JPS6210811B2 - - Google Patents
Info
- Publication number
- JPS6210811B2 JPS6210811B2 JP57091491A JP9149182A JPS6210811B2 JP S6210811 B2 JPS6210811 B2 JP S6210811B2 JP 57091491 A JP57091491 A JP 57091491A JP 9149182 A JP9149182 A JP 9149182A JP S6210811 B2 JPS6210811 B2 JP S6210811B2
- Authority
- JP
- Japan
- Prior art keywords
- polyvinyl alcohol
- water
- preform
- coating
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000576 coating method Methods 0.000 claims abstract description 103
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 101
- 239000011248 coating agent Substances 0.000 claims abstract description 86
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 67
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 62
- 238000000034 method Methods 0.000 claims abstract description 40
- 238000002844 melting Methods 0.000 claims abstract description 33
- 230000008018 melting Effects 0.000 claims abstract description 33
- 238000001816 cooling Methods 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 238000001125 extrusion Methods 0.000 claims abstract description 11
- 239000012768 molten material Substances 0.000 claims abstract description 10
- 238000005520 cutting process Methods 0.000 claims abstract description 9
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 8
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 8
- 230000004888 barrier function Effects 0.000 claims abstract description 7
- 230000008569 process Effects 0.000 claims abstract description 6
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 3
- 239000002243 precursor Substances 0.000 claims abstract description 3
- -1 poly(alkylene glycol Chemical compound 0.000 claims description 17
- 229920005992 thermoplastic resin Polymers 0.000 claims description 11
- 239000000155 melt Substances 0.000 claims description 10
- 238000004898 kneading Methods 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 238000004804 winding Methods 0.000 claims description 2
- 238000007664 blowing Methods 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 238000010008 shearing Methods 0.000 abstract description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 57
- 239000000758 substrate Substances 0.000 description 18
- 229920000728 polyester Polymers 0.000 description 14
- 238000000071 blow moulding Methods 0.000 description 11
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 10
- 239000010410 layer Substances 0.000 description 9
- 238000001035 drying Methods 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000005253 cladding Methods 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000011194 food seasoning agent Nutrition 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 229920008790 Amorphous Polyethylene terephthalate Polymers 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- FYIBGDKNYYMMAG-UHFFFAOYSA-N ethane-1,2-diol;terephthalic acid Chemical compound OCCO.OC(=O)C1=CC=C(C(O)=O)C=C1 FYIBGDKNYYMMAG-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004278 EU approved seasoning Substances 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 230000002547 anomalous effect Effects 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000010076 replication Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229920006126 semicrystalline polymer Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010104 thermoplastic forming Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/22—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor using multilayered preforms or parisons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/15—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
- B29C48/151—Coating hollow articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/78—Measuring, controlling or regulating
- B29C2049/7879—Stretching, e.g. stretch rod
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/08—Biaxial stretching during blow-moulding
- B29C49/087—Means for providing controlled or limited stretch ratio
Landscapes
- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Materials For Medical Uses (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Dental Preparations (AREA)
Description
æ¬çºæã¯ç®¡ç¶ãã©ã³ã¯ãããªãœã³åã¯ããªããª
ãŒã ãåºçºææãšããŠå¹èŸŒã¿æ圢ã«ãã補é ãã
ãç±å¯å¡æ§æš¹è補ã®äºè»žå»¶äŒžè€åäžç©ºäœã®è£œé æ¹
æ³ã«é¢ãããããã«è©³ããããã°ãæ¬çºæã¯ã¬ã¹
åã³èª¿å³çšéŠæã«å¯ŸããŠäžééæ§ã®ããªãšã¹ãã«
補äºè»žå»¶äŒžäžç©ºäœã®è£œé æ¹æ³ã«é¢ãããæ¬çºæã¯
ãŸãåæ¹æ³ã«ããåŸãããæ¹åãããæ§è³ªãæã
ãäžç©ºäœã«é¢ãããããã«ãæ¬çºæã¯åžèŸŒæ圢ã«
ãã€ãŠäºè»žå»¶äŒžäžç©ºäœãäžãã管ç¶ãã©ã³ã¯ãã
ãªãœã³åã¯ããªããªãŒã ã«é¢ããã æ¬æ现æžã«ãããŠã¯ãã管ç¶ãã©ã³ã¯ããšãã
çšèªã¯ã䞡端ã®éããäžè¬ã«é·ã管ã®äžéšåã§ã
ãããã®é·ããäŸãã°50cmãªããïŒïœä»¥äžã«éã
ãããšããããã®ãæå³ãããã®ãšããããããª
ãœã³ããšããçšèªã¯ã䞡端ã®éãã管ã®äžéšåã§
ããé·ããäžè¬ã«ïŒcmãªãã20cmã®ãã®ãæãã
ã®ãšããããããªããªãŒã ããšããçšèªã¯ãé·ã
ãããªãœã³ãšåããåã¯ç°ãªããäžç«¯ãéãä»ç«¯
ããã§ã«æçµç圢ç¶ã«æ圢ãããéæŸç«¯ãããªã
ã¡ããã¯ãã§ãã管ã®éšåãæããã®ãšããã äžç©ºäœã®åéã§ã¯è¿å¹Žç±å¯å¡æ§æš¹èãæ¥éãªçº
å±ãéããŠãããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãã¯
ããªããªãŒã ã®äºè»žå»¶äŒžå¹èŸŒæ圢ã«ãã€ãŠæ©æ¢°ç
æ§è³ªïŒç¹ã«èè¡ææ§åã³å å§æµææ§ïŒã«åªããã
ã³ã圢æãã泚ç®ãã¹ãèœåããã€ãŠããã®ã§å
å§æ¶²äœåã³çºæ³¡é£²æã®å å¡«ã«æå©ã«äœ¿çšã§ããã
ãšã¯åšç¥ã§ããããããã調å³çšéŠæãå ¥ã€ãŠã
ãããé žçŽ ã«å¯Ÿããæåæ§ãé«ãã€ãããçé žã
å ¥ã€ãŠãããããããã¯ããããçµã¿åããããŠ
ãããããªæ¶²äœã®å Žåã«ã¯ãããªãã¬ãã¿ã¬ãŒã
補äžç©ºäœã®ã¬ã¹åã³èª¿å³çšéŠæã«å¯Ÿããäžééæ§
ãäžååã§ããçµæãå å¡«ããã補åã¯ãã°ãã°
éãããæéããè¯å¥œãªç¶æ ãä¿ãŠãªãããã®çŸ
象ã¯ãäžç©ºäœã®å£åãèãã»ã©ããŸãå 容ç©ã®äœ
ç©ã«å¯Ÿãã容åšã®è¡šé¢ç©ã®æ¯ãé«ãã»ã©ãé¡èã«
ãªããäžç©ºäœã®ééçãäœäžãããããã«ãåºæ
ãããã¬ã¹ééçã®äœãããªã€ææãäžç©ºäœè¡šé¢
ã«å¡åžããããšããã§ã«ææ¡ãããŠããã ä»åœç¹èš±ç¬¬2416784å·åã³å第2416785å·ã«ã¯ã
ããªããã«ã¢ã«ã³ãŒã«ãããªãšãã¬ã³ãã¬ãã¿ã¬
ãŒã補äºè»žå»¶äŒžãã³çšã®åªç§ãªããªã€ææãšããŠ
䜿çšã§ããããšãèšèŒãããŠãããäžèšç¹èš±èšèŒ
ã®æ¹æ³ã«ããã°ãããªããªãŒã ãäºè»žå¹èŸŒå»¶äŒžã
ãåã«ãããªããã«ã¢ã«ã³ãŒã«æ°Žæº¶æ¶²ã®å¡åžåã¯
ããªããã«ã¢ã«ã³ãŒã«æº¶æ¶²åã³æ°Žã«å¯Ÿããæåæ§
ã®äœãéåäœã©ããã¯ã¹ãå«æããæ°Žæ§çµæç©ã®
å¡åžã«ãããããªããªãŒã ã®å£é¢ã®å°ãªããšãäž
é¢ã«è¢«èŠãé©çšãããã®è¢«èŠã也ç¥ããŠããããª
ããªãŒã ãäºè»žå¹èŸŒå»¶äŒžããŠããã ãããããã®ç¹æ®ãªæè¡ã¯äŸç¶ãšããŠååã«æº
足ã§ãããã®ã§ã¯ãªãããã®çç±ã¯ãããªããã«
ã¢ã«ã³ãŒã«èªäœããåºçºãããšè¢«èŠã®èæ°Žæ§ãäž
ååã§ããããã€å·¥æ¥çã«æå©ãªæ¹æ³ã§åã被èŠ
ã補é ããããšãã§ããªãããã§ãããå®éãæ°Ž
æ§å¡åžã«ãã被èŠã®é©çšã«ã¯éåäœæ¿åºŠã®äœãå¡
åžæ¶²ã®äœ¿çšãé¢äžããŠããããã®äž»ãªçç±ã¯ïŒã€
ããããã®äžã€ã¯ãããªããã«ã¢ã«ã³ãŒã«ã¯é«æ¿
床ã§ã¯æ°Žã«æº¶è§£ãåŸãªãããšãšãä»ã®çç±ã¯é«ç²
床åªäœã§å¡åžãè¡ãªãããšã¯å°é£ãªããã§ããã
åŸã€ãŠãå¡åžã«ãã€ãŠããªãå°éã®ææããä»ç
ããæçµçã«åŸããã被èŠã®åãã¯å°ãããäžè¬
ã«ããªããªãŒã ã§20ãªãã50ÎŒãæçµäžç©ºäœã§ïŒ
ãªããïŒÎŒã§ãããããå Žåã«ã¯ãç¹ã«ãã³ãé ž
çŽ æåæ§ãé«ããåã¯çé žã®å«æéã®é«ãããã
