JPS629192B2 - - Google Patents

Info

Publication number

JPS629192B2

JPS629192B2 JP55160117A JP16011780A JPS629192B2 JP S629192 B2 JPS629192 B2 JP S629192B2 JP 55160117 A JP55160117 A JP 55160117A JP 16011780 A JP16011780 A JP 16011780A JP S629192 B2 JPS629192 B2 JP S629192B2

Authority

JP

Japan

Prior art keywords

cathode

exchange membrane

anode

cation exchange

flexible

Prior art date

1980-11-15

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Links

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• 239000012528 membrane Substances 0.000 claims description 52
• 238000005341 cation exchange Methods 0.000 claims description 41
• 239000003513 alkali Substances 0.000 claims description 14
• 238000005868 electrolysis reaction Methods 0.000 claims description 13
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 12
• 230000000694 effects Effects 0.000 claims description 7
• 238000000034 method Methods 0.000 description 26
• PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 21
• 239000003014 ion exchange membrane Substances 0.000 description 19
• 229910052751 metal Inorganic materials 0.000 description 19
• 239000002184 metal Substances 0.000 description 19
• 239000000178 monomer Substances 0.000 description 13
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
• 125000002843 carboxylic acid group Chemical group 0.000 description 11
• 229920001577 copolymer Polymers 0.000 description 11
• -1 hydroxide ions Chemical class 0.000 description 10
• 229910052759 nickel Inorganic materials 0.000 description 10
• 229920000642 polymer Polymers 0.000 description 9
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
• RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
• 239000011737 fluorine Substances 0.000 description 8
• 229910052731 fluorine Inorganic materials 0.000 description 8
• BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
• 229920001343 polytetrafluoroethylene Polymers 0.000 description 8
• 239000004810 polytetrafluoroethylene Substances 0.000 description 8
• 229910052719 titanium Inorganic materials 0.000 description 8
• 239000010936 titanium Substances 0.000 description 8
• YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 7
• 229910001854 alkali hydroxide Inorganic materials 0.000 description 7
• 150000008044 alkali metal hydroxides Chemical class 0.000 description 7
• 238000010586 diagram Methods 0.000 description 7
• 239000000463 material Substances 0.000 description 7
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
• 229910045601 alloy Inorganic materials 0.000 description 6
• 239000000956 alloy Substances 0.000 description 6
• 239000000460 chlorine Substances 0.000 description 6
• 229910052801 chlorine Inorganic materials 0.000 description 6
• 125000000524 functional group Chemical group 0.000 description 6
• 238000005342 ion exchange Methods 0.000 description 6
• 239000000203 mixture Substances 0.000 description 6
• 239000000243 solution Substances 0.000 description 5
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
• KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
• 125000004432 carbon atom Chemical group C* 0.000 description 4
• 239000003792 electrolyte Substances 0.000 description 4
• 239000007789 gas Substances 0.000 description 4
• 229910052739 hydrogen Inorganic materials 0.000 description 4
• 239000001257 hydrogen Substances 0.000 description 4
• 229910052742 iron Inorganic materials 0.000 description 4
• 238000000465 moulding Methods 0.000 description 4
• 230000000704 physical effect Effects 0.000 description 4
• 239000000843 powder Substances 0.000 description 4
• 238000003825 pressing Methods 0.000 description 4
• 235000011121 sodium hydroxide Nutrition 0.000 description 4
• 125000000542 sulfonic acid group Chemical group 0.000 description 4
• 229910052715 tantalum Inorganic materials 0.000 description 4
• GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 4
• XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 4
• 229910001887 tin oxide Inorganic materials 0.000 description 4
• NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
• FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
• ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
• QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
• 150000001247 metal acetylides Chemical class 0.000 description 3
• 229910052758 niobium Inorganic materials 0.000 description 3
• 239000010955 niobium Substances 0.000 description 3
• GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 3
• 150000004767 nitrides Chemical class 0.000 description 3
