JPS6346297A - 高ｔｂｎ、低粘度の第２族金属過塩基化硫化アルキルフエノ−ル - Google Patents
高ｔｂｎ、低粘度の第２族金属過塩基化硫化アルキルフエノ−ルInfo
- Publication number
- JPS6346297A JPS6346297A JP62197989A JP19798987A JPS6346297A JP S6346297 A JPS6346297 A JP S6346297A JP 62197989 A JP62197989 A JP 62197989A JP 19798987 A JP19798987 A JP 19798987A JP S6346297 A JPS6346297 A JP S6346297A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- weight
- group
- metal overbased
- soluble group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052784 alkaline earth metal Inorganic materials 0.000 title claims description 44
- 125000000217 alkyl group Chemical group 0.000 title claims description 41
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title description 9
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 title description 3
- 229910052751 metal Inorganic materials 0.000 claims description 81
- 239000002184 metal Substances 0.000 claims description 81
- 239000011575 calcium Substances 0.000 claims description 73
- 239000003921 oil Substances 0.000 claims description 64
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 62
- 229910052791 calcium Inorganic materials 0.000 claims description 62
- -1 alkyl phenols Chemical class 0.000 claims description 48
- 125000004432 carbon atom Chemical group C* 0.000 claims description 36
- 230000001050 lubricating effect Effects 0.000 claims description 26
- 239000010687 lubricating oil Substances 0.000 claims description 25
- 239000012141 concentrate Substances 0.000 claims description 11
- 239000011777 magnesium Substances 0.000 claims description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 229910052788 barium Inorganic materials 0.000 claims description 6
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 4
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 121
- 238000006243 chemical reaction Methods 0.000 description 109
- 239000000047 product Substances 0.000 description 74
- 239000000203 mixture Substances 0.000 description 66
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 46
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 41
- 239000011593 sulfur Substances 0.000 description 41
- 229910052717 sulfur Inorganic materials 0.000 description 41
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 39
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 28
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 26
- 229910002092 carbon dioxide Inorganic materials 0.000 description 23
- 239000001569 carbon dioxide Substances 0.000 description 22
- 239000003054 catalyst Substances 0.000 description 22
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
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- 238000001914 filtration Methods 0.000 description 18
- 238000003756 stirring Methods 0.000 description 18
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 17
- 239000000920 calcium hydroxide Substances 0.000 description 17
- 235000011116 calcium hydroxide Nutrition 0.000 description 17
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- 229910052500 inorganic mineral Inorganic materials 0.000 description 17
- 235000010755 mineral Nutrition 0.000 description 17
- 239000011707 mineral Substances 0.000 description 17
- KZNICNPSHKQLFF-UHFFFAOYSA-N dihydromaleimide Natural products O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 15
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 14
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- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical class ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 229940014800 succinic anhydride Drugs 0.000 description 9
- 229960002317 succinimide Drugs 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 239000003085 diluting agent Substances 0.000 description 8
- 239000000314 lubricant Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 230000003301 hydrolyzing effect Effects 0.000 description 7
- 229920000768 polyamine Polymers 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 6
- 238000005160 1H NMR spectroscopy Methods 0.000 description 6
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 229940054266 2-mercaptobenzothiazole Drugs 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 6
- 125000001183 hydrocarbyl group Chemical group 0.000 description 6
- 229920001281 polyalkylene Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 150000004703 alkoxides Chemical class 0.000 description 5
