JPS6215676B2 - - Google Patents
Info
- Publication number
- JPS6215676B2 JPS6215676B2 JP54057867A JP5786779A JPS6215676B2 JP S6215676 B2 JPS6215676 B2 JP S6215676B2 JP 54057867 A JP54057867 A JP 54057867A JP 5786779 A JP5786779 A JP 5786779A JP S6215676 B2 JPS6215676 B2 JP S6215676B2
- Authority
- JP
- Japan
- Prior art keywords
- following structure
- formula
- chloride
- alkyl group
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 claims description 41
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 30
- 229920003043 Cellulose fiber Polymers 0.000 claims description 20
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 20
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 19
- -1 mordants Substances 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 13
- 239000000986 disperse dye Substances 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 13
- 238000010023 transfer printing Methods 0.000 claims description 13
- 239000000975 dye Substances 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 239000000835 fiber Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 239000000344 soap Substances 0.000 claims description 5
- 229920002994 synthetic fiber Polymers 0.000 claims description 5
- 239000012209 synthetic fiber Substances 0.000 claims description 5
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- 229910052788 barium Inorganic materials 0.000 claims description 4
- 229910052793 cadmium Inorganic materials 0.000 claims description 4
- 239000003431 cross linking reagent Substances 0.000 claims description 4
- 238000004043 dyeing Methods 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- 239000000981 basic dye Substances 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 3
- 238000010017 direct printing Methods 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 229910052745 lead Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 59
- YYROPELSRYBVMQ-UHFFFAOYSA-N 4-toluenesulfonyl chloride Chemical compound CC1=CC=C(S(Cl)(=O)=O)C=C1 YYROPELSRYBVMQ-UHFFFAOYSA-N 0.000 description 38
- 239000003795 chemical substances by application Substances 0.000 description 20
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000000243 solution Substances 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 13
- 238000005406 washing Methods 0.000 description 13
- 238000012546 transfer Methods 0.000 description 12
- 239000003513 alkali Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 238000001035 drying Methods 0.000 description 10
- 238000010025 steaming Methods 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 229920000728 polyester Polymers 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 8
- 238000007385 chemical modification Methods 0.000 description 8
- 238000012986 modification Methods 0.000 description 8
- 230000004048 modification Effects 0.000 description 8
- 229920002678 cellulose Polymers 0.000 description 7
- 239000001913 cellulose Substances 0.000 description 7
- 229920006395 saturated elastomer Polymers 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000002407 reforming Methods 0.000 description 6
- 235000011121 sodium hydroxide Nutrition 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 5
- 239000012345 acetylating agent Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- 238000007070 tosylation reaction Methods 0.000 description 5
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 150000001805 chlorine compounds Chemical class 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 4
- 239000002516 radical scavenger Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 3
- 239000005695 Ammonium acetate Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 150000003973 alkyl amines Chemical class 0.000 description 3
- 229940043376 ammonium acetate Drugs 0.000 description 3
- 235000019257 ammonium acetate Nutrition 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 3
- 239000011654 magnesium acetate Substances 0.000 description 3
- 235000011285 magnesium acetate Nutrition 0.000 description 3
- 229940069446 magnesium acetate Drugs 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 235000011118 potassium hydroxide Nutrition 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 238000000859 sublimation Methods 0.000 description 3
- 230000008022 sublimation Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- WPHUUIODWRNJLO-UHFFFAOYSA-N 2-nitrobenzenesulfonyl chloride Chemical compound [O-][N+](=O)C1=CC=CC=C1S(Cl)(=O)=O WPHUUIODWRNJLO-UHFFFAOYSA-N 0.000 description 2
- NIJZFHNDUJXJMR-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethanol Chemical compound C1C(CO)CCC2OC21 NIJZFHNDUJXJMR-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 241000156978 Erebia Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- NPAIMXWXWPJRES-UHFFFAOYSA-N butyltin(3+) Chemical compound CCCC[Sn+3] NPAIMXWXWPJRES-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- IIFKGJGNMKYHLT-FGSKAQBVSA-N dibutyltin;dimethyl (z)-but-2-enedioate Chemical compound CCCC[Sn]CCCC.COC(=O)\C=C/C(=O)OC IIFKGJGNMKYHLT-FGSKAQBVSA-N 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000983 mordant dye Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 235000011056 potassium acetate Nutrition 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- JNZRDLWZFWFSBK-UHFFFAOYSA-N tribenzyltin Chemical compound C=1C=CC=CC=1C[Sn](CC=1C=CC=CC=1)CC1=CC=CC=C1 JNZRDLWZFWFSBK-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- PMZIUAOBHNJYQT-UHFFFAOYSA-N (1-hydroxy-2-methylpropan-2-yl)azanium;chloride Chemical compound Cl.CC(C)(N)CO PMZIUAOBHNJYQT-UHFFFAOYSA-N 0.000 description 1
- VTWGIDKXXZRLGH-HJWRWDBZSA-N (z)-4-octoxy-4-oxobut-2-enoic acid Chemical compound CCCCCCCCOC(=O)\C=C/C(O)=O VTWGIDKXXZRLGH-HJWRWDBZSA-N 0.000 description 1
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- UYVWNPAMKCDKRB-UHFFFAOYSA-N 1,2,4,5-tetraoxane Chemical compound C1OOCOO1 UYVWNPAMKCDKRB-UHFFFAOYSA-N 0.000 description 1
- UUGLSEIATNSHRI-UHFFFAOYSA-N 1,3,4,6-tetrakis(hydroxymethyl)-3a,6a-dihydroimidazo[4,5-d]imidazole-2,5-dione Chemical compound OCN1C(=O)N(CO)C2C1N(CO)C(=O)N2CO UUGLSEIATNSHRI-UHFFFAOYSA-N 0.000 description 1
- HZUBBVGKQQJUME-UHFFFAOYSA-N 1,5-diamino-2-bromo-4,8-dihydroxyanthracene-9,10-dione Chemical compound O=C1C2=C(N)C(Br)=CC(O)=C2C(=O)C2=C1C(O)=CC=C2N HZUBBVGKQQJUME-UHFFFAOYSA-N 0.000 description 1
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- ZBBLRPRYYSJUCZ-UHFFFAOYSA-L 2,2-dibutyl-1,3,2-dioxastannepine-4,7-dione Chemical compound CCCC[Sn]1(CCCC)OC(=O)C=CC(=O)O1 ZBBLRPRYYSJUCZ-UHFFFAOYSA-L 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- ZGHZSTWONPNWHV-UHFFFAOYSA-N 2-(oxiran-2-yl)ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCC1CO1 ZGHZSTWONPNWHV-UHFFFAOYSA-N 0.000 description 1
- XYOSFLPUWVWHOA-UHFFFAOYSA-N 2-ethylidenepropane-1,3-diol;urea Chemical compound NC(N)=O.CC=C(CO)CO XYOSFLPUWVWHOA-UHFFFAOYSA-N 0.000 description 1