ãã¯ãã®åæ¹ã®æ¶²äœãå容ããããäŒå³ãããå Ž
åã«ã¯ãäžéæ§ããªã€ææã®æå¹æ§ãé«ãããã
ã«åã被èŠãèšããããšãæãŸãããããªãã¡ã
奜é©ãªè¢«èŠåã¯äžè¬ã«ããªããªãŒã ã§0.1ãªãã
ïŒmmãæçµäžç©ºäœã§10ãªãã200ÎŒã§ããããã®
ãããªåãã¯ãã¡ããæ°Žæ§å¡åžã«ããåŸããã
ãããã®ç®çãéæããããã«ã¯ãé£ç¶ããŠæ°å±€
ãé©çšããæºåãå®å°ã«ããå¿ èŠãããããäžé£
ã®æ°å±€ã®è¢«èŠå±€ã®å Žåã«ã¯è¡šé¢å±€ãäžå±€ã®ä¹Ÿç¥ã
劚ã也ç¥ããªããšåé¢ãèµ·ããã®ã§ãåäžéå±€ã
é©åœã«ä¹Ÿç¥ãããªããã°ãªããªããæåŸã«ã被èŠ
å±€ãè€æ°ã§ããããšãšä¹Ÿç¥æäœãå¿ èŠãªãããå
ãå±€ãä»çãããããã«å¡åžã«ãã被èŠããããš
ã®å·¥æ¥ç䟡å€ããã¹ãŠå€±ãªãããã æ¬çºæã®ç®çã¯ãå€å±€å¡åžãããéææ§ãšå æ²¢
ã®ææã®æ§è³ªãä¿æããåã被èŠãçŽæ¥ä»çãã
ããšã®ã§ããæ¹æ³ãæäŸããããšã«ããã æ¬çºæã®å¥ã®ç®çã¯ãåãã ãã§ãªãèæ°Žæ§ã®
éåžžã«ãã被èŠãä»çããããšã®ã§ããæ¹æ³ãæ
äŸããããšã«ããã ãããã®ç®çã®äžéšåã¯å šéšãæ¬çºæã®æ¹æ³ã«
ãã€ãŠéæããåŸãããšãèŠåºãããã ããªãã¡ãæ¬çºæã¯ããŸãããªããã«ã¢ã«ã³ãŒ
ã«ç³»ããªã€ææã§è¢«èŠããã管ç¶ãã©ã³ã¯ãããª
ãœã³åã¯ããªããªãŒã ã補é ãã次ãã§ããã®ç®¡
ç¶ãã©ã³ã¯ãããªãœã³åã¯ããªããªãŒã ãæ £çšã®
äºè»žå»¶äŒžæž©åºŠæ¡ä»¶ã§äºè»žå»¶äŒžå¹èŸŒæ圢ããããšã
ãæãã¬ã¹äžééæ§ã®èæ°Žæ§è¢«èŠãåããç±å¯å¡
æ§æš¹è補äºè»žå»¶äŒžäžç©ºäœã®è£œé æ¹æ³ã«ãããŠãäž
èšç®¡ç¶ãã©ã³ã¯ãããªãœã³åã¯ããªããªãŒã ã®è£œ
é ã以äžã®äžé£ã®å·¥çšã (a) 20æªæºã®ãšã¹ãã«äŸ¡ãæããçŽããªããã«ã¢
ã«ã³ãŒã«ãšæ°Žããæãå«æ°Žéã25ã35ééïŒ ã§
ãããã¬ãŒã¯ãæŒåºãæ©ã«å°å ¥ããå·¥çšã (b) åèšãã¬ãŒã¯ãæŒåºãæ©ã«ãããŠè©²ãã¬ãŒã¯
ãæ§æããããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©ã®
平衡èç¹ããã100â以äžé«ã枩床ã§æ··ç·Žè解
ããå·¥çšã (c) å·åŽã«ããããã€ã¹å ã®æº¶èæŒåºãç©ã®æž©åºŠ
ãåœè©²ããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©ã®å¹³è¡¡
èç¹ä»¥äžã§ãããæŒåºãæ©å€ã§ã®æ°æ³¡åœ¢æã«ã
ãææã®è¢«èŠã®èšåŒµãèµ·ããã®ã«ååãªæ°Žã®èž
æ°å§ãçãã枩床ããã¯äœãå€ã«ãªãããå¶åŸ¡
ããªãããç±å¯å¡æ§æš¹è補ã®ç®¡ãããªãœã³åã¯
ããªããªãŒã ãå¡åžããã®ã«é©ãã被èŠãã€ã¹
ãéããŠæº¶èææãæŒåºãããã®å Žåã«ãåèš
ã®æº¶èæŒåºç©ã®å·åŽãã溶èæŒåºç©ãããã€ã¹
ãééããåã«ãæŒåºãæ©ã®ã·ãŒã¹ç«¯éšãšè¢«èŠ
ãã€ã¹ãšã®éã«æ¿å ¥ãããå·åŽãã¢ãžãã€ã¶ã
䜿çšããŠå®æœããå·¥çšãããã³ (d) ãã®ããã«ããŠè¢«èŠããã管ãããªãœã³åã¯
ããªããªãŒã ãå·»åãã管ã®å Žåã«ã¯ããã«æ
æã®é·ãã«åæããããšã«ãã€ãŠç®¡ç¶ãã©ã³
ã¯ãããªãœã³ãåã¯ããªããªãŒã ã®åé§äœã®ç®¡
åçã«è»¢æããå·¥çšã ãå«ãããšãç¹åŸŽãšããæ¹æ³ãæäŸããã æ¬æ现æžã«ãããçšèªãå·åŽãã¢ãžãã€ã¶ã
ã¯ã倧ããªå§åéäžãªãã«å¹çã®ããå質ãªç±äº€
æãå¯èœã«ããïŒã€ä»¥äžã®éçãããµéšæãå«ã
æ§é ãæããå·åŽåšå Œãã¢ãžãã€ã¶ãæå³ããã äžèšæ¹æ³ã«é©çšãåŸãå€åœ¢äŸãšããŠãäžèšå·¥çš
(a)åã³(b)ã«ç¶ããŠäžèšå·¥çš(c)ã®æ¿ãã«ã (e) ã±ãŒã·ã³ã°ã圢æããããã«äžèšæž©åºŠæ¡ä»¶äž
ã§ç°ç¶ãã€ã¹ãéããŠæº¶èææãæŒåºãå¹èŸŒã¿
æ圢ããå·¥çšãå㯠(e)Ⲡ管ç¶ã®æº¶èææã®æŒåºãã«æ¬¡ãã§ç®¡ãªã³ã°
ã®è£œé æè¡ã«åŸãã€ãŠãæ»é¢å£ãæããå¯åã·
ãšãŒããçšããææã®ã±ãŒã·ã³ã°ã圢æããã
ãã«ããããªç©ºæ°å§ãå åŽããäžããŠç®çå®ã
æäœãããå·¥çšãåã³ (f) é©åœãªãã°æšªã«åæããåŸãäžèšã±ãŒã·ã³ã°
ã管ãããªãœã³åã¯ããªããªãŒã ã«é©çšãåŸã
ã¹ãªãŒããšããŠäœ¿çšããå·¥çšã ãå®æœããããšããæãäŸãæããããšãã§ã
ãã äžèšã®ããã«è¢«èŠããã管ãããªãœã³åã³ããª
ããªãŒã ã¯æçµçã«äºè»žå»¶äŒžå¹èŸŒæ圢工çšã§äœ¿çš
ããåã«å€§æ°äžã§å±éºãªãã«è²¯èµã§ããã æ¬çºæã®å¥œãŸããå®æœæ æ§ã¯å·¥çš(a)åã³(b)次ã
ã§(c)ãè¡ãªãã管ã¯ç©å±€ã«ãã€ãŠè¢«èŠããããã
ã®å Žåã¯ãç±å¯å¡æ§æš¹è補管ã®æŒåºãã«çŽæ¥æ¥ç¶
ããŠè¡ãªãããšãã§ããã æ¬çºæã®å¥ã®å¥œãŸããå®æœæ æ§ã¯å·¥çš(a)ã(b)ã
åã³(e)åã¯(e)â²ã次ãã§(f)ãè¡ãªããã¹ãªãŒãã¯
ããªããªãŒã ã«é©çšãããããã®å Žåã被èŠæäœ
ã¯ããªããªãŒã ã®ããã¯ã®åºéšããéãã端éšãŸ
ã§å»¶ã³ãŠãã延䌞å¯èœãªççŽã®éšåãåã«è¢«èŠã
ãããšã«ãã€ãŠè¡ãªãããã ãæŒåºãæ©ããšããçšèªã¯æŒåºãææãé²è¡ã
ãéäžæ垯ããããªãè£ çœ®ãæããã®ãšãããã
ã®çš®ã®è£ 眮ã¯åšç¥ã§ãããïŒã€ä»¥äžã®ã¹ã¯ãªãŠã
å ·åããããšãã§ããã æ¬çºæã®æ¹æ³ã¯ãäŸãã°æšæºåã¯é«è¡æåããª
ã¹ãã¬ã³ãå¡©åããã«ãšã¢ã¯ãªããããªã«ã®ãã¢
ããªããŒãšã³ããªããŒãããªã¢ã¯ãªã¬ãŒããšããª
ã¡ã¿ã¯ãªã¬ãŒãåã³ããªã«ãŒãããŒãã®ãããªé
æ¶æ§ããªããŒã«é©çšã§ããããŸããäŸãã°é«å¯åºŠ
åã³äœå¯åºŠããªãšãã¬ã³ãããªãããã¬ã³ãããª
ããã³âïŒäžŠã³ã«ãšãã¬ã³âãããã¬ã³å ±éåäœ
ã®ãããªããªãªã¬ãã€ã³é¡ãããªã«ããã©ã¯ã¿
ã ãããªã¢ããâïŒïŒïŒãããªã¢ããâ11åã³ã
ãªã¢ããâ12ã®ãããªããªã¢ããé¡ãããªãªãã·
ã¡ãã¬ã³é¡ãããªïŒãšãã¬ã³ã°ãªã³ãŒã«ïŒãããª
ïŒãããã¬ã³ã°ãªã³ãŒã«ïŒãããªïŒããã¬ã³ã°ãªã³
ãŒã«ïŒåã¯ããªïŒïŒïŒïŒâãžããããã·ã¡ãã«ã·
ã¯ããããµã³ïŒã®ãã¬ãã¿ã¬ãŒããããã¿ã¬ããŒ
ãåã³ããããã·ãã³ãŸãšãŒãããããã®å ±éå
äœåã³æ··åç©ã®ãããªé£œåããªãšã¹ãã«é¡ã®ãã
ãªåçµæ¶æ§ããªããŒã«ãé©çšã§ããã åºæã圢æããããã®å¥œãŸããç±å¯å¡æ§æš¹èã¯
ããªïŒã¢ã«ãã¬ã³ã°ãªã³ãŒã«ïŒãã¬ãã¿ã¬ãŒãã§
ãããç¹ã«æå©ãªææã¯ããšãã¬ã³ã°ãªã³ãŒã«ã
ã¬ãã¿ã¬ãŒãã®åç¬éåäœåã¯é žæåã95ïŒ ä»¥äž
ã®ãã¬ãã¿ã«é žããæãããžãªãŒã«æåã95ïŒ ä»¥
äžã®ãšãã¬ã³ã°ãªã³ãŒã«ããæããšãã¬ã³ã°ãªã³
ãŒã«ãã¬ãã¿ã¬ãŒãå ±éåäœããæãããªã«ãã¯
ããããšããŒã«äžã§æž¬å®ããåºæç²åºŠã奜ãŸãã
ã¯0.60ãªãã1.2dlïŒïœã§ããæš¹èã§ããã ããªããã«ã¢ã«ã³ãŒã«ã¯ãäžè¬ã«ããªé ¢é žãã
ã«ã®ãããªããªããã«ãšã¹ãã«é¡ã®å æ°Žå解ã«ã
ã€ãŠè£œé ãããã æ¬çºæã®æ¹æ³ã«ãããŠäœ¿çšãããããªããã«ã¢
ã«ã³ãŒã«ã¯é«çŽåºŠã®ååç©ã§ããã詳ãããã
ãšããšã¹ãã«äŸ¡ã20æªæºã®äœãšã¹ãã«äŸ¡ããã€ã
ãå æ°Žå解ãããããªããã«ã¢ã«ã³ãŒã«ã䜿çšã
ãŠããã ãã®ã°ã«ãŒãã®äœãšã¹ãã«äŸ¡ããã€ããªããã«
ã¢ã«ã³ãŒã«ãããã·ã³ãžãªã¿ã¯ãèŠçŽ ã®æ¯çïŒã·
ã³ãžãªã¿ã¯ã床ïŒ50ééïŒ è¶ ãç°åå«é1.5éé
ïŒ æªæºåã³ïŒïŒïŒâã°ãªã³ãŒã«é£éã®ãããªç°åžž
æ§é èŠçŽ ã®æ¯çã100ã¢ãããŒåœã1.5ç°åžžé£éæª
æºã§ããããªããã«ã¢ã«ã³ãŒã«ãéžã¶ã®ã奜ãŸã
ãã ãã®ã¿ã€ãã®ããªããã«ã¢ã«ã³ãŒã«ã§ãšã¹ãã«
䟡ã10æªæºã®ãã®ãç¹ã«å¥œé©ã§ããã ããªããã«ã¢ã«ã³ãŒã«ã®ååéã¯éèŠã§ã¯ãª
ããäžèšåŸæ¥æè¡ã§ããªããã«ã¢ã«ã³ãŒã«æ°Žæº¶æ¶²
ã䜿çšããå Žåãšã¯å¯Ÿç §çã§ãããéå床ããªã¹
ãã¯ã«ãåç²åºŠèšã䜿çšããŠ20âã§æž¬å®ãããæ°Ž
溶液ééã®ïŒééïŒ åŒ·åºŠã®ç²åºŠã«ãã€ãŠç¹åŸŽã¥ã
ãããå Žåã«ã¯ãïŒãªãã70cPoã«ããããã¹ãŠ
ã®ç²åºŠç¯å²ã®åžè²©è£œåã䜿çšããããšãã§ããã å·¥çš(a)ã®æŒåºãæ©ã«å°å ¥ããããªããã«ã¢ã«ã³
ãŒã«ã®ãã¬ãŒã¯ã«ã€ããŠã¯ããã®ééå«æ°Žéã¯ã
ãã以äžå€ããªããšç°å¢æž©åºŠïŒ20âïŒã§æº¶èæŒåº
ç©ãè¿ éã«çµæ¶åããªããªãããããã®é以äžã§
ããã詳ããããã°ããã¬ãŒã¯ã®å«æ°Žéã¯50éé
ïŒ ä»¥äžã奜ãŸããã¯25ãªãã35ééïŒ ã®å€ã«åºå®
ãããããããã®æ¡ä»¶ã®äžã§ã¯ãäžæŠç°å¢æž©åºŠãŸ
ã§å·åŽãããšãç±å¯å¡æ§æš¹è補åºæã«ä»çãã被
èŠã¯çŽã¡ã«ç²çæ§ã倱ãªãã®ã§ã被èŠãããåºæ
ã®åæ±ãã容æã§ãããäºãéšåçã«ä¹Ÿç¥ããå¿
èŠããªãã ããªããã«ã¢ã«ã³ãŒã«ã®ãã¬ãŒã¯ã¯å ¬ç¥ã®æ¹æ³
ã«åŸã€ãŠãããªããã«ã¢ã«ã³ãŒã«ã®ç²æ«ã«éžã°ã
ãéã®æ°Žãå«æµžãããé©åœãªãããµãŒã䜿çšããŠ
60âãªãã90âçšåºŠã®æž©åºŠã§åŠçããããšã«ãã
補é ããããæ°Žã®éãäžèšéçå ã«ãããšãç²ç
ããªãããè¯å¥œãªæµåæ§ãæãããã¬ãŒã¯ãåŸã
ããããã¬ãŒã¯ã®ãµã€ãºã¯ãæŒåºãæ©ã®åäžé絊
ã«é¢ä¿ããããéèŠãªæ§è³ªã§ã¯ãªããåºãç¯å²ã§
å€æŽããããšãã§ããã äžèšã®ããã«ãæ¬çºæã®æ¹æ³ãå®æœããäžã§æ¬
質çãªæ¡ä»¶ã®äžã€ã¯ããã¬ãŒã¯ã®æ··ç·Žãšè解ãã
ã¬ãŒã¯ãæ§æããããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··å
ç©ã®å¹³è¡¡èç¹ããé«ã枩床ã§è¡ãªãããšã§ããã ããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©ã®å¹³è¡¡èç¹ã¯
次ã®é¢ä¿åŒããèšç®ããããšãã§ããã ïŒïŒïŒïŒïŒ¶ïŒšïŒïŒ¯ã»ïŒïŒïŒïŒŽâïŒïŒïŒŽâ²ïŒïŒ3.6â0.8ã»
ïŒïŒ¯ïŒïŒŽã»103 äžåŒäžãH2Oã¯åé¡ã®æ··åç©äžã®æ°Žã®äœç©å
çã§ãããã¯åé¡ã®æ··åç©äžã®å¹³è¡¡èç¹ïŒãïŒ
ã§ããããã€Tâ²ã¯ããªããã«ã¢ã«ã³ãŒã«ã®èç¹
ïŒ493ãïŒã§ãããäžèšé¢ä¿åŒã¯ãžã€ãŒãã«ã»ãª
ãã»ã¢ãã©ã€ãã»ããªããŒã»ãµã€ãšã³ã¹ã第20å·»
第1457â1465é ïŒ1976ïŒã«æ²èŒãããè«æäžã®ã
ãŒã¿ã«åºããŠç¢ºç«ãããã®ã§ããã äžèšé¢ä¿åŒãã次ã®çåŒãå°ãããã ïŒãïŒïŒ1000ã»ïŒïŒïŒïŒïŒã»ïŒ¶ïŒšïŒïŒ¯ ïŒïŒïŒïŒïŒïŒ
ïŒïŒïŒïŒïŒã»ïŒ¶ïŒšïŒïŒ¯ ããã«ãæ°Žã®äœç©åçãH2Oãã¯ééåçH
ïŒïŒ¯ãšæ¬¡ã®ããã«é¢ä¿ã¥ããããã H2OïŒïœïŒ°ïŒ¶ïŒ¡ã»ïŒ°ïŒšïŒïŒ¯ïŒïŒïŒïŒ°ïŒšïŒïŒ¯ã»ïŒïœïŒ°
âïŒïŒ äžåŒäžãïœPVAã¯ããªããã«ã¢ã«ã³ãŒã«ã®å¯åºŠ
ãè¡šãããïœPVAã®å€ã1.29ãšãããšã次ã®é¢ä¿
åŒãåŸãããã H2OïŒïŒïŒïŒïŒã»ïŒ°ïŒšïŒïŒ¯ïŒïŒïŒïŒïŒïŒïŒã»ïŒ°ïŒšïŒ