- 159000000007 calcium salts Chemical class 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 229910000000 metal hydroxide Inorganic materials 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- 239000004711 α-olefin Substances 0.000 description 5
- YZUPZGFPHUVJKC-UHFFFAOYSA-N 1-bromo-2-methoxyethane Chemical group COCCBr YZUPZGFPHUVJKC-UHFFFAOYSA-N 0.000 description 4
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000005804 alkylation reaction Methods 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 238000000502 dialysis Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 150000004679 hydroxides Chemical class 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 150000003871 sulfonates Chemical class 0.000 description 4
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003729 cation exchange resin Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical group CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
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- 239000010802 sludge Substances 0.000 description 3
- SDKPSXWGRWWLKR-UHFFFAOYSA-M sodium;9,10-dioxoanthracene-1-sulfonate Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)[O-] SDKPSXWGRWWLKR-UHFFFAOYSA-M 0.000 description 3
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 3
- GGQQNYXPYWCUHG-RMTFUQJTSA-N (3e,6e)-deca-3,6-diene Chemical compound CCC\C=C\C\C=C\CC GGQQNYXPYWCUHG-RMTFUQJTSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
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- 239000001110 calcium chloride Substances 0.000 description 2
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- AIXAANGOTKPUOY-UHFFFAOYSA-N carbachol Chemical group [Cl-].C[N+](C)(C)CCOC(N)=O AIXAANGOTKPUOY-UHFFFAOYSA-N 0.000 description 2
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- 238000002474 experimental method Methods 0.000 description 2
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
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- GHKVUVOPHDYRJC-UHFFFAOYSA-N didodecyl hexanedioate Chemical compound CCCCCCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCCCCCC GHKVUVOPHDYRJC-UHFFFAOYSA-N 0.000 description 1
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- 239000003701 inert diluent Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 239000010707 multi-grade lubricating oil Substances 0.000 description 1
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 1
- BYELUCYOXPYOJA-UHFFFAOYSA-O n-[1-(2,4-dichlorophenyl)-2-(1h-imidazol-1-ium-1-yl)ethyl]-5-phenyl-1,3,4-oxadiazole-2-carboxamide Chemical compound ClC1=CC(Cl)=CC=C1C(NC(=O)C=1OC(=NN=1)C=1C=CC=CC=1)C[NH+]1C=NC=C1 BYELUCYOXPYOJA-UHFFFAOYSA-O 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000000069 prophylactic effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 210000004196 psta Anatomy 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical class O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- YZKRIHZCXGPZGB-UHFFFAOYSA-L zinc;oxido-propan-2-yloxy-propan-2-ylsulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound [Zn+2].CC(C)OP([O-])(=S)SC(C)C.CC(C)OP([O-])(=S)SC(C)C YZKRIHZCXGPZGB-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/24—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US89459986A | 1986-08-08 | 1986-08-08 | |
| US894599 | 1986-08-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6346297A true JPS6346297A (ja) | 1988-02-27 |
Family
ID=25403296
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62197989A Pending JPS6346297A (ja) | 1986-08-08 | 1987-08-07 | 高ｔｂｎ、低粘度の第２族金属過塩基化硫化アルキルフエノ−ル |
Country Status (15)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5627146A (en) * | 1994-12-27 | 1997-05-06 | Asahi Denka Kogyo K.K. | Lubricating oil composition |
| JP2008075085A (ja) * | 2006-09-19 | 2008-04-03 | Infineum Internatl Ltd | 潤滑油組成物 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5391310A (en) * | 1993-11-23 | 1995-02-21 | Cincinnati Milacron Inc. | Sulfurized aqueous machining fluid composition |
| US7405185B2 (en) | 2003-09-26 | 2008-07-29 | Chevron Oronite Company Llc | Process for making Group II metal overbased sulfurized alkylphenols |
| US8933002B2 (en) * | 2011-11-10 | 2015-01-13 | Chevron Oronite Company Llc | Lubricating oil compositions |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3464970A (en) * | 1967-03-13 | 1969-09-02 | Maruzen Oil Co Ltd | Process for preparing over-based sulfurized calcium phenates |