- PMUNIMVZCACZBB-UHFFFAOYSA-N 2-hydroxyethylazanium;chloride Chemical compound Cl.NCCO PMUNIMVZCACZBB-UHFFFAOYSA-N 0.000 description 1
- HDECRAPHCDXMIJ-UHFFFAOYSA-N 2-methylbenzenesulfonyl chloride Chemical compound CC1=CC=CC=C1S(Cl)(=O)=O HDECRAPHCDXMIJ-UHFFFAOYSA-N 0.000 description 1
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 description 1
- AOSPVUKRNAQARI-UHFFFAOYSA-N 2-n-(trimethoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COC(OC)(OC)NC1=NC(N)=NC(N)=N1 AOSPVUKRNAQARI-UHFFFAOYSA-N 0.000 description 1
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- MWWNNNAOGWPTQY-UHFFFAOYSA-N 3-nitrobenzenesulfonyl chloride Chemical compound [O-][N+](=O)C1=CC=CC(S(Cl)(=O)=O)=C1 MWWNNNAOGWPTQY-UHFFFAOYSA-N 0.000 description 1
- ZEYUSQVGRCPBPG-UHFFFAOYSA-N 4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one Chemical compound OCN1C(O)C(O)N(CO)C1=O ZEYUSQVGRCPBPG-UHFFFAOYSA-N 0.000 description 1
- JXRGUPLJCCDGKG-UHFFFAOYSA-N 4-nitrobenzenesulfonyl chloride Chemical compound [O-][N+](=O)C1=CC=C(S(Cl)(=O)=O)C=C1 JXRGUPLJCCDGKG-UHFFFAOYSA-N 0.000 description 1
- UKWUOTZGXIZAJC-UHFFFAOYSA-N 4-nitrosalicylic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1O UKWUOTZGXIZAJC-UHFFFAOYSA-N 0.000 description 1
- MEOFBWPFVVBHJF-UHFFFAOYSA-N 6-(2-hydroxyethyl)-1,4-bis(hydroxymethyl)-1,3,5-triazin-2-one Chemical compound OCCC1=NC(CO)=NC(=O)N1CO MEOFBWPFVVBHJF-UHFFFAOYSA-N 0.000 description 1
- ABXXXZLVKKIAGK-UHFFFAOYSA-N 6-methylheptyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCC1OC1CCCCCCCC(=O)OCCCCCC(C)C ABXXXZLVKKIAGK-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- KTGXQGRPFBVOLY-UDVCPWNYSA-L C(\C=C/C(=O)[O-])(=O)OCOC.C(CCC)[Sn+2]CCCC.COCOC(\C=C/C(=O)[O-])=O Chemical compound C(\C=C/C(=O)[O-])(=O)OCOC.C(CCC)[Sn+2]CCCC.COCOC(\C=C/C(=O)[O-])=O KTGXQGRPFBVOLY-UDVCPWNYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 1
- POIVNIHWEVEKNT-UHFFFAOYSA-N NC(=O)N.C(O)C(=O)C=O Chemical compound NC(=O)N.C(O)C(=O)C=O POIVNIHWEVEKNT-UHFFFAOYSA-N 0.000 description 1
- SVNIJTWPCZBRKV-UHFFFAOYSA-N NC(=O)N.NC(=O)N.C(O)C(=O)C=O Chemical compound NC(=O)N.NC(=O)N.C(O)C(=O)C=O SVNIJTWPCZBRKV-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- RAKMKCZMVZBODU-PIQLPZBWSA-L barium(2+);(z)-12-hydroxyoctadec-9-enoate Chemical compound [Ba+2].CCCCCCC(O)C\C=C/CCCCCCCC([O-])=O.CCCCCCC(O)C\C=C/CCCCCCCC([O-])=O RAKMKCZMVZBODU-PIQLPZBWSA-L 0.000 description 1
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- UUVBPJKVXXWZBO-NICPUWLCSA-N bis[(z)-octadec-9-enyl] (z)-but-2-enedioate;dibutyltin Chemical compound CCCC[Sn]CCCC.CCCCCCCC\C=C/CCCCCCCCOC(=O)\C=C/C(=O)OCCCCCCCC\C=C/CCCCCCCC UUVBPJKVXXWZBO-NICPUWLCSA-N 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- GWOWVOYJLHSRJJ-UHFFFAOYSA-L cadmium stearate Chemical compound [Cd+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O GWOWVOYJLHSRJJ-UHFFFAOYSA-L 0.000 description 1
- RXROCZREIWVERD-UHFFFAOYSA-L cadmium(2+);2-ethylhexanoate Chemical compound [Cd+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O RXROCZREIWVERD-UHFFFAOYSA-L 0.000 description 1
- ITQVEYJXZXMBTR-UHFFFAOYSA-L cadmium(2+);dodecanoate Chemical compound [Cd+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O ITQVEYJXZXMBTR-UHFFFAOYSA-L 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- CHNPVIBKPFVVQK-UHFFFAOYSA-L dibutyltin(2+);2-octyl-2-sulfanyldecanoate Chemical compound CCCC[Sn+2]CCCC.CCCCCCCCC(S)(C([O-])=O)CCCCCCCC.CCCCCCCCC(S)(C([O-])=O)CCCCCCCC CHNPVIBKPFVVQK-UHFFFAOYSA-L 0.000 description 1
- VAVCJRXBEBWZTI-OHDVSKATSA-L dibutyltin(2+);dodecanoate;(z)-4-methoxy-4-oxobut-2-enoate Chemical compound CCCC[Sn+2]CCCC.COC(=O)\C=C/C([O-])=O.CCCCCCCCCCCC([O-])=O VAVCJRXBEBWZTI-OHDVSKATSA-L 0.000 description 1
- WRZAGCUJZBBAAW-SWJSCKDZSA-N dibutyltin;dioctyl (z)-but-2-enedioate Chemical compound CCCC[Sn]CCCC.CCCCCCCCOC(=O)\C=C/C(=O)OCCCCCCCC WRZAGCUJZBBAAW-SWJSCKDZSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical compound CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 description 1
- 229950010007 dimantine Drugs 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229940073579 ethanolamine hydrochloride Drugs 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- SJOCPYUKFOTDAN-ZSOIEALJSA-N methyl (4z)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophene-1-carboxylate Chemical compound C1C(C)(C)C\C(=N\O)C=2C1=C(C(=O)OC)SC=2SC SJOCPYUKFOTDAN-ZSOIEALJSA-N 0.000 description 1
- SXVDZIOMWSPFCO-UHFFFAOYSA-N methyl n,n-bis(hydroxymethyl)carbamate Chemical compound COC(=O)N(CO)CO SXVDZIOMWSPFCO-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N monoethanolamine hydrochloride Natural products NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- TXSUIVPRHHQNTM-UHFFFAOYSA-N n'-(3-methylanilino)-n-phenyliminobenzenecarboximidamide Chemical compound CC1=CC=CC(NN=C(N=NC=2C=CC=CC=2)C=2C=CC=CC=2)=C1 TXSUIVPRHHQNTM-UHFFFAOYSA-N 0.000 description 1
- NHLUVTZJQOJKCC-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)C NHLUVTZJQOJKCC-UHFFFAOYSA-N 0.000 description 1
- SFBHPFQSSDCYSL-UHFFFAOYSA-N n,n-dimethyltetradecan-1-amine Chemical compound CCCCCCCCCCCCCCN(C)C SFBHPFQSSDCYSL-UHFFFAOYSA-N 0.000 description 1
- OMEMQVZNTDHENJ-UHFFFAOYSA-N n-methyldodecan-1-amine Chemical compound CCCCCCCCCCCCNC OMEMQVZNTDHENJ-UHFFFAOYSA-N 0.000 description 1
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- JFOJYGMDZRCSPA-UHFFFAOYSA-J octadecanoate;tin(4+) Chemical compound [Sn+4].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O JFOJYGMDZRCSPA-UHFFFAOYSA-J 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 1
- 229940066675 ricinoleate Drugs 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- FRKHZXHEZFADLA-UHFFFAOYSA-L strontium;octadecanoate Chemical compound [Sr+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O FRKHZXHEZFADLA-UHFFFAOYSA-L 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 125000002088 tosyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])[H])S(*)(=O)=O 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 description 1
- 229940100530 zinc ricinoleate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229940057977 zinc stearate Drugs 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Coloring (AREA)
Description
æ¬çºæã¯ãã»ã«ããŒã¹ç¹ç¶åã¯ãããå«ãæ§é
ç©ã®æè²æ¹æ³ã«é¢ããã åŸæ¥ãããåæ£ææçã®æ¬æ¥ã»ã«ããŒã¹ç¹ç¶ã«
æçæ§ãæããªãææãçšããŠã»ã«ããŒã¹ç¹ç¶ã
è¯å¥œã«æè²ããããšããè©Šã¿çãæ°å€ããªãããŠ
ããããããã®è©Šã¿ã¯äž»ã«åæ£ææã䜿çšããæ
è¯è»¢åæºææ³ã®çºéã«äŒŽã€ãŠæ°å€ããªããäŸãã°
ç¹æ®ãªåæ£ææãšèšæœ€å€ã䜿çšããç¹å ¬æ47â
40593ãã也åŒè»¢åæºææ¹æ³ã«æŒãŠæš¹èåŠçæ¹æ³
ã«ããç¹å ¬æ47â51734ãæ¶æ©å€ãèšæœ€å€ã䜵çš
ããç¹éæ50â12389ãç¹éæ50â38213ãç¹éæ
50â90788ãç¹å ¬æ50â29552ãªã©ã®äž»ã«ç¹ç¶åŠç
æ¹æ³ã«ãããã®ããéåžžã¯åæ£ææã«èŠªåæ§ã®ãª
ãã»ã«ããŒã¹ç¹ç¶ãååŠçã«ã¢ã»ãã«åå€ããã³
ãŸã€ã«åå€ãªã©ã®è¬å€ãçšããŠæ¹è³ªããããšã«ã
ã€ãŠåæ£ææã«èŠªåæ§ãæããæ§ãšããç¹éæ50
â18778ãç¹éæ51â99185ãªã©ãç¥ãããŠããã
ããããªããããããã®äžèšç¹ç¶åŠçå€æ¹æ³ã«ã
ããã®ã¯ãæ¯èŒçç°¡åãªè£ 眮ã䜿çšããããšã«ã
ãå¯èœã§ããããçºè²æ§ã«æŒããŠé®®æãã«æ¬ ãã
ããšããæè²å ç¢åºŠç¹ã«æ¹¿æœ€å ç¢åºŠãè¯å¥œã§ãª