• 239000002245 particle Substances 0.000 description 3
• 229910052697 platinum Inorganic materials 0.000 description 3
• 238000006116 polymerization reaction Methods 0.000 description 3
• 239000011347 resin Substances 0.000 description 3
• 229920005989 resin Polymers 0.000 description 3
• BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
• 229910052718 tin Inorganic materials 0.000 description 3
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
• 229910052726 zirconium Inorganic materials 0.000 description 3
• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
• ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
• WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
• 150000001336 alkenes Chemical class 0.000 description 2
• 125000000217 alkyl group Chemical group 0.000 description 2
• 229910052787 antimony Inorganic materials 0.000 description 2
• WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
• 239000007864 aqueous solution Substances 0.000 description 2
• 230000015572 biosynthetic process Effects 0.000 description 2
• 229910052797 bismuth Inorganic materials 0.000 description 2
• JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
• 150000001732 carboxylic acid derivatives Chemical group 0.000 description 2
• 229910017052 cobalt Inorganic materials 0.000 description 2
• 239000010941 cobalt Substances 0.000 description 2
• GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
• 238000005516 engineering process Methods 0.000 description 2
• 239000004744 fabric Substances 0.000 description 2
• 229910052735 hafnium Inorganic materials 0.000 description 2
• VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
• 230000007062 hydrolysis Effects 0.000 description 2
• 238000006460 hydrolysis reaction Methods 0.000 description 2
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
• 229910052738 indium Inorganic materials 0.000 description 2
• APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
• 229910052741 iridium Inorganic materials 0.000 description 2
• GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
• 239000007788 liquid Substances 0.000 description 2
• KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
• 229910052750 molybdenum Inorganic materials 0.000 description 2
• 239000011733 molybdenum Substances 0.000 description 2
• 238000006386 neutralization reaction Methods 0.000 description 2
• JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
• 229910052763 palladium Inorganic materials 0.000 description 2
• 125000005010 perfluoroalkyl group Chemical group 0.000 description 2
• 230000035699 permeability Effects 0.000 description 2
• 239000011148 porous material Substances 0.000 description 2
• 229910052703 rhodium Inorganic materials 0.000 description 2
• 239000010948 rhodium Substances 0.000 description 2
• MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
• 229910001925 ruthenium oxide Inorganic materials 0.000 description 2
• WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 2
• 239000000725 suspension Substances 0.000 description 2
• 239000011135 tin Substances 0.000 description 2
• WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
• 229910052721 tungsten Inorganic materials 0.000 description 2
• 239000010937 tungsten Substances 0.000 description 2
• 229910052720 vanadium Inorganic materials 0.000 description 2
• LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
• 229920002554 vinyl polymer Polymers 0.000 description 2
• SUTQSIHGGHVXFK-UHFFFAOYSA-N 1,2,2-trifluoroethenylbenzene Chemical compound FC(F)=C(F)C1=CC=CC=C1 SUTQSIHGGHVXFK-UHFFFAOYSA-N 0.000 description 1
• ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
• LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
• 229910052684 Cerium Inorganic materials 0.000 description 1
• KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
• VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
• 239000005977 Ethylene Substances 0.000 description 1
• GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
• 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
• 239000004698 Polyethylene Substances 0.000 description 1
• 239000004743 Polypropylene Substances 0.000 description 1
• KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
• BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
• BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
• 239000004809 Teflon Substances 0.000 description 1
• 229920006362 Teflon® Polymers 0.000 description 1
• 229910052776 Thorium Inorganic materials 0.000 description 1
• 239000013504 Triton X-100 Substances 0.000 description 1
• 229920004890 Triton X-100 Polymers 0.000 description 1
