JPS6336360B2 - - Google Patents
Info
- Publication number
- JPS6336360B2 JPS6336360B2 JP55153968A JP15396880A JPS6336360B2 JP S6336360 B2 JPS6336360 B2 JP S6336360B2 JP 55153968 A JP55153968 A JP 55153968A JP 15396880 A JP15396880 A JP 15396880A JP S6336360 B2 JPS6336360 B2 JP S6336360B2
- Authority
- JP
- Japan
- Prior art keywords
- softening
- fur
- compound
- general formula
- enzyme
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 claims description 34
- 102000004190 Enzymes Human genes 0.000 claims description 27
- 108090000790 Enzymes Proteins 0.000 claims description 27
- 150000003839 salts Chemical class 0.000 claims description 17
- 238000011282 treatment Methods 0.000 claims description 16
- 150000001875 compounds Chemical group 0.000 claims description 15
- 238000002791 soaking Methods 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 9
- 238000007654 immersion Methods 0.000 claims description 9
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- 125000000623 heterocyclic group Chemical group 0.000 claims description 4
- 229920000877 Melamine resin Polymers 0.000 claims description 3
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 claims description 3
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 3
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 2
- 102000035195 Peptidases Human genes 0.000 claims description 2
- 108091005804 Peptidases Proteins 0.000 claims description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 239000010985 leather Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000011593 sulfur Chemical group 0.000 claims 1
- 210000003491 skin Anatomy 0.000 description 19
- 229940088598 enzyme Drugs 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 210000004209 hair Anatomy 0.000 description 7
- 238000003860 storage Methods 0.000 description 6
- 230000001580 bacterial effect Effects 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 108010077805 Bacterial Proteins Proteins 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- 108010058643 Fungal Proteins Proteins 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 240000006439 Aspergillus oryzae Species 0.000 description 2
- 235000002247 Aspergillus oryzae Nutrition 0.000 description 2
- 241000193747 Bacillus firmus Species 0.000 description 2
- 235000014469 Bacillus subtilis Nutrition 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- -1 aromatic sulfates Chemical class 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 235000015277 pork Nutrition 0.000 description 2
- 230000002797 proteolythic effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 241000228212 Aspergillus Species 0.000 description 1
- 241000228197 Aspergillus flavus Species 0.000 description 1
- 241000228230 Aspergillus parasiticus Species 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 241000193375 Bacillus alcalophilus Species 0.000 description 1
- 241000194108 Bacillus licheniformis Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 241000283707 Capra Species 0.000 description 1
- 102000005593 Endopeptidases Human genes 0.000 description 1
- 108010059378 Endopeptidases Proteins 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 241000187747 Streptomyces Species 0.000 description 1
- 241000187392 Streptomyces griseus Species 0.000 description 1
- 101710172711 Structural protein Proteins 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 229940005348 bacillus firmus Drugs 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 244000309466 calf Species 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229940066758 endopeptidases Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 102000034240 fibrous proteins Human genes 0.000 description 1
- 108091005899 fibrous proteins Proteins 0.000 description 1
- 229960004198 guanidine Drugs 0.000 description 1
- 229960000789 guanidine hydrochloride Drugs 0.000 description 1
- PJJJBBJSCAKJQF-UHFFFAOYSA-N guanidinium chloride Chemical compound [Cl-].NC(N)=[NH2+] PJJJBBJSCAKJQF-UHFFFAOYSA-N 0.000 description 1