ããäžæ¹ã»ã«ããŒã¹ãååŠæ¹è³ªãããšããã®åŸæ¥
ããç¥ãããŠããæ¹æ³ã§ã¯ãäžèšè¬å€èªèº«ã®åºæ¿
æ§åã³èæ°ãªã©ããäœæ¥æ§ãæªããäžã€éåžžã«é«
䟡ãªèšåæè³ãå¿ èŠãšããã äŸãã°ã¢ã»ãã«åå€ããã³ãŸã€ã«åå€ãçšããŠ
ååŠæ¹è³ªããåŸã転åæºæããæ¹æ³çããããã
ã¢ã»ãã«åå€ããã³ãŸã€ã«åå€çã¯åºæ¿æ§ã®ãã
èæ°ãæããå空æ°äžã«é·ãä¿åããŠãããšå æ°Ž
å解ããããããšããæ¬ ç¹ããããã©ãããŠãã
ããåŒåã¯ããã«é¡äŒŒããããã»ã¹ã«ããåå¿ã
è¡ãã»ãã¯ãªãã€ããåãã¢ã»ãã«åå€ãçšããŠ
ååŠæ¹è³ªãããã®ã¯ãèæŽæ¿¯å ç¢åºŠãæªããšãã
æ¬ ç¹ãããã ãããã®åé¡ã解決ããçºãçºæè çã¯ã»ã«ã
ãŒã¹ç¹ç¶åã¯ã»ã«ããŒã¹ç¹ç¶ãå«ãæ··åæ§é ç©ã«
察ããäºãâãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®
é žå¡©åç©ãçšããŠãã»ã«ããŒã¹ãåæ£ææå¯ææ§
ã«ååŠæ¹è³ªãããã®åŸãåæ£ææã油溶æ§ææã
åªæææãå¡©åºæ§ææçãçšããŠæºæããæ¹æ³ã
èæ¡ããã æ¬çºæã®ïŒ°âãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®
é žå¡©åç©ãçšããŠã®ååŠæ¹è³ªã¯ãè©Šè¬ã®èæ°ãå
ã³ç©ºæ°äžã§ã®å æ°Žå解ãã¢ã»ãã«åå€ããã³ãŸã€
ã«åå€ã«æ¯ã¹ãŠå°ãããåãæ±ãã容æã§ããã
ãã®æ¹è³ªæ¹æ³ãé«äŸ¡ãªèšåãå¿ èŠãšãããæ¯èŒç
ç°¡åãªè£ 眮ã§ååŠæ¹è³ªãå¯èœã«ããããšãã§ã
ãã ããã§åŸæ¥ãããâãã«ãšã³ã¹ã«ããã«ã¯ã
ãªããçšããã»ã«ããŒã¹ã®ååŠæ¹è³ªæ¹æ³ã¯ãã¶ãž
ã€ãŒãã«ãªãã¢ã¡ãªã«ã³ã±ãã«ã«ãœãµã€ã¢ãã€ãŒ
第72å·»670ã674ããŒãžïŒ1950幎ïŒãããã¹ã¿ã€ã«
ãªãµãŒããžã€ãŒãã«ç¬¬32å·»797ã804ããŒãžïŒ1962
幎ïŒãããã¹ã¿ã€ã«ãªãµãŒããžã€ãŒãã«ç¬¬33å·»107
ã117ããŒãžïŒ1963幎ïŒãªã©çš®ã ã®æç®ã«å ±åã
ããŠãããããããã®æ¹æ³ã¯æ¹è³ªæéãé·ããå
æ±ãã®é£ãããè©Šè¬ã䜵çšãããããŠå·¥æ¥çã«ã¯
äžåããšèãããããŸãæè²æ§ãæ¹è¯ããããã®
ãã®ã§ã¯ãªããããã«å¯Ÿããæ¬çºæã¯ã»ã«ããŒã¹
ç¹ç¶ã®åæ£ææçãžã®æè²æ§ãåäžãããç®çã§
âãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®é žå¡©åç©ã
çšããŠæ¯èŒçç°¡åãªè£ 眮ã§å®çšé¢åã³çç£æ§ãå«
ããååŠæ¹è³ªæ³ãæ€èšãããã®ã§ããã ããªãã¡ããããããã»ã«ããŒã¹ç¹ç¶ã«ã¢ã«ã«
ãªå€ã§åŠçããåŸã«ïŒ°âãã«ãšã³ã¹ã«ããã«ã¯ã
ãªãçã®é žå¡©åç©ãåŠçãã次ãã§å¿ èŠã«å¿ã觊
åªãåŠçããæŽã«èžç±åŠçåã¯ä¹Ÿç±åŠçãè¡ãæ¹
質åžãåŸãæ¹æ³ãå®çšé¢ãçç£é¢ããè¯å¥œãªãã
ã»ã¹ã§ããããšãèŠãåºããå ããŠåå¿ããã»ã¹
ã®éçšã«æŒãŠäœããã®æ¹æ³ã«ããå¡©åæ°ŽçŽ ãäžæŽ»
æ§ã«ããååç©ãå ±åãããããšã«ãããäžå±€ã
å®çšé¢ãçç£é¢ããå¹æã®é«ãããã»ã¹ãèŠãåº
ããã 以äžãæ¬çºæã詳现ã«èšãã æ¹è³ªããã»ã¹ãšããŠã¯æç®ãªã©ã«èšèŒãããŠã
ãæ§ãªãã¢ã«ã«ãªã»ã«ããŒã¹ã«ããŠããâãã«
ãšã³ã¹ã«ããã«ã¯ããªã溶液äžã§åå¿ãããæ¹æ³
ãããã ãããã®ããã»ã¹ã§ã¯ãå§ãã®ãã¡ã¯ãè¯å¥œã«
åå¿ãé²ã¿æ¹è³ªãè¡ãããããé€ã ã«æ¹è³ªãããª
ããªããããã¯ãâãã«ãšã³ã¹ã«ããã«ã¯ããª
ã溶液äžã«ã¢ã«ã«ãªå€åã³æ°Žåãæ··å ¥ããåå¿ã«
é¢äžããªãâãã«ãšã³ã¹ã«ããã«ã¯ããªããŸã§
ãå æ°Žå解ãããçºã§ãããè©Šè¬ã®æµªè²»ã«ç¹ãã
å®çšçã§ãªãããšãããã€ãã ããã§çºæè çã¯éæç 究ã®çµæãåžå°ãå§ã
ã«ã¢ã«ã«ãªå€æº¶æ¶²ã«æµžæŒ¬ããã¢ã«ã«ãªã®åŠçéã
åäžã«ãªãæ§ã«äžå®ã®å²åã«çµã€ãåŸã«ä¹Ÿç¥ã
ãã次ã«ãããâãã«ãšã³ã¹ã«ããã«ã¯ããªã
çã®é žå¡©åç©ãäžå®éå«ã溶液ã«æµžæŒ¬ããåŠçé
ãåäžã«ãªãæ§ã«äžå®ã®å²åã«çµã€ãåŸã«ä¹Ÿç¥ã
ããããã«ããã«å¿ èŠã«å¿ã觊åªåŠçãæœããã
ãã«èžç±åŠçåã¯ä¹Ÿç±åŠçãæœãããšããã極ã
ãŠç°¡åã«ã»ã«ããŒã¹ã®ååŠæ¹è³ªãè¡ãããããšã
èŠåºããã ããã§èžç±åŠçæ¡ä»¶ãšããŠã¯100âã180âã®åžž
å§ã®é£œåèžæ°åã¯éç±èžæ°ãããã¯100âã140â
ã®é«æž©é«å§ã®é£œåèžæ°ã«ãŠ30ç§ã20åéåŠçãã
ããšã«ããè¯å¥œãªçµæãåŸãããšãã§ãã也ç±åŠ
çæ¡ä»¶ãšããŠã¯60âã180âã§30ç§ã20åéããŒ
ãã³ã°ããããšã«ããæ¯èŒçè¯å¥œãªçµæãåŸãã
ãšãã§ãããçºæè çã®å®éšçµæã§ã¯ä¹Ÿç±åŠçã
ããèžç±åŠçã®æ¹ããããè¯å¥œãªãçµæãåŸãã
ãããã®çç±ãšããŠã¯èžç±åŠçã§ã¯ä¹Ÿç±åŠçã«æ¯
ã¹ãŠãããããã¢ã«ã«ãªåŠçãããã»ã«ããŒã¹ç¹
ç¶ãâãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®é žå¡©å
ç©ã«ããååŠæ¹è³ªãããïŒä»¥äžãã·ã«åãšç§°ã
ãïŒéã«ãã»ã«ããŒã¹ã®èšæœ€ç¶æ ãèžç±ã«ããä¿
ããããŸãŸãã·ã«åãããããã«ã極ããŠå¹æç
ã«åå¿ãé²è¡ãããããšå€æããããã®æ§ãªèã
æ¹ã¯ãåèšå ¬ç¥ã®æç®ã«ã玹ä»ãããŠãããæ¬çº
æã®ç¹èšãã¹ãããšã®äžã€ã§ããã以äžã®æ§ãªæ¹
æ³ã¯ãâãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®é žå¡©
åç©åã³ã¢ã«ã«ãªå€ã®æµªè²»ãªã©ããªãå®çšçã§ã
ããé£ç¶åãå¯èœã§ãããçç£æ§ã«æŒãŠè¯å¥œã§ã
ãã ããããªãããããã§ïŒ°âãã«ãšã³ã¹ã«ããã«
ã¯ããªãçã®é žå¡©åç©ã®ç¹åŸŽãšããŠãåå¿ã®å¯ç
æç©ãšããŠå¿ ãå¡©åæ°ŽçŽ ãçºçãããããªãã¡ã
ãã·ã«ååå¿ãé²è¡ããå Žåããããã¯åçŽã«ïŒ°
âãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®é žå¡©åç©ãå
æ°Žå解ããå Žåãããããå¡©åæ°ŽçŽ ã®çºçã䌎ã
匷ãé žæ§ãåããã åšç¥ã®æ§ã«å¡©åæ°ŽçŽ ããªãã¡å¡©é žã¯åŒ·é žæ§ãå
ãããšåæã«åŒ·åãªéå±è èæ§ãæããæ¯èŒçé
é£ããšãããŠããéåžžã®ã¹ãã³ã¬ã¹ã®æ§ãªéå±ã
ãè èãããåŸã€ãŠæ¬çºæã§è¿°ã¹ãâãã«ãšã³
ã¹ã«ããã«ã¯ããªãçã®é žå¡©åç©ãçšããåå¿ã
çŸåšãæè²æŽç粟緎ãªã©ã«äœ¿çšãããŠããå å·¥æ©
ã§ããã¹ããŒããŒã也ç¥æ©ãçšããŠè¡ãããšãã
ãšããããã®å å·¥æ©ãè èãæå·ããããããã
ã§ä»®ã«å å·¥æ©ã«èå¡©é žæ§ã®è¯å¥œãªæ質ãçšãã
ããã°ã©ã¹ã©ã€ãã³ã°çã®èé žå å·¥ãæœãããã
ããšå å·¥æ©ã®ã³ã¹ãã¯é«ããã®ãšãªãããé«äŸ¡ãª
èšåãå¿ èŠãšãããæ¯èŒçç°¡åãªè£ 眮ã§ååŠæ¹è³ª
ãå¯èœãšããããšããæ¬çºæã®äž»æšã«åããããš
ã«ãªããå ããŠåå¿ç³»ã«å¡©åæ°ŽçŽ ãå€éã«çºçã
ããšããããšã¯ãåå¿äžã«åžå°ãèããå£åãã
ãæããããããã®æ§ã«åå¿ã®å¯çæç©ã§ããå¡©
åæ°ŽçŽ ã¯æ¥µããŠæ害ã§ããé€å»ãããäžæŽ»æ§ã«ã
ãããšãæãŸããã ãã®å¯Ÿçã®äžã€ãšããŠèããããæ¹æ³ãšããŠã
ãããããç¹ç¶ã«æœãã¢ã«ã«ãªå€ãéå°ã«åŠçã
ãŠãããçããŠããå¡©åæ°ŽçŽ ãã¢ã«ã«ãªå€ã«ãã
å³äžåãããšããæ¹æ³ãèããããããã¢ã«ã«ãª
å€ãšé žå¡©åç©ã®ã¢ã«æ¯ã«äžé£åãçããæ¹è³ªåå¿
ã¯é²è¡ããªããªãã ããã§çºæè çã¯éæç 究ã®çµæãåå¿ã®éçš
ã§äœããã®æ¹æ³ã«ãããâãã«ãšã³ã¹ã«ããã«
ã¯ããªãçã®é žå¡©åç©ãšå¡©åæ°ŽçŽ ãäžæŽ»æ§ãšãã
ååç©ãå ±åããããããåŸã«èžç±åŠçåã¯ä¹Ÿç±
åŠçãæœãããšã«ãããã®åé¡ã解決ã§ããããš
ãèŠåºããã ããã«è¿°ã¹ãå¡©åæ°ŽçŽ ãäžæŽ»æ§ãšããååç©ãš
ã¯ããã·ã«ååå¿ã«ã¯æ®ãã©é¢äžããªãã§çºçå¡©
é žãææããæ§è³ªãæãããã®åã³çºçå¡©é žã®æ
æã¯ããªãããå¡©é žã®ååšäžã§éå±ã®è èæ§ãè
ããé ããããã®çãå«ãŸããã ãããå¡©åæ°ŽçŽ ãäžæŽ»æ§ãšããååç©ãšã¯å ·äœ
çã«ã¯ ã¹ãã¢ãªã³é žã«ãããŠã ãã©ãŠãªã³é žã«ãããŠ
ã ããªã·ããŒã«é žã«ãããŠã ããããã³é žã«ã
ããŠã ãïŒãšãã«ãããœã€ã³é žã«ãããŠã ãã¹
ãã¢ãªã³é žããªãŠã ãã©ãŠãªã³é žããªãŠã ããª
ã·ããŒã«é žããªãŠã ããããã³é žããªãŠã ãïŒ
ãšãã«ãããœã€ã³é žããªãŠã ãã¹ãã¢ãªã³é žã«
ã«ã·ãŠã ããªã·ããŒã«é žã«ã«ã·ãŠã ãã¹ãã¢ãª
ã³é žã¹ããã³ããŠã ãã¹ãã¢ãªã³é žäºéãã©ãŠ
ãªã³é žäºéããªã·ããŒã«é žäºéãïŒãšãã«ãã
ãœã€ã³é žäºéãã¹ãã¢ãªã³é žéãäºå¡©åºæ§ã¹ã
ã¢ãªã³é žéããããã³é žéãã¹ãã¢ãªã³é žã¹
ãºãã¹ãã¢ãªã³é žã¢ã«ãããŠã ãã¹ãã¢ãªã³é ž
ãã°ãã·ãŠã ãªã©ã®ãäžèšæ§é ïŒïŒã®éå±ç³ãã () ïŒïŒOOCRïŒ2åã¯AlïŒOOCRïŒ2OH ïŒïŒã¯CaãBaãZnãSnãMgãCdãPbãªã©ã®
éå±ãã¯ã¢ã«ãã«åºãæå³ããïŒ ãããã¯æ¬¡ã«ç€ºããããããªææ©ã¹ãºååç© äŸãã°ã¢ãããã«ã¹ãºããªã¡ãã«ãã¬ãšãŒãã
ã¢ãããã«ã¹ãºããªãªã¯ãã«ãã¬ãšãŒãããžãã
ã«ã¹ãºãžã©ãŠã¬ãŒãããžããã«ã¹ãºã©ãŠã¬ãŒãã¡
ãã«ãã¬ãšãŒãããžããã«ã¹ãºãžãªã¬ã€ã«ãã¬ãš
ãŒãããžããã«ã¹ãºãžã¡ãã«ãã¬ãšãŒãããžãã
ã«ã¹ãºãã¬ãšãŒãããžããã«ã¹ãºã¡ããã·ã¡ãã«
ãã¬ãšãŒãããžããã«ã¹ãºãã¬ãšãŒããšãžããã«
ã¹ãºãžã¡ãã«ãã¬ãšãŒãã®æ··åç©ããžããã«ã¹ãº
ãžãªã¯ãã«ãã¬ãšãŒãããžããã«ã¹ãºãžãªã¯ãã«
ããªã°ãªã³ã¬ãŒãããžããã«ã¹ãºãžã©ãŠãªã«ã¡ã«
ã«ãã¿ã€ããããªãã³ãžã«ã¹ãºãªã¯ãã«ãã¬ãšãŒ
ããããªãã³ãžã«ã¹ãºããªã¡ãã«ãã¬ãšãŒã ãããã¯ãŸãã () äžèšæ§é ã®èèªæãšããã·ååç©
ç©ã®æè²æ¹æ³ã«é¢ããã åŸæ¥ãããåæ£ææçã®æ¬æ¥ã»ã«ããŒã¹ç¹ç¶ã«
æçæ§ãæããªãææãçšããŠã»ã«ããŒã¹ç¹ç¶ã
è¯å¥œã«æè²ããããšããè©Šã¿çãæ°å€ããªãããŠ
ããããããã®è©Šã¿ã¯äž»ã«åæ£ææã䜿çšããæ
è¯è»¢åæºææ³ã®çºéã«äŒŽã€ãŠæ°å€ããªããäŸãã°
ç¹æ®ãªåæ£ææãšèšæœ€å€ã䜿çšããç¹å ¬æ47â
40593ãã也åŒè»¢åæºææ¹æ³ã«æŒãŠæš¹èåŠçæ¹æ³
ã«ããç¹å ¬æ47â51734ãæ¶æ©å€ãèšæœ€å€ã䜵çš
ããç¹éæ50â12389ãç¹éæ50â38213ãç¹éæ
50â90788ãç¹å ¬æ50â29552ãªã©ã®äž»ã«ç¹ç¶åŠç
æ¹æ³ã«ãããã®ããéåžžã¯åæ£ææã«èŠªåæ§ã®ãª
ãã»ã«ããŒã¹ç¹ç¶ãååŠçã«ã¢ã»ãã«åå€ããã³
ãŸã€ã«åå€ãªã©ã®è¬å€ãçšããŠæ¹è³ªããããšã«ã
ã€ãŠåæ£ææã«èŠªåæ§ãæããæ§ãšããç¹éæ50
â18778ãç¹éæ51â99185ãªã©ãç¥ãããŠããã
ããããªããããããã®äžèšç¹ç¶åŠçå€æ¹æ³ã«ã
ããã®ã¯ãæ¯èŒçç°¡åãªè£ 眮ã䜿çšããããšã«ã
ãå¯èœã§ããããçºè²æ§ã«æŒããŠé®®æãã«æ¬ ãã
ããšããæè²å ç¢åºŠç¹ã«æ¹¿æœ€å ç¢åºŠãè¯å¥œã§ãª
ããäžæ¹ã»ã«ããŒã¹ãååŠæ¹è³ªãããšããã®åŸæ¥
ããç¥ãããŠããæ¹æ³ã§ã¯ãäžèšè¬å€èªèº«ã®åºæ¿
æ§åã³èæ°ãªã©ããäœæ¥æ§ãæªããäžã€éåžžã«é«
䟡ãªèšåæè³ãå¿ èŠãšããã äŸãã°ã¢ã»ãã«åå€ããã³ãŸã€ã«åå€ãçšããŠ
ååŠæ¹è³ªããåŸã転åæºæããæ¹æ³çããããã
ã¢ã»ãã«åå€ããã³ãŸã€ã«åå€çã¯åºæ¿æ§ã®ãã
èæ°ãæããå空æ°äžã«é·ãä¿åããŠãããšå æ°Ž
å解ããããããšããæ¬ ç¹ããããã©ãããŠãã
ããåŒåã¯ããã«é¡äŒŒããããã»ã¹ã«ããåå¿ã
è¡ãã»ãã¯ãªãã€ããåãã¢ã»ãã«åå€ãçšããŠ
ååŠæ¹è³ªãããã®ã¯ãèæŽæ¿¯å ç¢åºŠãæªããšãã
æ¬ ç¹ãããã ãããã®åé¡ã解決ããçºãçºæè çã¯ã»ã«ã
ãŒã¹ç¹ç¶åã¯ã»ã«ããŒã¹ç¹ç¶ãå«ãæ··åæ§é ç©ã«
察ããäºãâãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®
é žå¡©åç©ãçšããŠãã»ã«ããŒã¹ãåæ£ææå¯ææ§
ã«ååŠæ¹è³ªãããã®åŸãåæ£ææã油溶æ§ææã
åªæææãå¡©åºæ§ææçãçšããŠæºæããæ¹æ³ã
èæ¡ããã æ¬çºæã®ïŒ°âãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®
é žå¡©åç©ãçšããŠã®ååŠæ¹è³ªã¯ãè©Šè¬ã®èæ°ãå
ã³ç©ºæ°äžã§ã®å æ°Žå解ãã¢ã»ãã«åå€ããã³ãŸã€
ã«åå€ã«æ¯ã¹ãŠå°ãããåãæ±ãã容æã§ããã
ãã®æ¹è³ªæ¹æ³ãé«äŸ¡ãªèšåãå¿ èŠãšãããæ¯èŒç
ç°¡åãªè£ 眮ã§ååŠæ¹è³ªãå¯èœã«ããããšãã§ã
ãã ããã§åŸæ¥ãããâãã«ãšã³ã¹ã«ããã«ã¯ã
ãªããçšããã»ã«ããŒã¹ã®ååŠæ¹è³ªæ¹æ³ã¯ãã¶ãž
ã€ãŒãã«ãªãã¢ã¡ãªã«ã³ã±ãã«ã«ãœãµã€ã¢ãã€ãŒ
第72å·»670ã674ããŒãžïŒ1950幎ïŒãããã¹ã¿ã€ã«
ãªãµãŒããžã€ãŒãã«ç¬¬32å·»797ã804ããŒãžïŒ1962
幎ïŒãããã¹ã¿ã€ã«ãªãµãŒããžã€ãŒãã«ç¬¬33å·»107
ã117ããŒãžïŒ1963幎ïŒãªã©çš®ã ã®æç®ã«å ±åã
ããŠãããããããã®æ¹æ³ã¯æ¹è³ªæéãé·ããå
æ±ãã®é£ãããè©Šè¬ã䜵çšãããããŠå·¥æ¥çã«ã¯
äžåããšèãããããŸãæè²æ§ãæ¹è¯ããããã®
ãã®ã§ã¯ãªããããã«å¯Ÿããæ¬çºæã¯ã»ã«ããŒã¹
ç¹ç¶ã®åæ£ææçãžã®æè²æ§ãåäžãããç®çã§
âãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®é žå¡©åç©ã
çšããŠæ¯èŒçç°¡åãªè£ 眮ã§å®çšé¢åã³çç£æ§ãå«
ããååŠæ¹è³ªæ³ãæ€èšãããã®ã§ããã ããªãã¡ããããããã»ã«ããŒã¹ç¹ç¶ã«ã¢ã«ã«
ãªå€ã§åŠçããåŸã«ïŒ°âãã«ãšã³ã¹ã«ããã«ã¯ã
ãªãçã®é žå¡©åç©ãåŠçãã次ãã§å¿ èŠã«å¿ã觊
åªãåŠçããæŽã«èžç±åŠçåã¯ä¹Ÿç±åŠçãè¡ãæ¹
質åžãåŸãæ¹æ³ãå®çšé¢ãçç£é¢ããè¯å¥œãªãã
ã»ã¹ã§ããããšãèŠãåºããå ããŠåå¿ããã»ã¹
ã®éçšã«æŒãŠäœããã®æ¹æ³ã«ããå¡©åæ°ŽçŽ ãäžæŽ»
æ§ã«ããååç©ãå ±åãããããšã«ãããäžå±€ã
å®çšé¢ãçç£é¢ããå¹æã®é«ãããã»ã¹ãèŠãåº
ããã 以äžãæ¬çºæã詳现ã«èšãã æ¹è³ªããã»ã¹ãšããŠã¯æç®ãªã©ã«èšèŒãããŠã
ãæ§ãªãã¢ã«ã«ãªã»ã«ããŒã¹ã«ããŠããâãã«
ãšã³ã¹ã«ããã«ã¯ããªã溶液äžã§åå¿ãããæ¹æ³
ãããã ãããã®ããã»ã¹ã§ã¯ãå§ãã®ãã¡ã¯ãè¯å¥œã«
åå¿ãé²ã¿æ¹è³ªãè¡ãããããé€ã ã«æ¹è³ªãããª
ããªããããã¯ãâãã«ãšã³ã¹ã«ããã«ã¯ããª
ã溶液äžã«ã¢ã«ã«ãªå€åã³æ°Žåãæ··å ¥ããåå¿ã«
é¢äžããªãâãã«ãšã³ã¹ã«ããã«ã¯ããªããŸã§
ãå æ°Žå解ãããçºã§ãããè©Šè¬ã®æµªè²»ã«ç¹ãã
å®çšçã§ãªãããšãããã€ãã ããã§çºæè çã¯éæç 究ã®çµæãåžå°ãå§ã
ã«ã¢ã«ã«ãªå€æº¶æ¶²ã«æµžæŒ¬ããã¢ã«ã«ãªã®åŠçéã
åäžã«ãªãæ§ã«äžå®ã®å²åã«çµã€ãåŸã«ä¹Ÿç¥ã
ãã次ã«ãããâãã«ãšã³ã¹ã«ããã«ã¯ããªã
çã®é žå¡©åç©ãäžå®éå«ã溶液ã«æµžæŒ¬ããåŠçé
ãåäžã«ãªãæ§ã«äžå®ã®å²åã«çµã€ãåŸã«ä¹Ÿç¥ã
ããããã«ããã«å¿ èŠã«å¿ã觊åªåŠçãæœããã
ãã«èžç±åŠçåã¯ä¹Ÿç±åŠçãæœãããšããã極ã
ãŠç°¡åã«ã»ã«ããŒã¹ã®ååŠæ¹è³ªãè¡ãããããšã
èŠåºããã ããã§èžç±åŠçæ¡ä»¶ãšããŠã¯100âã180âã®åžž
å§ã®é£œåèžæ°åã¯éç±èžæ°ãããã¯100âã140â
ã®é«æž©é«å§ã®é£œåèžæ°ã«ãŠ30ç§ã20åéåŠçãã
ããšã«ããè¯å¥œãªçµæãåŸãããšãã§ãã也ç±åŠ
çæ¡ä»¶ãšããŠã¯60âã180âã§30ç§ã20åéããŒ
ãã³ã°ããããšã«ããæ¯èŒçè¯å¥œãªçµæãåŸãã
ãšãã§ãããçºæè çã®å®éšçµæã§ã¯ä¹Ÿç±åŠçã
ããèžç±åŠçã®æ¹ããããè¯å¥œãªãçµæãåŸãã
ãããã®çç±ãšããŠã¯èžç±åŠçã§ã¯ä¹Ÿç±åŠçã«æ¯
ã¹ãŠãããããã¢ã«ã«ãªåŠçãããã»ã«ããŒã¹ç¹
ç¶ãâãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®é žå¡©å
ç©ã«ããååŠæ¹è³ªãããïŒä»¥äžãã·ã«åãšç§°ã
ãïŒéã«ãã»ã«ããŒã¹ã®èšæœ€ç¶æ ãèžç±ã«ããä¿
ããããŸãŸãã·ã«åãããããã«ã極ããŠå¹æç
ã«åå¿ãé²è¡ãããããšå€æããããã®æ§ãªèã
æ¹ã¯ãåèšå ¬ç¥ã®æç®ã«ã玹ä»ãããŠãããæ¬çº
æã®ç¹èšãã¹ãããšã®äžã€ã§ããã以äžã®æ§ãªæ¹
æ³ã¯ãâãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®é žå¡©
åç©åã³ã¢ã«ã«ãªå€ã®æµªè²»ãªã©ããªãå®çšçã§ã
ããé£ç¶åãå¯èœã§ãããçç£æ§ã«æŒãŠè¯å¥œã§ã
ãã ããããªãããããã§ïŒ°âãã«ãšã³ã¹ã«ããã«
ã¯ããªãçã®é žå¡©åç©ã®ç¹åŸŽãšããŠãåå¿ã®å¯ç
æç©ãšããŠå¿ ãå¡©åæ°ŽçŽ ãçºçãããããªãã¡ã
ãã·ã«ååå¿ãé²è¡ããå Žåããããã¯åçŽã«ïŒ°
âãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®é žå¡©åç©ãå
æ°Žå解ããå Žåãããããå¡©åæ°ŽçŽ ã®çºçã䌎ã
匷ãé žæ§ãåããã åšç¥ã®æ§ã«å¡©åæ°ŽçŽ ããªãã¡å¡©é žã¯åŒ·é žæ§ãå
ãããšåæã«åŒ·åãªéå±è èæ§ãæããæ¯èŒçé
é£ããšãããŠããéåžžã®ã¹ãã³ã¬ã¹ã®æ§ãªéå±ã
ãè èãããåŸã€ãŠæ¬çºæã§è¿°ã¹ãâãã«ãšã³
ã¹ã«ããã«ã¯ããªãçã®é žå¡©åç©ãçšããåå¿ã
çŸåšãæè²æŽç粟緎ãªã©ã«äœ¿çšãããŠããå å·¥æ©
ã§ããã¹ããŒããŒã也ç¥æ©ãçšããŠè¡ãããšãã
ãšããããã®å å·¥æ©ãè èãæå·ããããããã
ã§ä»®ã«å å·¥æ©ã«èå¡©é žæ§ã®è¯å¥œãªæ質ãçšãã
ããã°ã©ã¹ã©ã€ãã³ã°çã®èé žå å·¥ãæœãããã
ããšå å·¥æ©ã®ã³ã¹ãã¯é«ããã®ãšãªãããé«äŸ¡ãª
èšåãå¿ èŠãšãããæ¯èŒçç°¡åãªè£ 眮ã§ååŠæ¹è³ª
ãå¯èœãšããããšããæ¬çºæã®äž»æšã«åããããš
ã«ãªããå ããŠåå¿ç³»ã«å¡©åæ°ŽçŽ ãå€éã«çºçã
ããšããããšã¯ãåå¿äžã«åžå°ãèããå£åãã
ãæããããããã®æ§ã«åå¿ã®å¯çæç©ã§ããå¡©
åæ°ŽçŽ ã¯æ¥µããŠæ害ã§ããé€å»ãããäžæŽ»æ§ã«ã
ãããšãæãŸããã ãã®å¯Ÿçã®äžã€ãšããŠèããããæ¹æ³ãšããŠã
ãããããç¹ç¶ã«æœãã¢ã«ã«ãªå€ãéå°ã«åŠçã
ãŠãããçããŠããå¡©åæ°ŽçŽ ãã¢ã«ã«ãªå€ã«ãã
å³äžåãããšããæ¹æ³ãèããããããã¢ã«ã«ãª
å€ãšé žå¡©åç©ã®ã¢ã«æ¯ã«äžé£åãçããæ¹è³ªåå¿
ã¯é²è¡ããªããªãã ããã§çºæè çã¯éæç 究ã®çµæãåå¿ã®éçš
ã§äœããã®æ¹æ³ã«ãããâãã«ãšã³ã¹ã«ããã«
ã¯ããªãçã®é žå¡©åç©ãšå¡©åæ°ŽçŽ ãäžæŽ»æ§ãšãã
ååç©ãå ±åããããããåŸã«èžç±åŠçåã¯ä¹Ÿç±
åŠçãæœãããšã«ãããã®åé¡ã解決ã§ããããš
ãèŠåºããã ããã«è¿°ã¹ãå¡©åæ°ŽçŽ ãäžæŽ»æ§ãšããååç©ãš
ã¯ããã·ã«ååå¿ã«ã¯æ®ãã©é¢äžããªãã§çºçå¡©
é žãææããæ§è³ªãæãããã®åã³çºçå¡©é žã®æ
æã¯ããªãããå¡©é žã®ååšäžã§éå±ã®è èæ§ãè
ããé ããããã®çãå«ãŸããã ãããå¡©åæ°ŽçŽ ãäžæŽ»æ§ãšããååç©ãšã¯å ·äœ
çã«ã¯ ã¹ãã¢ãªã³é žã«ãããŠã ãã©ãŠãªã³é žã«ãããŠ
ã ããªã·ããŒã«é žã«ãããŠã ããããã³é žã«ã
ããŠã ãïŒãšãã«ãããœã€ã³é žã«ãããŠã ãã¹
ãã¢ãªã³é žããªãŠã ãã©ãŠãªã³é žããªãŠã ããª
ã·ããŒã«é žããªãŠã ããããã³é žããªãŠã ãïŒ
ãšãã«ãããœã€ã³é žããªãŠã ãã¹ãã¢ãªã³é žã«
ã«ã·ãŠã ããªã·ããŒã«é žã«ã«ã·ãŠã ãã¹ãã¢ãª
ã³é žã¹ããã³ããŠã ãã¹ãã¢ãªã³é žäºéãã©ãŠ
ãªã³é žäºéããªã·ããŒã«é žäºéãïŒãšãã«ãã
ãœã€ã³é žäºéãã¹ãã¢ãªã³é žéãäºå¡©åºæ§ã¹ã
ã¢ãªã³é žéããããã³é žéãã¹ãã¢ãªã³é žã¹
ãºãã¹ãã¢ãªã³é žã¢ã«ãããŠã ãã¹ãã¢ãªã³é ž
ãã°ãã·ãŠã ãªã©ã®ãäžèšæ§é ïŒïŒã®éå±ç³ãã () ïŒïŒOOCRïŒ2åã¯AlïŒOOCRïŒ2OH ïŒïŒã¯CaãBaãZnãSnãMgãCdãPbãªã©ã®
éå±ãã¯ã¢ã«ãã«åºãæå³ããïŒ ãããã¯æ¬¡ã«ç€ºããããããªææ©ã¹ãºååç© äŸãã°ã¢ãããã«ã¹ãºããªã¡ãã«ãã¬ãšãŒãã
ã¢ãããã«ã¹ãºããªãªã¯ãã«ãã¬ãšãŒãããžãã
ã«ã¹ãºãžã©ãŠã¬ãŒãããžããã«ã¹ãºã©ãŠã¬ãŒãã¡
ãã«ãã¬ãšãŒãããžããã«ã¹ãºãžãªã¬ã€ã«ãã¬ãš
ãŒãããžããã«ã¹ãºãžã¡ãã«ãã¬ãšãŒãããžãã
ã«ã¹ãºãã¬ãšãŒãããžããã«ã¹ãºã¡ããã·ã¡ãã«
ãã¬ãšãŒãããžããã«ã¹ãºãã¬ãšãŒããšãžããã«
ã¹ãºãžã¡ãã«ãã¬ãšãŒãã®æ··åç©ããžããã«ã¹ãº
ãžãªã¯ãã«ãã¬ãšãŒãããžããã«ã¹ãºãžãªã¯ãã«
ããªã°ãªã³ã¬ãŒãããžããã«ã¹ãºãžã©ãŠãªã«ã¡ã«
ã«ãã¿ã€ããããªãã³ãžã«ã¹ãºãªã¯ãã«ãã¬ãšãŒ
ããããªãã³ãžã«ã¹ãºããªã¡ãã«ãã¬ãšãŒã ãããã¯ãŸãã () äžèšæ§é ã®èèªæãšããã·ååç©
ãåŒãäžã«
ãåŒããæãã
ïŒïŒ²ã¯ã¢ã«ãã«åºïŒ
ãŸãã¯
() äžèšæ§é ã®èèªæãšããã·ååç©
RCOORⲠäžã«
ãåŒããæãã
ïŒïŒ²ãRâ²ã¯ã¢ã«ãã«åºïŒ
ãŸãã¯
() äžèšæ§é ã®èèªæãšããã·ååç©
ãåŒã
ïŒïŒ²ã¯ã¢ã«ãã«åºãã¢ãªã«åºïŒ
ãŸãã¯
äŸãã°ããã«ã°ãªã·ãžã«ãšãŒãã«ãªã©ã®ã¢ã«ã
ã«ã°ãªã·ãžã«ãšãŒãã«åã³ãšããã·å倧è±æ²¹ããš
ããã·åã¢ããæ²¹ããšããã·ã¹ãã¢ãªã³é žãã
ã«ããšããã·åãžã¢ã»ãã¢ããªã¬ã€ã³åã³ïŒïŒïŒ
ãšããã·ã·ã¯ããããµã³ã«ã«ãã³é žãšã¹ãã«ã
ïŒïŒïŒãšããã·ã·ã¯ãããã·ã«ã¡ã¿ããŒã«ã®ïŒïŒ
10âãšããã·ã¹ãã¢ãªã³é žãšã¹ãã«ãïŒïŒïŒãšã
ãã·ã·ã¯ãããã·ã«ã¡ã¿ããŒã«ã®ïŒïŒ10ïŒâ12ïŒ
13âãžãšããã·ã¹ãã¢ãªã³é žãšã¹ãã«ãïŒïŒïŒâ
ãšããã·ã·ã¯ããããµã³ã«ã«ãã³é žã®ïŒâãšãã«
âïŒïŒïŒâãããµã³ãžãšã¹ãã«ãã€ãœãªã¯ãã«â
ïŒïŒ10âãšããã·ã¹ãã¢ã¬ãŒããªã©ããããã¯ãš
ãã«ã¢ãã³ããžãšãã«ã¢ãã³ãããã·ã«ã¢ãã³ã
ã€ã·ã¢ã«ãã«ã¢ãã³ãããã©ãã·ã«ã¢ãã³ããã
ãµãã·ã«ã¢ãã³ããªã¯ã¿ãã·ã«ã¢ãã³ã硬åçè
ã¢ã«ãã«ã¢ãã³ãçèã¢ã«ãã«ã¢ãã³ããªã¬ã€ã«
ã¢ãã³ãããã·ã«ã¡ãã«ã¢ãã³ãã€ã·ã¢ã«ãã«ãž
ã¡ãã«ã¢ãã³ãããã©ãã·ã«ãžã¡ãã«ã¢ãã³ãã
ããµãã·ã«ãžã¡ãã«ã¢ãã³ã硬åçèã¢ã«ãã«ãž
ã¡ãã«ã¢ãã³ããªã¯ã¿ãã·ã«ãžã¡ãã«ã¢ãã³ãç
èã¢ã«ãã«ãããã¬ã³ãžã¢ãã³ã硬åçèã¢ã«ã
ã«ãããã¬ã³ãžã¢ãã³ããžã¢ãã«ã¢ãã³ãβãã
ãã«ã¢ãã³ãããšãã«ãããã«ã¢ãã³ãããªãž
ã³ãããªãã³ãªã©ã®ææ©ã¢ãã³é¡ããããããã ãŸãäžè¬ã«é°ã€ãªã³æåãéé žåæ§ã§ããæ§ãª
ã¢ã³ã¢ããŠã å¡©ã¯å ç±ã«ããå解ããŠã¢ã³ã¢ãã¢
ãçºçããããšãç¥ãããŠãããããã®æ§ãªã¢ã³
ã¢ããŠã å¡©ãå ±åãããããšã«ããèžæ°åŠçãã
ããã¯ä¹Ÿç±åŠçå·¥çšäžã«çºçå¡©åæ°ŽçŽ ãäžåããª
ãã¡äžæŽ»æ§åããããšãå¯èœã§ããããã®æ§ãªã¢
ã³ã¢ããŠã å¡©ãšã¯å ·äœçã«ã¯çé žã¢ã³ã¢ããŠã ã
