JPS6361087A - 炭化水素供給原料の脱金属方法 - Google Patents
炭化水素供給原料の脱金属方法Info
- Publication number
- JPS6361087A JPS6361087A JP21154087A JP21154087A JPS6361087A JP S6361087 A JPS6361087 A JP S6361087A JP 21154087 A JP21154087 A JP 21154087A JP 21154087 A JP21154087 A JP 21154087A JP S6361087 A JPS6361087 A JP S6361087A
- Authority
- JP
- Japan
- Prior art keywords
- calcium
- metal
- oils
- edta
- removal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 19
- 239000002184 metal Substances 0.000 title claims description 19
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 15
- 229930195733 hydrocarbon Natural products 0.000 title claims description 15
- 239000002994 raw material Substances 0.000 title 1
- 239000011575 calcium Substances 0.000 claims description 41
- 229910052791 calcium Inorganic materials 0.000 claims description 39
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 31
- 239000010779 crude oil Substances 0.000 claims description 26
- 239000003921 oil Substances 0.000 claims description 26
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 24
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 20
- 150000003839 salts Chemical class 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 11
- 238000000926 separation method Methods 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 239000003352 sequestering agent Substances 0.000 claims description 8
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 238000000605 extraction Methods 0.000 claims description 7
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 6
- 229940043430 calcium compound Drugs 0.000 claims description 4
- 150000001674 calcium compounds Chemical class 0.000 claims description 4
- -1 porphyrin compound Chemical class 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 3
- 239000003245 coal Substances 0.000 claims description 2
- 239000003079 shale oil Substances 0.000 claims description 2
- 238000010612 desalination reaction Methods 0.000 claims 1
- 239000000356 contaminant Substances 0.000 description 11
- 239000008346 aqueous phase Substances 0.000 description 10
- 239000002738 chelating agent Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 5
- 239000000908 ammonium hydroxide Substances 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 229960003330 pentetic acid Drugs 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229940048195 n-(hydroxyethyl)ethylenediaminetriacetic acid Drugs 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 150000004032 porphyrins Chemical class 0.000 description 4
- 239000003446 ligand Substances 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000009533 lab test Methods 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 239000012465 retentate Substances 0.000 description 2
- NKFIBMOQAPEKNZ-UHFFFAOYSA-N 5-amino-1h-indole-2-carboxylic acid Chemical compound NC1=CC=C2NC(C(O)=O)=CC2=C1 NKFIBMOQAPEKNZ-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 206010027439 Metal poisoning Diseases 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- 241000183024 Populus tremula Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001669 calcium Chemical class 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000039 congener Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 125000000267 glycino group Chemical group [H]N([*])C([H])([H])C(=O)O[H] 0.000 description 1
- XKUKSGPZAADMRA-UHFFFAOYSA-N glycyl-glycyl-glycine Natural products NCC(=O)NCC(=O)NCC(O)=O XKUKSGPZAADMRA-UHFFFAOYSA-N 0.000 description 1
- 108010067216 glycyl-glycyl-glycine Proteins 0.000 description 1
- 208000010501 heavy metal poisoning Diseases 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000005608 naphthenic acid group Chemical group 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
Landscapes
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US901344 | 1986-08-28 | ||
| US06/901,344 US4778590A (en) | 1985-10-30 | 1986-08-28 | Decalcification of hydrocarbonaceous feedstocks using amino-carboxylic acids and salts thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6361087A true JPS6361087A (ja) | 1988-03-17 |
| JPH0470353B2 JPH0470353B2 (enrdf_load_html_response) | 1992-11-10 |
Family
ID=25413986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21154087A Granted JPS6361087A (ja) | 1986-08-28 | 1987-08-27 | 炭化水素供給原料の脱金属方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6361087A (enrdf_load_html_response) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009235411A (ja) * | 2002-08-30 | 2009-10-15 | Baker Hughes Inc | 精製脱塩処理における金属及びアミンの除去促進添加剤 |
| JP2013542306A (ja) * | 2010-11-15 | 2013-11-21 | ドルフ ケタール ケミカルズ（インド）プライベート リミテッド | ナフテン酸カルシウムを含む原油からカルシウムを除去するための添加剤及び方法 |
| JP2014518314A (ja) * | 2011-06-29 | 2014-07-28 | ドルフ ケタール ケミカルズ（インド）プライベート リミテッド | ナフテン酸カルシウム含有原油からカルシウム除去のための添加剤及び方法 |
-
1987
- 1987-08-27 JP JP21154087A patent/JPS6361087A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009235411A (ja) * | 2002-08-30 | 2009-10-15 | Baker Hughes Inc | 精製脱塩処理における金属及びアミンの除去促進添加剤 |
| JP2009235412A (ja) * | 2002-08-30 | 2009-10-15 | Baker Hughes Inc | 精製脱塩処理における金属及びアミンの除去促進添加剤を含む混合物 |
| JP2013542306A (ja) * | 2010-11-15 | 2013-11-21 | ドルフ ケタール ケミカルズ（インド）プライベート リミテッド | ナフテン酸カルシウムを含む原油からカルシウムを除去するための添加剤及び方法 |
| JP2014518314A (ja) * | 2011-06-29 | 2014-07-28 | ドルフ ケタール ケミカルズ（インド）プライベート リミテッド | ナフテン酸カルシウム含有原油からカルシウム除去のための添加剤及び方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0470353B2 (enrdf_load_html_response) | 1992-11-10 |
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