• 239000002253 acid Substances 0.000 description 1
• 239000004480 active ingredient Substances 0.000 description 1
• 229910052783 alkali metal Inorganic materials 0.000 description 1
• 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
• 150000001340 alkali metals Chemical class 0.000 description 1
• 229910052782 aluminium Inorganic materials 0.000 description 1
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
• 239000010425 asbestos Substances 0.000 description 1
• 229910052790 beryllium Inorganic materials 0.000 description 1
• ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
• 229910052799 carbon Inorganic materials 0.000 description 1
• 238000005266 casting Methods 0.000 description 1
• 230000003197 catalytic effect Effects 0.000 description 1
• 239000003518 caustics Substances 0.000 description 1
• GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
• UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
• 229910052804 chromium Inorganic materials 0.000 description 1
• 239000011651 chromium Substances 0.000 description 1
• 239000004020 conductor Substances 0.000 description 1
• 238000007796 conventional method Methods 0.000 description 1
• 238000001816 cooling Methods 0.000 description 1
• 238000007334 copolymerization reaction Methods 0.000 description 1
• 238000005260 corrosion Methods 0.000 description 1
• 230000007797 corrosion Effects 0.000 description 1
• 239000006185 dispersion Substances 0.000 description 1
• 238000004134 energy conservation Methods 0.000 description 1
• 238000001125 extrusion Methods 0.000 description 1
• 238000001914 filtration Methods 0.000 description 1
• 125000001153 fluoro group Chemical group F* 0.000 description 1
• 229910052733 gallium Inorganic materials 0.000 description 1
• 229910052732 germanium Inorganic materials 0.000 description 1
• GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
• 239000010439 graphite Substances 0.000 description 1
• 229910002804 graphite Inorganic materials 0.000 description 1
• 150000008282 halocarbons Chemical class 0.000 description 1
• 238000011835 investigation Methods 0.000 description 1
• 150000002500 ions Chemical class 0.000 description 1
• 229910052746 lanthanum Inorganic materials 0.000 description 1
• FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
• 229910052753 mercury Inorganic materials 0.000 description 1
• 150000002739 metals Chemical class 0.000 description 1
• 238000002156 mixing Methods 0.000 description 1
• 229910000480 nickel oxide Inorganic materials 0.000 description 1
• 229910000510 noble metal Inorganic materials 0.000 description 1
• 239000012811 non-conductive material Substances 0.000 description 1
• 239000002736 nonionic surfactant Substances 0.000 description 1
• 239000004745 nonwoven fabric Substances 0.000 description 1
• GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
• 229920000573 polyethylene Polymers 0.000 description 1
• 229920000098 polyolefin Polymers 0.000 description 1
• 229920001155 polypropylene Polymers 0.000 description 1
• 239000001103 potassium chloride Substances 0.000 description 1
• 235000011164 potassium chloride Nutrition 0.000 description 1
• 230000002265 prevention Effects 0.000 description 1
• 230000002250 progressing effect Effects 0.000 description 1
• 125000001453 quaternary ammonium group Chemical group 0.000 description 1
• 230000005855 radiation Effects 0.000 description 1
• 229910052761 rare earth metal Inorganic materials 0.000 description 1
• 229910052895 riebeckite Inorganic materials 0.000 description 1
• 229910052707 ruthenium Inorganic materials 0.000 description 1
• 238000007650 screen-printing Methods 0.000 description 1
• 229910052711 selenium Inorganic materials 0.000 description 1
• 239000011669 selenium Substances 0.000 description 1
• 229910052709 silver Inorganic materials 0.000 description 1
• 239000004332 silver Substances 0.000 description 1
• 239000011780 sodium chloride Substances 0.000 description 1
• 239000002904 solvent Substances 0.000 description 1
• 239000010935 stainless steel Substances 0.000 description 1
• 229910001220 stainless steel Inorganic materials 0.000 description 1
• 238000003756 stirring Methods 0.000 description 1
• 239000000126 substance Substances 0.000 description 1
• 239000000758 substrate Substances 0.000 description 1
• 239000004094 surface-active agent Substances 0.000 description 1
• 238000012719 thermal polymerization Methods 0.000 description 1
• 229910052727 yttrium Inorganic materials 0.000 description 1
• VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1