çé žæ°ŽçŽ ã¢ã³ã¢ããŠã ãé ¢é žã¢ã³ã¢ããŠã ãªã©ã
æããããã ãŸãæ¬çºæã§è¿°ã¹ãå¡©åæ°ŽçŽ ãäžæŽ»æ§ãšããå
åç©ãâãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®é žå¡©
åç©ãšäœããã®æ¹æ³ã«ããå ±åããããšããäºã¯
ãããäžæŽ»æ§ååç©ãç¹ç¶äžã«ã»ã«ããŒã¹ããã·
ã«åããããã®ã¢ã«ã«ãªå€ã觊åªããã·ã«åå€ã
åŠçããã®ãšåæã«åã¯çžååŸããŠåŠçããããš
ãæå³ããå ·äœçã«ã¯ãå¡©åæ°ŽçŽ äžæŽ»æ§åååç©
ã氎溶æ§ã®å Žåã«ã¯ã¢ã«ã«ãªå€æ°Žæº¶æ¶²ãããã¯è§Š
åªæ°Žæº¶æ¶²ã«æ·»å ããã¢ã»ãã³ããã«ãšã³çã®ææ©
溶å€å¯æº¶æ§ã®å Žåã«ã¯ãã·ã«åå€æº¶æ¶²ã«æ·»å ããŠ
åŠçããããšãå¯èœã§ãããåã åç¬ã«åŠçãã
ããšãå¯èœã§ããã ããããŠåŸãããæ¹è³ªåžããäŸãã°æè¯æ§åæ£
ææã䜿çšããåžè²©ã®è»¢åçŽãçšãã也åŒè»¢åã
è¡ã€ããšããåæ£ææã«å¯Ÿããæçæ§ãè¯å¥œãšãª
ããé«æ¿åºŠãã€æè²å ç¢åºŠã®è¯å¥œãªæºæç©ãåŸã
ããšãã§ããã ãã®æ¹æ³ã«äœ¿çšã§ããé žå¡©åç©ã¯äžåŒã®æ§é ã
æããååç©ã§ããã
ã«ã°ãªã·ãžã«ãšãŒãã«åã³ãšããã·å倧è±æ²¹ããš
ããã·åã¢ããæ²¹ããšããã·ã¹ãã¢ãªã³é žãã
ã«ããšããã·åãžã¢ã»ãã¢ããªã¬ã€ã³åã³ïŒïŒïŒ
ãšããã·ã·ã¯ããããµã³ã«ã«ãã³é žãšã¹ãã«ã
ïŒïŒïŒãšããã·ã·ã¯ãããã·ã«ã¡ã¿ããŒã«ã®ïŒïŒ
10âãšããã·ã¹ãã¢ãªã³é žãšã¹ãã«ãïŒïŒïŒãšã
ãã·ã·ã¯ãããã·ã«ã¡ã¿ããŒã«ã®ïŒïŒ10ïŒâ12ïŒ
13âãžãšããã·ã¹ãã¢ãªã³é žãšã¹ãã«ãïŒïŒïŒâ
ãšããã·ã·ã¯ããããµã³ã«ã«ãã³é žã®ïŒâãšãã«
âïŒïŒïŒâãããµã³ãžãšã¹ãã«ãã€ãœãªã¯ãã«â
ïŒïŒ10âãšããã·ã¹ãã¢ã¬ãŒããªã©ããããã¯ãš
ãã«ã¢ãã³ããžãšãã«ã¢ãã³ãããã·ã«ã¢ãã³ã
ã€ã·ã¢ã«ãã«ã¢ãã³ãããã©ãã·ã«ã¢ãã³ããã
ãµãã·ã«ã¢ãã³ããªã¯ã¿ãã·ã«ã¢ãã³ã硬åçè
ã¢ã«ãã«ã¢ãã³ãçèã¢ã«ãã«ã¢ãã³ããªã¬ã€ã«
ã¢ãã³ãããã·ã«ã¡ãã«ã¢ãã³ãã€ã·ã¢ã«ãã«ãž
ã¡ãã«ã¢ãã³ãããã©ãã·ã«ãžã¡ãã«ã¢ãã³ãã
ããµãã·ã«ãžã¡ãã«ã¢ãã³ã硬åçèã¢ã«ãã«ãž
ã¡ãã«ã¢ãã³ããªã¯ã¿ãã·ã«ãžã¡ãã«ã¢ãã³ãç
èã¢ã«ãã«ãããã¬ã³ãžã¢ãã³ã硬åçèã¢ã«ã
ã«ãããã¬ã³ãžã¢ãã³ããžã¢ãã«ã¢ãã³ãβãã
ãã«ã¢ãã³ãããšãã«ãããã«ã¢ãã³ãããªãž
ã³ãããªãã³ãªã©ã®ææ©ã¢ãã³é¡ããããããã ãŸãäžè¬ã«é°ã€ãªã³æåãéé žåæ§ã§ããæ§ãª
ã¢ã³ã¢ããŠã å¡©ã¯å ç±ã«ããå解ããŠã¢ã³ã¢ãã¢
ãçºçããããšãç¥ãããŠãããããã®æ§ãªã¢ã³
ã¢ããŠã å¡©ãå ±åãããããšã«ããèžæ°åŠçãã
ããã¯ä¹Ÿç±åŠçå·¥çšäžã«çºçå¡©åæ°ŽçŽ ãäžåããª
ãã¡äžæŽ»æ§åããããšãå¯èœã§ããããã®æ§ãªã¢
ã³ã¢ããŠã å¡©ãšã¯å ·äœçã«ã¯çé žã¢ã³ã¢ããŠã ã
çé žæ°ŽçŽ ã¢ã³ã¢ããŠã ãé ¢é žã¢ã³ã¢ããŠã ãªã©ã
æããããã ãŸãæ¬çºæã§è¿°ã¹ãå¡©åæ°ŽçŽ ãäžæŽ»æ§ãšããå
åç©ãâãã«ãšã³ã¹ã«ããã«ã¯ããªãçã®é žå¡©
åç©ãšäœããã®æ¹æ³ã«ããå ±åããããšããäºã¯
ãããäžæŽ»æ§ååç©ãç¹ç¶äžã«ã»ã«ããŒã¹ããã·
ã«åããããã®ã¢ã«ã«ãªå€ã觊åªããã·ã«åå€ã
åŠçããã®ãšåæã«åã¯çžååŸããŠåŠçããããš
ãæå³ããå ·äœçã«ã¯ãå¡©åæ°ŽçŽ äžæŽ»æ§åååç©
ã氎溶æ§ã®å Žåã«ã¯ã¢ã«ã«ãªå€æ°Žæº¶æ¶²ãããã¯è§Š
åªæ°Žæº¶æ¶²ã«æ·»å ããã¢ã»ãã³ããã«ãšã³çã®ææ©
溶å€å¯æº¶æ§ã®å Žåã«ã¯ãã·ã«åå€æº¶æ¶²ã«æ·»å ããŠ
åŠçããããšãå¯èœã§ãããåã åç¬ã«åŠçãã
ããšãå¯èœã§ããã ããããŠåŸãããæ¹è³ªåžããäŸãã°æè¯æ§åæ£
ææã䜿çšããåžè²©ã®è»¢åçŽãçšãã也åŒè»¢åã
è¡ã€ããšããåæ£ææã«å¯Ÿããæçæ§ãè¯å¥œãšãª
ããé«æ¿åºŠãã€æè²å ç¢åºŠã®è¯å¥œãªæºæç©ãåŸã
ããšãã§ããã ãã®æ¹æ³ã«äœ¿çšã§ããé žå¡©åç©ã¯äžåŒã®æ§é ã
æããååç©ã§ããã
ãåŒã
ïŒïŒžã¯ãâNO2ãâCH3ãæå³ããïŒ
ãã®æ¹æ³ã¯æŽã«ä»ã®åŸæ¥æ³ãšçµåãããŠå©çšã
ãããšãã§ãããäŸãã°ãäžèšæ¹æ³ã§åŸãããæ¹
質åžããåæ£ææã«å¯ææ§ããã€æš¹èãäŸãã°ã
ã¢ããã¢ã«ãããæš¹èãããªã¢ããããŠã¬ã¿ã³ã
å¡©åããã«ãé ¢é žããã«ãããªãšã¹ãã«ãã¢ã¯ãª
ã«ãã¢ã»ã¿ãŒã«ãããªããã«ã¢ã«ã³ãŒã«ãå¡©åã
ããªãã³ãããã«ã¢ã»ã¿ãŒã«ãã¹ãããŒã«ãããª
ã«ãŒãããŒãããšããã·æš¹èçã§åŠçãããã®åŸ
也åŒè»¢åæºæãè¡ããšæ¿åºŠãè²çžã®åœ©ããæ·±ã¿ç
ãäžå±€é«ããããšãã§ããããŸãæ¹è³ªåžããžã¡ã
ããŒã«ãŠã¬ã¢ããžã¡ãããŒã«ãããã¬ã³ãŠã¬ã¢ã
ãžã¡ãããŒã«ãžããããã·ãšãã¬ã³ãŠã¬ã¢ããžã¡
ãããŒã«ãŠãã³ãããªã¡ãããŒã«ã¡ã©ãã³ãããª
ã¡ããã·ã¡ãã«ã¡ã©ãã³ããããµã¡ããã·ã¡ãã«
ã¡ã©ãã³ããžã¡ãããŒã«ã¡ãã«ããªã¢ãŸã³ããžã¡
ãããŒã«ãšãã«ããªã¢ãŸã³ããžã¡ãããŒã«ãã€ã
ããã·ãšãã«ããªã¢ãŸã³ããžã¡ãããŒã«ã¡ãã«ã«
ãŒãã¡ãŒãããžã¡ãããŒã«ãšãã«ã«ãŒãã¡ãŒãã
ãžã¡ãããŒã«ãã€ãããã·ãšãã«ã«ãŒãã¡ãŒãã
âã¡ãããŒã«ã¢ã¯ãªã«ã¢ãããã¡ãããŒã«ã°ãª
ãªãã¶ãŒã«ã¢ããŠã¬ã¢ãã¡ãããŒã«ã°ãªãªãã¶ãŒ
ã«ãžãŠã¬ã¢ããã«ã ã¢ã«ããããããã©ãªããµã³
ã°ãªã¿ã«ã¢ã«ãããããžãšãããµã€ãããžããã«
ã¹ã«ãã³ãïŒâã¡ããã·âïŒâãžã¡ãã«ãžã¡ãã
ãŒã«ãããã¬ã³ãŠã¬ã¢ãããã©ã¡ãããŒã«ã¢ã»ã
ã¬ã³ãžãŠã¬ã¢çã®ç¹ç¶æ¶æ©å€ãšãæ¶æ©è§ŠåªãäŸã
ã°é ¢é žããã¬ã€ã³é žçã®ææ©é žãå¡©åã¢ã³ã¢ããŠ
ã ãç¡«é žã¢ã³ã¢ããŠã ãçé žæ°ŽçŽ ã¢ã³ã¢ããŠã ã
çã®ã¢ã³ã¢ããŠã å¡©ããšã¿ããŒã«ã¢ãã³å¡©é žå¡©ã
ïŒâã¢ããâïŒâã¡ãã«ãããããŒã«ãã€ããã¯
ããªãçã®ã¢ãã³ãå¡©åãã°ãã·ãŠã ãç¡é žäº
éãå¡©åäºéãç¡é žãã°ãã·ãŠã ãããŠããåäº
éãå¡©åã¢ã«ãããŠã ãçé žãã°ãã·ãŠã çã§åŠ
çããæ¶æ©å€ãæ¶æ©ãããããšã«ãã颚åãæ¹è¯
ããããšãå¯èœã§ãäŸãã°ç¡¬ä»äžããè»ä»äžããª
ã©èªç±ã«èª¿ç¯ããããšãã§ããã æ¬æ¹æ³ã«é©çšãããã»ã«ããŒã¹ç³»ç¹ç¶ãšã¯ãæš
綿ã®æ§ãªå€©ç¶ã»ã«ããŒã¹ç¹ç¶ã®ã»ãããã¹ã³ãŒã¹
ã¬ãŒãšã³ã®æ§ãªåçã»ã«ããŒã¹ç¹ç¶ãå«ã¿ããã
ãã®ç¹ç¶ãšããªãšã¹ãã«çã®åæç¹ç¶ãšã®æ··åç©
ããé©çšããããšãã§ããåžåžã®ä»ã糞ã®ç¶æ ã§
ãè¯ãã åãæ¬æ¹æ³ã«æŒããŠäœ¿çšãããã¢ã«ã«ãªå€ãšã
ãŠã¯æ°Žé žåãããªãŠã ãæ°Žé žåãã°ãã·ãŠã ãæ°Ž
é žåã«ãªãŠã ãæ°Žé žåã«ã«ã·ãŠã ãçé žãããªãŠ
ã ãçé žæ°ŽçŽ ãããªãŠã ãé ¢é žã«ãªãŠã ãé ¢é žã
ããªãŠã ãé ¢é žãã°ãã·ãŠã çãçšããããšãã§
ããã åãæ¬æ¹æ³ã«é©çšãããé žå¡©åç©ãšã¯ãâã
ã«ãšã³ã¹ã«ããã«ã¯ããªããïœâããããã³ãŒã³
ã¹ã«ããã«ã¯ããªããïœâããããã³ãŒã³ã¹ã«ã
ãã«ã¯ããªããïœâããããã³ãŒã³ã¹ã«ããã«ã¯
ããªããçãçšããããšãã§ããã åãæ¬æ¹æ³ã«é©çšããã觊åªãšã¯ãæ°Žé žåãã
ãªãŠã ãæ°Žé žåã«ãªãŠã ãæ°Žé žåã«ã«ã·ãŠã ãç
é žãããªãŠã ãçé žæ°ŽçŽ ãããªãŠã ãé ¢é žã«ãªãŠ
ã ãé ¢é žãããªãŠã ãé ¢é žãã°ãã·ãŠã ãçãçš
ããããšãã§ããå ã«è¿°ã¹ãã¢ã«ã«ãªå€ãšæ®ãã©
åæ§ãªè©Šè¬ãçšããããããã¢ã«ã«ãªå€ã®å Žåã¯
é žå¡©åç©ããå ã«ç¹ç¶æ§é ç©ã«é©çšãããã»ã«ã
ãŒã¹ã®èšæœ€äœçšãšãã·ã«ååå¿ãšå¹³è¡¡ããŠé žå¡©å
ç©ããçããé žæ§ç©è³ªã®äžååå¿ã«äž»ãªãå¹æã
瀺ãã®ã«å¯Ÿããããã§è¿°ã¹ãã¢ã«ã«ãªæ§ã®è§Šåªã¯
é žå¡©åç©ã®åŸã«ç¹ç¶æ§é ç©ã«é©çšãããŠãåå¿ã®
é²è¡ã«å¯äžããäœçšå¹æãç°ã«ããããå¹æçãª
ãã·ã«ååå¿ãè¡ãããšãã§ããã ãŸãæ¬çºæã«ãããŠäœ¿çšã§ããææã¯æè¯æ§ã
æãããåã¯æããªãåæ£ææã油溶æ§ææãåª
æææãå¡©åºæ§ææã建æãææçã§ãããçŽæ¥
æºæåã¯è»¢åæºæã«ããæºæããããšãã§ããã
ç¹ã«æè¯æ§ææãçšããå Žåã¯ä¹ŸåŒè»¢åæºææ³ã
å¯èœã§ããã 以äžæŽã«ãæ¬çºæãå³é¢ãçšãã詳现ã«èª¬æã
ããããªãã¡ç¬¬ïŒå³ã¯ãæ¬çºæã«äœ¿çšããæ¹è³ªè£
眮ã®æŠç¥å³ã瀺ããã®ã§ãã»ã«ããŒã¹ç¹ç¶æ§é ç©
åã³ã»ã«ããŒã¹ç¹ç¶ãšåæç¹ç¶ã®æ··åæ§é ç©ãã
ãªãã¡ååžïŒããªãŒãããŒã«R1ãä»ããŠã¢ã«ã«
ãªå€åŠç济槜ïŒäžã«å°å ¥ãã次ãã§ã¢ã«ã«ãªå€ã®
åŠçéãåäžã«ãªãæ§ã«çµãããŒã«ïŒã«ãŠçµãã
也ç¥ãã©ã€ã€ãŒïŒãã³ãã³ã¿ãŒãªãŒãã³ïŒïŒã«ãŠ
也ç¥ãããã次ãã§ãªãŒãããŒã«R2ãä»ããŠå
åžïŒããé žå¡©åç©åŠç济槜ïŒäžã«å°å ¥ãé žå¡©åç©
ã®åŠçéãåäžã«ãªãæ§ã«çµãããŒã«ïŒã«ãŠçµ
ãã也ç¥ãã©ã€ã€ãŒïŒãã³ãã³ã¿ãŒãªãŒãã³ïŒïŒ
ã«ãŠä¹Ÿç¥ãããæŽã«ãªãŒãããŒã«R3ãä»ããŠè§Š
åªåŠç济槜ïŒäžã«å°å ¥ãã次ãã§è§Šåªã®åŠçéã
åäžã«ãªãããã«çµãããŒã«ïŒã«ãŠçµãã也ç¥ã
ã©ã€ã€ãŒïŒãã³ãã³ã¿ãŒãªãŒãã³ïŒïŒïŒã«ãŠä¹Ÿç¥
ãããã次ã«åèšåŠçããååžïŒãæŽã«èžç±åŠç
ãæœãç®çã§ãªãŒãããŒã«R4ãä»ããŠé£ç¶ã«ãŒ
ãã¹ããŒããŒïŒïŒäžã«å°å ¥ããåŸã以äžé 次氎æŽ
ïŒåã¯æ¹¯æŽïŒæµŽæ§œïŒïŒããœãŒãã³ã°æµŽæ§œïŒïŒãæ°Ž
æŽæµŽæ§œïŒïŒäžã«å°å ¥ãã次ãã§ä¹Ÿç¥ãã©ã€ã€ãŒ
ïŒãã³ãã³ã¿ãŒãªãŒãã³ïŒïŒïŒäžã«å°å ¥ããŠååŠ
æ¹è³ªåžïŒïŒã¯åŸãããã 第ïŒå³ã¯ã第ïŒå³ãšæ®ãã©åæ§ãªæ¹è³ªè£ 眮ã®æŠ
ç¥å³ã§ãããããã®å Žåã«ã¯è§ŠåªåŠç济槜ãçç¥
ããã¢ã«ã«ãªå€åŠçãšé žå¡©åç©åŠçã®ïŒå·¥çšåŠç
ã®åŸãèžç±ãè¡ãååŠæ¹è³ªãè¡ãã 以äžç¬¬ïŒå³ãšåæ§ã« ïŒååžãïŒã¢ã«ã«ãªå€åŠç济槜ãïŒçµãããŒ
ã«ãïŒä¹Ÿç¥ãã©ã€ã€ãŒãïŒé žå¡©åç©åŠç济槜ãïŒ
çµãããŒã«ãïŒä¹Ÿç¥ãã©ã€ã€ãŒãïŒïŒé£ç¶ã«ãŒã
ã¹ããŒããŒãïŒïŒæ°ŽæŽïŒåã¯æ¹¯æŽïŒæµŽæ§œãïŒïŒãœ
ãŒãã³ã°æµŽæ§œãïŒïŒæ°ŽæŽæµŽæ§œãïŒïŒä¹Ÿç¥ãã©ã€ã€
ãŒãïŒïŒååŠæ¹è³ªåžãR1ãR2ãR3ã¯ãªãŒãããŒ
ã«ã瀺ãã ããã§ç¬¬ïŒå³åã³ç¬¬ïŒå³ã«æŒãŠå¡©åæ°ŽçŽ äžæŽ»æ§
ååç©ã¯ãã®æ§è³ªã«ããé©å®ãã¢ã«ã«ãªå€åŠç济
槜ã觊åªåŠç济槜ãé žå¡©åç©åŠç济槜ã«é©éãæ·»
å ããã以äžå®æœäŸããã€ãŠèª¬æããã å®æœäŸ ïŒ (1) 第ïŒå³ã«ç€ºãè£ çœ®ãçšããŠæ¬¡ã®æ§ãªæé ã§å
åŠæ¹è³ªãè¡ã€ãã ã·ã«ã±ããå å·¥æžã¿ã®ããªãšã¹ãã«ïŒæšç¶¿ïŒ
65ïŒ35ãªã混玡ãããŒãåžãäºãã20ïŒ æ°Žé žå
ãããªãŠã 氎溶液äžã«30ç§é浞挬ããåŸãçµã
ç100ïŒ ã«ãªãæ§çµãããŒã«ã«ãŠçµã€ãã次ã«
ãã®åžã100âã®ãã³ãã³ã¿ãŒãªãŒãã³äžã«40
ç§éæ»åšãã也ç¥ãããåŸã30ïŒ éééšïŒ°âã
ã«ãšã³ã¹ã«ããã«ã¯ããªãã20ïŒ éééšããã«
ã°ãªã·ãžã«ãšãŒãã«ãåååïŒãããµã³ãšããª
ãŒã«ïŒ¢ïŒæ¥æ¬æ²¹è瀟補ïŒããã¢ã»ãã³äžã«æº¶è§£
ããã溶液äžã«30ç§é浞挬ãããããã«çµãç