 æ·»ä»å³é¢ã®ç¬¬ïŒå³ã¯ã平衡èç¹ã®å€ãâïŒïŒŽâ
273ïŒã§ããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©äžã®æ°Ž
ã®ééåçH2Oã®é¢æ°ãšããŠè¡šãã代衚çã°ã©
ãã§ããã ããªããã«ã¢ã«ã³ãŒã«ã®ãã¬ãŒã¯ã®æ··ç·Žåã³è
解枩床ã¯æº¶èç©äžã«ç°è³ªçžãçããªãããã«éžã°
ããããã®æž©åºŠã¯ã䜿çšããæ°Žã®éã«äŸåãã以
å€ã«ã·ã€ãªã³ã°ïŒããæïŒã®çšåºŠåã³æéã«äŸå
ãã奜ãŸããã¯ãåé¡ã®ããªããã«ã¢ã«ã³ãŒã«â
æ°Žæ··åç©ã®å¹³è¡¡èç¹ãã100â以äžé«ã枩床ã§ã
ããããã«å¥œãŸããã¯ãäžèšã®å¥œãŸããç¯å²å ã
ã150âãªãã220âã®ç¯å²ãšãªãããã«éžã°ã
ãã æ°ŽãçŽ30ééïŒ ã®æ¯çïŒïŒ°H2OïŒ0.3ïŒã§å«æã
ããã¬ãŒã¯ãäŸã«æããŠèå¯ãããããã®æ¯çã¯
æ¬çºæã®å®æœã«ç¹ã«é©ããŠããããšã«æ³šæãã¹ã
ã§ããã第ïŒå³ã®ã°ã©ãã¯çŽ60âã®å¹³è¡¡èç¹ã瀺
ããŠãããããã«ãããšãæŒåºãæ©äžã®ãã¬ãŒã¯
ã®æ··ç·Žã»è解ã¯60âããé«ã枩床ã奜ãŸããã¯
160â以äžã®æž©åºŠã§è¡ãªããããããã«å¥œãŸãã
ã¯ã160âãš220âã®éã®æž©åºŠãéžã°ããã äžèšã®ããã«ãæ¬çºæã®æ¹æ³ãå®æœããããã®
ããäžã€ã®æ¬è³ªçæ¡ä»¶ã¯ã被èŠãã€ã¹äžã§ã溶è
æŒåºææ枩床ããã®æž©åºŠã«ãããæ°Žã®èžæ°å§ãçº
泡ã«ããæŒåºãæ©å€ã§ç®çãšãã被èŠã®èšåŒµãã²
ãèµ·ããã®ã«ååãªå§åãšãªããããªæž©åºŠã«ããª
ããã°ãªããªãããšããããšã§ãããããã«è©³ã
ããããšããã€ã¹äžã®æº¶èææã®æž©åºŠã¯105âæª
æºã§ããããã®æž©åºŠã¯å¥œãŸããã¯æé«98âã§ã
ãã æŒåºãæ©äžã®ãã¬ãŒã¯ã®æ··ç·Žã»è解ã平衡èç¹
ããé«ã105âæªæºã®æž©åºŠã§è¡ãªãããå Žåãã
ã€ã¹åºå£ã§ç®çãšãã被èŠäžã«æ°æ³¡åœ¢æãèµ·ãã
å±éºã¯ãªãããã€ã¹ãéããŠã®æº¶èææã®æŒåºã
ã¯ãã€ã¹æž©åºŠãå€ããããšãªãçŽã¡ã«è¡ãªãããš
ãã§ããã ä»æ¹ããã¬ãŒã¯ã®æ··ç·Žã»è解ã105âããé«ã
枩床ã§è¡ãªãããå Žåããã®æ段ã¯éåžžã«å¥œãŸã
ãå®æœæ æ§ã«çžå¿ããããšãæ³èµ·ãããã®ã ãã
溶èæŒåºç©ã¯æ¬¡ãã§å·åŽããªããã°ãªããªããã
ã®å·åŽã¯ãã€ã¹èªäœã®äžã§è¡ãªãããšãã§ããã
ããã¯æº¶èæŒåºç©ããã€ã¹ãééããåã«è¡ãªã
ããšãã§ãããå·åŽã¯å質ã«è¡ãªããªããã°ãªã
ãªããããªãã¡ãè¡šé¢å±€ã ãã§ãªãã溶èãžãšã
ãã®å šäœãå®åžžçã«æå®ã®å·åŽæž©åºŠã«ãããªãã
ã°ãªããªããå·åŽæ¡ä»¶ãæ»çæéååžãç±å¯å¡æ§
æš¹è補åºæäžã«ä»çãããç¬éãŸã§çµæ¶æ žã®åºçŸ
ãé²æ¢ãããããã«èª¿ç¯ããªããã°ãªããªããç¹
ã«ã溶èæŒåºç©ã®æž©åºŠã¯åé¡ã®ããªããã«ã¢ã«ã³
ãŒã«ãšæ°Žã®æ··åç©ã®å¹³è¡¡èç¹ããäœã枩床ã«äžã
ãŠã¯ãããªãã æåŸã«ãäžèšã«ããã被èŠãã€ã¹äžã®æº¶èæŒåº
ç©ã®æž©åºŠã¯å¥œãŸããã¯å¹³è¡¡èç¹ãš98âã®éã®å€ã§
ãªããã°ãªãããèŠããã°èª¿ç¯ãããå·åŽãè¡ãª
ããããã«å¥œãŸããã¯ããã®æž©åºŠã¯å¹³è¡¡æº¶è枩床
ããïŒâé«ã枩床ãš98âã®éã®æž©åºŠã«éžå®ãã
ãã å·åŽçšåºŠãããã»ã©ã§ãªãå ŽåãäŸãã°æ°åºŠãª
ããçŽ40床çšåºŠã®å Žåãå·åŽã¯é«ãç±äŒå°çãã
ã€ãã€ã¹ã䜿çšããæŒåºãã¹ã溶èææã®ééé
ã調æŽããŠè¡ãªãããšãã§ãããé·ãã¹ã¯ãªãŠã
åããæŒåºãæ©ã䜿çšããããšãå¯èœã§ãããå
æŒåºãæ©äžã§æº¶èææã¯ã¹ã¯ãªãŠç«¯éšã«åã€ãŠé²
è¡ããéã«å·åŽããã æ¬çºæã®å¥œãŸããå®æœæ æ§ã«åŸãã°ãææã®æž©
床ãžã®å·åŽã¯ãæŒåºãæ©ã®ã·ãŒã¹ïŒå€è£ äœïŒã®ç«¯
éšãšè¢«èŠãã€ã¹ãšã®éã«æ¿å ¥ãããå·åŽãã¢ãžã
ã€ã¶ã䜿çšããŠè¡ãªããããæ¬çºæãå®æœããã
ãã«äœ¿çšããããšãã§ããç°¡åãªè£ 眮ã¯ã倧ããª
å§åéäžãªãã«å¹çã®ããå質ãªç±äº€æãå¯èœã«
ããå©ç¹ãšãèŠçŽ ã®æ°ã圢ç¶åã³æž©åºŠãé©åœã«éž
æããããšã«ãã€ãŠå®æœãã¹ãå·åŽã®çšåºŠã«é©å
ãããããšãã§ããå©ç¹ãæããéçãããµãã
èŠã€ããããšãã§ããããã®è£ 眮ã®è©³çŽ°ã¯ä»åœç¹
蚱第2373385å·ã«èšèŒãããŠããã çŽ30ééïŒ ã®æ°Žãå«æãããã¬ãŒã¯ã®äŸã«æ»ã
ãšã被èŠãã€ã¹äžã®æº¶èæŒåºç©ã®æž©åºŠã¯60â以äž
105âæªæºã奜ãŸããã¯60âãš98âã®éãã®æž©åºŠ
ã«çããã65âãš98âã®éã®æž©åºŠãç¹ã«å¥œé©ã§ã
ãã è¯å¥œãªæ§è³ªãæãã被èŠã®è£œé ã¯æ¬è³ªçã«äžèš
å®æœæ æ§ã«åŸãããšã«äŸåããŠããã泚æãã¹ã
ããšã«ãåºæãžã®è¢«èŠã®æ¥çã容æã«ãããã
ã«ãç±å¯å¡æ§æš¹èã®è¡šé¢ãäŸãã°ã³ããæŸé»å¹
æãç«çåŠçåã¯æ¥çä¿é²ããã©ã€ããŒãããªã
ã¡æ¥çå€ã®ä»çã«ãã€ãŠååŠçããããšãå¯èœã§
ããã被èŠåŠçãã¹ãªãŒãã管ãããªãœã³åã¯ã
ãªããªãŒã ã«é©çšããŠè¡ãªãå Žåã«ã¯æ¥çå€ã®äž
éå±€ã䜿çšããããšãç¹ã«æšå¥šããããæ¥çå€ãš
ããŠã¯ç¹ã«ããªãŠã¬ã¿ã³ç³»æ¥çå€æº¶æ¶²ã䜿çšãã
ããšãã§ããæ¥çå€ã®ä»çã«ç¶ããŠãäžéå±€ã®ç²
床ãé«ããªãéããããšããªãããã«æº¶åªã®å€§éš
åãé€å»ããããã«ããããã«ä¹Ÿç¥ãããã泚æ
ãã¹ãããšã«ãæ¥çå€ã®äžéå±€ãç±å¯å¡æ§åºæãš
æ¥è§ŠããåŽã®è¢«èŠå±€è¡šé¢ã«åããããè£ çããã
ããšãã§ãããäžè¬ã«ãæ¥çãããæ¥çå€ã®é
ã¯ã溶åªã®é€å»åŸã«æž¬å®ãããšãç±å¯å¡æ§æš¹èåº
æïŒè¢«èŠçé¢ã®m2åœãçŽïŒïœãšïŒïœã®éã§ããã æ¬çºæã®æ¹æ³ã«åŸã€ãŠè¢«èŠããã管ç¶ãã©ã³
ã¯ãããªãœã³åã¯ããªããªãŒã ã®äºè»žå»¶äŒžäžç©ºäœ
ãžã®æçµç転æã«é¢ããŠäžèšã«è©³çŽ°ã«èª¬æããã 管ç¶ãã©ã³ã¯ã®å Žåãããããã®ãŸãŸäœ¿çšããŠ
äºè»žå»¶äŒžå¹èŸŒã¿æ圢ã«ãã€ãŠãæ¬é¡åºé¡äººã«ãã
1980幎ïŒæ13æ¥åºé¡ã®ä»åœç¹èš±åºé¡ç¬¬80ïŒ13158
å·ã«èšèŒãããæè¡ã䜿çšããŠãã©ã®ãããªæšªæ
é¢åã³çžŠæé¢åœ¢ç¶ãæããé·å°ºã®äºè»žå»¶äŒžç°åœ¢æ
ã§ãåŸãããšãã§ããããã®æè¡ã¯æ¬¡ã®äžé£ã®æ
äœããæããããªãã¡ãææã®äºè»žå»¶äŒžæž©åºŠã«äº
åå ç±ãã管ç¶ãã©ã³ã¯ãç®çãšããç°åœ¢æã®åœ¢
ç¶åã³å¯žæ³ããã€éåã®è»žã«æ²¿ã€ãŠçœ®ãæäœãå
äžãªçžŠæ¹åã®å»¶äŒžåã³ãããšåæã«ææã®èªç¶ãª
äºè»žå»¶äŒžæ¯ç以äžè¿ã®åäžãªååŸæ¹åã®äºåå¹èŸŒ
ã¿ãããããã«å å§ãé©çšããæäœã暪æ¹åã®é
延䌞ãèµ·ããããã«ãã©ã³ã¯ãå®å šã«èšåŒµãããŠ
éåå£ã«å¯çããããã«ããããã«å å§ãå¢å ã
ãæäœãåã³ç°åœ¢æãå·åŽãå§åãç·©åãããæ
äœã§ãããåŸãããç°åœ¢æã¯ãäŸãã°å å§æµäœã
茞éããããã«ã軜éåã®ããã®ä¿è·ç®¡æãšã
ãŠãåã¯åæåŸã«å è£ å·¥æ¥ã«ãããŠå®¹åšæ¬äœãšã
ãŠäœ¿çšããããšãã§ããã 容åšæ¬äœã補é ããããã«ã¯ãç°åœ¢æã®åœ¢ç¶ã¯
æèŠã®èŠçŽ ã®åœ¢ç¶ã®è€è£œã«äžèŽããããã«éžã°ã
ããåèŠçŽ ã®éšåã«çªåºããæºãèšããããšãæ
å©ã«ã§ããåæã¯æºã§èµ·ããã®ã§ãéå±è£œåã¯ã
ã©ã¹ããã¯è£œã®å¥è£œã®ç«¯éšãã²ã ä»åã¯æº¶æ¥ã«ã
ã€ãŠå®¹åšæ¬äœã«åºå®ããã®ã容æã«ãããåŸãã
ã容åšã¯çé žæ¿åºŠã®é«ã液äœåã³éåžžã«é žçŽ æå
æ§ã®é«ãé£åãä¿åããã®ã«äœ¿çšããããšãã§ã
ãã 管ç¶ãã©ã³ã¯ã¯åæã«ããããªãœã³ã«è»¢æãã
ããšãã§ããã転æãããŠã§ããããªãœã³ã¯äžè¬
ã«ãŸãäžç«¯åã¯äž¡ç«¯ããã€ã¹ã䜿çšããã¹ã¿ã³ã
ã³ã°ã«ãããåã¯ããä»åã¯æº¶æ¥ã«ããéå±è£œå
ã¯ãã©ã¹ããã¯è£œã®ç«¯éšãåºçããããšã«ããé
ããŠããå ¬ç¥ã®æè¡ãçšããŠäºè»žå»¶äŒžå¹èŸŒã¿æ圢
ããããšã«ããäºè»žå»¶äŒžäžç©ºäœïŒå®¹åšæ¬äœããã©
ã¹ã³ããã³çïŒã«è»¢æãããã 転æãããŠã§ããããªããªãŒã ã¯åãå ¬ç¥æè¡
ãçšããŠçŽæ¥äºè»žå»¶äŒžå¹èŸŒã¿æåãããã äºè»žå»¶äŒžå¹èŸŒã¿æåå·¥çšã§ç®¡ç¶ãã©ã³ã¯ãããª
ãœã³åã¯ããªããªãŒã ãå ç±ããã枩床ã¯åºæã
æ§æããç±å¯å¡æ§ãã©ã¹ããã¯ã®æ§è³ªã«äŸããåº
æãããªãšã¹ãã«ã§ããå Žåãã¬ã©ã¹è»¢ç§»ç¹ãšçµ
æ¶å枩床ã®éã®æž©åºŠãããªãã¡85âãš120âã®é
ã®æž©åºŠããäžè¬ã«å¥œé©ã§ããã åŸãããäžç©ºäœã¯è¡æ匷ããå æ²¢åã³éææ§ã«
ã€ããŠè¢«èŠããªãäžç©ºäœã®æ§è³ªãä¿æããŠããã
被èŠã®åãã«é¢ããŠã¯ãäžèšã®æè¡ã«ããã°ãæ°Ž
æ§å¡åžæ³ãšæ¯ã¹ãŠãåäžæäœã§çŽã¡ã«10ãªãã
200ÎŒã®åã被èŠãåŸãããšãå¯èœã«ãªãããã®
ããã«ããŠè¢«èŠãããäžç©ºäœã¯é«çé žæ¿åºŠåã³ïŒ
åã¯é žçŽ æåæ§æ¶²äœã®å è£ ã«å®å šã«é©ãããã®ãš
ãªãã åŸåã®æè¡ãšæ¯èŒããå Žåãä»ã®å©ç¹ã¯ãæ°Žã
é€å»ããå¿ èŠããªãåã被èŠãåŸãããããšã§ã
ããå®éãæ°Žæ§å¡åžã®éã«èµ·ããããšãšã¯å¯Ÿç §ç
ã«ãæ¬çºæã®ç®¡ç¶ãã©ã³ã¯ãããªãœã³åã¯ããªã
ãªãŒã ã¯ãåãã0.1ãªããïŒmmã®ç¯å²ã«ãåŸã
ãã被èŠå±€ã®äºåã®ä¹Ÿç¥ãè¡ãªãå¿ èŠãªãã«è¢«èŠ
ããªãç±å¯å¡æ§æš¹èã®å»¶äŒžæ¡ä»¶ãšåã延䌞æ¡ä»¶äž
ã§å®¹æã«å»¶äŒžãåŸãããšã芳å¯ãããŠããããã
ã«ãããããã管ã管ç¶ãã©ã³ã¯ãããªãœã³åã¯
ããªããªãŒã ã®è²¯èµäžåã³ïŒåã¯ãããã®äºè»žå»¶
䌞å¹èŸŒã¿æååã®äºåå ç±äžã«éšåç也ç¥ãèµ·ã
åŸãããããã¯å»¶äŒžæåã«ã€ããŠãä»äžãäžç©ºäœ
ã®æ§è³ªã«ã€ããŠãåé¡ãšãªããªãã ãŸããå šãé©ãã¹ãããšã«ãäžèšã®å¥œé©ãªå®æœ
æ æ§ã«åŸã€ãŠãç¹ã«ãã¬ãŒã¯ã®æ°Žå«æéãšèç¹ã
éµå®ããããšã«ãã€ãŠãé«æž©ã§åŸåŠçå ç±ããã
ãšãªãããªããã«ã¢ã«ã³ãŒã«è¢«èŠãèæ°Žæ§ãæã
ãäžç©ºäœãåŸãããããèæ°Žæ§ããšããçšèªã¯ã
被èŠãå·æ°Žã«äžæº¶ã§ãããé©åœãªå Žåã¯60âã«å
ç±ããæ°Žã«æµžæŒ¬ãããšãã«çŽã¡ã«æº¶ããããšãªã
èšæœ€ãèµ·ããã ãã§ããããšãæå³ãããã®ãšç
解ãããããåŸåã®æ°Žæ§å¡åžæ³ã®æè¡ã§ã¯ãããª
ããã«ã¢ã«ã³ãŒã«å±€ãäºè»žå»¶äŒžã®ååã¯åŸã«130
âããé«ã枩床ã奜ãŸããã¯140âãš210âã®éã®
枩床ã®å ç±åŠçã«ãããå Žåã«éã€ãŠè¢«èŠã®èæ°Ž
æ§ãåŸãããšãã§ããããã®åŸåŠçå ç±ã®ç®çã¯
被èŠã®çµæ¶åºŠãé²å±ãããçµæãæ°Žäžæº¶æ§ãå«ã
ç©ççæ§è³ªãæ¹åããããšã§ãã€ããæ¬çºæã®æ
è¡ã§ã¯çµæ¶åºŠã®é«ãèæ°Žæ§ã®è¢«èŠãçŽæ¥åŸãããš
ãå¯èœã§ããã130âããé«ã枩床åã³140âãªã
ã210âã®æž©åºŠã§ã被èŠãããåºæåã¯äžç©ºäœã
å ç±éåå£ã«å¯çãããããšãå«ãåŸåŠçå ç±ã
å«ã段éãçç¥ããããšã«ããåœæ¥è ã®äœ¿çšãã
ããšãã§ããæè¡ã¯ç°¡ç¥åãããã æ¬æ现æžã®å®éšéšåã«ãããŠã¯ããªããã«ã¢ã«
ã³ãŒã«ã®å»¶äŒžåã¯æªå»¶äŒžè¢«èŠã®çµæ¶åºŠã¯ãå±æç
ïœïŒçæ¹æ§ããªããã«ã¢ã«ã³ãŒã«ã®å ŽåïŒåã¯å¹³
åå±æçïŒç°æ¹æ§ããªããã«ã¢ã«ã³ãŒã«ã®å ŽåïŒ
ã決å®ããããšã«ãã枬å®ãããå¹³åå±æçã¯è¢«
èŠãã€ã«ã é¢ã®äž»é åæ¹åïŒn1ïŒn2ïŒãšåçŽæ¹å
ïŒn3ïŒã®åå ã§ã¢ããå±æç枬å®åšãçšããŠæ±ºå®ã
ãïŒã€ã®äž»å±æçã®ç®è¡å¹³åã§ãããããªããã«
ã¢ã«ã³ãŒã«è¢«èŠäžã«æ°Žãååšãããšå±æçåã¯å¹³
åå±æçãäœäžããã®ã§ãçµæ¶åºŠã¯å®å šã«ä¹Ÿç¥ã
ã被èŠã§æž¬å®ããªããã°ãªããªãã也ç¥æ¡ä»¶ã«ã
ã€ãŠè¢«èŠã®çµæ¶åºŠãå€åããã®ãé²æ¢ãããã60
âãè¶ããªã枩床ã§ç空也ç¥ã«ããæ®åããæ°Žã
é€å»ããã ãã¡ãããæ¬çºæã®ç¯å²å ã§ã管ç¶ãã©ã³ã¯ã
ããªãœã³åã¯ããªããªãŒã ãæãã¯ä»äžãã補å
ã«é©çšãããå¥ã®éåäœè¢«èŠãããã«èšããããš
ã«ããåŸããã被èŠã®ä¿è·ã匷åããããšãã§ã
ãããã®æ°ãã被èŠã¯ã©ããã¯ã¹åã¯æº¶èéåäœ
ã®å¡åžãåææŒåºãå¡åžåã¯æº¶èéåäœã§ã®å å
ã®ãããªå ¬ç¥æè¡ã«ããä»çã§ãããäžç©ºäœã«å»¶
䌞å¯èœåã¯åçž®å¯èœã®ã¹ãªãŒããé©çšããããšã
å¯èœã§ããããã®é©çšãå å¡«ã®ååã¯åŸã«ç¹ã«ã
ã³è©°ç®çç·äžã«è¡ãªãããšãå¯èœã§ãããã¹ãªãŒ
ãã¯æŒåºãå¹èŸŒã¿ïŒäœå¯åºŠããªãšãã¬ã³ãããªã
ããã¬ã³ããšãã¬ã³âå¡©åããã«ãã¢ã€ãªãããŒ
æš¹èåã¯ã¢ã¯ãªããããªã«å ±éåäœã®ã±ãŒã·ã³ã°
ã®æãæ®éã®å ŽåïŒã«ããåŸãããããåã¯å·»ã
äžããŠæº¶æ¥åã¯åºçããå¹³åŠãªãã€ã«ã ããåŸã
ããã±ãŒã·ã³ã°ã®æšªã®åæã«ãã補é ããããšã
ã§ããããã¡ãããã¹ãªãŒãã¯çš®ã ã®è£å©å€ãç¹
ã«çè²å€åã³UVåžåå€ãå«æããããšãã§ãã
ãã€éæåã¯äžéæã§å°å·ãããŠããŠãããå°å·
ãããŠããªããŠããããã¹ãªãŒãã¯äžç©ºäœã®å šè¡š
é¢ãèŠã€ãŠããå¿ èŠã¯ãªããäŸãã°ãã³ããã©ã¹
ã³ã®å Žåã¯ãççŽãªåçéšã®ã¿ãä¿è·ããŠããã°
ãããåºéšãšããã¯ã¯é€å€ãããŠããã 以äžã®å®æœäŸã«ããæ¬çºæã説æããããæ¬çº
æã®ç¯å²ã¯ãããã«éå®ãããªãã äŸ ïŒ æ¬å®æœäŸã¯æ°Žæ§å¡åžæ³ã䜿çšããåŸåã®æè¡ã®
å Žåã«èµ·ããçŸè±¡ã瀺ãæ¯èŒäŸã§ããã ããŒãã»ããŒã©ã³ç€Ÿè£œã®RHODOVIOL30âïŒ
ãšããåæšã®æ¬¡ã®æ§è³ªããã€åžè²©ã®ããªããã«ã¢
ã«ã³ãŒã«ïŒ âãšã¹ãã«å€ïŒ ïŒïŒããªãã¡99ééïŒ åã¯99.5
ã¢ã«ïŒ ã®å æ°Žå解床ïŒã âãªã¹ãã¯ã«ãç²åºŠèšã§20âã«ãããŠæž¬å®ããïŒ
ééïŒ åŒ·åºŠæº¶æ¶²ã®ç²åºŠïŒ 28ã»ã³ããã€ãºã âç°åå«æéïŒ ïŒééïŒ æªæºã âã·ã³ãžãªã¿ã¯ãçšåºŠïŒ ã·ã³ãžãªã¿ã¯ãäžã€çµ
54ïŒ ã枬å®ã¯ã€ããŠãšããããªããŒã»ãžã€ãŒãã«
ïŒ1973ïŒp.244ãåã³ãŠãŒåã³ãªãããŒã«ããã¯ã
ã¢ã¬ããŠãŒã«ãºïŒ1973ïŒp.582ãã®æ¹æ³ã«åŸã€
ãŠã VARIAN CFT20NMRã䜿çšããŠéæ°Ž
äž80âã§è¡ãªã€ãã âïŒïŒïŒâã°ãªã³ãŒã«é£éïŒ åéäœåäœ100åœ
ã0.66é£éã ã䜿çšããŠ15ïŒ åŒ·åºŠã®æ°Žæº¶æ¶²ïŒéåäœééïŒæº¶æ¶²
ééïŒã調補ãããããããªãšãã¬ã³ãã¬ãã¿ã¬
ãŒãïŒããŒãã»ããŒã©ã³ç€Ÿè£œRHODESTER85TX
éåäœãåºæç²åºŠ0.83dlïŒïœïŒè£œã®éæãªå°åºæ
åããªããªãŒã ã«æµžæŒ¬ã«ãã50âã§å¡åžããã®ã«
䜿çšããã浞挬åã³æ液åŸãããªããªãŒã äžã«æ¯
èŒçåäžãªè¢«èŠãåŸãããå®å šä¹Ÿç¥åŸã®å¹³ååã
ã¯27ÎŒã§ããã ç空çäž60âã®å®åžžééã«ä¹Ÿç¥ããã被èŠã®çµ
æ¶ç¶æ ã調ã¹ãã枬å®ã¯ããã€ã«ã é¢ã®äž¡ç«¯çžã®
å±æçå€n1åã³n2ãšãã€ã«ã é¢ã«åçŽã«æž¬å®ãã
å€n3ãèŠåºãããã«ã¢ããå±æç枬å®åšã䜿çšã
ãŠ23âã«ãããŠè¡ãªãããã ãããã®å€ã¯ã
ãŒã ãåºçºææãšããŠå¹èŸŒã¿æ圢ã«ãã補é ãã
ãç±å¯å¡æ§æš¹è補ã®äºè»žå»¶äŒžè€åäžç©ºäœã®è£œé æ¹
æ³ã«é¢ãããããã«è©³ããããã°ãæ¬çºæã¯ã¬ã¹
åã³èª¿å³çšéŠæã«å¯ŸããŠäžééæ§ã®ããªãšã¹ãã«
補äºè»žå»¶äŒžäžç©ºäœã®è£œé æ¹æ³ã«é¢ãããæ¬çºæã¯
ãŸãåæ¹æ³ã«ããåŸãããæ¹åãããæ§è³ªãæã
ãäžç©ºäœã«é¢ãããããã«ãæ¬çºæã¯åžèŸŒæ圢ã«
ãã€ãŠäºè»žå»¶äŒžäžç©ºäœãäžãã管ç¶ãã©ã³ã¯ãã
ãªãœã³åã¯ããªããªãŒã ã«é¢ããã æ¬æ现æžã«ãããŠã¯ãã管ç¶ãã©ã³ã¯ããšãã
çšèªã¯ã䞡端ã®éããäžè¬ã«é·ã管ã®äžéšåã§ã
ãããã®é·ããäŸãã°50cmãªããïŒïœä»¥äžã«éã
ãããšããããã®ãæå³ãããã®ãšããããããª
ãœã³ããšããçšèªã¯ã䞡端ã®éãã管ã®äžéšåã§
ããé·ããäžè¬ã«ïŒcmãªãã20cmã®ãã®ãæãã
ã®ãšããããããªããªãŒã ããšããçšèªã¯ãé·ã
ãããªãœã³ãšåããåã¯ç°ãªããäžç«¯ãéãä»ç«¯
ããã§ã«æçµç圢ç¶ã«æ圢ãããéæŸç«¯ãããªã
ã¡ããã¯ãã§ãã管ã®éšåãæããã®ãšããã äžç©ºäœã®åéã§ã¯è¿å¹Žç±å¯å¡æ§æš¹èãæ¥éãªçº
å±ãéããŠãããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãã¯
ããªããªãŒã ã®äºè»žå»¶äŒžå¹èŸŒæ圢ã«ãã€ãŠæ©æ¢°ç
æ§è³ªïŒç¹ã«èè¡ææ§åã³å å§æµææ§ïŒã«åªããã
ã³ã圢æãã泚ç®ãã¹ãèœåããã€ãŠããã®ã§å
å§æ¶²äœåã³çºæ³¡é£²æã®å å¡«ã«æå©ã«äœ¿çšã§ããã
ãšã¯åšç¥ã§ããããããã調å³çšéŠæãå ¥ã€ãŠã
ãããé žçŽ ã«å¯Ÿããæåæ§ãé«ãã€ãããçé žã
å ¥ã€ãŠãããããããã¯ããããçµã¿åããããŠ
ãããããªæ¶²äœã®å Žåã«ã¯ãããªãã¬ãã¿ã¬ãŒã
補äžç©ºäœã®ã¬ã¹åã³èª¿å³çšéŠæã«å¯Ÿããäžééæ§
ãäžååã§ããçµæãå å¡«ããã補åã¯ãã°ãã°
éãããæéããè¯å¥œãªç¶æ ãä¿ãŠãªãããã®çŸ
象ã¯ãäžç©ºäœã®å£åãèãã»ã©ããŸãå 容ç©ã®äœ
ç©ã«å¯Ÿãã容åšã®è¡šé¢ç©ã®æ¯ãé«ãã»ã©ãé¡èã«
ãªããäžç©ºäœã®ééçãäœäžãããããã«ãåºæ
ãããã¬ã¹ééçã®äœãããªã€ææãäžç©ºäœè¡šé¢
ã«å¡åžããããšããã§ã«ææ¡ãããŠããã ä»åœç¹èš±ç¬¬2416784å·åã³å第2416785å·ã«ã¯ã
ããªããã«ã¢ã«ã³ãŒã«ãããªãšãã¬ã³ãã¬ãã¿ã¬
ãŒã補äºè»žå»¶äŒžãã³çšã®åªç§ãªããªã€ææãšããŠ
䜿çšã§ããããšãèšèŒãããŠãããäžèšç¹èš±èšèŒ
ã®æ¹æ³ã«ããã°ãããªããªãŒã ãäºè»žå¹èŸŒå»¶äŒžã
ãåã«ãããªããã«ã¢ã«ã³ãŒã«æ°Žæº¶æ¶²ã®å¡åžåã¯
ããªããã«ã¢ã«ã³ãŒã«æº¶æ¶²åã³æ°Žã«å¯Ÿããæåæ§
ã®äœãéåäœã©ããã¯ã¹ãå«æããæ°Žæ§çµæç©ã®
å¡åžã«ãããããªããªãŒã ã®å£é¢ã®å°ãªããšãäž
é¢ã«è¢«èŠãé©çšãããã®è¢«èŠã也ç¥ããŠããããª
ããªãŒã ãäºè»žå¹èŸŒå»¶äŒžããŠããã ãããããã®ç¹æ®ãªæè¡ã¯äŸç¶ãšããŠååã«æº
足ã§ãããã®ã§ã¯ãªãããã®çç±ã¯ãããªããã«
ã¢ã«ã³ãŒã«èªäœããåºçºãããšè¢«èŠã®èæ°Žæ§ãäž
ååã§ããããã€å·¥æ¥çã«æå©ãªæ¹æ³ã§åã被èŠ
ã補é ããããšãã§ããªãããã§ãããå®éãæ°Ž
æ§å¡åžã«ãã被èŠã®é©çšã«ã¯éåäœæ¿åºŠã®äœãå¡
åžæ¶²ã®äœ¿çšãé¢äžããŠããããã®äž»ãªçç±ã¯ïŒã€
ããããã®äžã€ã¯ãããªããã«ã¢ã«ã³ãŒã«ã¯é«æ¿
床ã§ã¯æ°Žã«æº¶è§£ãåŸãªãããšãšãä»ã®çç±ã¯é«ç²
床åªäœã§å¡åžãè¡ãªãããšã¯å°é£ãªããã§ããã
åŸã€ãŠãå¡åžã«ãã€ãŠããªãå°éã®ææããä»ç
ããæçµçã«åŸããã被èŠã®åãã¯å°ãããäžè¬
ã«ããªããªãŒã ã§20ãªãã50ÎŒãæçµäžç©ºäœã§ïŒ
ãªããïŒÎŒã§ãããããå Žåã«ã¯ãç¹ã«ãã³ãé ž
çŽ æåæ§ãé«ããåã¯çé žã®å«æéã®é«ãããã
ãã¯ãã®åæ¹ã®æ¶²äœãå容ããããäŒå³ãããå Ž
åã«ã¯ãäžéæ§ããªã€ææã®æå¹æ§ãé«ãããã
ã«åã被èŠãèšããããšãæãŸãããããªãã¡ã
奜é©ãªè¢«èŠåã¯äžè¬ã«ããªããªãŒã ã§0.1ãªãã
ïŒmmãæçµäžç©ºäœã§10ãªãã200ÎŒã§ããããã®
ãããªåãã¯ãã¡ããæ°Žæ§å¡åžã«ããåŸããã
ãããã®ç®çãéæããããã«ã¯ãé£ç¶ããŠæ°å±€
ãé©çšããæºåãå®å°ã«ããå¿ èŠãããããäžé£
ã®æ°å±€ã®è¢«èŠå±€ã®å Žåã«ã¯è¡šé¢å±€ãäžå±€ã®ä¹Ÿç¥ã
劚ã也ç¥ããªããšåé¢ãèµ·ããã®ã§ãåäžéå±€ã
é©åœã«ä¹Ÿç¥ãããªããã°ãªããªããæåŸã«ã被èŠ
å±€ãè€æ°ã§ããããšãšä¹Ÿç¥æäœãå¿ èŠãªãããå
ãå±€ãä»çãããããã«å¡åžã«ãã被èŠããããš
ã®å·¥æ¥ç䟡å€ããã¹ãŠå€±ãªãããã æ¬çºæã®ç®çã¯ãå€å±€å¡åžãããéææ§ãšå æ²¢
ã®ææã®æ§è³ªãä¿æããåã被èŠãçŽæ¥ä»çãã
ããšã®ã§ããæ¹æ³ãæäŸããããšã«ããã æ¬çºæã®å¥ã®ç®çã¯ãåãã ãã§ãªãèæ°Žæ§ã®
éåžžã«ãã被èŠãä»çããããšã®ã§ããæ¹æ³ãæ
äŸããããšã«ããã ãããã®ç®çã®äžéšåã¯å šéšãæ¬çºæã®æ¹æ³ã«
ãã€ãŠéæããåŸãããšãèŠåºãããã ããªãã¡ãæ¬çºæã¯ããŸãããªããã«ã¢ã«ã³ãŒ
ã«ç³»ããªã€ææã§è¢«èŠããã管ç¶ãã©ã³ã¯ãããª
ãœã³åã¯ããªããªãŒã ã補é ãã次ãã§ããã®ç®¡
ç¶ãã©ã³ã¯ãããªãœã³åã¯ããªããªãŒã ãæ £çšã®
äºè»žå»¶äŒžæž©åºŠæ¡ä»¶ã§äºè»žå»¶äŒžå¹èŸŒæ圢ããããšã
ãæãã¬ã¹äžééæ§ã®èæ°Žæ§è¢«èŠãåããç±å¯å¡
æ§æš¹è補äºè»žå»¶äŒžäžç©ºäœã®è£œé æ¹æ³ã«ãããŠãäž
èšç®¡ç¶ãã©ã³ã¯ãããªãœã³åã¯ããªããªãŒã ã®è£œ
é ã以äžã®äžé£ã®å·¥çšã (a) 20æªæºã®ãšã¹ãã«äŸ¡ãæããçŽããªããã«ã¢
ã«ã³ãŒã«ãšæ°Žããæãå«æ°Žéã25ã35ééïŒ ã§
ãããã¬ãŒã¯ãæŒåºãæ©ã«å°å ¥ããå·¥çšã (b) åèšãã¬ãŒã¯ãæŒåºãæ©ã«ãããŠè©²ãã¬ãŒã¯
ãæ§æããããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©ã®
平衡èç¹ããã100â以äžé«ã枩床ã§æ··ç·Žè解
ããå·¥çšã (c) å·åŽã«ããããã€ã¹å ã®æº¶èæŒåºãç©ã®æž©åºŠ
ãåœè©²ããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©ã®å¹³è¡¡
èç¹ä»¥äžã§ãããæŒåºãæ©å€ã§ã®æ°æ³¡åœ¢æã«ã
ãææã®è¢«èŠã®èšåŒµãèµ·ããã®ã«ååãªæ°Žã®èž
æ°å§ãçãã枩床ããã¯äœãå€ã«ãªãããå¶åŸ¡
ããªãããç±å¯å¡æ§æš¹è補ã®ç®¡ãããªãœã³åã¯
ããªããªãŒã ãå¡åžããã®ã«é©ãã被èŠãã€ã¹
ãéããŠæº¶èææãæŒåºãããã®å Žåã«ãåèš
ã®æº¶èæŒåºç©ã®å·åŽãã溶èæŒåºç©ãããã€ã¹
ãééããåã«ãæŒåºãæ©ã®ã·ãŒã¹ç«¯éšãšè¢«èŠ
