JPS62119237A - 導電性有機高分子化合物用ド−パント - Google Patents
導電性有機高分子化合物用ド−パントInfo
- Publication number
- JPS62119237A JPS62119237A JP25877085A JP25877085A JPS62119237A JP S62119237 A JPS62119237 A JP S62119237A JP 25877085 A JP25877085 A JP 25877085A JP 25877085 A JP25877085 A JP 25877085A JP S62119237 A JPS62119237 A JP S62119237A
- Authority
- JP
- Japan
- Prior art keywords
- dopant
- fluorine
- electrically
- polymer compound
- polypyrrole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002019 doping agent Substances 0.000 title claims abstract description 21
- 150000001875 compounds Chemical class 0.000 title claims description 13
- 229920000642 polymer Polymers 0.000 title description 7
- 239000002253 acid Substances 0.000 claims abstract description 18
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 14
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011737 fluorine Substances 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 5
- 229920000620 organic polymer Polymers 0.000 claims description 10
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 14
- 229920000128 polypyrrole Polymers 0.000 abstract description 12
- 229920001940 conductive polymer Polymers 0.000 abstract description 6
- 229920000123 polythiophene Polymers 0.000 abstract description 4
- 238000002848 electrochemical method Methods 0.000 abstract description 2
- 230000002441 reversible effect Effects 0.000 abstract description 2
- 239000007772 electrode material Substances 0.000 abstract 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 12
- 239000003792 electrolyte Substances 0.000 description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 5
- -1 p-toluenesulfonic acid ions Chemical class 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- 229920000767 polyaniline Polymers 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 239000008151 electrolyte solution Substances 0.000 description 4
- 238000000921 elemental analysis Methods 0.000 description 4
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- QENGPZGAWFQWCZ-UHFFFAOYSA-N 3-Methylthiophene Chemical compound CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- YVBBRRALBYAZBM-UHFFFAOYSA-N perfluorooctane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YVBBRRALBYAZBM-UHFFFAOYSA-N 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical class CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N p-toluenesulfonic acid Substances CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 229920000414 polyfuran Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- VBQDSLGFSUGBBE-UHFFFAOYSA-N benzyl(triethyl)azanium Chemical class CC[N+](CC)(CC)CC1=CC=CC=C1 VBQDSLGFSUGBBE-UHFFFAOYSA-N 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 229940021013 electrolyte solution Drugs 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002468 redox effect Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical class CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25877085A JPS62119237A (ja) | 1985-11-20 | 1985-11-20 | 導電性有機高分子化合物用ド−パント |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25877085A JPS62119237A (ja) | 1985-11-20 | 1985-11-20 | 導電性有機高分子化合物用ド−パント |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62119237A true JPS62119237A (ja) | 1987-05-30 |
| JPH0138808B2 JPH0138808B2 (enrdf_load_stackoverflow) | 1989-08-16 |
Family
ID=17324842
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25877085A Granted JPS62119237A (ja) | 1985-11-20 | 1985-11-20 | 導電性有機高分子化合物用ド−パント |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62119237A (enrdf_load_stackoverflow) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0218416A (ja) * | 1988-07-06 | 1990-01-22 | Tosoh Corp | 導電性高分子複合体の製造方法 |
| JPH03501264A (ja) * | 1987-08-07 | 1991-03-22 | アライド‐シグナル・インコーポレーテッド | 導電性ポリアニリンの熱安定な形 |
| WO2005100473A1 (en) * | 2004-04-13 | 2005-10-27 | E.I. Dupont De Nemours And Company | Conductive polymer composites |
| WO2005100464A1 (en) * | 2004-04-13 | 2005-10-27 | E.I. Dupont De Nemours And Company | Compositions of electrically conductive polymers and non-polymeric fluorinated organic acids |
| JP2009093880A (ja) * | 2007-10-05 | 2009-04-30 | Toyota Central R&D Labs Inc | 蓄電デバイス |
| JP2010509405A (ja) * | 2006-06-30 | 2010-03-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 導電性ポリマーと部分フッ素化酸ポリマーとの安定化組成物 |
| US8216680B2 (en) | 2006-02-03 | 2012-07-10 | E I Du Pont De Nemours And Company | Transparent composite conductors having high work function |
| US8241526B2 (en) | 2007-05-18 | 2012-08-14 | E I Du Pont De Nemours And Company | Aqueous dispersions of electrically conducting polymers containing high boiling solvent and additives |
| US8318046B2 (en) | 2002-09-24 | 2012-11-27 | E I Du Pont De Nemours And Company | Water dispersible polyanilines made with polymeric acid colloids for electronics applications |
| US8338512B2 (en) | 2002-09-24 | 2012-12-25 | E I Du Pont De Nemours And Company | Electrically conducting organic polymer/nanoparticle composites and method for use thereof |
| US8409476B2 (en) | 2005-06-28 | 2013-04-02 | E I Du Pont De Nemours And Company | High work function transparent conductors |
| USRE44853E1 (en) | 2005-06-28 | 2014-04-22 | E I Du Pont De Nemours And Company | Buffer compositions |