100ïŒ ã®æ¡ä»¶ã«ãŠçµãåŸé¢šä¹Ÿãããããã«ãã®
åžãïŒïŒ æ°Žé žåãããªãŠã 氎溶液äžã«ïŒåé浞
挬ãããåŸã100ïŒ ã®çµãçã«ãŠçµã100âã®ã
ã³ãã³ã¿ãŒãªãŒãã³äžã«ãŠ25ç§é也ç¥ãããã
次ã«ãã®åžã100âã®åžžå§é£œåæ°Žèžæ°äžã§ïŒå
éèžç±ãè¡ããããã«æ°ŽæŽããã«ã»ã«ã»ãã±ã³
ã«ãããœãŒãã³ã°ãæ°ŽæŽãè¡ããã®åŸä¹Ÿç¥ãã
ãŠæ¹è³ªåžãåŸãã ããã§ããã«ã°ãªã·ãžã«ãšãŒãã«ã®æ·»å ã«ã
ãèžç±äžã®å¡©åæ°ŽçŽ ã®çºçã¯æžå°ããç¡æ·»å ã®
å Žåãã¹ããŒããŒããåºãŠããçŽåŸã®åžã®PH
ïŒïŒã§ãã€ãã®ã«å¯Ÿããæ·»å åŸã¯PHïŒ11ã瀺
ãããã€ã¹ããŒããŒãããããæ°Žèžæ°ã¯å šãŠäž
æ§ã瀺ããã (2) 次ã«60gïŒm2ã®çé¢ã¹ã¿ãŒãã³ãŒãçŽã«äžèš
ã®çµæã®ã€ã³ãã«ããã°ã©ãã¢å°å·ããŠè»¢åçŽ
ãåŸãã ïŒã€ã³ãïŒ ïŒã¹ãã«ãã³ã¬ããâFBL ïŒåæ«ïŒïœäœåååŠç€Ÿè£œã»ææïœ
10éš ãšãã«ã»ã«ããŒã¹ âïŒ ïŒã çé¢æŽ»æ§å€ ïŒã ã€ãœãããã«ã¢ã«ã³ãŒã« 40ã ãšã¿ããŒã« 40ã ïŒ (3) (1)ãªãæ¹è³ªåžã«(2)ãªã転åçŽãéãåããæž©
床195âãå§300gïŒcm2ãæé40ç§ã®æ¡ä»¶ã«ãŠå
ç±ãå å§ããŠè»¢åæºæãè¡ã€ããšãããããªãš
ã¹ãã«éšãæšç¶¿éšåäžèµ€è²ã®æ¿åºŠããæºæåžã
åŸãããšãã§ãããå°JISã«åºã¥ãæŽæ¿¯å ç¢åºŠ
ïŒïŒ¡âïŒïŒæ³ã«ãŠæž¬å®ãããšããïŒçŽã§ããã
å ç¢ãªæºæåžã§ãã€ãã å®æœäŸ ïŒ (1) 第ïŒå³ã«ç€ºãè£ çœ®ãçšããŠæ¬¡ã®æ§ãªæé ã§å
åŠæ¹è³ªãè¡ã€ããã·ã«ã±ããå å·¥æžã¿ã®ããªãš
ã¹ãã«ïŒæšç¶¿ïŒ65ïŒ35ãªã混玡ãã€ã³ããªãã¯
åžãäºã10ïŒ æ°Žé žåãããªãŠã 氎溶液äžã«20ç§
é浞挬ããåŸãçµãç100ïŒ ã«ãªãæ§ã«çµãã
ãŒã«ã«ãŠçµã€ãã次ã«ãã®åžã100âã®ãã³ã
ã³ã¿ãŒãªãŒãã³äžã«40ç§éæ»åšãã也ç¥ããã
åŸã30ïŒ éééšïŒ°âãã«ãšã³ã¹ã«ããã«ã¯ããª
ãã10ïŒ éééšMARK BTâ31ïŒã¢ãã«ã¢ãŒ
ã¬ã¹ç€Ÿè£œãžããã«é«ãã¬ãšãŒã系塩åæ°ŽçŽ ææ
å€ïŒãã¢ã»ãã³äžã«æº¶è§£ããã溶液äžã«20ç§é
浞挬ãããããã«çµãç120ïŒ ã®æ¡ä»¶ã«ãŠçµ
ããåŸé¢šä¹Ÿããã 次ã«ãã®åžã100âã®åžžå§é£œåæ°Žèžæ°äžã§ïŒ
åéèžç±ãè¡ããããã«æ°ŽæŽããã«ã»ã«ã»ãã±
ã³ã«ãããœãŒãã³ã°ãæ°ŽæŽãè¡ãããã®åŸä¹Ÿç¥
ãããŠæ¹è³ªåžãåŸããããã§ãžããã«é«ãã¬ãš
ãŒãç³»ã®å¡©åæ°ŽçŽ ææå€ã®æ·»å ã«ããèžç±äžã®
å¡©åæ°ŽçŽ ã®çºçã¯å®æœäŸïŒãšåæ§ã¹ããŒããŒã
ãåºãŠããçŽåŸã®åžã®PHã¯ã¢ã«ã«ãªæ§ã瀺ã
ãã€ã¹ããŒããŒãããããæ°Žèžæ°ã¯å šãŠäžæ§ã
瀺ããã ãªãããã®æã®åžã®æ¹è³ªçœ®æ床ïŒD.SïŒã¯æ¬¡
åŒã«ããèšç®ãããš0.22ã§ãã€ãã D.S.ïŒ æ¹è³ªåŸã®åžééå¢å éÃïŒã°ã«ã³ãŒã¹åäœïŒæ¹è³ªå
ã®åžééÃ混玡çÃïŒãã·ã«åºâïŒïŒ (2) 次ã«ãã®æ¹è³ªåžã«å®æœäŸïŒã®(2)ã§åŸããã転
åçŽãçšããŠã枩床195âãå§å300gïŒcm2ãæ
é40ç§ã®æ¡ä»¶ã§è»¢åæºæãè¡ã€ããšãã極ããŠ
çŸããæºæåžãåŸãã å®æœäŸ ïŒ (1) 第ïŒå³ã«ç€ºãè£ çœ®ãçšããŠæ¬¡ã®æ§ãªæé ã§å
åŠæ¹è³ªãè¡ã€ããã·ã«ã±ããå å·¥æžã¿ã®ããªãš
ã¹ãã«ïŒæšç¶¿ïŒ65ïŒ35ãªã混玡ãããŒãåžãäº
ãã10ïŒ éééšæ°Žé žåãããªãŠã åã³15ïŒ éé
éšé ¢é žã¢ã³ã¢ããŠã æ··å氎溶液äžã«20ç§é浞挬
ããåŸãçµãç100ïŒ ã«ãªãæ§ã«çµãããŒã«ã«
ãŠçµã€ãã次ã«ãã®åžã100âã®ãã³ãã³ã¿ãŒ
ãªãŒãã³äžã«40ç§éãæ»åšãã也ç¥ãããåŸ30
ïŒ éééšïŒ°âãã«ãšã³ã¹ã«ããã«ã¯ããªãåã³
10ïŒ éééšMARK ACâ141ïŒã¢ãã«ã¢ãŒã¬ã¹
瀟補BaâZnè€åéå±ç³ãããå¡©åæ°ŽçŽ ææ
å€ïŒæ··åç©ãã¡ãã«ãšãã«ã±ãã³äžã«æº¶è§£ãã
ã溶液äžã«20ç§é浞挬ãããããã«çµãç120
ïŒ ã®æ¡ä»¶ã«ãŠçµããåŸé¢šä¹Ÿããã次ã«ãã®åžã
100âã®åžžå§é£œåæ°Žèžæ°äžã§ïŒåéèžç±ãè¡
ããããã«æ°ŽæŽããœãŒãã³ã°æ°ŽæŽãè¡ãããã®
åŸä¹Ÿç¥ãããŠæ¹è³ªåžãåŸããããã§é ¢é žã¢ã³ã¢
ããŠã åã³è€åéå±ç³ããã®æ·»å ã«ããã¹ããŒ
ããŒããåºãŠããçŽåŸã®åžã®PHã¯ã¢ã«ã«ãªæ§
ã瀺ãã®ãšåæã«ã¹ããŒããŒãããããæ°Žèžæ°
ã¯è¥å¹²ã®ã¢ã³ã¢ãã¢èãæããäžæ§ãªããã¯ã¢
ã«ã«ãªæ§ãåããã (2) 次ã«ãã®æ¹è³ªåžã«å®æœäŸïŒåæ§è»¢åæºæãè¡
ã€ããšããçŸããæºæåžãåŸãã å®æœäŸ ïŒ (1) å®æœäŸïŒã®åŠãæ¹è³ªåžãåŸãã次ã«ãã®æ¹è³ª
åžã以äž(ã€)ã®åŠæ¹ã®æº¶æ¶²ã«æµžãããã®åŸçµãç
80ïŒ ã«çµãã100âãïŒåéå也ç¥ããã次ã
ã§150âãïŒåéããŒãã³ã°ããã (ã€) åŠæ¹ ïŒã¹ãããã¯ã¹ã¬ãžã³AMH3000ïŒäœåå
åŠïŒ ïŒã¢ã¯ãªã«é žãšã¹ãã«ãšãã«ãžãšã³ïŒ
10éééš ã¹ãããã¯ã¹ã¢ã¯ã»ã¬ã¬ãŒã¿ãŒïŒžâ80 ïŒäœåååŠïŒ ïŒéééš ïŒæ°Ž 90 ã ïŒïŒ (2) 次ã«è»¢åçŽã¯ïŒå®æœäŸïŒïŒã®åŠãäœæããã (3) (1)ãªãæ¹è³ªåžã«(2)ãªã転åçŽãéãåããã
枩床195âãå§300gïŒcm2ãæé40ç§ã®æ¡ä»¶ã§å
ç±ãå å§ããŠè»¢åãè¡ã€ããšãããããªãšã¹ã
ã«éšãæšç¶¿éšåäžèµ€è²ã®æ¿åºŠã圩ããæ·±ã¿ã®ã
ãæºæåžãåŸãããšãã§ãããæŽæ¿¯å ç¢åºŠã枬
å®ãããšããïŒïŒ¡âïŒïŒæ³ã«ãŠïŒçŽã§ãããå
ç¢ãªæºæåžã§ãã€ããå°ãæš¹èåŠçãããã®ãš
ããªããã®ã®è»¢åæºæåžããã¯ãã¹åå°æ¿åºŠèš
ã«ãŠçºè²æ¿åºŠã枬å®ãããšãããåè ã¯1.05ã
åŸè ã¯1.28ã§ãããæãããªæ¿åºŠã®å¢ãã¿ãã
ãã å®æœäŸ ïŒ (1) æ¹è³ªåžãïŒå®æœäŸïŒïŒã®åŠãäœæããã次ã«
ãã®æ¹è³ªåžã以äž(ã)ã®åŠæ¹ã®æº¶æ¶²ã«æµžãããã®
åŸçµãç80ïŒ ã«çµãã100âãïŒåéå也ç¥
ãã次ãã§150âãïŒåéããŒãã³ã°ããã (ã) åŠæ¹ ã¹ãããã¯ã¹ã¬ãžã³NSâ16ïŒäœåååŠïŒ
10éééš ïŒã¹ãããã¯ã¹ã¢ã¯ã»ã¬ã¬ãŒã¿ãŒïŒžâ80 ïŒäœåååŠïŒ ïŒ ã ïŒã¹ãããã¯ã¹ãœãããŒïŒ¬ïŒäœåååŠïŒ
ïŒ ã ïŒ ïŒæ°Ž 90 ã ïŒ (2) 転åçŽã¯å®æœäŸ ïŒã®åŠãäœæããã (3) (1)ãªãæ¹è³ªåžã«(2)ãªã転åçŽãéãåããã
枩床200âãå§300gïŒcm2ãæé40ç§ã®æ¡ä»¶ã§å
ç±ãå å§ããŠè»¢åãè¡ã€ããšãããããªãšã¹ã
ã«éšãæšç¶¿éšåäžèµ€è²ã®æ¿åºŠãåã³é¢šåã®è¯å¥œ
ãªæºæåžãåŸãããã å®æœäŸ ïŒ (1) ã·ã«ã±ããå å·¥æžã¿ã®ããªãšã¹ãã«ïŒæšç¶¿ïŒ
65ïŒ35ãªã混玡ãããŒãåžãäºã20ïŒ æ°Žé žåã«
ãªãŠã 氎溶液äžã«30ç§é浞挬ããåŸãçµãç
100ïŒ ã®å²åã§çµã€ãã次ã«ãã®åžã100âã®ãª
ãŒãã³äžã§40ç§é也ç¥ãããåŸã25ïŒ éééšïŒ¯
âããããã³ãŒã³ã¹ã«ããã«ã¯ããªããã¢ã»ã
ã³ïŒãã«ãªãŒã«ïŒïŒïŒïŒæ··å溶液äžã«æº¶è§£ãã
ãäžã«30ç§é浞挬ãããããã«çµãç100ïŒ ã®
æ¡ä»¶ã«ãŠçµãåŸé¢šä¹Ÿããã ããã«ãã®åžã15ïŒ éééšã®é ¢é žãã°ãã·ãŠ
ã åã³ïŒïŒ éééšã®ãããã³ïŒ¡âïŒïŒã¹ã®ã ã©
ååŠå·¥æ¥ç€Ÿè£œé žæŽæå¶å€ïŒææ©ã¢ãã³ç³»ïŒæ··å
氎溶液äžã«ïŒåé浞挬ãããåŸã100ïŒ ã®çµã
çã«ãŠçµã100âã®ãªãŒãã³äžã«ãŠ25ç§é也ç¥
ãããã次ã«ãã®åžã130âã®é«æž©ãé«å§é£œå
æ°Žèžæ°äžã«ãŠ10åéèžç±ãè¡ããæ°ŽæŽãœãŒãã³
ã°ãè¡ã€ãåŸã也ç¥ãããŠæ¹è³ªåžãåŸãã ãã®å Žåãå¡©åæ°ŽçŽ ã®çºçã¯èªãããããã¹
ããŒããŒã®æ質ã§ãã18âïŒã¹ãã³ã¬ã¹
ïŒSUS304ïŒãžã®è èæ§ã¯èããããããããšã
ã§ããã (2) 次ã«ãã®æ¹è³ªåžã«åžçå°å·ïŒæ ªïŒç€Ÿè£œã®æè¯
転åæºæçŽã«ãŠ195âã300gïŒcm2ã40ç§ãªãæ¡
件ã«ãŠè»¢åæºæãè¡ã€ããšããçŸããããªã³ã
åžãåŸãã å®æœäŸ ïŒ å®æœäŸ ïŒã§åŸãããååŠæ¹è³ªåžãçšããäžèš
ããåŠæ¹ãããªãæºæã€ã³ãã«ãŠã·ã«ã¯ã¹ã¯ãªãŒ
ã³å°å·æ¹åŒã«ããçŽæ¥æºæãè¡ã€ãåŸã130âã®
é«æž©é«å§é£œåèžæ°äžã«ãŠ20åéã¹ããŒãã³ã°ãè¡
ã€ãåŸããœãŒãã³ã°ã也ç¥ãããšãã極ããŠçŸã
ãããªã³ãåžãåŸãã ïŒæºæã€ã³ãïŒ ïŒã¬ãŸãªã³ãã«ãŒFBLïŒãã€ãšã«ç€ŸææïŒ
ïŒéš ã¢ã«ã®ã³é žãœãŒã㌠ïŒéš æ°Ž 87éšïŒ å®æœäŸ ïŒ å®æœäŸ ïŒã«æŒãŠ100âåžžå§é£œåæ°Žèžæ°äžã§ïŒ
åéèžç±ãè¡ã代ãã«ã130âã®ä¹Ÿç±ãªãŒãã³äž
ã«ãŠïŒåéããŒãã³ã°ãè¡ã€ããšããå®æœäŸïŒãš
åæ§ååŠæ¹è³ªåžã¯åŸããããã転åæºæããåŸã®
çºè²æ¿åºŠããã¯ãã¹ã®åå°æ¿åºŠèšã«ãŠãå®æœäŸïŒ
ã§ã¯1.30ã§ããã®ã«å¯Ÿããå®æœäŸïŒã§ã¯1.05ãšæ¹
質ã®å¹æãèžç±ã®æ¹ãåªããŠããããšãå€æã
ãã
ãããšãã§ãããäŸãã°ãäžèšæ¹æ³ã§åŸãããæ¹
質åžããåæ£ææã«å¯ææ§ããã€æš¹èãäŸãã°ã
ã¢ããã¢ã«ãããæš¹èãããªã¢ããããŠã¬ã¿ã³ã
å¡©åããã«ãé ¢é žããã«ãããªãšã¹ãã«ãã¢ã¯ãª
ã«ãã¢ã»ã¿ãŒã«ãããªããã«ã¢ã«ã³ãŒã«ãå¡©åã
ããªãã³ãããã«ã¢ã»ã¿ãŒã«ãã¹ãããŒã«ãããª
ã«ãŒãããŒãããšããã·æš¹èçã§åŠçãããã®åŸ
也åŒè»¢åæºæãè¡ããšæ¿åºŠãè²çžã®åœ©ããæ·±ã¿ç
ãäžå±€é«ããããšãã§ããããŸãæ¹è³ªåžããžã¡ã
ããŒã«ãŠã¬ã¢ããžã¡ãããŒã«ãããã¬ã³ãŠã¬ã¢ã
ãžã¡ãããŒã«ãžããããã·ãšãã¬ã³ãŠã¬ã¢ããžã¡
ãããŒã«ãŠãã³ãããªã¡ãããŒã«ã¡ã©ãã³ãããª
ã¡ããã·ã¡ãã«ã¡ã©ãã³ããããµã¡ããã·ã¡ãã«
ã¡ã©ãã³ããžã¡ãããŒã«ã¡ãã«ããªã¢ãŸã³ããžã¡
ãããŒã«ãšãã«ããªã¢ãŸã³ããžã¡ãããŒã«ãã€ã
ããã·ãšãã«ããªã¢ãŸã³ããžã¡ãããŒã«ã¡ãã«ã«
ãŒãã¡ãŒãããžã¡ãããŒã«ãšãã«ã«ãŒãã¡ãŒãã
ãžã¡ãããŒã«ãã€ãããã·ãšãã«ã«ãŒãã¡ãŒãã
âã¡ãããŒã«ã¢ã¯ãªã«ã¢ãããã¡ãããŒã«ã°ãª
ãªãã¶ãŒã«ã¢ããŠã¬ã¢ãã¡ãããŒã«ã°ãªãªãã¶ãŒ
ã«ãžãŠã¬ã¢ããã«ã ã¢ã«ããããããã©ãªããµã³
ã°ãªã¿ã«ã¢ã«ãããããžãšãããµã€ãããžããã«
ã¹ã«ãã³ãïŒâã¡ããã·âïŒâãžã¡ãã«ãžã¡ãã
ãŒã«ãããã¬ã³ãŠã¬ã¢ãããã©ã¡ãããŒã«ã¢ã»ã
ã¬ã³ãžãŠã¬ã¢çã®ç¹ç¶æ¶æ©å€ãšãæ¶æ©è§ŠåªãäŸã
ã°é ¢é žããã¬ã€ã³é žçã®ææ©é žãå¡©åã¢ã³ã¢ããŠ
ã ãç¡«é žã¢ã³ã¢ããŠã ãçé žæ°ŽçŽ ã¢ã³ã¢ããŠã ã
çã®ã¢ã³ã¢ããŠã å¡©ããšã¿ããŒã«ã¢ãã³å¡©é žå¡©ã
ïŒâã¢ããâïŒâã¡ãã«ãããããŒã«ãã€ããã¯
ããªãçã®ã¢ãã³ãå¡©åãã°ãã·ãŠã ãç¡é žäº
éãå¡©åäºéãç¡é žãã°ãã·ãŠã ãããŠããåäº
éãå¡©åã¢ã«ãããŠã ãçé žãã°ãã·ãŠã çã§åŠ
çããæ¶æ©å€ãæ¶æ©ãããããšã«ãã颚åãæ¹è¯
ããããšãå¯èœã§ãäŸãã°ç¡¬ä»äžããè»ä»äžããª
ã©èªç±ã«èª¿ç¯ããããšãã§ããã æ¬æ¹æ³ã«é©çšãããã»ã«ããŒã¹ç³»ç¹ç¶ãšã¯ãæš
綿ã®æ§ãªå€©ç¶ã»ã«ããŒã¹ç¹ç¶ã®ã»ãããã¹ã³ãŒã¹
ã¬ãŒãšã³ã®æ§ãªåçã»ã«ããŒã¹ç¹ç¶ãå«ã¿ããã
ãã®ç¹ç¶ãšããªãšã¹ãã«çã®åæç¹ç¶ãšã®æ··åç©
ããé©çšããããšãã§ããåžåžã®ä»ã糞ã®ç¶æ ã§
ãè¯ãã åãæ¬æ¹æ³ã«æŒããŠäœ¿çšãããã¢ã«ã«ãªå€ãšã
ãŠã¯æ°Žé žåãããªãŠã ãæ°Žé žåãã°ãã·ãŠã ãæ°Ž
