JPS62110922A - リグニン炭素繊維の製造法 - Google Patents
リグニン炭素繊維の製造法Info
- Publication number
- JPS62110922A JPS62110922A JP24779385A JP24779385A JPS62110922A JP S62110922 A JPS62110922 A JP S62110922A JP 24779385 A JP24779385 A JP 24779385A JP 24779385 A JP24779385 A JP 24779385A JP S62110922 A JPS62110922 A JP S62110922A
- Authority
- JP
- Japan
- Prior art keywords
- lignin
- organic solvent
- treating
- heat
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005610 lignin Polymers 0.000 title claims abstract description 76
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 14
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title abstract description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 28
- 239000003960 organic solvent Substances 0.000 claims abstract description 20
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 13
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 10
- 238000002844 melting Methods 0.000 claims abstract description 9
- 230000008018 melting Effects 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000009987 spinning Methods 0.000 claims abstract description 6
- 239000003513 alkali Substances 0.000 claims abstract description 4
- 238000010000 carbonizing Methods 0.000 claims abstract description 3
- 239000011261 inert gas Substances 0.000 claims abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 33
- 239000002023 wood Substances 0.000 abstract description 20
- 238000007254 oxidation reaction Methods 0.000 abstract description 7
- 230000003381 solubilizing effect Effects 0.000 abstract description 2
- 229910001873 dinitrogen Inorganic materials 0.000 abstract 2
- 244000274847 Betula papyrifera Species 0.000 abstract 1
- 235000009113 Betula papyrifera Nutrition 0.000 abstract 1
- 235000009109 Betula pendula Nutrition 0.000 abstract 1
- 235000010928 Betula populifolia Nutrition 0.000 abstract 1
- 235000002992 Betula pubescens Nutrition 0.000 abstract 1
- 238000004517 catalytic hydrocracking Methods 0.000 abstract 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 17
- 238000010438 heat treatment Methods 0.000 description 14
- 239000002994 raw material Substances 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 229920002488 Hemicellulose Polymers 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000012943 hotmelt Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 230000000977 initiatory effect Effects 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- 238000011105 stabilization Methods 0.000 description 4
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 238000003763 carbonization Methods 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 239000000401 methanolic extract Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229930183217 Genin Natural products 0.000 description 2
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 2
- 229910000564 Raney nickel Inorganic materials 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000007380 fibre production Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000003808 methanol extraction Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003809 water extraction Methods 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- 241000616862 Belliella Species 0.000 description 1
- 240000006055 Dacrydium cupressinum Species 0.000 description 1
- 235000018782 Dacrydium cupressinum Nutrition 0.000 description 1
- 241001602688 Pama Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 235000013697 Pinus resinosa Nutrition 0.000 description 1
- 239000007868 Raney catalyst Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 206010061592 cardiac fibrillation Diseases 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 244000309146 drought grass Species 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000002600 fibrillogenic effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 229920005611 kraft lignin Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Compounds Of Unknown Constitution (AREA)
- Inorganic Fibers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24779385A JPS62110922A (ja) | 1985-11-05 | 1985-11-05 | リグニン炭素繊維の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24779385A JPS62110922A (ja) | 1985-11-05 | 1985-11-05 | リグニン炭素繊維の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62110922A true JPS62110922A (ja) | 1987-05-22 |
| JPH0433889B2 JPH0433889B2 (enExample) | 1992-06-04 |
Family
ID=17168732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24779385A Granted JPS62110922A (ja) | 1985-11-05 | 1985-11-05 | リグニン炭素繊維の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62110922A (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012112108A1 (en) * | 2011-02-14 | 2012-08-23 | Innventia Ab | Method for producing a lignin fiber |
| CN103397404A (zh) * | 2013-07-15 | 2013-11-20 | 北京林业大学 | 一种提高木质活性碳纤维比表面积的方法 |
| JP2015508128A (ja) * | 2012-01-23 | 2015-03-16 | インヴェンティア・アクチボラゲットＩｎｎｖｅｎｔｉａ Ａｂ | 炭素繊維へとさらに変換するためのリグニン繊維の安定化方法 |
| TWI611054B (zh) * | 2017-03-28 | 2018-01-11 | 柯漢哲 | 酒糟與貝殼炭化粉粒複合纖維之製法 |
| JP2022065830A (ja) * | 2020-10-16 | 2022-04-28 | 林テレンプ株式会社 | 車両のフロア敷設構造体 |
-
1985
- 1985-11-05 JP JP24779385A patent/JPS62110922A/ja active Granted
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012112108A1 (en) * | 2011-02-14 | 2012-08-23 | Innventia Ab | Method for producing a lignin fiber |
| US9446955B2 (en) | 2011-02-14 | 2016-09-20 | Innventia Ab | Method for producing a lignin fiber |
| JP2015508128A (ja) * | 2012-01-23 | 2015-03-16 | インヴェンティア・アクチボラゲットＩｎｎｖｅｎｔｉａ Ａｂ | 炭素繊維へとさらに変換するためのリグニン繊維の安定化方法 |
| CN103397404A (zh) * | 2013-07-15 | 2013-11-20 | 北京林业大学 | 一种提高木质活性碳纤维比表面积的方法 |
| TWI611054B (zh) * | 2017-03-28 | 2018-01-11 | 柯漢哲 | 酒糟與貝殼炭化粉粒複合纖維之製法 |
| JP2022065830A (ja) * | 2020-10-16 | 2022-04-28 | 林テレンプ株式会社 | 車両のフロア敷設構造体 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0433889B2 (enExample) | 1992-06-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |