | |
| AU657154B2 (en) | Copolyadipamide containing ethyltetramethyleneadipamide units and products prepared therefrom | |
| US5206308A (en) | Grafting of amine functional polymers onto functionalized oxymethylene polymers and the resulting graft polymers thereof | |
| JPS649334B2 (cs) | ||
| JPS6243417A (ja) | ポリエ−テルアミド樹脂の製造方法 | |
| KR0171611B1 (ko) | 도데칸 테레프탈아미드의 공중합체 | |
| US5079339A (en) | Copolymer of dodecane terephthalamide | |
| US5162491A (en) | Copolyadipamide containing trimethylhexamethyleneadipamide units | |
| JPS59197429A (ja) | ポリエステル−ポリアミドブロツク重合体類の製造方法 | |
| JPS62252424A (ja) | 末端変性ポリアミドおよびその製法 | |
| JPS63110245A (ja) | ポリアセタ−ル樹脂組成物 | |
| JPS6255532B2 (cs) | ||
| JPS60228532A (ja) | ポリエ−テルエステルアミドの製造法 | |
| JPH02123132A (ja) | 芳香族ポリアミド樹脂及びその製造方法 | |
| JPS60166323A (ja) | ポリエ−テルエステルアミドの製造方法 |