JPS62256708A - Coの精製方法 - Google Patents
Coの精製方法Info
- Publication number
- JPS62256708A JPS62256708A JP61098509A JP9850986A JPS62256708A JP S62256708 A JPS62256708 A JP S62256708A JP 61098509 A JP61098509 A JP 61098509A JP 9850986 A JP9850986 A JP 9850986A JP S62256708 A JPS62256708 A JP S62256708A
- Authority
- JP
- Japan
- Prior art keywords
- copper
- gas
- contg
- solution
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 35
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- 239000010949 copper Substances 0.000 claims abstract description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 4
- -1 metal complex salt Chemical class 0.000 claims description 4
- 230000006866 deterioration Effects 0.000 abstract description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract description 2
- 239000005751 Copper oxide Substances 0.000 abstract description 2
- 229910052804 chromium Inorganic materials 0.000 abstract description 2
- 229910000431 copper oxide Inorganic materials 0.000 abstract description 2
- RYGMFSIKBFXOCR-AHCXROLUSA-N copper-60 Chemical compound [60Cu] RYGMFSIKBFXOCR-AHCXROLUSA-N 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 229910052759 nickel Inorganic materials 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 239000011701 zinc Substances 0.000 abstract description 2
- 229910052725 zinc Inorganic materials 0.000 abstract description 2
- 239000011787 zinc oxide Substances 0.000 abstract description 2
- 239000008246 gaseous mixture Substances 0.000 abstract 4
- 238000006392 deoxygenation reaction Methods 0.000 abstract 3
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 42
- 239000000243 solution Substances 0.000 description 33
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 13
- 239000007788 liquid Substances 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 9
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 8
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000007791 dehumidification Methods 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 229910021536 Zeolite Inorganic materials 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 239000010457 zeolite Substances 0.000 description 4
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 3
- 229940045803 cuprous chloride Drugs 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000002879 Lewis base Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000009291 secondary effect Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/40—Carbon monoxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Industrial Gases (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61098509A JPS62256708A (ja) | 1986-04-28 | 1986-04-28 | Coの精製方法 |
AU72116/87A AU586333B2 (en) | 1986-04-28 | 1987-04-27 | Method of purifying CO |
DE19873714126 DE3714126A1 (de) | 1986-04-28 | 1987-04-28 | Verfahren zum reinigen von co |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61098509A JPS62256708A (ja) | 1986-04-28 | 1986-04-28 | Coの精製方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62256708A true JPS62256708A (ja) | 1987-11-09 |
JPH048368B2 JPH048368B2 (enrdf_load_html_response) | 1992-02-14 |
Family
ID=14221616
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61098509A Granted JPS62256708A (ja) | 1986-04-28 | 1986-04-28 | Coの精製方法 |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPS62256708A (enrdf_load_html_response) |
AU (1) | AU586333B2 (enrdf_load_html_response) |
DE (1) | DE3714126A1 (enrdf_load_html_response) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010202426A (ja) * | 2009-02-27 | 2010-09-16 | Mitsubishi Heavy Ind Ltd | Co2回収装置及びその方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57145018A (en) * | 1981-03-04 | 1982-09-07 | Babcock Hitachi Kk | Separating and concentrating method of carbon monoxide |
JPS59206317A (ja) * | 1983-05-06 | 1984-11-22 | エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− | 銅(i)錯体による一酸化炭素及び不飽和炭化水素の分離回収 |
JPS60151207A (ja) * | 1984-01-20 | 1985-08-09 | Mitsubishi Heavy Ind Ltd | 一酸化炭素分離法 |
JPS60161317A (ja) * | 1984-01-31 | 1985-08-23 | Kansai Coke & Chem Co Ltd | 一酸化炭素を主成分とする含酸素ガスから酸素を除去する方法 |
JPS60187336A (ja) * | 1984-03-05 | 1985-09-24 | Chiyoda Chem Eng & Constr Co Ltd | 一酸化炭素の吸収剤 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2031475A (en) * | 1931-06-25 | 1936-02-18 | Joseph C W Frazer | Oxidizing catalysts |
US3776972A (en) * | 1972-06-02 | 1973-12-04 | Exxon Research Engineering Co | Ligand complexes of cu(i)salts |
DE3017998C2 (de) * | 1980-05-10 | 1994-05-26 | Krupp Koppers Gmbh | Verfahren zur katalytischen Behandlung von Partialoxidationsrohgas |
DE3243206A1 (de) * | 1982-11-23 | 1984-05-24 | Basf Ag, 6700 Ludwigshafen | Verfahren zur reinigung von co und/oder co(pfeil abwaerts)2(pfeil abwaerts) enthaltenden gasen |
-
1986
- 1986-04-28 JP JP61098509A patent/JPS62256708A/ja active Granted
-
1987
- 1987-04-27 AU AU72116/87A patent/AU586333B2/en not_active Ceased
- 1987-04-28 DE DE19873714126 patent/DE3714126A1/de active Granted
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57145018A (en) * | 1981-03-04 | 1982-09-07 | Babcock Hitachi Kk | Separating and concentrating method of carbon monoxide |
JPS59206317A (ja) * | 1983-05-06 | 1984-11-22 | エクソン・リサ−チ・アンド・エンジニアリング・カンパニ− | 銅(i)錯体による一酸化炭素及び不飽和炭化水素の分離回収 |
JPS60151207A (ja) * | 1984-01-20 | 1985-08-09 | Mitsubishi Heavy Ind Ltd | 一酸化炭素分離法 |
JPS60161317A (ja) * | 1984-01-31 | 1985-08-23 | Kansai Coke & Chem Co Ltd | 一酸化炭素を主成分とする含酸素ガスから酸素を除去する方法 |
JPS60187336A (ja) * | 1984-03-05 | 1985-09-24 | Chiyoda Chem Eng & Constr Co Ltd | 一酸化炭素の吸収剤 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010202426A (ja) * | 2009-02-27 | 2010-09-16 | Mitsubishi Heavy Ind Ltd | Co2回収装置及びその方法 |
US8377184B2 (en) | 2009-02-27 | 2013-02-19 | Mitsubishi Heavy Industries, Ltd. | CO2 recovery apparatus and CO2 recovery method |
Also Published As
Publication number | Publication date |
---|---|
AU7211687A (en) | 1987-11-12 |
DE3714126A1 (de) | 1987-10-29 |
JPH048368B2 (enrdf_load_html_response) | 1992-02-14 |
DE3714126C2 (enrdf_load_html_response) | 1989-08-03 |
AU586333B2 (en) | 1989-07-06 |
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