JPS6312086B2 - - Google Patents
Info
- Publication number
- JPS6312086B2 JPS6312086B2 JP53072436A JP7243678A JPS6312086B2 JP S6312086 B2 JPS6312086 B2 JP S6312086B2 JP 53072436 A JP53072436 A JP 53072436A JP 7243678 A JP7243678 A JP 7243678A JP S6312086 B2 JPS6312086 B2 JP S6312086B2
- Authority
- JP
- Japan
- Prior art keywords
- olefin
- propylene
- polymerization
- copolymer
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004711 α-olefin Substances 0.000 claims description 41
- 238000006116 polymerization reaction Methods 0.000 claims description 33
- 229920001577 copolymer Polymers 0.000 claims description 31
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 24
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 20
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 11
- -1 aluminum compound Chemical class 0.000 claims description 8
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 230000003213 activating effect Effects 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 28
- 229920000642 polymer Polymers 0.000 description 23
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 20
- 239000000843 powder Substances 0.000 description 15
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 238000007789 sealing Methods 0.000 description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
- 239000005977 Ethylene Substances 0.000 description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 8
- 229920006125 amorphous polymer Polymers 0.000 description 8
- 230000000903 blocking effect Effects 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 239000008096 xylene Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000004743 Polypropylene Substances 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 150000002367 halogens Chemical group 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 239000012442 inert solvent Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 239000011949 solid catalyst Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- 230000002087 whitening effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001545 azulenes Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7243678A JPS54162785A (en) | 1978-06-14 | 1978-06-14 | Production of crystalline propylene-alpha-olefin copolymer |
| BR7903705A BR7903705A (pt) | 1978-06-14 | 1979-06-12 | Processo para producao de um copolimero de propileno,copolprocesso para producao de um copolimero de propileno,copolimero de propileno e pelicula de polipropileno de camadas imero de propileno e pelicula de polipropileno de camadas multiplas multiplas |
| IT49388/79A IT1193760B (it) | 1978-06-14 | 1979-06-12 | Procedimento per produrre copolimeri di propilene e pellicola di polipropilene a piu' strati con esso ottenuta |
| DE2923754A DE2923754C3 (de) | 1978-06-14 | 1979-06-12 | Verfahren zur Herstellung eines Propylencopolymeren und dessen Verwendung in einem vielschichtigen Polypropylen-Propylencopolymer-Film |
| BE0/195712A BE876947A (fr) | 1978-06-14 | 1979-06-13 | Procede pour la production de copolymeres de propylene et pellicule de polypropylene a plusieurs couches |
| CA000329679A CA1198355A (en) | 1978-06-14 | 1979-06-13 | Multilayer polypropylene film |
| GB7920608A GB2027720B (en) | 1978-06-14 | 1979-06-13 | Process for producing a propylene copolymer and a multilayer polypropylene film |
| FR7915301A FR2428651B1 (fr) | 1978-06-14 | 1979-06-14 | Procede pour produire des copolymeres de propylene et une pellicule multicouche de polypropylene |
| NL7904659A NL190783C (nl) | 1978-06-14 | 1979-06-14 | Werkwijze voor de bereiding van een propeencopolymeer en multilaag polypropeenfilm. |
| GB08137613A GB2105651B (en) | 1978-06-14 | 1981-12-14 | Multi-layer polypropylene film |
| SG567/83A SG56783G (en) | 1978-06-14 | 1983-09-07 | Process for producing propylene copolymers |
| CA000469444A CA1215198A (en) | 1978-06-14 | 1984-12-05 | Process for producing propylene copolymers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7243678A JPS54162785A (en) | 1978-06-14 | 1978-06-14 | Production of crystalline propylene-alpha-olefin copolymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54162785A JPS54162785A (en) | 1979-12-24 |
| JPS6312086B2 true JPS6312086B2 (pt) | 1988-03-17 |
Family
ID=13489241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7243678A Granted JPS54162785A (en) | 1978-06-14 | 1978-06-14 | Production of crystalline propylene-alpha-olefin copolymer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS54162785A (pt) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5898315A (ja) * | 1981-12-07 | 1983-06-11 | Chisso Corp | ポリオレフイン共重合体の粉体流動性改良法 |
| JPS6065007A (ja) * | 1983-09-21 | 1985-04-13 | Chisso Corp | 架橋発泡用プロピレン・ブテン共重合体 |
| JPS6065008A (ja) * | 1983-09-21 | 1985-04-13 | Chisso Corp | 架橋発泡用エチレン・プロピレン・ブテン共重合体 |
| JP2533321B2 (ja) * | 1987-05-08 | 1996-09-11 | 住友化学工業株式会社 | ポリプロピレン積層フィルム |
| JPH085174B2 (ja) * | 1987-10-19 | 1996-01-24 | 三井石油化学工業株式会社 | ポリプロピレン複合積層成形体 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4935487A (pt) * | 1972-07-20 | 1974-04-02 | ||
| JPS5074595A (pt) * | 1973-11-02 | 1975-06-19 | ||
| JPS50128781A (pt) * | 1974-03-29 | 1975-10-11 | ||
| JPS5331787A (en) * | 1976-09-07 | 1978-03-25 | Chisso Corp | Polymerization of propylene using pre-activated catalyst |
-
1978
- 1978-06-14 JP JP7243678A patent/JPS54162785A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4935487A (pt) * | 1972-07-20 | 1974-04-02 | ||
| JPS5074595A (pt) * | 1973-11-02 | 1975-06-19 | ||
| JPS50128781A (pt) * | 1974-03-29 | 1975-10-11 | ||
| JPS5331787A (en) * | 1976-09-07 | 1978-03-25 | Chisso Corp | Polymerization of propylene using pre-activated catalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54162785A (en) | 1979-12-24 |
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