ãã€ã¹ãšã®éã«æ¿å ¥ãããå·åŽãã¢ãžãã€ã¶ã
䜿çšããŠå®æœããå·¥çšãããã³ (d) ãã®ããã«ããŠè¢«èŠããã管ãããªãœã³åã¯
ããªããªãŒã ãå·»åãã管ã®å Žåã«ã¯ããã«æ
æã®é·ãã«åæããããšã«ãã€ãŠç®¡ç¶ãã©ã³
ã¯ãããªãœã³ãåã¯ããªããªãŒã ã®åé§äœã®ç®¡
åçã«è»¢æããå·¥çšã ãå«ãããšãç¹åŸŽãšããæ¹æ³ãæäŸããã æ¬æ现æžã«ãããçšèªãå·åŽãã¢ãžãã€ã¶ã
ã¯ã倧ããªå§åéäžãªãã«å¹çã®ããå質ãªç±äº€
æãå¯èœã«ããïŒã€ä»¥äžã®éçãããµéšæãå«ã
æ§é ãæããå·åŽåšå Œãã¢ãžãã€ã¶ãæå³ããã äžèšæ¹æ³ã«é©çšãåŸãå€åœ¢äŸãšããŠãäžèšå·¥çš
(a)åã³(b)ã«ç¶ããŠäžèšå·¥çš(c)ã®æ¿ãã«ã (e) ã±ãŒã·ã³ã°ã圢æããããã«äžèšæž©åºŠæ¡ä»¶äž
ã§ç°ç¶ãã€ã¹ãéããŠæº¶èææãæŒåºãå¹èŸŒã¿
æ圢ããå·¥çšãå㯠(e)Ⲡ管ç¶ã®æº¶èææã®æŒåºãã«æ¬¡ãã§ç®¡ãªã³ã°
ã®è£œé æè¡ã«åŸãã€ãŠãæ»é¢å£ãæããå¯åã·
ãšãŒããçšããææã®ã±ãŒã·ã³ã°ã圢æããã
ãã«ããããªç©ºæ°å§ãå åŽããäžããŠç®çå®ã
æäœãããå·¥çšãåã³ (f) é©åœãªãã°æšªã«åæããåŸãäžèšã±ãŒã·ã³ã°
ã管ãããªãœã³åã¯ããªããªãŒã ã«é©çšãåŸã
ã¹ãªãŒããšããŠäœ¿çšããå·¥çšã ãå®æœããããšããæãäŸãæããããšãã§ã
ãã äžèšã®ããã«è¢«èŠããã管ãããªãœã³åã³ããª
ããªãŒã ã¯æçµçã«äºè»žå»¶äŒžå¹èŸŒæ圢工çšã§äœ¿çš
ããåã«å€§æ°äžã§å±éºãªãã«è²¯èµã§ããã æ¬çºæã®å¥œãŸããå®æœæ æ§ã¯å·¥çš(a)åã³(b)次ã
ã§(c)ãè¡ãªãã管ã¯ç©å±€ã«ãã€ãŠè¢«èŠããããã
ã®å Žåã¯ãç±å¯å¡æ§æš¹è補管ã®æŒåºãã«çŽæ¥æ¥ç¶
ããŠè¡ãªãããšãã§ããã æ¬çºæã®å¥ã®å¥œãŸããå®æœæ æ§ã¯å·¥çš(a)ã(b)ã
åã³(e)åã¯(e)â²ã次ãã§(f)ãè¡ãªããã¹ãªãŒãã¯
ããªããªãŒã ã«é©çšãããããã®å Žåã被èŠæäœ
ã¯ããªããªãŒã ã®ããã¯ã®åºéšããéãã端éšãŸ
ã§å»¶ã³ãŠãã延䌞å¯èœãªççŽã®éšåãåã«è¢«èŠã
ãããšã«ãã€ãŠè¡ãªãããã ãæŒåºãæ©ããšããçšèªã¯æŒåºãææãé²è¡ã
ãéäžæ垯ããããªãè£ çœ®ãæããã®ãšãããã
ã®çš®ã®è£ 眮ã¯åšç¥ã§ãããïŒã€ä»¥äžã®ã¹ã¯ãªãŠã
å ·åããããšãã§ããã æ¬çºæã®æ¹æ³ã¯ãäŸãã°æšæºåã¯é«è¡æåããª
ã¹ãã¬ã³ãå¡©åããã«ãšã¢ã¯ãªããããªã«ã®ãã¢
ããªããŒãšã³ããªããŒãããªã¢ã¯ãªã¬ãŒããšããª
ã¡ã¿ã¯ãªã¬ãŒãåã³ããªã«ãŒãããŒãã®ãããªé
æ¶æ§ããªããŒã«é©çšã§ããããŸããäŸãã°é«å¯åºŠ
åã³äœå¯åºŠããªãšãã¬ã³ãããªãããã¬ã³ãããª
ããã³âïŒäžŠã³ã«ãšãã¬ã³âãããã¬ã³å ±éåäœ
ã®ãããªããªãªã¬ãã€ã³é¡ãããªã«ããã©ã¯ã¿
ã ãããªã¢ããâïŒïŒïŒãããªã¢ããâ11åã³ã
ãªã¢ããâ12ã®ãããªããªã¢ããé¡ãããªãªãã·
ã¡ãã¬ã³é¡ãããªïŒãšãã¬ã³ã°ãªã³ãŒã«ïŒãããª
ïŒãããã¬ã³ã°ãªã³ãŒã«ïŒãããªïŒããã¬ã³ã°ãªã³
ãŒã«ïŒåã¯ããªïŒïŒïŒïŒâãžããããã·ã¡ãã«ã·
ã¯ããããµã³ïŒã®ãã¬ãã¿ã¬ãŒããããã¿ã¬ããŒ
ãåã³ããããã·ãã³ãŸãšãŒãããããã®å ±éå
äœåã³æ··åç©ã®ãããªé£œåããªãšã¹ãã«é¡ã®ãã
ãªåçµæ¶æ§ããªããŒã«ãé©çšã§ããã åºæã圢æããããã®å¥œãŸããç±å¯å¡æ§æš¹èã¯
ããªïŒã¢ã«ãã¬ã³ã°ãªã³ãŒã«ïŒãã¬ãã¿ã¬ãŒãã§
ãããç¹ã«æå©ãªææã¯ããšãã¬ã³ã°ãªã³ãŒã«ã
ã¬ãã¿ã¬ãŒãã®åç¬éåäœåã¯é žæåã95ïŒ ä»¥äž
ã®ãã¬ãã¿ã«é žããæãããžãªãŒã«æåã95ïŒ ä»¥
äžã®ãšãã¬ã³ã°ãªã³ãŒã«ããæããšãã¬ã³ã°ãªã³
ãŒã«ãã¬ãã¿ã¬ãŒãå ±éåäœããæãããªã«ãã¯
ããããšããŒã«äžã§æž¬å®ããåºæç²åºŠã奜ãŸãã
ã¯0.60ãªãã1.2dlïŒïœã§ããæš¹èã§ããã ããªããã«ã¢ã«ã³ãŒã«ã¯ãäžè¬ã«ããªé ¢é žãã
ã«ã®ãããªããªããã«ãšã¹ãã«é¡ã®å æ°Žå解ã«ã
ã€ãŠè£œé ãããã æ¬çºæã®æ¹æ³ã«ãããŠäœ¿çšãããããªããã«ã¢
ã«ã³ãŒã«ã¯é«çŽåºŠã®ååç©ã§ããã詳ãããã
ãšããšã¹ãã«äŸ¡ã20æªæºã®äœãšã¹ãã«äŸ¡ããã€ã
ãå æ°Žå解ãããããªããã«ã¢ã«ã³ãŒã«ã䜿çšã
ãŠããã ãã®ã°ã«ãŒãã®äœãšã¹ãã«äŸ¡ããã€ããªããã«
ã¢ã«ã³ãŒã«ãããã·ã³ãžãªã¿ã¯ãèŠçŽ ã®æ¯çïŒã·
ã³ãžãªã¿ã¯ã床ïŒ50ééïŒ è¶ ãç°åå«é1.5éé
ïŒ æªæºåã³ïŒïŒïŒâã°ãªã³ãŒã«é£éã®ãããªç°åžž
æ§é èŠçŽ ã®æ¯çã100ã¢ãããŒåœã1.5ç°åžžé£éæª
æºã§ããããªããã«ã¢ã«ã³ãŒã«ãéžã¶ã®ã奜ãŸã
ãã ãã®ã¿ã€ãã®ããªããã«ã¢ã«ã³ãŒã«ã§ãšã¹ãã«
䟡ã10æªæºã®ãã®ãç¹ã«å¥œé©ã§ããã ããªããã«ã¢ã«ã³ãŒã«ã®ååéã¯éèŠã§ã¯ãª
ããäžèšåŸæ¥æè¡ã§ããªããã«ã¢ã«ã³ãŒã«æ°Žæº¶æ¶²
ã䜿çšããå Žåãšã¯å¯Ÿç §çã§ãããéå床ããªã¹
ãã¯ã«ãåç²åºŠèšã䜿çšããŠ20âã§æž¬å®ãããæ°Ž
溶液ééã®ïŒééïŒ åŒ·åºŠã®ç²åºŠã«ãã€ãŠç¹åŸŽã¥ã
ãããå Žåã«ã¯ãïŒãªãã70cPoã«ããããã¹ãŠ
ã®ç²åºŠç¯å²ã®åžè²©è£œåã䜿çšããããšãã§ããã å·¥çš(a)ã®æŒåºãæ©ã«å°å ¥ããããªããã«ã¢ã«ã³
ãŒã«ã®ãã¬ãŒã¯ã«ã€ããŠã¯ããã®ééå«æ°Žéã¯ã
ãã以äžå€ããªããšç°å¢æž©åºŠïŒ20âïŒã§æº¶èæŒåº
ç©ãè¿ éã«çµæ¶åããªããªãããããã®é以äžã§
ããã詳ããããã°ããã¬ãŒã¯ã®å«æ°Žéã¯50éé
ïŒ ä»¥äžã奜ãŸããã¯25ãªãã35ééïŒ ã®å€ã«åºå®
ãããããããã®æ¡ä»¶ã®äžã§ã¯ãäžæŠç°å¢æž©åºŠãŸ
ã§å·åŽãããšãç±å¯å¡æ§æš¹è補åºæã«ä»çãã被
èŠã¯çŽã¡ã«ç²çæ§ã倱ãªãã®ã§ã被èŠãããåºæ
ã®åæ±ãã容æã§ãããäºãéšåçã«ä¹Ÿç¥ããå¿
èŠããªãã ããªããã«ã¢ã«ã³ãŒã«ã®ãã¬ãŒã¯ã¯å ¬ç¥ã®æ¹æ³
ã«åŸã€ãŠãããªããã«ã¢ã«ã³ãŒã«ã®ç²æ«ã«éžã°ã
ãéã®æ°Žãå«æµžãããé©åœãªãããµãŒã䜿çšããŠ
60âãªãã90âçšåºŠã®æž©åºŠã§åŠçããããšã«ãã
補é ããããæ°Žã®éãäžèšéçå ã«ãããšãç²ç
ããªãããè¯å¥œãªæµåæ§ãæãããã¬ãŒã¯ãåŸã
ããããã¬ãŒã¯ã®ãµã€ãºã¯ãæŒåºãæ©ã®åäžé絊
ã«é¢ä¿ããããéèŠãªæ§è³ªã§ã¯ãªããåºãç¯å²ã§
å€æŽããããšãã§ããã äžèšã®ããã«ãæ¬çºæã®æ¹æ³ãå®æœããäžã§æ¬
質çãªæ¡ä»¶ã®äžã€ã¯ããã¬ãŒã¯ã®æ··ç·Žãšè解ãã
ã¬ãŒã¯ãæ§æããããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··å
ç©ã®å¹³è¡¡èç¹ããé«ã枩床ã§è¡ãªãããšã§ããã ããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©ã®å¹³è¡¡èç¹ã¯
次ã®é¢ä¿åŒããèšç®ããããšãã§ããã ïŒïŒïŒïŒïŒ¶ïŒšïŒïŒ¯ã»ïŒïŒïŒïŒŽâïŒïŒïŒŽâ²ïŒïŒ3.6â0.8ã»
ïŒïŒ¯ïŒïŒŽã»103 äžåŒäžãH2Oã¯åé¡ã®æ··åç©äžã®æ°Žã®äœç©å
çã§ãããã¯åé¡ã®æ··åç©äžã®å¹³è¡¡èç¹ïŒãïŒ
ã§ããããã€Tâ²ã¯ããªããã«ã¢ã«ã³ãŒã«ã®èç¹
ïŒ493ãïŒã§ãããäžèšé¢ä¿åŒã¯ãžã€ãŒãã«ã»ãª
ãã»ã¢ãã©ã€ãã»ããªããŒã»ãµã€ãšã³ã¹ã第20å·»
第1457â1465é ïŒ1976ïŒã«æ²èŒãããè«æäžã®ã
ãŒã¿ã«åºããŠç¢ºç«ãããã®ã§ããã äžèšé¢ä¿åŒãã次ã®çåŒãå°ãããã ïŒãïŒïŒ1000ã»ïŒïŒïŒïŒïŒã»ïŒ¶ïŒšïŒïŒ¯ ïŒïŒïŒïŒïŒïŒ
ïŒïŒïŒïŒïŒã»ïŒ¶ïŒšïŒïŒ¯ ããã«ãæ°Žã®äœç©åçãH2Oãã¯ééåçH
ïŒïŒ¯ãšæ¬¡ã®ããã«é¢ä¿ã¥ããããã H2OïŒïœïŒ°ïŒ¶ïŒ¡ã»ïŒ°ïŒšïŒïŒ¯ïŒïŒïŒïŒ°ïŒšïŒïŒ¯ã»ïŒïœïŒ°
âïŒïŒ äžåŒäžãïœPVAã¯ããªããã«ã¢ã«ã³ãŒã«ã®å¯åºŠ
ãè¡šãããïœPVAã®å€ã1.29ãšãããšã次ã®é¢ä¿
åŒãåŸãããã H2OïŒïŒïŒïŒïŒã»ïŒ°ïŒšïŒïŒ¯ïŒïŒïŒïŒïŒïŒïŒã»ïŒ°ïŒšïŒ
 æ·»ä»å³é¢ã®ç¬¬ïŒå³ã¯ã平衡èç¹ã®å€ãâïŒïŒŽâ
273ïŒã§ããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©äžã®æ°Ž
ã®ééåçH2Oã®é¢æ°ãšããŠè¡šãã代衚çã°ã©
ãã§ããã ããªããã«ã¢ã«ã³ãŒã«ã®ãã¬ãŒã¯ã®æ··ç·Žåã³è
解枩床ã¯æº¶èç©äžã«ç°è³ªçžãçããªãããã«éžã°
ããããã®æž©åºŠã¯ã䜿çšããæ°Žã®éã«äŸåãã以
å€ã«ã·ã€ãªã³ã°ïŒããæïŒã®çšåºŠåã³æéã«äŸå
ãã奜ãŸããã¯ãåé¡ã®ããªããã«ã¢ã«ã³ãŒã«â
æ°Žæ··åç©ã®å¹³è¡¡èç¹ãã100â以äžé«ã枩床ã§ã
ããããã«å¥œãŸããã¯ãäžèšã®å¥œãŸããç¯å²å ã
ã150âãªãã220âã®ç¯å²ãšãªãããã«éžã°ã
ãã æ°ŽãçŽ30ééïŒ ã®æ¯çïŒïŒ°H2OïŒ0.3ïŒã§å«æã
ããã¬ãŒã¯ãäŸã«æããŠèå¯ãããããã®æ¯çã¯
æ¬çºæã®å®æœã«ç¹ã«é©ããŠããããšã«æ³šæãã¹ã
ã§ããã第ïŒå³ã®ã°ã©ãã¯çŽ60âã®å¹³è¡¡èç¹ã瀺
ããŠãããããã«ãããšãæŒåºãæ©äžã®ãã¬ãŒã¯
ã®æ··ç·Žã»è解ã¯60âããé«ã枩床ã奜ãŸããã¯
160â以äžã®æž©åºŠã§è¡ãªããããããã«å¥œãŸãã
ã¯ã160âãš220âã®éã®æž©åºŠãéžã°ããã äžèšã®ããã«ãæ¬çºæã®æ¹æ³ãå®æœããããã®
ããäžã€ã®æ¬è³ªçæ¡ä»¶ã¯ã被èŠãã€ã¹äžã§ã溶è
æŒåºææ枩床ããã®æž©åºŠã«ãããæ°Žã®èžæ°å§ãçº
泡ã«ããæŒåºãæ©å€ã§ç®çãšãã被èŠã®èšåŒµãã²
ãèµ·ããã®ã«ååãªå§åãšãªããããªæž©åºŠã«ããª
ããã°ãªããªãããšããããšã§ãããããã«è©³ã
ããããšããã€ã¹äžã®æº¶èææã®æž©åºŠã¯105âæª
æºã§ããããã®æž©åºŠã¯å¥œãŸããã¯æé«98âã§ã
ãã æŒåºãæ©äžã®ãã¬ãŒã¯ã®æ··ç·Žã»è解ã平衡èç¹
ããé«ã105âæªæºã®æž©åºŠã§è¡ãªãããå Žåãã
ã€ã¹åºå£ã§ç®çãšãã被èŠäžã«æ°æ³¡åœ¢æãèµ·ãã
å±éºã¯ãªãããã€ã¹ãéããŠã®æº¶èææã®æŒåºã
ã¯ãã€ã¹æž©åºŠãå€ããããšãªãçŽã¡ã«è¡ãªãããš
ãã§ããã ä»æ¹ããã¬ãŒã¯ã®æ··ç·Žã»è解ã105âããé«ã
枩床ã§è¡ãªãããå Žåããã®æ段ã¯éåžžã«å¥œãŸã
ãå®æœæ æ§ã«çžå¿ããããšãæ³èµ·ãããã®ã ãã
溶èæŒåºç©ã¯æ¬¡ãã§å·åŽããªããã°ãªããªããã
ã®å·åŽã¯ãã€ã¹èªäœã®äžã§è¡ãªãããšãã§ããã
ããã¯æº¶èæŒåºç©ããã€ã¹ãééããåã«è¡ãªã
ããšãã§ãããå·åŽã¯å質ã«è¡ãªããªããã°ãªã
ãªããããªãã¡ãè¡šé¢å±€ã ãã§ãªãã溶èãžãšã
ãã®å šäœãå®åžžçã«æå®ã®å·åŽæž©åºŠã«ãããªãã
ã°ãªããªããå·åŽæ¡ä»¶ãæ»çæéååžãç±å¯å¡æ§
æš¹è補åºæäžã«ä»çãããç¬éãŸã§çµæ¶æ žã®åºçŸ
ãé²æ¢ãããããã«èª¿ç¯ããªããã°ãªããªããç¹
ã«ã溶èæŒåºç©ã®æž©åºŠã¯åé¡ã®ããªããã«ã¢ã«ã³
ãŒã«ãšæ°Žã®æ··åç©ã®å¹³è¡¡èç¹ããäœã枩床ã«äžã
