JPS621577B2 - - Google Patents
Info
- Publication number
- JPS621577B2 JPS621577B2 JP57195843A JP19584382A JPS621577B2 JP S621577 B2 JPS621577 B2 JP S621577B2 JP 57195843 A JP57195843 A JP 57195843A JP 19584382 A JP19584382 A JP 19584382A JP S621577 B2 JPS621577 B2 JP S621577B2
- Authority
- JP
- Japan
- Prior art keywords
- exchange resin
- ion exchange
- resin
- uranium
- ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011347 resin Substances 0.000 claims description 34
- 229920005989 resin Polymers 0.000 claims description 34
- 239000003456 ion exchange resin Substances 0.000 claims description 30
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 30
- 239000000243 solution Substances 0.000 claims description 25
- 229910052768 actinide Inorganic materials 0.000 claims description 22
- 239000003957 anion exchange resin Substances 0.000 claims description 18
- -1 Actinide ions Chemical class 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 16
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 14
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 13
- 229910017604 nitric acid Inorganic materials 0.000 claims description 13
- 238000010828 elution Methods 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 125000003277 amino group Chemical group 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000007857 degradation product Substances 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims 1
- 229910052770 Uranium Inorganic materials 0.000 description 26
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 26
- 238000002474 experimental method Methods 0.000 description 17
- 238000001179 sorption measurement Methods 0.000 description 12
- 229910052778 Plutonium Inorganic materials 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 150000001255 actinides Chemical class 0.000 description 7
- OYEHPCDNVJXUIW-UHFFFAOYSA-N plutonium atom Chemical compound [Pu] OYEHPCDNVJXUIW-UHFFFAOYSA-N 0.000 description 7
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- 150000001450 anions Chemical class 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 5
- 229910052781 Neptunium Inorganic materials 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- LFNLGNPSGWYGGD-UHFFFAOYSA-N neptunium atom Chemical compound [Np] LFNLGNPSGWYGGD-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000007790 solid phase Substances 0.000 description 4
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical compound CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 description 3
- 229920001429 chelating resin Polymers 0.000 description 3
- 239000003480 eluent Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000003758 nuclear fuel Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- BNMJSBUIDQYHIN-UHFFFAOYSA-N butyl dihydrogen phosphate Chemical compound CCCCOP(O)(O)=O BNMJSBUIDQYHIN-UHFFFAOYSA-N 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920003053 polystyrene-divinylbenzene Polymers 0.000 description 2
- 238000012958 reprocessing Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- YPNPCVTYEPGNDZ-UHFFFAOYSA-H [U+6].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O Chemical compound [U+6].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O YPNPCVTYEPGNDZ-UHFFFAOYSA-H 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910002005 actinide nitrate Inorganic materials 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000002901 radioactive waste Substances 0.000 description 1
- 238000003608 radiolysis reaction Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- DSERHVOICOPXEJ-UHFFFAOYSA-L uranyl carbonate Chemical class [U+2].[O-]C([O-])=O DSERHVOICOPXEJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G56/00—Compounds of transuranic elements
- C01G56/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
- C01G56/002—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange by adsorption or by ion-exchange on a solid support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3144974.3 | 1981-11-12 | ||
| DE3144974A DE3144974C2 (de) | 1981-11-12 | 1981-11-12 | Verfahren zur Abtrennung von Aktinoidenionen aus wäßrigen, basischen, carbonathaltigen Lösungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5895616A JPS5895616A (ja) | 1983-06-07 |
| JPS621577B2 true JPS621577B2 (US07413550-20080819-C00001.png) | 1987-01-14 |
Family
ID=6146249
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57195843A Granted JPS5895616A (ja) | 1981-11-12 | 1982-11-08 | 塩基性水溶液からアクチノイドイオンを分離する方法 |
Country Status (7)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6422267U (US07413550-20080819-C00001.png) * | 1987-07-29 | 1989-02-06 | ||
| JPS6452464U (US07413550-20080819-C00001.png) * | 1987-09-26 | 1989-03-31 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4606895A (en) * | 1983-11-09 | 1986-08-19 | Mobil Oil Corporation | Ion exchange loading |
| DE3428877A1 (de) * | 1984-08-04 | 1986-02-13 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur trennung von grossen mengen uran von geringen mengen von radioaktiven spaltprodukten, die in waessrigen basischen, karbonathaltigen loesungen vorliegen |
| DE3428878A1 (de) * | 1984-08-04 | 1986-02-13 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur rueckgewinnung von uran-werten in einem extraktiven wiederaufarbeitungsprozess fuer bestrahlte kernbrennstoffe |
| JP4294253B2 (ja) * | 2002-03-18 | 2009-07-08 | オルガノ株式会社 | 陰イオン性金属錯体の除去方法 |
| JP4114076B2 (ja) * | 2004-02-17 | 2008-07-09 | 独立行政法人 日本原子力研究開発機構 | アクチノイド元素の分離方法 |
| DE102004022705B4 (de) * | 2004-05-05 | 2012-05-31 | Atc-Advanced Technologies Dr. Mann Gmbh | Verfahren zur Abtrennung von Uranspecies aus Wasser und Verwendung eines schwachbasischen Anionenaustauschers hierfür |
| EP1669607B1 (en) * | 2004-12-13 | 2010-04-21 | Ingersoll-Rand Company | Compressor lubricant system including acid filtration |
| WO2009076629A2 (en) * | 2007-12-12 | 2009-06-18 | The Regents Of The University Of Michigan | Compositions and methods for treating cancer |
| KR100961832B1 (ko) * | 2008-04-25 | 2010-06-08 | 한국원자력연구원 | 고 알카리 탄산염 용액 계를 사용하는 사용후핵연료의우라늄 분리회수방법과 그 장치 |
| CN207038182U (zh) * | 2017-03-29 | 2018-02-23 | 泰拉能源有限责任公司 | 铯收集器 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2864667A (en) * | 1953-06-16 | 1958-12-16 | Richard H Bailes | Anionic exchange process for the recovery of uranium and vanadium from carbonate solutions |
| BE538248A (US07413550-20080819-C00001.png) * | 1954-05-20 | |||
| GB805745A (en) * | 1956-07-02 | 1958-12-10 | Permutit Co Ltd | Improvements relating to the recovery of uranium by ion exchange |
| US3835044A (en) * | 1972-10-16 | 1974-09-10 | Atomic Energy Commission | Process for separating neptunium from thorium |
| US4026987A (en) * | 1974-10-11 | 1977-05-31 | Rohm And Haas Company | Recovery of uranium sulfate anions on a weak base anion exchange resin |
| JPS51143198A (en) * | 1975-06-03 | 1976-12-09 | Asahi Chem Ind Co Ltd | New separation method |
| DE2627540A1 (de) * | 1976-06-19 | 1978-01-05 | Uranerzbergbau Gmbh & Co Kg | Verfahren zur selektiven trennung von uran aus loesungen mittels eines ionenaustauschers |
| US4199470A (en) * | 1977-05-13 | 1980-04-22 | Koei Chemical Co., Ltd. | Material for recovering uranium and method for recovering a uranium solution of high purity and high concentration, using the same |
| US4312838A (en) * | 1979-08-27 | 1982-01-26 | Mobil Oil Corporation | Ion exchange resins of high loading capacity, high chloride tolerance and rapid elution for uranium recovery |
| US4423008A (en) * | 1979-10-01 | 1983-12-27 | Mobil Oil Corporation | Direct acid elution of anionic exchange resins for recovery of uranium |
-
1981
- 1981-11-12 DE DE3144974A patent/DE3144974C2/de not_active Expired
-
1982
- 1982-08-25 FR FR8214613A patent/FR2516068B1/fr not_active Expired
- 1982-10-27 GB GB08230634A patent/GB2111850B/en not_active Expired
- 1982-10-27 BE BE1/10622A patent/BE894818A/fr not_active IP Right Cessation
- 1982-10-28 US US06/437,511 patent/US4460547A/en not_active Expired - Fee Related
- 1982-11-08 JP JP57195843A patent/JPS5895616A/ja active Granted
- 1982-11-11 BR BR8206570A patent/BR8206570A/pt unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6422267U (US07413550-20080819-C00001.png) * | 1987-07-29 | 1989-02-06 | ||
| JPS6452464U (US07413550-20080819-C00001.png) * | 1987-09-26 | 1989-03-31 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3144974C2 (de) | 1986-01-09 |
| DE3144974A1 (de) | 1983-05-19 |
| GB2111850B (en) | 1985-01-09 |
| FR2516068B1 (fr) | 1987-04-24 |
| JPS5895616A (ja) | 1983-06-07 |
| GB2111850A (en) | 1983-07-13 |
| BE894818A (fr) | 1983-02-14 |
| US4460547A (en) | 1984-07-17 |
| BR8206570A (pt) | 1983-09-27 |
| FR2516068A1 (fr) | 1983-05-13 |
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