| US8845933B2 (en) | 2009-04-21 | 2014-09-30 | E I Du Pont De Nemours And Company | Electrically conductive polymer compositions and films made therefrom |
| US8945427B2 (en) | 2009-04-24 | 2015-02-03 | E I Du Pont De Nemours And Company | Electrically conductive polymer compositions and films made therefrom |
| US8945426B2 (en) | 2009-03-12 | 2015-02-03 | E I Du Pont De Nemours And Company | Electrically conductive polymer compositions for coating applications |
-
1985
- 1985-11-20 JP JP25877085A patent/JPS62119237A/ja active Granted
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03501264A (ja) * | 1987-08-07 | 1991-03-22 | アライド‐シグナル・インコーポレーテッド | 導電性ポリアニリンの熱安定な形 |
| JPH0218416A (ja) * | 1988-07-06 | 1990-01-22 | Tosoh Corp | 導電性高分子複合体の製造方法 |
| US8318046B2 (en) | 2002-09-24 | 2012-11-27 | E I Du Pont De Nemours And Company | Water dispersible polyanilines made with polymeric acid colloids for electronics applications |
| US8338512B2 (en) | 2002-09-24 | 2012-12-25 | E I Du Pont De Nemours And Company | Electrically conducting organic polymer/nanoparticle composites and method for use thereof |
| WO2005100473A1 (en) * | 2004-04-13 | 2005-10-27 | E.I. Dupont De Nemours And Company | Conductive polymer composites |
| WO2005100464A1 (en) * | 2004-04-13 | 2005-10-27 | E.I. Dupont De Nemours And Company | Compositions of electrically conductive polymers and non-polymeric fluorinated organic acids |
| JP2007532359A (ja) * | 2004-04-13 | 2007-11-15 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 導電性ポリマー複合体 |
| US7354532B2 (en) * | 2004-04-13 | 2008-04-08 | E.I. Du Pont De Nemours And Company | Compositions of electrically conductive polymers and non-polymeric fluorinated organic acids |
| US7837902B2 (en) | 2004-04-13 | 2010-11-23 | E. I. Du Pont De Nemours And Company | Compositions of electrically conductive polymers and non-polymeric fluorinated organic acids |
| US8147962B2 (en) | 2004-04-13 | 2012-04-03 | E. I. Du Pont De Nemours And Company | Conductive polymer composites |
| USRE44853E1 (en) | 2005-06-28 | 2014-04-22 | E I Du Pont De Nemours And Company | Buffer compositions |
| US8409476B2 (en) | 2005-06-28 | 2013-04-02 | E I Du Pont De Nemours And Company | High work function transparent conductors |
| US8216680B2 (en) | 2006-02-03 | 2012-07-10 | E I Du Pont De Nemours And Company | Transparent composite conductors having high work function |
| US8273459B2 (en) | 2006-02-03 | 2012-09-25 | E I Du Pont De Nemours And Company | Transparent composite conductors having high work function |
| US8343630B2 (en) | 2006-02-03 | 2013-01-01 | E I Du Pont De Nemours And Company | Transparent composite conductors having high work function |
| US8383009B2 (en) | 2006-06-30 | 2013-02-26 | E I Du Pont De Nemours And Company | Stabilized compositions of conductive polymers and partially fluorinated acid polymers |
| JP2010509405A (ja) * | 2006-06-30 | 2010-03-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 導電性ポリマーと部分フッ素化酸ポリマーとの安定化組成物 |
| US8241526B2 (en) | 2007-05-18 | 2012-08-14 | E I Du Pont De Nemours And Company | Aqueous dispersions of electrically conducting polymers containing high boiling solvent and additives |
| JP2009093880A (ja) * | 2007-10-05 | 2009-04-30 | Toyota Central R&D Labs Inc | 蓄電デバイス |
| US8945426B2 (en) | 2009-03-12 | 2015-02-03 | E I Du Pont De Nemours And Company | Electrically conductive polymer compositions for coating applications |
| US8845933B2 (en) | 2009-04-21 | 2014-09-30 | E I Du Pont De Nemours And Company | Electrically conductive polymer compositions and films made therefrom |
| US8945427B2 (en) | 2009-04-24 | 2015-02-03 | E I Du Pont De Nemours And Company | Electrically conductive polymer compositions and films made therefrom |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0138808B2 (enrdf_load_stackoverflow) | 1989-08-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4992559A (en) | Polymerizable thiophene monomers | |
| Palaniappan | Chemical and electrochemical polymerization of aniline using tartaric acid | |
| JPS62119237A (ja) | 導電性有機高分子化合物用ド−パント | |
| CN1059914A (zh) | 自掺杂聚合物的制备方法 | |
| PT85579B (pt) | Processo para a preparacao de polimeros soluveis electricamente condutores | |
| JP7084587B2 (ja) | ポリマー、電極活物質及び二次電池 | |
| US5120807A (en) | Polymerization of pyrrole and its derivatives | |
| KR100996257B1 (ko) | 폴리(5-아미노퀴녹살린)의 제조 방법 | |
| JPS63215722A (ja) | 電導性ポリアニリン系化合物の製造方法 | |
| US4505842A (en) | Heteroazole electroactive polymers | |
| JPH02240163A (ja) | 高分子導電性溶液 | |
| JPS6253328A (ja) | Ｎ，ｎ’―ジフェニルベンジジン重合体の製造方法 | |
| GB2268500A (en) | Conductive polymeric composite | |
| JPH0574467A (ja) | 高分子固体電解質 | |
| JPH02218716A (ja) | 有機半導体及びその製造方法 | |
| JPH03174437A (ja) | 導電性ポリマー | |
| JPH06239996A (ja) | 電導性高分子及びその製造方法 | |
| JPH01261471A (ja) | 改善された溶解性を持つ導電性重合体 | |
| JP2003040856A (ja) | ｍ−フルオロベンゼンスルホン酸誘導体およびドーパント剤 | |
| US5331072A (en) | Polyazopyrroles and electric cells based thereon | |
| US5162470A (en) | Polymers with electrical and nonlinear optical properties | |
| JPH07238150A (ja) | 自己ドープ型導電性ポリマー水溶液及びその製造方法 | |
| JPH0555533B2 (enrdf_load_stackoverflow) | ||
| JPH01144418A (ja) | ポリ芳香族アミンの製造方法 | |
| US5210219A (en) | Bis-sulfonium salts of 2,5-dimethylstilbene |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |