JPS6330314B2 - - Google Patents
Info
- Publication number
- JPS6330314B2 JPS6330314B2 JP7734485A JP7734485A JPS6330314B2 JP S6330314 B2 JPS6330314 B2 JP S6330314B2 JP 7734485 A JP7734485 A JP 7734485A JP 7734485 A JP7734485 A JP 7734485A JP S6330314 B2 JPS6330314 B2 JP S6330314B2
- Authority
- JP
- Japan
- Prior art keywords
- cyclic siloxane
- group
- acrylate
- following formula
- methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 Cyclic siloxane Chemical class 0.000 claims description 22
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 4
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 4
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 claims description 4
- 239000005052 trichlorosilane Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000007259 addition reaction Methods 0.000 claims 1
- 125000005641 methacryl group Chemical group 0.000 claims 1
- 230000002194 synthesizing effect Effects 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 125000005395 methacrylic acid group Chemical group 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- DOGMJCPBZJUYGB-UHFFFAOYSA-N 3-trichlorosilylpropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC[Si](Cl)(Cl)Cl DOGMJCPBZJUYGB-UHFFFAOYSA-N 0.000 description 3
- 238000005481 NMR spectroscopy Methods 0.000 description 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 3
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 1
- VCYDUTCMKSROID-UHFFFAOYSA-N 2,2,4,4,6,6-hexakis-phenyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound O1[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 VCYDUTCMKSROID-UHFFFAOYSA-N 0.000 description 1
- URZHQOCYXDNFGN-UHFFFAOYSA-N 2,4,6-trimethyl-2,4,6-tris(3,3,3-trifluoropropyl)-1,3,5,2,4,6-trioxatrisilinane Chemical compound FC(F)(F)CC[Si]1(C)O[Si](C)(CCC(F)(F)F)O[Si](C)(CCC(F)(F)F)O1 URZHQOCYXDNFGN-UHFFFAOYSA-N 0.000 description 1
- LEPRPXBFZRAOGU-UHFFFAOYSA-N 3-trichlorosilylpropyl prop-2-enoate Chemical compound Cl[Si](Cl)(Cl)CCCOC(=O)C=C LEPRPXBFZRAOGU-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229910020175 SiOH Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229920006268 silicone film Polymers 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7734485A JPS61236786A (ja) | 1985-04-11 | 1985-04-11 | 環状シロキサンおよびその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7734485A JPS61236786A (ja) | 1985-04-11 | 1985-04-11 | 環状シロキサンおよびその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61236786A JPS61236786A (ja) | 1986-10-22 |
| JPS6330314B2 true JPS6330314B2 (OSRAM) | 1988-06-17 |
Family
ID=13631301
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7734485A Granted JPS61236786A (ja) | 1985-04-11 | 1985-04-11 | 環状シロキサンおよびその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61236786A (OSRAM) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111116627A (zh) * | 2019-12-16 | 2020-05-08 | 株洲时代新材料科技股份有限公司 | 多功能硅烷偶联剂、其制备及在阻燃天然橡胶中的应用 |
| CN111269460A (zh) * | 2020-01-20 | 2020-06-12 | 株洲时代新材料科技股份有限公司 | 多功能硅烷偶联剂的应用、橡胶制品及制备方法 |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2978435B2 (ja) | 1996-01-24 | 1999-11-15 | チッソ株式会社 | アクリロキシプロピルシランの製造方法 |
| CN1060199C (zh) * | 1997-02-26 | 2001-01-03 | 罗晓京 | 烧烤食品器具用的防粘耐热涂料及其制备方法 |
| CN1061364C (zh) * | 1997-10-15 | 2001-01-31 | 上海市建筑科学研究院 | 涂料用硅丙树脂及其生产方法 |
| JP5278040B2 (ja) * | 2009-02-27 | 2013-09-04 | 信越化学工業株式会社 | 嵩高い置換基を有するシロキシ基含有シリル（メタ）アクリレート化合物及びその製造方法 |
| JP2025166284A (ja) * | 2024-04-24 | 2025-11-06 | 信越化学工業株式会社 | ラジカル重合性基含有環状オルガノシロキサン、その製造方法およびそれを含む硬化性組成物 |
-
1985
- 1985-04-11 JP JP7734485A patent/JPS61236786A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111116627A (zh) * | 2019-12-16 | 2020-05-08 | 株洲时代新材料科技股份有限公司 | 多功能硅烷偶联剂、其制备及在阻燃天然橡胶中的应用 |
| CN111116627B (zh) * | 2019-12-16 | 2022-09-27 | 株洲时代新材料科技股份有限公司 | 多功能硅烷偶联剂、其制备及在阻燃天然橡胶中的应用 |
| CN111269460A (zh) * | 2020-01-20 | 2020-06-12 | 株洲时代新材料科技股份有限公司 | 多功能硅烷偶联剂的应用、橡胶制品及制备方法 |
| CN111269460B (zh) * | 2020-01-20 | 2021-07-06 | 株洲时代新材料科技股份有限公司 | 多功能硅烷偶联剂的应用、橡胶制品及制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61236786A (ja) | 1986-10-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4646152B2 (ja) | 眼科デバイス製造用モノマー | |
| EP3385268A1 (en) | Linear organopolysiloxane having different functional groups at both terminals, and method for producing same | |
| US4665147A (en) | Novel methacrylated siloxanes | |
| JPH0662647B2 (ja) | 含フッ素有機ケイ素化合物 | |
| JPH0583568B2 (OSRAM) | ||
| US5049617A (en) | Organopolysiloxane compound | |
| JPS6330314B2 (OSRAM) | ||
| JPH06511463A (ja) | 改質表面を有する珪素またはシリカの基質、これの製造方法、新規なオルトエステル類およびこれの製造方法 | |
| JP2751622B2 (ja) | オルガノポリシロキサン及びその製造方法 | |
| JP5119843B2 (ja) | カゴ型シルセスキオキサン誘導体の製造方法 | |
| JPH0632904A (ja) | 含フッ素シロキサン化合物 | |
| CN107922442A (zh) | 具有（甲基）丙烯酸酯基团的有机硅化合物及用于制备其的方法 | |
| JP2655683B2 (ja) | ポリオルガノシロキサン | |
| JPH06298773A (ja) | ジオール置換有機ケイ素化合物及びその製造方法 | |
| JP2715652B2 (ja) | ハイドロジェンポリシロキサンの製造方法 | |
| JP2716346B2 (ja) | アルファ，オメガ−フェニルエチニルシロキサンモノマー、オリゴマー、及びそのポリマー | |
| JPH0377892A (ja) | 含フッ素有機けい素化合物及びその製造方法 | |
| JP2625604B2 (ja) | 含フッ素有機けい素化合物 | |
| JP2014101458A (ja) | オルガノポリシロキサン及びその製造方法 | |
| WO2017094392A1 (ja) | 両末端に異なる官能基を有する直鎖オルガノポリシロキサン、及びその製造方法 | |
| JP3622215B2 (ja) | 新規ポリシロキサンとその製造法 | |
| JP3674667B2 (ja) | （メタ）アクリロキシプロピル基を有するシクロテトラシロキサン及びその製造方法 | |
| JPH0848779A (ja) | オルガノポリシロキサンの製造方法 | |
| JP2551213B2 (ja) | 光ファイバ用コア材及び光ファイバ | |
| JPS6314787A (ja) | ２，４，６，８−テトラメチル−４，６，８−トリビニル−２−（３−メタクリロキシプロピル）シクロテトラシロキサン |