JPS621297B2 - - Google Patents
Info
- Publication number
- JPS621297B2 JPS621297B2 JP15707081A JP15707081A JPS621297B2 JP S621297 B2 JPS621297 B2 JP S621297B2 JP 15707081 A JP15707081 A JP 15707081A JP 15707081 A JP15707081 A JP 15707081A JP S621297 B2 JPS621297 B2 JP S621297B2
- Authority
- JP
- Japan
- Prior art keywords
- uranium
- lower alkyl
- alkyl group
- general formula
- ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052770 Uranium Inorganic materials 0.000 claims description 46
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims description 24
- 239000003463 adsorbent Substances 0.000 claims description 23
- 239000004793 Polystyrene Substances 0.000 claims description 13
- 229920002223 polystyrene Polymers 0.000 claims description 13
- 239000011324 bead Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 229920000620 organic polymer Polymers 0.000 claims description 4
- HFFXLYHRNRKAPM-UHFFFAOYSA-N 2,4,5-trichloro-n-(5-methyl-1,2-oxazol-3-yl)benzenesulfonamide Chemical compound O1C(C)=CC(NS(=O)(=O)C=2C(=CC(Cl)=C(Cl)C=2)Cl)=N1 HFFXLYHRNRKAPM-UHFFFAOYSA-N 0.000 claims 2
- -1 uranium ion Chemical class 0.000 description 26
- 238000001179 sorption measurement Methods 0.000 description 11
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 8
- 239000013535 sea water Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 6
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 6
- 239000004471 Glycine Substances 0.000 description 5
- 239000003446 ligand Substances 0.000 description 5
- 229940000635 beta-alanine Drugs 0.000 description 4
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000001099 ammonium carbonate Substances 0.000 description 3
- 235000012501 ammonium carbonate Nutrition 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 2
- 108010077895 Sarcosine Proteins 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 235000004279 alanine Nutrition 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- SFZULDYEOVSIKM-UHFFFAOYSA-N chembl321317 Chemical group C1=CC(C(=N)NO)=CC=C1C1=CC=C(C=2C=CC(=CC=2)C(=N)NO)O1 SFZULDYEOVSIKM-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229940043230 sarcosine Drugs 0.000 description 2
- 229940124530 sulfonamide Drugs 0.000 description 2
- 150000003456 sulfonamides Chemical class 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- TXPKUUXHNFRBPS-UHFFFAOYSA-N 3-(2-carboxyethylamino)propanoic acid Chemical compound OC(=O)CCNCCC(O)=O TXPKUUXHNFRBPS-UHFFFAOYSA-N 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- ORRFEHQKEUMQKF-UHFFFAOYSA-N OCCNS(=O)=O Chemical compound OCCNS(=O)=O ORRFEHQKEUMQKF-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- BUSBFZWLPXDYIC-UHFFFAOYSA-N arsonic acid Chemical group O[AsH](O)=O BUSBFZWLPXDYIC-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000000565 sulfonamide group Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15707081A JPS5858149A (ja) | 1981-10-01 | 1981-10-01 | 溶存ウランイオン吸着剤およびその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15707081A JPS5858149A (ja) | 1981-10-01 | 1981-10-01 | 溶存ウランイオン吸着剤およびその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5858149A JPS5858149A (ja) | 1983-04-06 |
| JPS621297B2 true JPS621297B2 (enrdf_load_stackoverflow) | 1987-01-12 |
Family
ID=15641569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15707081A Granted JPS5858149A (ja) | 1981-10-01 | 1981-10-01 | 溶存ウランイオン吸着剤およびその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5858149A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0428387U (enrdf_load_stackoverflow) * | 1990-06-29 | 1992-03-06 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101408773B1 (ko) * | 2012-12-14 | 2014-06-17 | 한국수산자원관리공단 | 우라늄 이온 회수용 아미드옥심-풍부 나노 섬유 및 이의 제조방법 |
-
1981
- 1981-10-01 JP JP15707081A patent/JPS5858149A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0428387U (enrdf_load_stackoverflow) * | 1990-06-29 | 1992-03-06 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5858149A (ja) | 1983-04-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101701042B (zh) | 羧甲基壳聚糖硫脲树脂,其制备方法和应用 | |
| CN112280052B (zh) | 一种多级孔zif-8材料及其制备方法与应用 | |
| CN114768780A (zh) | 一种Zn-Fe普鲁士蓝类似物复合材料的制备方法及应用 | |
| JPH0822722B2 (ja) | 混合ガスからの酸素分離方法及びそれに使用する固体状組成物 | |
| JPH0420930B2 (enrdf_load_stackoverflow) | ||
| JPS621297B2 (enrdf_load_stackoverflow) | ||
| JP4228077B2 (ja) | ハイドロタルサイトの脱炭酸イオンによる、イオン交換性のある陰イオンを有する層状水酸化物の製造方法 | |
| JPS587412A (ja) | キレ−ト樹脂とその製造方法及び吸着処理方法 | |
| US4830999A (en) | Zeolite containing entrapped anionic material | |
| JPS6248725A (ja) | 金属キレート形成能を有する架橋ポリエチレンイミン系高分子化合物の製法 | |
| JP4873751B2 (ja) | 二酸化炭素除去剤とその再生方法 | |
| JP2894788B2 (ja) | ガス吸着用複鎖構造型粘度鉱物金属担持担体の製造方法 | |
| CN115216022A (zh) | 硫醇化的Zr基金属有机骨架及其制备方法和应用 | |
| JPS63224735A (ja) | ガリウム回収用吸着剤 | |
| He et al. | Preparation and coordination behavior of cellulose beads derivative modified by 1, 5‐diaminoethyl‐3‐hydroxy‐1, 5‐diazacycloheptane | |
| Kawamoto et al. | Regeneration and reuse of hydrotalcite-like anion exchanger with high selectivity to phosphate anion | |
| CN113856633B (zh) | 一种双金属配位聚合物吸附剂、制备方法及其应用 | |
| JPS637837A (ja) | ウラン吸着材 | |
| JPS63277240A (ja) | ウラン吸着材 | |
| Mphahlele et al. | Recovery of Pt and Pd From Aqueous Solutions by N, N-di (trimethoxysilylpropyl)-N′-benzoylthiourea Modified Silica Gel | |
| JPS63287547A (ja) | 弗化物イオンの吸着剤 | |
| JP3589510B2 (ja) | 新規鉄錯体、その製造方法及び用途 | |
| JPS63205140A (ja) | 一酸化窒素の吸着剤および分離除去法 | |
| CN116536770A (zh) | 一种钴(ii)配合物单晶及其制备方法和应用 | |
| JPH0675674B2 (ja) | ウラン吸着材 |