ãŠã¯ãããªãã æåŸã«ãäžèšã«ããã被èŠãã€ã¹äžã®æº¶èæŒåº
ç©ã®æž©åºŠã¯å¥œãŸããã¯å¹³è¡¡èç¹ãš98âã®éã®å€ã§
ãªããã°ãªãããèŠããã°èª¿ç¯ãããå·åŽãè¡ãª
ããããã«å¥œãŸããã¯ããã®æž©åºŠã¯å¹³è¡¡æº¶è枩床
ããïŒâé«ã枩床ãš98âã®éã®æž©åºŠã«éžå®ãã
ãã å·åŽçšåºŠãããã»ã©ã§ãªãå ŽåãäŸãã°æ°åºŠãª
ããçŽ40床çšåºŠã®å Žåãå·åŽã¯é«ãç±äŒå°çãã
ã€ãã€ã¹ã䜿çšããæŒåºãã¹ã溶èææã®ééé
ã調æŽããŠè¡ãªãããšãã§ãããé·ãã¹ã¯ãªãŠã
åããæŒåºãæ©ã䜿çšããããšãå¯èœã§ãããå
æŒåºãæ©äžã§æº¶èææã¯ã¹ã¯ãªãŠç«¯éšã«åã€ãŠé²
è¡ããéã«å·åŽããã æ¬çºæã®å¥œãŸããå®æœæ æ§ã«åŸãã°ãææã®æž©
床ãžã®å·åŽã¯ãæŒåºãæ©ã®ã·ãŒã¹ïŒå€è£ äœïŒã®ç«¯
éšãšè¢«èŠãã€ã¹ãšã®éã«æ¿å ¥ãããå·åŽãã¢ãžã
ã€ã¶ã䜿çšããŠè¡ãªããããæ¬çºæãå®æœããã
ãã«äœ¿çšããããšãã§ããç°¡åãªè£ 眮ã¯ã倧ããª
å§åéäžãªãã«å¹çã®ããå質ãªç±äº€æãå¯èœã«
ããå©ç¹ãšãèŠçŽ ã®æ°ã圢ç¶åã³æž©åºŠãé©åœã«éž
æããããšã«ãã€ãŠå®æœãã¹ãå·åŽã®çšåºŠã«é©å
ãããããšãã§ããå©ç¹ãæããéçãããµãã
èŠã€ããããšãã§ããããã®è£ 眮ã®è©³çŽ°ã¯ä»åœç¹
蚱第2373385å·ã«èšèŒãããŠããã çŽ30ééïŒ ã®æ°Žãå«æãããã¬ãŒã¯ã®äŸã«æ»ã
ãšã被èŠãã€ã¹äžã®æº¶èæŒåºç©ã®æž©åºŠã¯60â以äž
105âæªæºã奜ãŸããã¯60âãš98âã®éãã®æž©åºŠ
ã«çããã65âãš98âã®éã®æž©åºŠãç¹ã«å¥œé©ã§ã
ãã è¯å¥œãªæ§è³ªãæãã被èŠã®è£œé ã¯æ¬è³ªçã«äžèš
å®æœæ æ§ã«åŸãããšã«äŸåããŠããã泚æãã¹ã
ããšã«ãåºæãžã®è¢«èŠã®æ¥çã容æã«ãããã
ã«ãç±å¯å¡æ§æš¹èã®è¡šé¢ãäŸãã°ã³ããæŸé»å¹
æãç«çåŠçåã¯æ¥çä¿é²ããã©ã€ããŒãããªã
ã¡æ¥çå€ã®ä»çã«ãã€ãŠååŠçããããšãå¯èœã§
ããã被èŠåŠçãã¹ãªãŒãã管ãããªãœã³åã¯ã
ãªããªãŒã ã«é©çšããŠè¡ãªãå Žåã«ã¯æ¥çå€ã®äž
éå±€ã䜿çšããããšãç¹ã«æšå¥šããããæ¥çå€ãš
ããŠã¯ç¹ã«ããªãŠã¬ã¿ã³ç³»æ¥çå€æº¶æ¶²ã䜿çšãã
ããšãã§ããæ¥çå€ã®ä»çã«ç¶ããŠãäžéå±€ã®ç²
床ãé«ããªãéããããšããªãããã«æº¶åªã®å€§éš
åãé€å»ããããã«ããããã«ä¹Ÿç¥ãããã泚æ
ãã¹ãããšã«ãæ¥çå€ã®äžéå±€ãç±å¯å¡æ§åºæãš
æ¥è§ŠããåŽã®è¢«èŠå±€è¡šé¢ã«åããããè£ çããã
ããšãã§ãããäžè¬ã«ãæ¥çãããæ¥çå€ã®é
ã¯ã溶åªã®é€å»åŸã«æž¬å®ãããšãç±å¯å¡æ§æš¹èåº
æïŒè¢«èŠçé¢ã®m2åœãçŽïŒïœãšïŒïœã®éã§ããã æ¬çºæã®æ¹æ³ã«åŸã€ãŠè¢«èŠããã管ç¶ãã©ã³
ã¯ãããªãœã³åã¯ããªããªãŒã ã®äºè»žå»¶äŒžäžç©ºäœ
ãžã®æçµç転æã«é¢ããŠäžèšã«è©³çŽ°ã«èª¬æããã 管ç¶ãã©ã³ã¯ã®å Žåãããããã®ãŸãŸäœ¿çšããŠ
äºè»žå»¶äŒžå¹èŸŒã¿æ圢ã«ãã€ãŠãæ¬é¡åºé¡äººã«ãã
1980幎ïŒæ13æ¥åºé¡ã®ä»åœç¹èš±åºé¡ç¬¬80ïŒ13158
å·ã«èšèŒãããæè¡ã䜿çšããŠãã©ã®ãããªæšªæ
é¢åã³çžŠæé¢åœ¢ç¶ãæããé·å°ºã®äºè»žå»¶äŒžç°åœ¢æ
ã§ãåŸãããšãã§ããããã®æè¡ã¯æ¬¡ã®äžé£ã®æ
äœããæããããªãã¡ãææã®äºè»žå»¶äŒžæž©åºŠã«äº
åå ç±ãã管ç¶ãã©ã³ã¯ãç®çãšããç°åœ¢æã®åœ¢
ç¶åã³å¯žæ³ããã€éåã®è»žã«æ²¿ã€ãŠçœ®ãæäœãå
äžãªçžŠæ¹åã®å»¶äŒžåã³ãããšåæã«ææã®èªç¶ãª
äºè»žå»¶äŒžæ¯ç以äžè¿ã®åäžãªååŸæ¹åã®äºåå¹èŸŒ
ã¿ãããããã«å å§ãé©çšããæäœã暪æ¹åã®é
延䌞ãèµ·ããããã«ãã©ã³ã¯ãå®å šã«èšåŒµãããŠ
éåå£ã«å¯çããããã«ããããã«å å§ãå¢å ã
ãæäœãåã³ç°åœ¢æãå·åŽãå§åãç·©åãããæ
äœã§ãããåŸãããç°åœ¢æã¯ãäŸãã°å å§æµäœã
茞éããããã«ã軜éåã®ããã®ä¿è·ç®¡æãšã
ãŠãåã¯åæåŸã«å è£ å·¥æ¥ã«ãããŠå®¹åšæ¬äœãšã
ãŠäœ¿çšããããšãã§ããã 容åšæ¬äœã補é ããããã«ã¯ãç°åœ¢æã®åœ¢ç¶ã¯
æèŠã®èŠçŽ ã®åœ¢ç¶ã®è€è£œã«äžèŽããããã«éžã°ã
ããåèŠçŽ ã®éšåã«çªåºããæºãèšããããšãæ
å©ã«ã§ããåæã¯æºã§èµ·ããã®ã§ãéå±è£œåã¯ã
ã©ã¹ããã¯è£œã®å¥è£œã®ç«¯éšãã²ã ä»åã¯æº¶æ¥ã«ã
ã€ãŠå®¹åšæ¬äœã«åºå®ããã®ã容æã«ãããåŸãã
ã容åšã¯çé žæ¿åºŠã®é«ã液äœåã³éåžžã«é žçŽ æå
æ§ã®é«ãé£åãä¿åããã®ã«äœ¿çšããããšãã§ã
ãã 管ç¶ãã©ã³ã¯ã¯åæã«ããããªãœã³ã«è»¢æãã
ããšãã§ããã転æãããŠã§ããããªãœã³ã¯äžè¬
ã«ãŸãäžç«¯åã¯äž¡ç«¯ããã€ã¹ã䜿çšããã¹ã¿ã³ã
ã³ã°ã«ãããåã¯ããä»åã¯æº¶æ¥ã«ããéå±è£œå
ã¯ãã©ã¹ããã¯è£œã®ç«¯éšãåºçããããšã«ããé
ããŠããå ¬ç¥ã®æè¡ãçšããŠäºè»žå»¶äŒžå¹èŸŒã¿æ圢
ããããšã«ããäºè»žå»¶äŒžäžç©ºäœïŒå®¹åšæ¬äœããã©
ã¹ã³ããã³çïŒã«è»¢æãããã 転æãããŠã§ããããªããªãŒã ã¯åãå ¬ç¥æè¡
ãçšããŠçŽæ¥äºè»žå»¶äŒžå¹èŸŒã¿æåãããã äºè»žå»¶äŒžå¹èŸŒã¿æåå·¥çšã§ç®¡ç¶ãã©ã³ã¯ãããª
ãœã³åã¯ããªããªãŒã ãå ç±ããã枩床ã¯åºæã
æ§æããç±å¯å¡æ§ãã©ã¹ããã¯ã®æ§è³ªã«äŸããåº
æãããªãšã¹ãã«ã§ããå Žåãã¬ã©ã¹è»¢ç§»ç¹ãšçµ
æ¶å枩床ã®éã®æž©åºŠãããªãã¡85âãš120âã®é
ã®æž©åºŠããäžè¬ã«å¥œé©ã§ããã åŸãããäžç©ºäœã¯è¡æ匷ããå æ²¢åã³éææ§ã«
ã€ããŠè¢«èŠããªãäžç©ºäœã®æ§è³ªãä¿æããŠããã
被èŠã®åãã«é¢ããŠã¯ãäžèšã®æè¡ã«ããã°ãæ°Ž
æ§å¡åžæ³ãšæ¯ã¹ãŠãåäžæäœã§çŽã¡ã«10ãªãã
200ÎŒã®åã被èŠãåŸãããšãå¯èœã«ãªãããã®
ããã«ããŠè¢«èŠãããäžç©ºäœã¯é«çé žæ¿åºŠåã³ïŒ
åã¯é žçŽ æåæ§æ¶²äœã®å è£ ã«å®å šã«é©ãããã®ãš
ãªãã åŸåã®æè¡ãšæ¯èŒããå Žåãä»ã®å©ç¹ã¯ãæ°Žã
é€å»ããå¿ èŠããªãåã被èŠãåŸãããããšã§ã
ããå®éãæ°Žæ§å¡åžã®éã«èµ·ããããšãšã¯å¯Ÿç §ç
ã«ãæ¬çºæã®ç®¡ç¶ãã©ã³ã¯ãããªãœã³åã¯ããªã
ãªãŒã ã¯ãåãã0.1ãªããïŒmmã®ç¯å²ã«ãåŸã
ãã被èŠå±€ã®äºåã®ä¹Ÿç¥ãè¡ãªãå¿ èŠãªãã«è¢«èŠ
ããªãç±å¯å¡æ§æš¹èã®å»¶äŒžæ¡ä»¶ãšåã延䌞æ¡ä»¶äž
ã§å®¹æã«å»¶äŒžãåŸãããšã芳å¯ãããŠããããã
ã«ãããããã管ã管ç¶ãã©ã³ã¯ãããªãœã³åã¯
ããªããªãŒã ã®è²¯èµäžåã³ïŒåã¯ãããã®äºè»žå»¶
䌞å¹èŸŒã¿æååã®äºåå ç±äžã«éšåç也ç¥ãèµ·ã
åŸãããããã¯å»¶äŒžæåã«ã€ããŠãä»äžãäžç©ºäœ
ã®æ§è³ªã«ã€ããŠãåé¡ãšãªããªãã ãŸããå šãé©ãã¹ãããšã«ãäžèšã®å¥œé©ãªå®æœ
æ æ§ã«åŸã€ãŠãç¹ã«ãã¬ãŒã¯ã®æ°Žå«æéãšèç¹ã
éµå®ããããšã«ãã€ãŠãé«æž©ã§åŸåŠçå ç±ããã
ãšãªãããªããã«ã¢ã«ã³ãŒã«è¢«èŠãèæ°Žæ§ãæã
ãäžç©ºäœãåŸãããããèæ°Žæ§ããšããçšèªã¯ã
被èŠãå·æ°Žã«äžæº¶ã§ãããé©åœãªå Žåã¯60âã«å
ç±ããæ°Žã«æµžæŒ¬ãããšãã«çŽã¡ã«æº¶ããããšãªã
èšæœ€ãèµ·ããã ãã§ããããšãæå³ãããã®ãšç
解ãããããåŸåã®æ°Žæ§å¡åžæ³ã®æè¡ã§ã¯ãããª
ããã«ã¢ã«ã³ãŒã«å±€ãäºè»žå»¶äŒžã®ååã¯åŸã«130
âããé«ã枩床ã奜ãŸããã¯140âãš210âã®éã®
枩床ã®å ç±åŠçã«ãããå Žåã«éã€ãŠè¢«èŠã®èæ°Ž
æ§ãåŸãããšãã§ããããã®åŸåŠçå ç±ã®ç®çã¯
被èŠã®çµæ¶åºŠãé²å±ãããçµæãæ°Žäžæº¶æ§ãå«ã
ç©ççæ§è³ªãæ¹åããããšã§ãã€ããæ¬çºæã®æ
è¡ã§ã¯çµæ¶åºŠã®é«ãèæ°Žæ§ã®è¢«èŠãçŽæ¥åŸãããš
ãå¯èœã§ããã130âããé«ã枩床åã³140âãªã
ã210âã®æž©åºŠã§ã被èŠãããåºæåã¯äžç©ºäœã
å ç±éåå£ã«å¯çãããããšãå«ãåŸåŠçå ç±ã
å«ã段éãçç¥ããããšã«ããåœæ¥è ã®äœ¿çšãã
ããšãã§ããæè¡ã¯ç°¡ç¥åãããã æ¬æ现æžã®å®éšéšåã«ãããŠã¯ããªããã«ã¢ã«
ã³ãŒã«ã®å»¶äŒžåã¯æªå»¶äŒžè¢«èŠã®çµæ¶åºŠã¯ãå±æç
ïœïŒçæ¹æ§ããªããã«ã¢ã«ã³ãŒã«ã®å ŽåïŒåã¯å¹³
åå±æçïŒç°æ¹æ§ããªããã«ã¢ã«ã³ãŒã«ã®å ŽåïŒ
ã決å®ããããšã«ãã枬å®ãããå¹³åå±æçã¯è¢«
èŠãã€ã«ã é¢ã®äž»é åæ¹åïŒn1ïŒn2ïŒãšåçŽæ¹å
ïŒn3ïŒã®åå ã§ã¢ããå±æç枬å®åšãçšããŠæ±ºå®ã
ãïŒã€ã®äž»å±æçã®ç®è¡å¹³åã§ãããããªããã«
ã¢ã«ã³ãŒã«è¢«èŠäžã«æ°Žãååšãããšå±æçåã¯å¹³
åå±æçãäœäžããã®ã§ãçµæ¶åºŠã¯å®å šã«ä¹Ÿç¥ã
ã被èŠã§æž¬å®ããªããã°ãªããªãã也ç¥æ¡ä»¶ã«ã
ã€ãŠè¢«èŠã®çµæ¶åºŠãå€åããã®ãé²æ¢ãããã60
âãè¶ããªã枩床ã§ç空也ç¥ã«ããæ®åããæ°Žã
é€å»ããã ãã¡ãããæ¬çºæã®ç¯å²å ã§ã管ç¶ãã©ã³ã¯ã
ããªãœã³åã¯ããªããªãŒã ãæãã¯ä»äžãã補å
ã«é©çšãããå¥ã®éåäœè¢«èŠãããã«èšããããš
ã«ããåŸããã被èŠã®ä¿è·ã匷åããããšãã§ã
ãããã®æ°ãã被èŠã¯ã©ããã¯ã¹åã¯æº¶èéåäœ
ã®å¡åžãåææŒåºãå¡åžåã¯æº¶èéåäœã§ã®å å
ã®ãããªå ¬ç¥æè¡ã«ããä»çã§ãããäžç©ºäœã«å»¶
䌞å¯èœåã¯åçž®å¯èœã®ã¹ãªãŒããé©çšããããšã
å¯èœã§ããããã®é©çšãå å¡«ã®ååã¯åŸã«ç¹ã«ã
ã³è©°ç®çç·äžã«è¡ãªãããšãå¯èœã§ãããã¹ãªãŒ
ãã¯æŒåºãå¹èŸŒã¿ïŒäœå¯åºŠããªãšãã¬ã³ãããªã
ããã¬ã³ããšãã¬ã³âå¡©åããã«ãã¢ã€ãªãããŒ
æš¹èåã¯ã¢ã¯ãªããããªã«å ±éåäœã®ã±ãŒã·ã³ã°
ã®æãæ®éã®å ŽåïŒã«ããåŸãããããåã¯å·»ã
äžããŠæº¶æ¥åã¯åºçããå¹³åŠãªãã€ã«ã ããåŸã
ããã±ãŒã·ã³ã°ã®æšªã®åæã«ãã補é ããããšã
ã§ããããã¡ãããã¹ãªãŒãã¯çš®ã ã®è£å©å€ãç¹
ã«çè²å€åã³UVåžåå€ãå«æããããšãã§ãã
ãã€éæåã¯äžéæã§å°å·ãããŠããŠãããå°å·
ãããŠããªããŠããããã¹ãªãŒãã¯äžç©ºäœã®å šè¡š
é¢ãèŠã€ãŠããå¿ èŠã¯ãªããäŸãã°ãã³ããã©ã¹
ã³ã®å Žåã¯ãççŽãªåçéšã®ã¿ãä¿è·ããŠããã°
ãããåºéšãšããã¯ã¯é€å€ãããŠããã 以äžã®å®æœäŸã«ããæ¬çºæã説æããããæ¬çº
æã®ç¯å²ã¯ãããã«éå®ãããªãã äŸ ïŒ æ¬å®æœäŸã¯æ°Žæ§å¡åžæ³ã䜿çšããåŸåã®æè¡ã®
å Žåã«èµ·ããçŸè±¡ã瀺ãæ¯èŒäŸã§ããã ããŒãã»ããŒã©ã³ç€Ÿè£œã®RHODOVIOL30âïŒ
ãšããåæšã®æ¬¡ã®æ§è³ªããã€åžè²©ã®ããªããã«ã¢
ã«ã³ãŒã«ïŒ âãšã¹ãã«å€ïŒ ïŒïŒããªãã¡99ééïŒ åã¯99.5
ã¢ã«ïŒ ã®å æ°Žå解床ïŒã âãªã¹ãã¯ã«ãç²åºŠèšã§20âã«ãããŠæž¬å®ããïŒ
ééïŒ åŒ·åºŠæº¶æ¶²ã®ç²åºŠïŒ 28ã»ã³ããã€ãºã âç°åå«æéïŒ ïŒééïŒ æªæºã âã·ã³ãžãªã¿ã¯ãçšåºŠïŒ ã·ã³ãžãªã¿ã¯ãäžã€çµ
54ïŒ ã枬å®ã¯ã€ããŠãšããããªããŒã»ãžã€ãŒãã«
ïŒ1973ïŒp.244ãåã³ãŠãŒåã³ãªãããŒã«ããã¯ã
ã¢ã¬ããŠãŒã«ãºïŒ1973ïŒp.582ãã®æ¹æ³ã«åŸã€
ãŠã VARIAN CFT20NMRã䜿çšããŠéæ°Ž
äž80âã§è¡ãªã€ãã âïŒïŒïŒâã°ãªã³ãŒã«é£éïŒ åéäœåäœ100åœ
ã0.66é£éã ã䜿çšããŠ15ïŒ åŒ·åºŠã®æ°Žæº¶æ¶²ïŒéåäœééïŒæº¶æ¶²
ééïŒã調補ãããããããªãšãã¬ã³ãã¬ãã¿ã¬
ãŒãïŒããŒãã»ããŒã©ã³ç€Ÿè£œRHODESTER85TX
éåäœãåºæç²åºŠ0.83dlïŒïœïŒè£œã®éæãªå°åºæ
åããªããªãŒã ã«æµžæŒ¬ã«ãã50âã§å¡åžããã®ã«
䜿çšããã浞挬åã³æ液åŸãããªããªãŒã äžã«æ¯
èŒçåäžãªè¢«èŠãåŸãããå®å šä¹Ÿç¥åŸã®å¹³ååã
ã¯27ÎŒã§ããã ç空çäž60âã®å®åžžééã«ä¹Ÿç¥ããã被èŠã®çµ
æ¶ç¶æ ã調ã¹ãã枬å®ã¯ããã€ã«ã é¢ã®äž¡ç«¯çžã®
å±æçå€n1åã³n2ãšãã€ã«ã é¢ã«åçŽã«æž¬å®ãã
å€n3ãèŠåºãããã«ã¢ããå±æç枬å®åšã䜿çšã
ãŠ23âã«ãããŠè¡ãªãããã ãããã®å€ã¯ã
ãè¡šã
ãã®ããã«ããŠåŸãããããªããã«ã¢ã«ã³ãŒã«
被èŠçã®æ©æ¢°çæ§è³ªåã³èæ°Žæ§ãããªãšã¹ãã«åº
æããåé¢ããåŸã«è©Šéšãã次ã®çµæãåŸãã
ãã âããåŒäžåŒŸæ§çïŒä¹Ÿç¥åã§23âã«ãããŠæž¬
å®ïŒïŒ ïŒïŒïŒ885MPaã âèæ°Žæ§ïŒ 被èŠçã20âã®æ°Žã«æµžæŒ¬ïŒ é ããå®å šãªæº¶è§£
ã芳å¯ãããã 60âã®æ°Žã«15åéæµžæŒ¬ïŒ æ¥éãªæº¶è§£ã芳å¯ã
ããã 湿ã€ãæã§è§Šããéã«ããªããªãŒã ã®è¢«èŠã®è
æ°Žæ§ãæªãããšãæããã«ãªã€ããæåã¯ããã
ã ãã§ããããç°å¢æž©åºŠã§åã«ãããã ãã§è¢«èŠ
ã«ããåãããã ãã®ããã«ããŠè¢«èŠããããªããªãŒã ã¯è¢«èŠã
ãªããªãŒã ã100âã®ç±æ°çå ã§äºåå ç±ãã
åŸã空æ°å§ã§äºè»žå»¶äŒžããããšã«ãã€ãŠå€§å®¹é
ïŒ1.5ïŒã®ãã³ã補é ããã®ã«äœ¿çšãããã 被èŠã®å»¶äŒžæ¯ã¯çžŠæ¹åã«2.5ã暪æ¹åã«3.8ã§ã
ãããã®çµæããªããã«ã¢ã«ã³ãŒã«ãã€ã«ã ã®å
ãã¯27ÎŒãã2.84ÎŒïŒä¹Ÿç¥ç¶æ ïŒã«æžå°ããã å¹èŸŒã¿éåã¯å·ãã®ã§ãé¢åã¯å¹èŸŒã¿æ圢çŽåŸ
ã«è¡ãªãããããã®ããé åçãªå€èŠ³ãæããé
æãªãã³ãåŸãããããã®ãã®ã®å€éšè¢«èŠã®çµæ¶
床ãå±æç枬å®åšãçšããŠåæããã延䌞ã®çµæ
ããªãšã¹ãã«ã®åãã¯300ÎŒã«è¿ãå€ã«æžå°ããŠ
ããã®ã§ã延䌞ãããããªãšã¹ãã«åºæããåé¢
ããã«è¢«èŠã®å åŠçæ§è³ªãåæããããšãå¯èœã§
ããããã®ããã«ããã³ãã䜿çšããŠãã³ã®äžå€®
éšåããçŽåŸïŒmmã®åæ¿ãåãåºããããªããã«
ã¢ã«ã³ãŒã«ã§è¢«èŠãããé¢ã泚ææ·±ã枬å®ããªãº
ã ã«æ¥è§Šããããã«çœ®ãã 延䌞ãã€ã«ã ã§æž¬å®ããå€ã¯ãã€ã«ã ã®ä¹Ÿç¥ã
å®äºããŠãäŸç¶ãšããŠå®è³ªçã«å€åããç空çäž
60âã§ä¹Ÿç¥ãããµã³ãã«ã§ä»¥äžã®å€ã«å®å®ããã
被èŠçã®æ©æ¢°çæ§è³ªåã³èæ°Žæ§ãããªãšã¹ãã«åº
æããåé¢ããåŸã«è©Šéšãã次ã®çµæãåŸãã
ãã âããåŒäžåŒŸæ§çïŒä¹Ÿç¥åã§23âã«ãããŠæž¬
å®ïŒïŒ ïŒïŒïŒ885MPaã âèæ°Žæ§ïŒ 被èŠçã20âã®æ°Žã«æµžæŒ¬ïŒ é ããå®å šãªæº¶è§£
ã芳å¯ãããã 60âã®æ°Žã«15åéæµžæŒ¬ïŒ æ¥éãªæº¶è§£ã芳å¯ã
ããã 湿ã€ãæã§è§Šããéã«ããªããªãŒã ã®è¢«èŠã®è
æ°Žæ§ãæªãããšãæããã«ãªã€ããæåã¯ããã
ã ãã§ããããç°å¢æž©åºŠã§åã«ãããã ãã§è¢«èŠ
ã«ããåãããã ãã®ããã«ããŠè¢«èŠããããªããªãŒã ã¯è¢«èŠã
ãªããªãŒã ã100âã®ç±æ°çå ã§äºåå ç±ãã
åŸã空æ°å§ã§äºè»žå»¶äŒžããããšã«ãã€ãŠå€§å®¹é
ïŒ1.5ïŒã®ãã³ã補é ããã®ã«äœ¿çšãããã 被èŠã®å»¶äŒžæ¯ã¯çžŠæ¹åã«2.5ã暪æ¹åã«3.8ã§ã
ãããã®çµæããªããã«ã¢ã«ã³ãŒã«ãã€ã«ã ã®å
ãã¯27ÎŒãã2.84ÎŒïŒä¹Ÿç¥ç¶æ ïŒã«æžå°ããã å¹èŸŒã¿éåã¯å·ãã®ã§ãé¢åã¯å¹èŸŒã¿æ圢çŽåŸ
ã«è¡ãªãããããã®ããé åçãªå€èŠ³ãæããé
æãªãã³ãåŸãããããã®ãã®ã®å€éšè¢«èŠã®çµæ¶
床ãå±æç枬å®åšãçšããŠåæããã延䌞ã®çµæ
ããªãšã¹ãã«ã®åãã¯300ÎŒã«è¿ãå€ã«æžå°ããŠ
ããã®ã§ã延䌞ãããããªãšã¹ãã«åºæããåé¢
ããã«è¢«èŠã®å åŠçæ§è³ªãåæããããšãå¯èœã§
ããããã®ããã«ããã³ãã䜿çšããŠãã³ã®äžå€®
éšåããçŽåŸïŒmmã®åæ¿ãåãåºããããªããã«
ã¢ã«ã³ãŒã«ã§è¢«èŠãããé¢ã泚ææ·±ã枬å®ããªãº
ã ã«æ¥è§Šããããã«çœ®ãã 延䌞ãã€ã«ã ã§æž¬å®ããå€ã¯ãã€ã«ã ã®ä¹Ÿç¥ã
å®äºããŠãäŸç¶ãšããŠå®è³ªçã«å€åããç空çäž
60âã§ä¹Ÿç¥ãããµã³ãã«ã§ä»¥äžã®å€ã«å®å®ããã
ãè¡šã
ãã³ã«æ¹¿ã€ãæãåã«è§Šããããšã«ãã€ãŠè¡ãª
ã€ãç°å¢æž©åºŠã«ããã延䌞ãã€ã«ã ã®èæ°Žæ§è©Šéš
ã«ããã被èŠã¯æåæ§ãé«ããæ¥éã«åŽ©å£ããã
åºæããåé¢ãã被èŠã®ãµã³ãã«ã60âã®æ°Žã«15
åé浞挬ãããšè¢«èŠã®å®å šãªæº¶è§£ã芳å¯ãããã 以äžã®è©Šéšã§ã¯æªå»¶äŒžåã¯å»¶äŒžè¢«èŠã®çµæ¶åºŠå
ã³èæ°Žæ§ã®å€åã«å¯ŸããåŸåŠçå ç±ã®åœ±é¿ã説æ
ããã æªå»¶äŒžè¢«èŠ ããªãšã¹ãã«åºæããåé¢ããæªå»¶äŒžããªãã
ã«ã¢ã«ã³ãŒã«è¢«èŠã®ãµã³ãã«ãããªããªãŒã ãã
åããç空äž60âã§é£ç¶ä¹Ÿç¥ãã100âãã170â
ãžææž©ããŠå ç±åŠçãããåŠçæéã¯10åéã§ã
ãããã®åŠçã®ããã«äœ¿çšããå ç±ãããéå±æ¿
ã«ãµã³ãã«ã確å®ã«å¯çããããã«æ³šæããã ãã®ããã«åŠçãããµã³ãã«ã®å¹³åå±æçãš60
â15åéåŠçæã®èæ°Žæ§ã«ã€ããŠä»¥äžã®å€ãåŸã
ããã 枩床 ïœ è æ°Ž æ§ 100â 1.5356 溶解ãã 120â 1.5378 ããããã溶解ãã 130â 1.5406 溶解ããªã 150â 1.5421 溶解ããªã 170â 1.5433 溶解ããªã å»¶äŒžè¢«èŠ äžèšã®ããã«è£œé ããäžé£ã®1.5ãã³ã䜿çš
ããããã³ã¯100âãã170âã«ææž©ããå ç±åŠç
ããããå ç±ã®ãããåãã³ãæå®ã®æž©åºŠã«å ç±
ããéåã®å£ã«å§åã䜿çšããŠ15ç§éå¯çãã
ããå ç±åŠçåŸãåºæïŒè¢«èŠè€åäœããæãçŽåŸ
ïŒmmã®åæ¿ãåãã³ã®äžå€®éšåããåãåºããã
éãããµã³ãã«ãç空äž60âã§ä¹Ÿç¥ããåãµã³ã
ã«ã®å¹³åå±æçã枬å®ãããèæ°Žæ§è©Šéšã¯åŒãè£
ãã«ããããªãšã¹ãã«åºæããåé¢ãã被èŠçã
60âã®æ°Žã«15åé浞挬ããããšã«ãã€ãŠè¡ãªãã
以äžã®çµæãåŸãã 枩床 ïœ è æ°Ž æ§ 100â 1.5298 溶解ãã 120â 1.5342 溶解ãã 140â 1.5372 溶解ããªã 160â 1.5387 溶解ããªã 170â 1.5402 溶解ããªã åŸã€ãŠãæ°Žæ§å¡åžã«ããä»çãããã®ã¿ã€ãã®
ããªããã«ã¢ã«ã³ãŒã«è¢«èŠã«ã€ããŠã¯ã延䌞åã¯
æªå»¶äŒžèæ°Žæ§è¢«èŠãåŸãããã«å³ããåŸåŠçå ç±
ãè¡ãªãå¿ èŠãããããšãæããã§ãããæªå»¶äŒž
被èŠã¯å¹³åå±æç1.5380ãè¶ ããå€ã§èæ°Žæ§ã«ãª
ããšèŠç©ããããã延䌞被èŠã®å Žåã¯å±æç
1.5360ãè¶ ããå€ã§èæ°Žæ§ã«ãªããšèŠç©ãããã
被èŠãèæ°Žæ§ã§ããã°ã湿ã€ãæã觊ããŠãããª
ããã«ã¢ã«ã³ãŒã«ãã€ã«ã ã®åŽ©å£åã³åããã¯ã
ã¯ã芳å¯ãããªãã äŸ ïŒ åãççŽã®ããªããã«ã¢ã«ã³ãŒã«ã
RHODOVIOL30âïŒãã®ç²æ«ã䜿çšããŠãä»ã®
å¯å¡åå€ãªãã«æŒåºãç®çã§ã30ééïŒ ã®æ°Žãå«
æãããã¬ãŒã¯ã調æŽãããäºããç²æ«åããã
ããªããã«ã¢ã«ã³ãŒã«ãå·æ°Žã§é å¿æŽæµããææ
ã®éã®ã»ãŒ10ïŒ éå°éã®æ°Žãã·ã°ãç¶ç¿Œãæãã
äœéãããµïŒGUITTARDç€Ÿè£œè£ çœ®ïŒã«å°å ¥ã
ãããã®è£ 眮ã®ãããããžã€ã±ããã§80âã«å ç±
ãããããŠæ¹¿ã€ãææã®æž©åºŠã75âã«éããŠãã
æ¬æãïŒæéç¶æããã ãã®æ··ç·Žãæžãã åŸããããããã®ãžã€ã±ãã
ã§å·åŽãããããŠãã®ããã«ããŠåäžã«å«æµžãã
ã補åãæåºããã補åã¯ãã¬ãŒã¯ãç²çããåŸ
åã¯å°ãããªãè¯å¥œãªæµåæ§ãæããŠãããçäž
ã§ã®æ倱ééã§æž¬å®ããæ°Žåå«æéã¯31ïŒ ãš31.6
ïŒ ãšã®éã§ãã€ãããã¬ãŒã¯ã¯æŒåºå®éšãŸã§æ°Žã®
æ倱ãªãã«ä¿åããããã«å¯éããè¢ã«è²¯èµã
ãã ãã®ããã«ããŠèšæœ€ãããããªããã«ã¢ã«ã³ãŒ
ã«ããïŒã€ã®å ç±ãŸãŒã³ãæããç°ç¶ãã€ã¹ãå
ããŠè©²ãã€ã¹ã®è»žãšåå¿ã«ãªãããã«æ¡å ããã
管ã®åšçžã«ææã®æµããåé ããã®ãå¯èœã«ãã
ANDOUARTåäžè»žæŒåºãæ©ïŒçŽåŸ60mmãé·ã
20DïŒã®ãããã«é絊ãããïŒåã®å¥ã ã«èª¿ç¯ã
ãããŸãŒã³ã«ããå ç±ãããã·ãŒã¹å ã«é 眮ãã
çŽåŸïŒã€ã³ãã®ïŒåã®èŠçŽ ããæãéçãããµã
ã·ãŒã¹ç«¯éšãšãã€ã¹ã®éã«æ¿å ¥ãããæŒåºç©ã®æž©
床ãããã€ã«ãåäžæäœæ¡ä»¶äžã§ä»¥äžã®ããã«å¹³
è¡¡åããã âæŒåºãæ©ïŒ å ¥å£ïŒ90â æ©äœäžå€®ïŒ200â210â çµç«¯ïŒ170â âå·åŽè£ çœ®ïŒ ç¬¬ïŒãŸãŒã³ïŒ110â 第ïŒãŸãŒã³ïŒ 95â âãã€ã¹ ïŒ 95â ã¹ã¯ãªãŠã®å転é床ã¯27rpmã«åºå®ããããã€
ã¹äžã®å§åæ倱ã®ãããéå£éšã¯åç®åãïŒæªå»¶
䌞ç¶æ ïŒ800ÎŒã®ä»çã«å¯ŸããŠç®çãããŠããã
æŒåºè£œåã®éééã¯ïŒKgïŒæçšåºŠã§ããã ããªããã«ã¢ã«ã³ãŒã«ã¯ããŒãã»ããŒã©ã³ç€Ÿã®
RHODESTER85ããå¥é補é ãããéæ¶è³ªããª
ãšãã¬ã³ãã¬ãã¿ã¬ãŒãã®æŒåºã管äžã«ä»çãã
管ã®å€åŸã¯24.8mmã§ããã管ã®éãé床ã¯è¢«èŠã®
åãã450ÎŒã®å€ã«èª¿æŽãããããã«åºå®ããã
ãã®åãã¯ä¹Ÿç¥è¢«èŠç®¡ã§ããšãã¯ããã åŸããã被èŠã¯å®å šã«éæã§æ°æ³¡ãç²åããª
ãããŸããã€ã¹äžã®æµãã®åé¢ã®ããå溶æ¥ç·ã
æããã«ãªããªããããã«ãç²çæ§ããªãã®ã§è¢«
èŠãç°å¢æž©åºŠã«æ»ã次第ã被èŠããã管ãåäžã
ãããšãå¯èœã§ããããšãèŠåºãããã ãããã®æ¡ä»¶äžã§ã¯ã茞éç³»ãšã®æ¥è§Šã«ãã被
èŠãæå·ããå±éºãªãã«ãéžã§è¢«èŠç®¡ãåæãã
ããšãã§ããã ãã®ããã«ããŠæŒåºãããããªããã«ã¢ã«ã³ãŒ
ã«ã®çµæ¶ç¶æ ã調ã¹ãããã«ãç空äž60âã§è¢«èŠ
çã也ç¥ãå±æçã調ã¹ããæ®å湿床ãå®å šã«é€
å»ããåŸã以äžã®å€ãåŸãããã
ã€ãç°å¢æž©åºŠã«ããã延䌞ãã€ã«ã ã®èæ°Žæ§è©Šéš
ã«ããã被èŠã¯æåæ§ãé«ããæ¥éã«åŽ©å£ããã
åºæããåé¢ãã被èŠã®ãµã³ãã«ã60âã®æ°Žã«15
åé浞挬ãããšè¢«èŠã®å®å šãªæº¶è§£ã芳å¯ãããã 以äžã®è©Šéšã§ã¯æªå»¶äŒžåã¯å»¶äŒžè¢«èŠã®çµæ¶åºŠå
ã³èæ°Žæ§ã®å€åã«å¯ŸããåŸåŠçå ç±ã®åœ±é¿ã説æ