é žåã«ãªãŠã ãæ°Žé žåã«ã«ã·ãŠã ãçé žãããªãŠ
ã ãçé žæ°ŽçŽ ãããªãŠã ãé ¢é žã«ãªãŠã ãé ¢é žã
ããªãŠã ãé ¢é žãã°ãã·ãŠã çãçšããããšãã§
ããã åãæ¬æ¹æ³ã«é©çšãããé žå¡©åç©ãšã¯ãâã
ã«ãšã³ã¹ã«ããã«ã¯ããªããïœâããããã³ãŒã³
ã¹ã«ããã«ã¯ããªããïœâããããã³ãŒã³ã¹ã«ã
ãã«ã¯ããªããïœâããããã³ãŒã³ã¹ã«ããã«ã¯
ããªããçãçšããããšãã§ããã åãæ¬æ¹æ³ã«é©çšããã觊åªãšã¯ãæ°Žé žåãã
ãªãŠã ãæ°Žé žåã«ãªãŠã ãæ°Žé žåã«ã«ã·ãŠã ãç
é žãããªãŠã ãçé žæ°ŽçŽ ãããªãŠã ãé ¢é žã«ãªãŠ
ã ãé ¢é žãããªãŠã ãé ¢é žãã°ãã·ãŠã ãçãçš
ããããšãã§ããå ã«è¿°ã¹ãã¢ã«ã«ãªå€ãšæ®ãã©
åæ§ãªè©Šè¬ãçšããããããã¢ã«ã«ãªå€ã®å Žåã¯
é žå¡©åç©ããå ã«ç¹ç¶æ§é ç©ã«é©çšãããã»ã«ã
ãŒã¹ã®èšæœ€äœçšãšãã·ã«ååå¿ãšå¹³è¡¡ããŠé žå¡©å
ç©ããçããé žæ§ç©è³ªã®äžååå¿ã«äž»ãªãå¹æã
瀺ãã®ã«å¯Ÿããããã§è¿°ã¹ãã¢ã«ã«ãªæ§ã®è§Šåªã¯
é žå¡©åç©ã®åŸã«ç¹ç¶æ§é ç©ã«é©çšãããŠãåå¿ã®
é²è¡ã«å¯äžããäœçšå¹æãç°ã«ããããå¹æçãª
ãã·ã«ååå¿ãè¡ãããšãã§ããã ãŸãæ¬çºæã«ãããŠäœ¿çšã§ããææã¯æè¯æ§ã
æãããåã¯æããªãåæ£ææã油溶æ§ææãåª
æææãå¡©åºæ§ææã建æãææçã§ãããçŽæ¥
æºæåã¯è»¢åæºæã«ããæºæããããšãã§ããã
ç¹ã«æè¯æ§ææãçšããå Žåã¯ä¹ŸåŒè»¢åæºææ³ã
å¯èœã§ããã 以äžæŽã«ãæ¬çºæãå³é¢ãçšãã詳现ã«èª¬æã
ããããªãã¡ç¬¬ïŒå³ã¯ãæ¬çºæã«äœ¿çšããæ¹è³ªè£
眮ã®æŠç¥å³ã瀺ããã®ã§ãã»ã«ããŒã¹ç¹ç¶æ§é ç©
åã³ã»ã«ããŒã¹ç¹ç¶ãšåæç¹ç¶ã®æ··åæ§é ç©ãã
ãªãã¡ååžïŒããªãŒãããŒã«R1ãä»ããŠã¢ã«ã«
ãªå€åŠç济槜ïŒäžã«å°å ¥ãã次ãã§ã¢ã«ã«ãªå€ã®
åŠçéãåäžã«ãªãæ§ã«çµãããŒã«ïŒã«ãŠçµãã
也ç¥ãã©ã€ã€ãŒïŒãã³ãã³ã¿ãŒãªãŒãã³ïŒïŒã«ãŠ
也ç¥ãããã次ãã§ãªãŒãããŒã«R2ãä»ããŠå
åžïŒããé žå¡©åç©åŠç济槜ïŒäžã«å°å ¥ãé žå¡©åç©
ã®åŠçéãåäžã«ãªãæ§ã«çµãããŒã«ïŒã«ãŠçµ
ãã也ç¥ãã©ã€ã€ãŒïŒãã³ãã³ã¿ãŒãªãŒãã³ïŒïŒ
ã«ãŠä¹Ÿç¥ãããæŽã«ãªãŒãããŒã«R3ãä»ããŠè§Š
åªåŠç济槜ïŒäžã«å°å ¥ãã次ãã§è§Šåªã®åŠçéã
åäžã«ãªãããã«çµãããŒã«ïŒã«ãŠçµãã也ç¥ã
ã©ã€ã€ãŒïŒãã³ãã³ã¿ãŒãªãŒãã³ïŒïŒïŒã«ãŠä¹Ÿç¥
ãããã次ã«åèšåŠçããååžïŒãæŽã«èžç±åŠç
ãæœãç®çã§ãªãŒãããŒã«R4ãä»ããŠé£ç¶ã«ãŒ
ãã¹ããŒããŒïŒïŒäžã«å°å ¥ããåŸã以äžé 次氎æŽ
ïŒåã¯æ¹¯æŽïŒæµŽæ§œïŒïŒããœãŒãã³ã°æµŽæ§œïŒïŒãæ°Ž
æŽæµŽæ§œïŒïŒäžã«å°å ¥ãã次ãã§ä¹Ÿç¥ãã©ã€ã€ãŒ
ïŒãã³ãã³ã¿ãŒãªãŒãã³ïŒïŒïŒäžã«å°å ¥ããŠååŠ
æ¹è³ªåžïŒïŒã¯åŸãããã 第ïŒå³ã¯ã第ïŒå³ãšæ®ãã©åæ§ãªæ¹è³ªè£ 眮ã®æŠ
ç¥å³ã§ãããããã®å Žåã«ã¯è§ŠåªåŠç济槜ãçç¥
ããã¢ã«ã«ãªå€åŠçãšé žå¡©åç©åŠçã®ïŒå·¥çšåŠç
ã®åŸãèžç±ãè¡ãååŠæ¹è³ªãè¡ãã 以äžç¬¬ïŒå³ãšåæ§ã« ïŒååžãïŒã¢ã«ã«ãªå€åŠç济槜ãïŒçµãããŒ
ã«ãïŒä¹Ÿç¥ãã©ã€ã€ãŒãïŒé žå¡©åç©åŠç济槜ãïŒ
çµãããŒã«ãïŒä¹Ÿç¥ãã©ã€ã€ãŒãïŒïŒé£ç¶ã«ãŒã
ã¹ããŒããŒãïŒïŒæ°ŽæŽïŒåã¯æ¹¯æŽïŒæµŽæ§œãïŒïŒãœ
ãŒãã³ã°æµŽæ§œãïŒïŒæ°ŽæŽæµŽæ§œãïŒïŒä¹Ÿç¥ãã©ã€ã€
ãŒãïŒïŒååŠæ¹è³ªåžãR1ãR2ãR3ã¯ãªãŒãããŒ
ã«ã瀺ãã ããã§ç¬¬ïŒå³åã³ç¬¬ïŒå³ã«æŒãŠå¡©åæ°ŽçŽ äžæŽ»æ§
ååç©ã¯ãã®æ§è³ªã«ããé©å®ãã¢ã«ã«ãªå€åŠç济
槜ã觊åªåŠç济槜ãé žå¡©åç©åŠç济槜ã«é©éãæ·»
å ããã以äžå®æœäŸããã€ãŠèª¬æããã å®æœäŸ ïŒ (1) 第ïŒå³ã«ç€ºãè£ çœ®ãçšããŠæ¬¡ã®æ§ãªæé ã§å
åŠæ¹è³ªãè¡ã€ãã ã·ã«ã±ããå å·¥æžã¿ã®ããªãšã¹ãã«ïŒæšç¶¿ïŒ
65ïŒ35ãªã混玡ãããŒãåžãäºãã20ïŒ æ°Žé žå
ãããªãŠã 氎溶液äžã«30ç§é浞挬ããåŸãçµã
ç100ïŒ ã«ãªãæ§çµãããŒã«ã«ãŠçµã€ãã次ã«
ãã®åžã100âã®ãã³ãã³ã¿ãŒãªãŒãã³äžã«40
ç§éæ»åšãã也ç¥ãããåŸã30ïŒ éééšïŒ°âã
ã«ãšã³ã¹ã«ããã«ã¯ããªãã20ïŒ éééšããã«
ã°ãªã·ãžã«ãšãŒãã«ãåååïŒãããµã³ãšããª
ãŒã«ïŒ¢ïŒæ¥æ¬æ²¹è瀟補ïŒããã¢ã»ãã³äžã«æº¶è§£
ããã溶液äžã«30ç§é浞挬ãããããã«çµãç
100ïŒ ã®æ¡ä»¶ã«ãŠçµãåŸé¢šä¹Ÿãããããã«ãã®
åžãïŒïŒ æ°Žé žåãããªãŠã 氎溶液äžã«ïŒåé浞
挬ãããåŸã100ïŒ ã®çµãçã«ãŠçµã100âã®ã
ã³ãã³ã¿ãŒãªãŒãã³äžã«ãŠ25ç§é也ç¥ãããã
次ã«ãã®åžã100âã®åžžå§é£œåæ°Žèžæ°äžã§ïŒå
éèžç±ãè¡ããããã«æ°ŽæŽããã«ã»ã«ã»ãã±ã³
ã«ãããœãŒãã³ã°ãæ°ŽæŽãè¡ããã®åŸä¹Ÿç¥ãã
ãŠæ¹è³ªåžãåŸãã ããã§ããã«ã°ãªã·ãžã«ãšãŒãã«ã®æ·»å ã«ã
ãèžç±äžã®å¡©åæ°ŽçŽ ã®çºçã¯æžå°ããç¡æ·»å ã®
å Žåãã¹ããŒããŒããåºãŠããçŽåŸã®åžã®PH
ïŒïŒã§ãã€ãã®ã«å¯Ÿããæ·»å åŸã¯PHïŒ11ã瀺
ãããã€ã¹ããŒããŒãããããæ°Žèžæ°ã¯å šãŠäž
æ§ã瀺ããã (2) 次ã«60gïŒm2ã®çé¢ã¹ã¿ãŒãã³ãŒãçŽã«äžèš
ã®çµæã®ã€ã³ãã«ããã°ã©ãã¢å°å·ããŠè»¢åçŽ
ãåŸãã ïŒã€ã³ãïŒ ïŒã¹ãã«ãã³ã¬ããâFBL ïŒåæ«ïŒïœäœåååŠç€Ÿè£œã»ææïœ
10éš ãšãã«ã»ã«ããŒã¹ âïŒ ïŒã çé¢æŽ»æ§å€ ïŒã ã€ãœãããã«ã¢ã«ã³ãŒã« 40ã ãšã¿ããŒã« 40ã ïŒ (3) (1)ãªãæ¹è³ªåžã«(2)ãªã転åçŽãéãåããæž©
床195âãå§300gïŒcm2ãæé40ç§ã®æ¡ä»¶ã«ãŠå
ç±ãå å§ããŠè»¢åæºæãè¡ã€ããšãããããªãš
ã¹ãã«éšãæšç¶¿éšåäžèµ€è²ã®æ¿åºŠããæºæåžã
åŸãããšãã§ãããå°JISã«åºã¥ãæŽæ¿¯å ç¢åºŠ
ïŒïŒ¡âïŒïŒæ³ã«ãŠæž¬å®ãããšããïŒçŽã§ããã
å ç¢ãªæºæåžã§ãã€ãã å®æœäŸ ïŒ (1) 第ïŒå³ã«ç€ºãè£ çœ®ãçšããŠæ¬¡ã®æ§ãªæé ã§å
åŠæ¹è³ªãè¡ã€ããã·ã«ã±ããå å·¥æžã¿ã®ããªãš
ã¹ãã«ïŒæšç¶¿ïŒ65ïŒ35ãªã混玡ãã€ã³ããªãã¯
åžãäºã10ïŒ æ°Žé žåãããªãŠã 氎溶液äžã«20ç§
é浞挬ããåŸãçµãç100ïŒ ã«ãªãæ§ã«çµãã
ãŒã«ã«ãŠçµã€ãã次ã«ãã®åžã100âã®ãã³ã
ã³ã¿ãŒãªãŒãã³äžã«40ç§éæ»åšãã也ç¥ããã
åŸã30ïŒ éééšïŒ°âãã«ãšã³ã¹ã«ããã«ã¯ããª
ãã10ïŒ éééšMARK BTâ31ïŒã¢ãã«ã¢ãŒ
ã¬ã¹ç€Ÿè£œãžããã«é«ãã¬ãšãŒã系塩åæ°ŽçŽ ææ
å€ïŒãã¢ã»ãã³äžã«æº¶è§£ããã溶液äžã«20ç§é
浞挬ãããããã«çµãç120ïŒ ã®æ¡ä»¶ã«ãŠçµ
ããåŸé¢šä¹Ÿããã 次ã«ãã®åžã100âã®åžžå§é£œåæ°Žèžæ°äžã§ïŒ
åéèžç±ãè¡ããããã«æ°ŽæŽããã«ã»ã«ã»ãã±
ã³ã«ãããœãŒãã³ã°ãæ°ŽæŽãè¡ãããã®åŸä¹Ÿç¥
ãããŠæ¹è³ªåžãåŸããããã§ãžããã«é«ãã¬ãš
ãŒãç³»ã®å¡©åæ°ŽçŽ ææå€ã®æ·»å ã«ããèžç±äžã®
å¡©åæ°ŽçŽ ã®çºçã¯å®æœäŸïŒãšåæ§ã¹ããŒããŒã
ãåºãŠããçŽåŸã®åžã®PHã¯ã¢ã«ã«ãªæ§ã瀺ã
ãã€ã¹ããŒããŒãããããæ°Žèžæ°ã¯å šãŠäžæ§ã
瀺ããã ãªãããã®æã®åžã®æ¹è³ªçœ®æ床ïŒD.SïŒã¯æ¬¡
åŒã«ããèšç®ãããš0.22ã§ãã€ãã D.S.ïŒ æ¹è³ªåŸã®åžééå¢å éÃïŒã°ã«ã³ãŒã¹åäœïŒæ¹è³ªå
ã®åžééÃ混玡çÃïŒãã·ã«åºâïŒïŒ (2) 次ã«ãã®æ¹è³ªåžã«å®æœäŸïŒã®(2)ã§åŸããã転
åçŽãçšããŠã枩床195âãå§å300gïŒcm2ãæ
é40ç§ã®æ¡ä»¶ã§è»¢åæºæãè¡ã€ããšãã極ããŠ
çŸããæºæåžãåŸãã å®æœäŸ ïŒ (1) 第ïŒå³ã«ç€ºãè£ çœ®ãçšããŠæ¬¡ã®æ§ãªæé ã§å
åŠæ¹è³ªãè¡ã€ããã·ã«ã±ããå å·¥æžã¿ã®ããªãš
ã¹ãã«ïŒæšç¶¿ïŒ65ïŒ35ãªã混玡ãããŒãåžãäº
ãã10ïŒ éééšæ°Žé žåãããªãŠã åã³15ïŒ éé
éšé ¢é žã¢ã³ã¢ããŠã æ··å氎溶液äžã«20ç§é浞挬
ããåŸãçµãç100ïŒ ã«ãªãæ§ã«çµãããŒã«ã«
ãŠçµã€ãã次ã«ãã®åžã100âã®ãã³ãã³ã¿ãŒ
ãªãŒãã³äžã«40ç§éãæ»åšãã也ç¥ãããåŸ30
ïŒ éééšïŒ°âãã«ãšã³ã¹ã«ããã«ã¯ããªãåã³
10ïŒ éééšMARK ACâ141ïŒã¢ãã«ã¢ãŒã¬ã¹
瀟補BaâZnè€åéå±ç³ãããå¡©åæ°ŽçŽ ææ
å€ïŒæ··åç©ãã¡ãã«ãšãã«ã±ãã³äžã«æº¶è§£ãã
ã溶液äžã«20ç§é浞挬ãããããã«çµãç120
ïŒ ã®æ¡ä»¶ã«ãŠçµããåŸé¢šä¹Ÿããã次ã«ãã®åžã
100âã®åžžå§é£œåæ°Žèžæ°äžã§ïŒåéèžç±ãè¡
ããããã«æ°ŽæŽããœãŒãã³ã°æ°ŽæŽãè¡ãããã®
åŸä¹Ÿç¥ãããŠæ¹è³ªåžãåŸããããã§é ¢é žã¢ã³ã¢
ããŠã åã³è€åéå±ç³ããã®æ·»å ã«ããã¹ããŒ
ããŒããåºãŠããçŽåŸã®åžã®PHã¯ã¢ã«ã«ãªæ§
ã瀺ãã®ãšåæã«ã¹ããŒããŒãããããæ°Žèžæ°
ã¯è¥å¹²ã®ã¢ã³ã¢ãã¢èãæããäžæ§ãªããã¯ã¢
ã«ã«ãªæ§ãåããã (2) 次ã«ãã®æ¹è³ªåžã«å®æœäŸïŒåæ§è»¢åæºæãè¡
ã€ããšããçŸããæºæåžãåŸãã å®æœäŸ ïŒ (1) å®æœäŸïŒã®åŠãæ¹è³ªåžãåŸãã次ã«ãã®æ¹è³ª
åžã以äž(ã€)ã®åŠæ¹ã®æº¶æ¶²ã«æµžãããã®åŸçµãç
80ïŒ ã«çµãã100âãïŒåéå也ç¥ããã次ã
ã§150âãïŒåéããŒãã³ã°ããã (ã€) åŠæ¹ ïŒã¹ãããã¯ã¹ã¬ãžã³AMH3000ïŒäœåå
åŠïŒ ïŒã¢ã¯ãªã«é žãšã¹ãã«ãšãã«ãžãšã³ïŒ
10éééš ã¹ãããã¯ã¹ã¢ã¯ã»ã¬ã¬ãŒã¿ãŒïŒžâ80 ïŒäœåååŠïŒ ïŒéééš ïŒæ°Ž 90 ã ïŒïŒ (2) 次ã«è»¢åçŽã¯ïŒå®æœäŸïŒïŒã®åŠãäœæããã (3) (1)ãªãæ¹è³ªåžã«(2)ãªã転åçŽãéãåããã
枩床195âãå§300gïŒcm2ãæé40ç§ã®æ¡ä»¶ã§å
ç±ãå å§ããŠè»¢åãè¡ã€ããšãããããªãšã¹ã
ã«éšãæšç¶¿éšåäžèµ€è²ã®æ¿åºŠã圩ããæ·±ã¿ã®ã
ãæºæåžãåŸãããšãã§ãããæŽæ¿¯å ç¢åºŠã枬
å®ãããšããïŒïŒ¡âïŒïŒæ³ã«ãŠïŒçŽã§ãããå
ç¢ãªæºæåžã§ãã€ããå°ãæš¹èåŠçãããã®ãš
ããªããã®ã®è»¢åæºæåžããã¯ãã¹åå°æ¿åºŠèš
ã«ãŠçºè²æ¿åºŠã枬å®ãããšãããåè ã¯1.05ã
åŸè ã¯1.28ã§ãããæãããªæ¿åºŠã®å¢ãã¿ãã
ãã å®æœäŸ ïŒ (1) æ¹è³ªåžãïŒå®æœäŸïŒïŒã®åŠãäœæããã次ã«
ãã®æ¹è³ªåžã以äž(ã)ã®åŠæ¹ã®æº¶æ¶²ã«æµžãããã®
åŸçµãç80ïŒ ã«çµãã100âãïŒåéå也ç¥
ãã次ãã§150âãïŒåéããŒãã³ã°ããã (ã) åŠæ¹ ã¹ãããã¯ã¹ã¬ãžã³NSâ16ïŒäœåååŠïŒ
10éééš ïŒã¹ãããã¯ã¹ã¢ã¯ã»ã¬ã¬ãŒã¿ãŒïŒžâ80 ïŒäœåååŠïŒ ïŒ ã ïŒã¹ãããã¯ã¹ãœãããŒïŒ¬ïŒäœåååŠïŒ
ïŒ ã ïŒ ïŒæ°Ž 90 ã ïŒ (2) 転åçŽã¯å®æœäŸ ïŒã®åŠãäœæããã (3) (1)ãªãæ¹è³ªåžã«(2)ãªã転åçŽãéãåããã
枩床200âãå§300gïŒcm2ãæé40ç§ã®æ¡ä»¶ã§å
ç±ãå å§ããŠè»¢åãè¡ã€ããšãããããªãšã¹ã
ã«éšãæšç¶¿éšåäžèµ€è²ã®æ¿åºŠãåã³é¢šåã®è¯å¥œ
ãªæºæåžãåŸãããã å®æœäŸ ïŒ (1) ã·ã«ã±ããå å·¥æžã¿ã®ããªãšã¹ãã«ïŒæšç¶¿ïŒ
65ïŒ35ãªã混玡ãããŒãåžãäºã20ïŒ æ°Žé žåã«
ãªãŠã 氎溶液äžã«30ç§é浞挬ããåŸãçµãç
100ïŒ ã®å²åã§çµã€ãã次ã«ãã®åžã100âã®ãª