- 210000003780 hair follicle Anatomy 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 125000003607 serino group Chemical group [H]N([H])[C@]([H])(C(=O)[*])C(O[H])([H])[H] 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/04—Soaking
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Cosmetics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Coloring (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19792944461 DE2944461A1 (de) | 1979-11-03 | 1979-11-03 | Verfahren zum weichen von fellen und haeuten |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5674200A JPS5674200A (en) | 1981-06-19 |
JPS6336360B2 true JPS6336360B2 (US07534539-20090519-C00280.png) | 1988-07-20 |
Family
ID=6085088
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15396880A Granted JPS5674200A (en) | 1979-11-03 | 1980-11-04 | Method of softening stock fur and leather |
Country Status (10)
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3312840A1 (de) * | 1983-04-09 | 1984-10-11 | Röhm GmbH, 6100 Darmstadt | Verfahren zur nassentfettung von hautmaterial |
DE3533203A1 (de) * | 1985-09-18 | 1987-03-26 | Roehm Gmbh | Verwendung von phosphonsaeurederivaten als lederhilfsmittel |
DE3802640A1 (de) * | 1988-01-29 | 1989-08-03 | Roehm Gmbh | Haarerhaltendes aescherverfahren |
DE3922748B4 (de) * | 1989-07-11 | 2006-01-05 | Röhm GmbH & Co. KG | Enzymatisches Weichverfahren |
US8507102B1 (en) * | 2012-08-07 | 2013-08-13 | Fownes Brothers & Co., Inc. | Conductive leather materials and methods for making the same |
US10221519B2 (en) | 2014-12-10 | 2019-03-05 | Fownes Brothers & Co., Inc. | Water-repellant conductive fabrics and methods for making the same |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2033163A (en) * | 1932-05-25 | 1936-03-10 | Wallerstein Co Inc | Process of depilating and rating hides and a bate for these purposes |
US2212750A (en) * | 1939-02-16 | 1940-08-27 | Wallerstein Co Inc | Method of treating hides, skins, and pelts |
DE1046251B (de) * | 1957-01-22 | 1958-12-11 | Boehme Fettchemie Gmbh | Weichen von Haeuten und Fellen |
US3582254A (en) * | 1969-04-16 | 1971-06-01 | Gillette Co | Unhairing hides |
ES391930A1 (es) * | 1970-12-03 | 1973-06-16 | Roehm Gmbh | Procedimiento para el remojo de pellejos y cueros. |
ES421535A1 (es) * | 1973-01-13 | 1976-06-16 | Roehm Gmbh | Procedimiento para la preparacion de pellejos dispuestos para curtir a partir de cuero y pieles de origen animal. |
DE2813075A1 (de) * | 1978-03-25 | 1979-10-11 | Roehm Gmbh | Aufbereitungsverfahren von kollagenhaltigem rohmaterial |
DE2929844A1 (de) * | 1979-07-23 | 1981-02-26 | Roehm Gmbh | Weichverfahren |
-
1979
- 1979-11-03 DE DE19792944461 patent/DE2944461A1/de not_active Withdrawn
-
1980
- 1980-10-27 BR BR8006897A patent/BR8006897A/pt unknown
- 1980-10-27 US US06/201,048 patent/US4344762A/en not_active Expired - Lifetime
- 1980-10-29 FR FR8023111A patent/FR2468649A1/fr active Granted
- 1980-10-30 AU AU63859/80A patent/AU536064B2/en not_active Ceased
- 1980-10-31 ES ES496477A patent/ES8200144A1/es not_active Expired
- 1980-10-31 IT IT68678/80A patent/IT1141630B/it active
- 1980-11-03 IN IN791/DEL/80A patent/IN159807B/en unknown
- 1980-11-03 GB GB8035305A patent/GB2062002B/en not_active Expired
- 1980-11-04 JP JP15396880A patent/JPS5674200A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
FR2468649A1 (fr) | 1981-05-08 |
ES496477A0 (es) | 1981-10-16 |
AU536064B2 (en) | 1984-04-19 |
GB2062002A (en) | 1981-05-20 |
IT1141630B (it) | 1986-10-01 |
IT8068678A0 (it) | 1980-10-31 |
FR2468649B1 (US07534539-20090519-C00280.png) | 1984-08-24 |
ES8200144A1 (es) | 1981-10-16 |
US4344762A (en) | 1982-08-17 |
DE2944461A1 (de) | 1981-05-14 |
BR8006897A (pt) | 1981-05-05 |
GB2062002B (en) | 1983-05-25 |
AU6385980A (en) | 1981-05-07 |
IN159807B (US07534539-20090519-C00280.png) | 1987-06-06 |
JPS5674200A (en) | 1981-06-19 |
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