JPS637205B2 - - Google Patents

Info

Publication number

JPS637205B2

JPS637205B2 JP55036371A JP3637180A JPS637205B2 JP S637205 B2 JPS637205 B2 JP S637205B2 JP 55036371 A JP55036371 A JP 55036371A JP 3637180 A JP3637180 A JP 3637180A JP S637205 B2 JPS637205 B2 JP S637205B2

Authority

JP

Japan

Prior art keywords

weight

hydrogenated

polyhydroxybutadiene

liquid rubber

polymer

Prior art date

1980-03-22

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Links

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• 229920001971 elastomer Polymers 0.000 claims description 30
• 239000005060 rubber Substances 0.000 claims description 30
• 229920000642 polymer Polymers 0.000 claims description 28
• 239000003063 flame retardant Substances 0.000 claims description 27
• 239000007788 liquid Substances 0.000 claims description 23
• RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 21
• 239000000203 mixture Substances 0.000 claims description 20
• 150000001875 compounds Chemical class 0.000 claims description 17
• 239000012948 isocyanate Substances 0.000 claims description 15
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
• VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 13
• 239000003795 chemical substances by application Substances 0.000 claims description 12
• 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 12
• 239000000347 magnesium hydroxide Substances 0.000 claims description 12
• KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 11
• -1 isocyanate compound Chemical class 0.000 claims description 9
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
• 125000000217 alkyl group Chemical group 0.000 claims description 5
• 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 3
• 125000004432 carbon atom Chemical group C* 0.000 claims description 2
• IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 2
• 239000000047 product Substances 0.000 description 23
• 238000001723 curing Methods 0.000 description 12
• 238000000034 method Methods 0.000 description 12
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
• 238000005266 casting Methods 0.000 description 6
• 150000002513 isocyanates Chemical class 0.000 description 6
• 238000005470 impregnation Methods 0.000 description 5
• 238000009413 insulation Methods 0.000 description 5
• 239000000463 material Substances 0.000 description 5
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
• 238000010292 electrical insulation Methods 0.000 description 4
• 238000005984 hydrogenation reaction Methods 0.000 description 4
• 239000012778 molding material Substances 0.000 description 4
• 238000000465 moulding Methods 0.000 description 4
• 229920005989 resin Polymers 0.000 description 4
• 239000011347 resin Substances 0.000 description 4
• 229920002554 vinyl polymer Polymers 0.000 description 4
• 229920005549 butyl rubber Polymers 0.000 description 3
• 239000006229 carbon black Substances 0.000 description 3
• 238000002425 crystallisation Methods 0.000 description 3
• 230000008025 crystallization Effects 0.000 description 3
• 230000006866 deterioration Effects 0.000 description 3
• 239000000945 filler Substances 0.000 description 3
• 150000002484 inorganic compounds Chemical class 0.000 description 3
• 229910010272 inorganic material Inorganic materials 0.000 description 3
• 239000002075 main ingredient Substances 0.000 description 3
• 238000004519 manufacturing process Methods 0.000 description 3
• 238000002156 mixing Methods 0.000 description 3
• KFZMGEQAYNKOFK-UHFFFAOYSA-N 2-propanol Substances CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
• 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
• 229910000410 antimony oxide Inorganic materials 0.000 description 2
• 238000006243 chemical reaction Methods 0.000 description 2
• 239000013013 elastic material Substances 0.000 description 2
• 239000003822 epoxy resin Substances 0.000 description 2
• 229910052736 halogen Inorganic materials 0.000 description 2
• 150000002367 halogens Chemical class 0.000 description 2
• 229910052739 hydrogen Inorganic materials 0.000 description 2
• 239000001257 hydrogen Substances 0.000 description 2
• 238000005259 measurement Methods 0.000 description 2
• VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
• 229920000647 polyepoxide Polymers 0.000 description 2
• 229920000098 polyolefin Polymers 0.000 description 2
• 238000003756 stirring Methods 0.000 description 2
• 238000005979 thermal decomposition reaction Methods 0.000 description 2
• 230000001988 toxicity Effects 0.000 description 2
• 231100000419 toxicity Toxicity 0.000 description 2
• 229920006337 unsaturated polyester resin Polymers 0.000 description 2
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
• RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
• UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
• 208000034068 Bazex-Dupré-Christol syndrome Diseases 0.000 description 1
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
• 229910019440 Mg(OH) Inorganic materials 0.000 description 1
• 229910019142 PO4 Inorganic materials 0.000 description 1
• 239000004743 Polypropylene Substances 0.000 description 1
• 229910000564 Raney nickel Inorganic materials 0.000 description 1
• NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
• XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
• BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
• 239000000654 additive Substances 0.000 description 1
• 230000000996 additive effect Effects 0.000 description 1
• 238000002485 combustion reaction Methods 0.000 description 1
• 238000000748 compression moulding Methods 0.000 description 1
• 238000007796 conventional method Methods 0.000 description 1
• 229920001577 copolymer Polymers 0.000 description 1
• 230000006378 damage Effects 0.000 description 1
• 230000007547 defect Effects 0.000 description 1
• 230000000694 effects Effects 0.000 description 1
• 238000005265 energy consumption Methods 0.000 description 1
• HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
• 238000001125 extrusion Methods 0.000 description 1
• 239000007789 gas Substances 0.000 description 1
• LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
• 238000013007 heat curing Methods 0.000 description 1
• 230000007062 hydrolysis Effects 0.000 description 1
• 238000006460 hydrolysis reaction Methods 0.000 description 1
• WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
• 239000011810 insulating material Substances 0.000 description 1
• 239000012212 insulator Substances 0.000 description 1
• 238000004898 kneading Methods 0.000 description 1
• 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
• 239000000178 monomer Substances 0.000 description 1
• 150000002896 organic halogen compounds Chemical class 0.000 description 1
• 239000011368 organic material Substances 0.000 description 1
• 239000010452 phosphate Substances 0.000 description 1
• 150000003014 phosphoric acid esters Chemical class 0.000 description 1
• 230000000704 physical effect Effects 0.000 description 1
• 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
• 229920005672 polyolefin resin Polymers 0.000 description 1
• 229920001155 polypropylene Polymers 0.000 description 1
• 239000002244 precipitate Substances 0.000 description 1
• 230000002028 premature Effects 0.000 description 1
• HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
• 230000009257 reactivity Effects 0.000 description 1
• 230000002787 reinforcement Effects 0.000 description 1
• 230000003014 reinforcing effect Effects 0.000 description 1
• 238000011160 research Methods 0.000 description 1
• 229920001897 terpolymer Polymers 0.000 description 1
• 229920001187 thermosetting polymer Polymers 0.000 description 1
• DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
• 231100000331 toxic Toxicity 0.000 description 1
• 230000002588 toxic effect Effects 0.000 description 1
• 238000001721 transfer moulding Methods 0.000 description 1