| JPS5946262A (ja) * | 1982-06-24 | 1984-03-15 | ソシエテ・オロジル | 潤滑油用添加剤として使用できるアルカリ土金属の硫化アルキルフエナ−トの製造方法 |
| JPS6044595A (ja) * | 1983-07-11 | 1985-03-09 | オロジル | カルシウムを基にした高アルカリ度の清浄分散添加剤の製造方法 |
| JPS6272791A (ja) * | 1985-09-17 | 1987-04-03 | オロジル | 潤滑油用の加水分解に安定な新規高アルカリ性化洗浄剤・分散剤添加物およびそれらの製造方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3178368A (en) * | 1962-05-15 | 1965-04-13 | California Research Corp | Process for basic sulfurized metal phenates |
| NL134001C (US07652168-20100126-C00068.png) * | 1965-10-29 | |||
| US3367867A (en) * | 1966-01-04 | 1968-02-06 | Chevron Res | Low-foaming overbased phenates |
| US3424679A (en) * | 1966-08-15 | 1969-01-28 | Chevron Res | Nonvicinal glycols in overbased phenate preparation |
| GB1144084A (en) * | 1966-08-24 | 1969-03-05 | Orobis Ltd | Improvements in or relating to lubricant additives |
| GB1280749A (en) * | 1970-06-18 | 1972-07-05 | Maruzen Oil Company Ltd | Process for preparation of over-based sulphurized phenates |
| US3801507A (en) * | 1972-08-18 | 1974-04-02 | Chevron Res | Sulfurized metal phenates |
| GB1429243A (en) * | 1973-02-22 | 1976-03-24 | Orobis Ltd | Overbased phenates |
| GB1551819A (en) * | 1975-05-23 | 1979-09-05 | Exxon Research Engineering Co | Production of basic magnesium detergent additives |
| US4104180A (en) * | 1975-05-23 | 1978-08-01 | Exxon Research & Engineering Co. | Production of overbased metal phenates |
| FR2408648A1 (fr) * | 1977-11-11 | 1979-06-08 | Orobis Ltd | Procede de production de detergents a action dispersante, et compositions d'huiles lubrifiantes contenant un tel additif |
| EP0094814B1 (en) * | 1982-05-14 | 1989-04-19 | Exxon Research And Engineering Company | Lubricating oil additives |
-
1987
- 1987-07-20 NZ NZ221128A patent/NZ221128A/xx unknown
- 1987-07-28 CA CA000543119A patent/CA1341002C/en not_active Expired - Fee Related
- 1987-07-31 ZA ZA875686A patent/ZA875686B/xx unknown
- 1987-07-31 AU AU76334/87A patent/AU602343B2/en not_active Ceased
- 1987-08-06 DK DK410087A patent/DK410087A/da not_active Application Discontinuation
- 1987-08-07 JP JP62197989A patent/JPS6346297A/ja active Pending
- 1987-08-07 DE DE3785807T patent/DE3785807T3/de not_active Expired - Fee Related
- 1987-08-07 MX MX026955A patent/MX168483B/es unknown
- 1987-08-07 ES ES87307025T patent/ES2054677T3/es not_active Expired - Lifetime
- 1987-08-07 KR KR1019870008668A patent/KR880002818A/ko not_active Application Discontinuation
- 1987-08-07 BR BR8704053A patent/BR8704053A/pt not_active Application Discontinuation
- 1987-08-07 EP EP87307025A patent/EP0259974B2/en not_active Expired - Lifetime
- 1987-08-07 NO NO873316A patent/NO167659C/no unknown
- 1987-08-08 CN CN87105448A patent/CN1021345C/zh not_active Expired - Fee Related
-
1988
- 1988-01-05 IN IN05/MAS/88A patent/IN170575B/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3464970A (en) * | 1967-03-13 | 1969-09-02 | Maruzen Oil Co Ltd | Process for preparing over-based sulfurized calcium phenates |
| JPS5946262A (ja) * | 1982-06-24 | 1984-03-15 | ソシエテ・オロジル | 潤滑油用添加剤として使用できるアルカリ土金属の硫化アルキルフエナ−トの製造方法 |
| JPS6044595A (ja) * | 1983-07-11 | 1985-03-09 | オロジル | カルシウムを基にした高アルカリ度の清浄分散添加剤の製造方法 |
| JPS6272791A (ja) * | 1985-09-17 | 1987-04-03 | オロジル | 潤滑油用の加水分解に安定な新規高アルカリ性化洗浄剤・分散剤添加物およびそれらの製造方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5627146A (en) * | 1994-12-27 | 1997-05-06 | Asahi Denka Kogyo K.K. | Lubricating oil composition |
| JP2008075085A (ja) * | 2006-09-19 | 2008-04-03 | Infineum Internatl Ltd | 潤滑油組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3785807T3 (de) | 1997-06-12 |
| KR880002818A (ko) | 1988-05-11 |
| ZA875686B (en) | 1988-04-27 |
| AU7633487A (en) | 1988-02-11 |
| CN1021345C (zh) | 1993-06-23 |
| IN170575B (US07652168-20100126-C00068.png) | 1992-04-11 |
| DK410087A (da) | 1988-02-09 |
| CN87105448A (zh) | 1988-04-13 |
| AU602343B2 (en) | 1990-10-11 |
| EP0259974B1 (en) | 1993-05-12 |
| NO167659C (no) | 1991-11-27 |
| ES2054677T3 (es) | 1994-08-16 |
| BR8704053A (pt) | 1988-04-05 |
| NO873316L (no) | 1988-02-09 |
| EP0259974A3 (en) | 1988-08-10 |
| NO873316D0 (no) | 1987-08-07 |
| NO167659B (no) | 1991-08-19 |
| DE3785807D1 (de) | 1993-06-17 |
| DE3785807T2 (de) | 1993-10-07 |
| EP0259974A2 (en) | 1988-03-16 |
| CA1341002C (en) | 2000-05-30 |
| NZ221128A (en) | 1989-09-27 |
| EP0259974B2 (en) | 1997-03-26 |
| DK410087D0 (da) | 1987-08-06 |
| MX168483B (es) | 1993-05-26 |
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