JPS6243519B2 - - Google Patents
Info
- Publication number
- JPS6243519B2 JPS6243519B2 JP15830279A JP15830279A JPS6243519B2 JP S6243519 B2 JPS6243519 B2 JP S6243519B2 JP 15830279 A JP15830279 A JP 15830279A JP 15830279 A JP15830279 A JP 15830279A JP S6243519 B2 JPS6243519 B2 JP S6243519B2
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- radioactive
- waste liquid
- cesium
- ferrocyanide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010457 zeolite Substances 0.000 claims description 28
- 229910021536 Zeolite Inorganic materials 0.000 claims description 27
- 229910052792 caesium Inorganic materials 0.000 claims description 27
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 27
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 26
- 230000002285 radioactive effect Effects 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- 239000002699 waste material Substances 0.000 claims description 19
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 13
- 229910052802 copper Inorganic materials 0.000 claims description 13
- 239000010949 copper Substances 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 239000002901 radioactive waste Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000012530 fluid Substances 0.000 claims description 8
- 239000003463 adsorbent Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000012857 radioactive material Substances 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims 1
- 230000004992 fission Effects 0.000 description 7
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 5
- 239000008346 aqueous phase Substances 0.000 description 5
- 229910001431 copper ion Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 4
- 230000003588 decontaminative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- TVFDJXOCXUVLDH-OUBTZVSYSA-N cesium-134 Chemical class [134Cs] TVFDJXOCXUVLDH-OUBTZVSYSA-N 0.000 description 2
- TVFDJXOCXUVLDH-RNFDNDRNSA-N cesium-137 Chemical compound [137Cs] TVFDJXOCXUVLDH-RNFDNDRNSA-N 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- -1 cesium ions Chemical class 0.000 description 1
- TVFDJXOCXUVLDH-NJFSPNSNSA-N cesium-135 Chemical compound [135Cs] TVFDJXOCXUVLDH-NJFSPNSNSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001410 inorganic ion Inorganic materials 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000000276 potassium ferrocyanide Substances 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- JFALSRSLKYAFGM-OIOBTWANSA-N uranium-235 Chemical compound [235U] JFALSRSLKYAFGM-OIOBTWANSA-N 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15830279A JPS5679999A (en) | 1979-12-06 | 1979-12-06 | Radioactive waste processing method |
| US06/213,005 US4448711A (en) | 1979-12-06 | 1980-12-04 | Process for producing zeolite adsorbent and process for treating radioactive liquid waste with the zeolite adsorbent |
| DE3045921A DE3045921C2 (de) | 1979-12-06 | 1980-12-05 | Adsorbentien auf Zeolithbasis, ihre Herstellung sowie ihre Verwendung zur Behandlung radioaktiver Abwässer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15830279A JPS5679999A (en) | 1979-12-06 | 1979-12-06 | Radioactive waste processing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5679999A JPS5679999A (en) | 1981-06-30 |
| JPS6243519B2 true JPS6243519B2 (enrdf_load_stackoverflow) | 1987-09-14 |
Family
ID=15668641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15830279A Granted JPS5679999A (en) | 1979-12-06 | 1979-12-06 | Radioactive waste processing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5679999A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01155915U (enrdf_load_stackoverflow) * | 1988-03-29 | 1989-10-26 | ||
| WO2014010417A1 (ja) * | 2012-07-10 | 2014-01-16 | 東亞合成株式会社 | セシウム吸着材の製造方法およびセシウム吸着材 |
| WO2014010638A1 (ja) * | 2012-07-11 | 2014-01-16 | ユニオン昭和株式会社 | セシウム及びストロンチウムを含む多核種の元素の分離安定固定化方法 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62176913A (ja) * | 1986-01-29 | 1987-08-03 | Agency Of Ind Science & Technol | ナトリウム塩含有処理液からのセシウムの分離、回収方法 |
| JP5858473B2 (ja) * | 2011-05-06 | 2016-02-10 | 国立研究開発法人産業技術総合研究所 | 金属錯体を含む複合体及びそれを用いた放射性セシウム吸着材 |
| JP5250140B1 (ja) * | 2011-07-12 | 2013-07-31 | 三菱製紙株式会社 | 磁性吸着剤粒子 |
| JP5834272B2 (ja) * | 2011-09-20 | 2015-12-16 | 株式会社湘南数理研究会 | 汚染土の除染方法 |
| JP5866233B2 (ja) * | 2012-03-07 | 2016-02-17 | 大日精化工業株式会社 | 農園芸産物へのセシウムの移行を回避する方法 |
| JP5957276B2 (ja) * | 2012-04-26 | 2016-07-27 | 大日精化工業株式会社 | ポリビニルブチラール樹脂及びフェロシアン化金属化合物を含有するセシウム除去材及びセシウム除去材用ペレットの製造方法 |
| JP2014018734A (ja) * | 2012-07-18 | 2014-02-03 | Dainichiseika Color & Chem Mfg Co Ltd | 被覆ゼオライト粒子及びそれを含むセシウム除去材 |
| JP5750409B2 (ja) * | 2012-07-18 | 2015-07-22 | 株式会社神鋼環境ソリューション | 放射性セシウム量の推定方法 |
| JP5910397B2 (ja) * | 2012-07-31 | 2016-04-27 | 王子ホールディングス株式会社 | 防水シート |
| JP6347766B2 (ja) * | 2015-06-29 | 2018-06-27 | 学校法人近畿大学 | 放射性セシウム除去用コンクリート製品の製造方法、及び放射性セシウムの除去方法 |
-
1979
- 1979-12-06 JP JP15830279A patent/JPS5679999A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01155915U (enrdf_load_stackoverflow) * | 1988-03-29 | 1989-10-26 | ||
| WO2014010417A1 (ja) * | 2012-07-10 | 2014-01-16 | 東亞合成株式会社 | セシウム吸着材の製造方法およびセシウム吸着材 |
| WO2014010638A1 (ja) * | 2012-07-11 | 2014-01-16 | ユニオン昭和株式会社 | セシウム及びストロンチウムを含む多核種の元素の分離安定固定化方法 |
| JP2014016311A (ja) * | 2012-07-11 | 2014-01-30 | Union Showa Kk | セシウム及びストロンチウムを含む多核種の元素の分離安定固定化方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5679999A (en) | 1981-06-30 |
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