ãŒãã³äžã§40ç§é也ç¥ãããåŸã25ïŒ éééšïŒ¯
âããããã³ãŒã³ã¹ã«ããã«ã¯ããªããã¢ã»ã
ã³ïŒãã«ãªãŒã«ïŒïŒïŒïŒæ··å溶液äžã«æº¶è§£ãã
ãäžã«30ç§é浞挬ãããããã«çµãç100ïŒ ã®
æ¡ä»¶ã«ãŠçµãåŸé¢šä¹Ÿããã ããã«ãã®åžã15ïŒ éééšã®é ¢é žãã°ãã·ãŠ
ã åã³ïŒïŒ éééšã®ãããã³ïŒ¡âïŒïŒã¹ã®ã ã©
ååŠå·¥æ¥ç€Ÿè£œé žæŽæå¶å€ïŒææ©ã¢ãã³ç³»ïŒæ··å
氎溶液äžã«ïŒåé浞挬ãããåŸã100ïŒ ã®çµã
çã«ãŠçµã100âã®ãªãŒãã³äžã«ãŠ25ç§é也ç¥
ãããã次ã«ãã®åžã130âã®é«æž©ãé«å§é£œå
æ°Žèžæ°äžã«ãŠ10åéèžç±ãè¡ããæ°ŽæŽãœãŒãã³
ã°ãè¡ã€ãåŸã也ç¥ãããŠæ¹è³ªåžãåŸãã ãã®å Žåãå¡©åæ°ŽçŽ ã®çºçã¯èªãããããã¹
ããŒããŒã®æ質ã§ãã18âïŒã¹ãã³ã¬ã¹
ïŒSUS304ïŒãžã®è èæ§ã¯èããããããããšã
ã§ããã (2) 次ã«ãã®æ¹è³ªåžã«åžçå°å·ïŒæ ªïŒç€Ÿè£œã®æè¯
転åæºæçŽã«ãŠ195âã300gïŒcm2ã40ç§ãªãæ¡
件ã«ãŠè»¢åæºæãè¡ã€ããšããçŸããããªã³ã
åžãåŸãã å®æœäŸ ïŒ å®æœäŸ ïŒã§åŸãããååŠæ¹è³ªåžãçšããäžèš
ããåŠæ¹ãããªãæºæã€ã³ãã«ãŠã·ã«ã¯ã¹ã¯ãªãŒ
ã³å°å·æ¹åŒã«ããçŽæ¥æºæãè¡ã€ãåŸã130âã®
é«æž©é«å§é£œåèžæ°äžã«ãŠ20åéã¹ããŒãã³ã°ãè¡
ã€ãåŸããœãŒãã³ã°ã也ç¥ãããšãã極ããŠçŸã
ãããªã³ãåžãåŸãã ïŒæºæã€ã³ãïŒ ïŒã¬ãŸãªã³ãã«ãŒFBLïŒãã€ãšã«ç€ŸææïŒ
ïŒéš ã¢ã«ã®ã³é žãœãŒã㌠ïŒéš æ°Ž 87éšïŒ å®æœäŸ ïŒ å®æœäŸ ïŒã«æŒãŠ100âåžžå§é£œåæ°Žèžæ°äžã§ïŒ
åéèžç±ãè¡ã代ãã«ã130âã®ä¹Ÿç±ãªãŒãã³äž
ã«ãŠïŒåéããŒãã³ã°ãè¡ã€ããšããå®æœäŸïŒãš
åæ§ååŠæ¹è³ªåžã¯åŸããããã転åæºæããåŸã®
çºè²æ¿åºŠããã¯ãã¹ã®åå°æ¿åºŠèšã«ãŠãå®æœäŸïŒ
ã§ã¯1.30ã§ããã®ã«å¯Ÿããå®æœäŸïŒã§ã¯1.05ãšæ¹
質ã®å¹æãèžç±ã®æ¹ãåªããŠããããšãå€æã
ãã
å³é¢ã¯æ¬çºæã®äžå®æœäŸã瀺ããã®ã§ç¬¬ïŒå³å
ã³ç¬¬ïŒå³ã¯æ¬çºæã®æè²æ¹æ³ã«äœ¿çšããæ¹è³ªè£ 眮
ã®æŠç¥å³ã瀺ãã ïŒâŠååžãïŒâŠã¢ã«ã«ãªå€åŠç济槜ãïŒïŒïŒïŒ
ïŒâŠçµãããŒã«ãïŒïŒïŒïŒïŒïŒïŒïŒïŒâŠä¹Ÿç¥ãã©
ã€ã€ãŒïŒãã³ãã³ã¿ãŒãªãŒãã³ïŒãïŒâŠé žå¡©åç©
åŠç济槜ãïŒâŠè§ŠåªåŠç济槜ãïŒïŒâŠé£ç¶ã«ãŒã
ã¹ããŒããŒãïŒïŒâŠæ°ŽæŽïŒåã¯æ¹¯æŽïŒæµŽæ§œãïŒïŒ
âŠãœãŒãã³ã°æµŽæ§œãïŒïŒâŠæ°ŽæŽæµŽæ§œãïŒïŒâŠååŠ
æ¹è³ªåžãïŒïŒâŠæ°ŽæŽæµŽæ§œãR1ïŒR2ïŒR3ïŒR4âŠãª
ãŒãããŒã«ã
ã³ç¬¬ïŒå³ã¯æ¬çºæã®æè²æ¹æ³ã«äœ¿çšããæ¹è³ªè£ 眮
ã®æŠç¥å³ã瀺ãã ïŒâŠååžãïŒâŠã¢ã«ã«ãªå€åŠç济槜ãïŒïŒïŒïŒ
ïŒâŠçµãããŒã«ãïŒïŒïŒïŒïŒïŒïŒïŒïŒâŠä¹Ÿç¥ãã©
ã€ã€ãŒïŒãã³ãã³ã¿ãŒãªãŒãã³ïŒãïŒâŠé žå¡©åç©
åŠç济槜ãïŒâŠè§ŠåªåŠç济槜ãïŒïŒâŠé£ç¶ã«ãŒã
ã¹ããŒããŒãïŒïŒâŠæ°ŽæŽïŒåã¯æ¹¯æŽïŒæµŽæ§œãïŒïŒ
âŠãœãŒãã³ã°æµŽæ§œãïŒïŒâŠæ°ŽæŽæµŽæ§œãïŒïŒâŠååŠ
æ¹è³ªåžãïŒïŒâŠæ°ŽæŽæµŽæ§œãR1ïŒR2ïŒR3ïŒR4âŠãª
ãŒãããŒã«ã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ã»ã«ããŒã¹ç¹ç¶æ§é ç©åã³ã»ã«ããŒã¹ç¹ç¶ãš
åæç¹ç¶ã®æ··åæ§é ç©ããäžèšããæ§é ïŒïŒã
æããååç©ãçšããŠå¡©åæ°ŽçŽ ãäžæŽ»æ§ãšããå
åç©ïŒïŒãïŒïŒãïŒïŒãïŒïŒãïŒïŒãææ©ã¢
ã
ã³ãåã¯ã¢ã³ã¢ããŠã å¡©ã®ããããã®å ±åäžã§èž
ç±åŠçåã¯ä¹Ÿç±åŠçã«ãŠååŠæ¹è³ªãããã®åŸã«å
æ£ææã油溶æ§ææãåªæã æãå¡©åºæ§ææã建
æãææçã«ãŠçŽæ¥åã¯è»¢åæºæããããšãç¹åŸŽ
ãšããæè²æ¹æ³ã () ãåŒã ïŒïŒžã¯âNO2ãâCH3ããæå³ããïŒ () äžèšæ§é ã®éå±ç³ããã ïŒïŒOOCRïŒ2åã¯AlïŒOOCRïŒ2ïŒOHïŒ ïŒïŒã¯CaãBaãZnãSnãMgãCdãPbãªã©ã®
éå±ãã¯ãã¢ã«ãã«åºïŒ ãæå³ããã () äžèšæ§é ã®ææ©ã¹ãºååç© ïŒïœã¯ïœåã¯æŽæ°ãã¯ã¢ã«ãã«åº ã¯ãR1COOâãR2OOCâïŒïŒ£âCOOâã
R3SâãR4OOCâCH2ââïŒR1ãR2ãR3ãR4ã¯
ã¢ã«ãã«åºïŒ ã¯ãããâOOCCHïŒCHCOOâãæå³ã
ããïŒ () äžèšæ§é ã®èèªæãšããã·ååç© ãåŒã äžã«ãåŒããæãã ïŒïŒ²ã¯ã¢ã«ãã«åºïŒ () äžèšæ§é ã®èèªæãšããã·ååç© RCOORⲠäžã«ãåŒããæãã ïŒïŒ²ãRâ²ã¯ã¢ã«ãã«åºïŒ () äžèšæ§é ã®èèªæãšããã·ååç© ãåŒã ïŒïŒ²ã¯ã¢ã«ãã«åºãã¢ãªã«åºïŒ ïŒ ã»ã«ããŒã¹ç¹ç¶æ§é ç©åã³ã»ã«ããŒã¹ç¹ç¶ãš
åæç¹ç¶ã®æ··åæ§é ç©ãååŠæ¹è³ªããåŸãæŽã«å
æ£ææã«å¯ææ§ããã€æš¹èã«ãŠåŠçããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®æ¹æ³ã ïŒ ã»ã«ããŒã¹ç¹ç¶æ§é ç©åã³ã»ã«ããŒã¹ç¹ç¶ãš
åæç¹ç¶ã®æ··åæ§é ç©ãååŠæ¹è³ªããåŸãæŽã«ç¹
ç¶æ¶æ©å€ãšæ¶æ©è§Šåªã«ãŠåŠçããç¹èš±è«æ±ã®ç¯å²
第ïŒé ãã第ïŒé ã®ããããã«èšèŒã®æ¹æ³ã
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5786779A JPS55152877A (en) | 1979-05-11 | 1979-05-11 | Dyeing method |
| US06/087,923 US4286958A (en) | 1978-11-01 | 1979-10-25 | Method of dyeing cellulose fiber-containing structures |
| DE19792943175 DE2943175A1 (de) | 1978-11-01 | 1979-10-25 | Verfahren zum anfaerben von aus cellulosefasern oder einem gemisch aus cellulosefasern und kunstfasern bestehenden fasergebilden |
| AU52324/79A AU530012B2 (en) | 1978-11-01 | 1979-10-30 | Dyeing cellulose fibre-containing structures |
| FR7927061A FR2441016A1 (fr) | 1978-11-01 | 1979-10-31 | Procede de teinture de structures contenant des fibres de cellulose |
| CA000338899A CA1139503A (en) | 1978-11-01 | 1979-10-31 | Method of dyeing cellulose fiber-containing structures |
| GB7937791A GB2035386B (en) | 1978-11-01 | 1979-10-31 | Method of dyeing cellulose fibre-containing structures |
| CH982779A CH651996GA3 (ja) | 1978-11-01 | 1979-11-01 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5786779A JPS55152877A (en) | 1979-05-11 | 1979-05-11 | Dyeing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55152877A JPS55152877A (en) | 1980-11-28 |
| JPS6215676B2 true JPS6215676B2 (ja) | 1987-04-08 |
Family
ID=13067930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5786779A Granted JPS55152877A (en) | 1978-11-01 | 1979-05-11 | Dyeing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55152877A (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH044589U (ja) * | 1990-04-27 | 1992-01-16 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5442478A (en) * | 1977-09-09 | 1979-04-04 | Toyo Boseki | Dyeability enhancing method of cellulosic fiber |
-
1979
- 1979-05-11 JP JP5786779A patent/JPS55152877A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5442478A (en) * | 1977-09-09 | 1979-04-04 | Toyo Boseki | Dyeability enhancing method of cellulosic fiber |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH044589U (ja) * | 1990-04-27 | 1992-01-16 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55152877A (en) | 1980-11-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Vickerstaff | Reactive dyes for textiles | |
| US4369041A (en) | Technique for dyeing and printing of textiles with quaternary ammonium compound | |
| US6500215B1 (en) | Utility of selected amine oxides in textile technology | |
| DE2417335B2 (de) | Verfahren zum FÀrben von PoIyÀthylenterephthalat-Fasern enthaltendem Textilgut | |
| US2228369A (en) | Dyeing animal fibrous materials | |
| US3049446A (en) | Process for the manufacture of urea, glyoxal and formaldehye reaction product useful for improving cellulosic textile materials | |
| JP3438504B2 (ja) | ã»ã«ããŒã¹ç³»ç¹ç¶å«æç¹ç·šç©ã®æš¹èå å·¥æ¹æ³ | |
| US5667533A (en) | Heather dyed fabric and method of producing same | |
| US3211514A (en) | Process for dyeing and printing netrugen-containhng fibers | |
| JPS6215676B2 (ja) | ||
| US3178250A (en) | Fiber improving process and product | |
| US2316057A (en) | Textile material | |
| US4286958A (en) | Method of dyeing cellulose fiber-containing structures | |
| US20230089849A1 (en) | Pad-steam cationization of textiles | |
| DE1109135B (de) | Textilveredlungsverfahren | |
| US3492080A (en) | Reaction of polymeric materials containing reactive hydrogen with monofunctional beta-oxyethyl sulfones | |
| JPS6039790B2 (ja) | æ¹è³ªæ¹æ³ | |
| JPS6215675B2 (ja) | ||
| JPS5917230B2 (ja) | æè²æ¹æ³ | |
| JPS5934829B2 (ja) | æè²æ¹æ³ | |
| JPS6316518B2 (ja) | ||
| US3895907A (en) | Turnbull{3 s blue single bath mineral dyeing process (ferri-zirc) for cellulosic textiles | |
| JPS6158597B2 (ja) | ||
| US3794466A (en) | Single bath chromic chloride mineral dyeing process for cellulosics | |
| JPS6220318B2 (ja) |