ããã æªå»¶äŒžè¢«èŠ ããªãšã¹ãã«åºæããåé¢ããæªå»¶äŒžããªãã
ã«ã¢ã«ã³ãŒã«è¢«èŠã®ãµã³ãã«ãããªããªãŒã ãã
åããç空äž60âã§é£ç¶ä¹Ÿç¥ãã100âãã170â
ãžææž©ããŠå ç±åŠçãããåŠçæéã¯10åéã§ã
ãããã®åŠçã®ããã«äœ¿çšããå ç±ãããéå±æ¿
ã«ãµã³ãã«ã確å®ã«å¯çããããã«æ³šæããã ãã®ããã«åŠçãããµã³ãã«ã®å¹³åå±æçãš60
â15åéåŠçæã®èæ°Žæ§ã«ã€ããŠä»¥äžã®å€ãåŸã
ããã 枩床 ïœ è æ°Ž æ§ 100â 1.5356 溶解ãã 120â 1.5378 ããããã溶解ãã 130â 1.5406 溶解ããªã 150â 1.5421 溶解ããªã 170â 1.5433 溶解ããªã å»¶äŒžè¢«èŠ äžèšã®ããã«è£œé ããäžé£ã®1.5ãã³ã䜿çš
ããããã³ã¯100âãã170âã«ææž©ããå ç±åŠç
ããããå ç±ã®ãããåãã³ãæå®ã®æž©åºŠã«å ç±
ããéåã®å£ã«å§åã䜿çšããŠ15ç§éå¯çãã
ããå ç±åŠçåŸãåºæïŒè¢«èŠè€åäœããæãçŽåŸ
ïŒmmã®åæ¿ãåãã³ã®äžå€®éšåããåãåºããã
éãããµã³ãã«ãç空äž60âã§ä¹Ÿç¥ããåãµã³ã
ã«ã®å¹³åå±æçã枬å®ãããèæ°Žæ§è©Šéšã¯åŒãè£
ãã«ããããªãšã¹ãã«åºæããåé¢ãã被èŠçã
60âã®æ°Žã«15åé浞挬ããããšã«ãã€ãŠè¡ãªãã
以äžã®çµæãåŸãã 枩床 ïœ è æ°Ž æ§ 100â 1.5298 溶解ãã 120â 1.5342 溶解ãã 140â 1.5372 溶解ããªã 160â 1.5387 溶解ããªã 170â 1.5402 溶解ããªã åŸã€ãŠãæ°Žæ§å¡åžã«ããä»çãããã®ã¿ã€ãã®
ããªããã«ã¢ã«ã³ãŒã«è¢«èŠã«ã€ããŠã¯ã延䌞åã¯
æªå»¶äŒžèæ°Žæ§è¢«èŠãåŸãããã«å³ããåŸåŠçå ç±
ãè¡ãªãå¿ èŠãããããšãæããã§ãããæªå»¶äŒž
被èŠã¯å¹³åå±æç1.5380ãè¶ ããå€ã§èæ°Žæ§ã«ãª
ããšèŠç©ããããã延䌞被èŠã®å Žåã¯å±æç
1.5360ãè¶ ããå€ã§èæ°Žæ§ã«ãªããšèŠç©ãããã
被èŠãèæ°Žæ§ã§ããã°ã湿ã€ãæã觊ããŠãããª
ããã«ã¢ã«ã³ãŒã«ãã€ã«ã ã®åŽ©å£åã³åããã¯ã
ã¯ã芳å¯ãããªãã äŸ ïŒ åãççŽã®ããªããã«ã¢ã«ã³ãŒã«ã
RHODOVIOL30âïŒãã®ç²æ«ã䜿çšããŠãä»ã®
å¯å¡åå€ãªãã«æŒåºãç®çã§ã30ééïŒ ã®æ°Žãå«
æãããã¬ãŒã¯ã調æŽãããäºããç²æ«åããã
ããªããã«ã¢ã«ã³ãŒã«ãå·æ°Žã§é å¿æŽæµããææ
ã®éã®ã»ãŒ10ïŒ éå°éã®æ°Žãã·ã°ãç¶ç¿Œãæãã
äœéãããµïŒGUITTARDç€Ÿè£œè£ çœ®ïŒã«å°å ¥ã
ãããã®è£ 眮ã®ãããããžã€ã±ããã§80âã«å ç±
ãããããŠæ¹¿ã€ãææã®æž©åºŠã75âã«éããŠãã
æ¬æãïŒæéç¶æããã ãã®æ··ç·Žãæžãã åŸããããããã®ãžã€ã±ãã
ã§å·åŽãããããŠãã®ããã«ããŠåäžã«å«æµžãã
ã補åãæåºããã補åã¯ãã¬ãŒã¯ãç²çããåŸ
åã¯å°ãããªãè¯å¥œãªæµåæ§ãæããŠãããçäž
ã§ã®æ倱ééã§æž¬å®ããæ°Žåå«æéã¯31ïŒ ãš31.6
ïŒ ãšã®éã§ãã€ãããã¬ãŒã¯ã¯æŒåºå®éšãŸã§æ°Žã®
æ倱ãªãã«ä¿åããããã«å¯éããè¢ã«è²¯èµã
ãã ãã®ããã«ããŠèšæœ€ãããããªããã«ã¢ã«ã³ãŒ
ã«ããïŒã€ã®å ç±ãŸãŒã³ãæããç°ç¶ãã€ã¹ãå
ããŠè©²ãã€ã¹ã®è»žãšåå¿ã«ãªãããã«æ¡å ããã
管ã®åšçžã«ææã®æµããåé ããã®ãå¯èœã«ãã
ANDOUARTåäžè»žæŒåºãæ©ïŒçŽåŸ60mmãé·ã
20DïŒã®ãããã«é絊ãããïŒåã®å¥ã ã«èª¿ç¯ã
ãããŸãŒã³ã«ããå ç±ãããã·ãŒã¹å ã«é 眮ãã
çŽåŸïŒã€ã³ãã®ïŒåã®èŠçŽ ããæãéçãããµã
ã·ãŒã¹ç«¯éšãšãã€ã¹ã®éã«æ¿å ¥ãããæŒåºç©ã®æž©
床ãããã€ã«ãåäžæäœæ¡ä»¶äžã§ä»¥äžã®ããã«å¹³
è¡¡åããã âæŒåºãæ©ïŒ å ¥å£ïŒ90â æ©äœäžå€®ïŒ200â210â çµç«¯ïŒ170â âå·åŽè£ çœ®ïŒ ç¬¬ïŒãŸãŒã³ïŒ110â 第ïŒãŸãŒã³ïŒ 95â âãã€ã¹ ïŒ 95â ã¹ã¯ãªãŠã®å転é床ã¯27rpmã«åºå®ããããã€
ã¹äžã®å§åæ倱ã®ãããéå£éšã¯åç®åãïŒæªå»¶
䌞ç¶æ ïŒ800ÎŒã®ä»çã«å¯ŸããŠç®çãããŠããã
æŒåºè£œåã®éééã¯ïŒKgïŒæçšåºŠã§ããã ããªããã«ã¢ã«ã³ãŒã«ã¯ããŒãã»ããŒã©ã³ç€Ÿã®
RHODESTER85ããå¥é補é ãããéæ¶è³ªããª
ãšãã¬ã³ãã¬ãã¿ã¬ãŒãã®æŒåºã管äžã«ä»çãã
管ã®å€åŸã¯24.8mmã§ããã管ã®éãé床ã¯è¢«èŠã®
åãã450ÎŒã®å€ã«èª¿æŽãããããã«åºå®ããã
ãã®åãã¯ä¹Ÿç¥è¢«èŠç®¡ã§ããšãã¯ããã åŸããã被èŠã¯å®å šã«éæã§æ°æ³¡ãç²åããª
ãããŸããã€ã¹äžã®æµãã®åé¢ã®ããå溶æ¥ç·ã
æããã«ãªããªããããã«ãç²çæ§ããªãã®ã§è¢«
èŠãç°å¢æž©åºŠã«æ»ã次第ã被èŠããã管ãåäžã
ãããšãå¯èœã§ããããšãèŠåºãããã ãããã®æ¡ä»¶äžã§ã¯ã茞éç³»ãšã®æ¥è§Šã«ãã被
èŠãæå·ããå±éºãªãã«ãéžã§è¢«èŠç®¡ãåæãã
ããšãã§ããã ãã®ããã«ããŠæŒåºãããããªããã«ã¢ã«ã³ãŒ
ã«ã®çµæ¶ç¶æ ã調ã¹ãããã«ãç空äž60âã§è¢«èŠ
çã也ç¥ãå±æçã調ã¹ããæ®å湿床ãå®å šã«é€
å»ããåŸã以äžã®å€ãåŸãããã
ãè¡šã
ãã®ææã«ã€ããŠåŒåŒµåŒ·åºŠè©Šéšãè¡ãªã€ããšã
ã匟æ§çã¯æ°Žæº¶æ¶²ããåŸãããã³ã³ãããŒã«ãšæ¯
èŒããŠå®è³ªçã«å¢å ããŠ6.750MPaã®å€ãšãªã€ã
ïŒäŸïŒåç §ïŒã èæ°Žæ§è©Šéšã«ãããã®è¢«èŠã¯ç°å¢æž©åºŠïŒ20âïŒ
ã«ãããŠäžæº¶æ§ã§ããã湿ã€ãæã觊ããŠãå€å
ããªãããšã瀺ãããã60âã®æ°Žã«15åé浞挬ã
ãŠã被èŠã¯äžæº¶æ§ã®ãŸãŸã§ãã€ãã äžèšã®ããã«è¢«èŠããïŒçŸ€ã®ããªãšã¹ãã«ç®¡ã
äºè»žå»¶äŒžãã³ã補é ããããã«äœ¿çšããïŒã€ã®é
ææ¹æ³ãé£ç¶çã«äœ¿çšããã 第ïŒæ¹æ³ åé¡ã®ç®¡ã®çŸ€ã¯ããªãšã¹ãã«ã®åå0.8mmã®ç®¡
ããæãã10cmã®é·ãã«åæããããã®ç¬¬ïŒæ¹æ³
ã«ãããŠã¯éå±ã€ã³ãµãŒãã管ã®ååçã®äž¡ç«¯ã«
ããä»ã«ããåºå®ããããããã®ã€ã³ãµãŒãã®ã
ã¡ã®ïŒã€ã¯åºéšãšããŠåãç²ç®¡éå±çã§ãããä»
æ¹ã®ã€ã³ãµãŒãã¯ããã¯ãšããŠåãäžç©ºã§ããã
ãããã®ããªãœã³ã¯100âã®å ç±ç©ºæ°äžã§äºåå
ç±ãå·åŽéåäžã§å¹èŸŒã¿æ圢ããããã®æäœã§æ
æã¯çžŠæ¹åã«ã¯ããããã延䌞ãããã暪æ¹åã®
延䌞æ¯çã¯ïŒæªæºïŒ2.6ãš2.9ã®éïŒã§ããã ç空äž60âã§ä¹Ÿç¥ããåŸãåŸããããã³ã®äžå€®
éšåããå£ã®ãµã³ãã«ãåãåºããå±æç枬å®æ©
ã®ããªãºã ã«æ¥è§Šããè¡šé¢ãçå®ã«è¢«èŠãããè¡š
é¢ã§ããããã«æ³šæããŠã延䌞補åã®å±æçãå
æããã åŸãããå€ã¯æ¬¡ã®éãã§ããã
ã匟æ§çã¯æ°Žæº¶æ¶²ããåŸãããã³ã³ãããŒã«ãšæ¯
èŒããŠå®è³ªçã«å¢å ããŠ6.750MPaã®å€ãšãªã€ã
ïŒäŸïŒåç §ïŒã èæ°Žæ§è©Šéšã«ãããã®è¢«èŠã¯ç°å¢æž©åºŠïŒ20âïŒ
ã«ãããŠäžæº¶æ§ã§ããã湿ã€ãæã觊ããŠãå€å
ããªãããšã瀺ãããã60âã®æ°Žã«15åé浞挬ã
ãŠã被èŠã¯äžæº¶æ§ã®ãŸãŸã§ãã€ãã äžèšã®ããã«è¢«èŠããïŒçŸ€ã®ããªãšã¹ãã«ç®¡ã
äºè»žå»¶äŒžãã³ã補é ããããã«äœ¿çšããïŒã€ã®é
ææ¹æ³ãé£ç¶çã«äœ¿çšããã 第ïŒæ¹æ³ åé¡ã®ç®¡ã®çŸ€ã¯ããªãšã¹ãã«ã®åå0.8mmã®ç®¡
ããæãã10cmã®é·ãã«åæããããã®ç¬¬ïŒæ¹æ³
ã«ãããŠã¯éå±ã€ã³ãµãŒãã管ã®ååçã®äž¡ç«¯ã«
ããä»ã«ããåºå®ããããããã®ã€ã³ãµãŒãã®ã
ã¡ã®ïŒã€ã¯åºéšãšããŠåãç²ç®¡éå±çã§ãããä»
æ¹ã®ã€ã³ãµãŒãã¯ããã¯ãšããŠåãäžç©ºã§ããã
ãããã®ããªãœã³ã¯100âã®å ç±ç©ºæ°äžã§äºåå
ç±ãå·åŽéåäžã§å¹èŸŒã¿æ圢ããããã®æäœã§æ
æã¯çžŠæ¹åã«ã¯ããããã延䌞ãããã暪æ¹åã®
延䌞æ¯çã¯ïŒæªæºïŒ2.6ãš2.9ã®éïŒã§ããã ç空äž60âã§ä¹Ÿç¥ããåŸãåŸããããã³ã®äžå€®
éšåããå£ã®ãµã³ãã«ãåãåºããå±æç枬å®æ©
ã®ããªãºã ã«æ¥è§Šããè¡šé¢ãçå®ã«è¢«èŠãããè¡š
é¢ã§ããããã«æ³šæããŠã延䌞補åã®å±æçãå
æããã åŸãããå€ã¯æ¬¡ã®éãã§ããã
ãè¡šã
被èŠã¯æ¹¿ã€ãæã觊ããŠãå
šãäžæåæ§ã§ã
ãããã€ç°å¢æž©åºŠïŒ20âïŒã«ãããŠæ°Žã«äžæº¶ã§ã
ãããŸãã60âã®æ°Žã«15åé浞挬ããŠãäžæº¶ã§ã
ãã 第ïŒæ¹æ³ åæåŸãããªãšã¹ãã«ã®åå3.5mmã®è¢«èŠç®¡ã®
第ïŒçŸ€ã䜿çšããŠãCORPOPLAST VBFå®éšå®€
æ©ã®ãã€ã¹ã§åºéšãšããã¯ãäºåå ç±åã³ã¹ã¿ã³
ãã³ã°ã«ãããäžç«¯ã®éããå¹èŸŒã¿æ圢å¯èœãªã
ãªããªãŒã ã補é ããã ãããã®ããªããªãŒã ã1.5ã®å®¹éåã³55ïœ
ã®ééããã€ãã³ãå¹èŸŒã¿æ圢ããããã«äœ¿çš
ããææãšè¢«èŠã®åããäžå€®éšã«ã€ããŠïŒå¯Ÿ9.5
ã®æ¯çã«æžå°ãã延䌞ãè¡ãªãã ããªããªãŒã ã®äºåå ç±ã¯ïŒã€ã®å ç±ãããå
æ®»ããæãéåã«æ¥è§ŠãããŠè¡ãªããããããã
ãšããªããªãŒã å ã®è¯å¥œãªç±ååžãä¿èšŒãããã
å¹èŸŒã¿æž©åºŠã¯95âã§ãããå¹èŸŒã¿æã®ããªããã«
ã¢ã«ã³ãŒã«ã®æ°Žåå«æéã¯1.6ééïŒ ã«çããã
ãšãå€æããã äºè»žå»¶äŒžåŸã被èŠã®åãã¯47ÎŒã§ãã€ããç¹ã«
åé¡ããããšãã蚌æ ããªãã®ã§ã被èŠããªãã
ãªãšã¹ãã«ã»ããªããªãŒã ãšåæ§90âãš110âã®
éã®çš®ã ã®æž©åºŠæ¡ä»¶äžã§å¹èŸŒã¿æ圢ãè¡ãªãããš
ãå¯èœã§ãããåŸããããã³ã¯å æ²¢ã«å¯ãå¹³æ»ãª
å€èŠ³ããã€ãŠãããããªããªãŒã ãäºã也ç¥ãã
å¿ èŠã¯ãªããå¹èŸŒã¿ã®å質ãæããããšãªããäº
軞延䌞段éã«ãããããªããªãŒã ã®æ°Žå«æéãã
ãªãå€æŽããããšãå¯èœã§ããã 60âã«ãããŠç空也ç¥åŸã延䌞被èŠã®å±æçã
枬å®ãããã®æž¬å®ã¯æã¡æãããµã³ãã«ã䜿çšã
ãŠãã³ïŒè¢«èŠè€åäœã«ã€ããŠçŽæ¥ã«è¡ãªãã 以äžã®å€ãåŸãããã
ãããã€ç°å¢æž©åºŠïŒ20âïŒã«ãããŠæ°Žã«äžæº¶ã§ã
ãããŸãã60âã®æ°Žã«15åé浞挬ããŠãäžæº¶ã§ã
ãã 第ïŒæ¹æ³ åæåŸãããªãšã¹ãã«ã®åå3.5mmã®è¢«èŠç®¡ã®
第ïŒçŸ€ã䜿çšããŠãCORPOPLAST VBFå®éšå®€
æ©ã®ãã€ã¹ã§åºéšãšããã¯ãäºåå ç±åã³ã¹ã¿ã³
ãã³ã°ã«ãããäžç«¯ã®éããå¹èŸŒã¿æ圢å¯èœãªã
ãªããªãŒã ã補é ããã ãããã®ããªããªãŒã ã1.5ã®å®¹éåã³55ïœ
ã®ééããã€ãã³ãå¹èŸŒã¿æ圢ããããã«äœ¿çš
ããææãšè¢«èŠã®åããäžå€®éšã«ã€ããŠïŒå¯Ÿ9.5
ã®æ¯çã«æžå°ãã延䌞ãè¡ãªãã ããªããªãŒã ã®äºåå ç±ã¯ïŒã€ã®å ç±ãããå
æ®»ããæãéåã«æ¥è§ŠãããŠè¡ãªããããããã
ãšããªããªãŒã å ã®è¯å¥œãªç±ååžãä¿èšŒãããã
å¹èŸŒã¿æž©åºŠã¯95âã§ãããå¹èŸŒã¿æã®ããªããã«
ã¢ã«ã³ãŒã«ã®æ°Žåå«æéã¯1.6ééïŒ ã«çããã
ãšãå€æããã äºè»žå»¶äŒžåŸã被èŠã®åãã¯47ÎŒã§ãã€ããç¹ã«
åé¡ããããšãã蚌æ ããªãã®ã§ã被èŠããªãã
ãªãšã¹ãã«ã»ããªããªãŒã ãšåæ§90âãš110âã®
éã®çš®ã ã®æž©åºŠæ¡ä»¶äžã§å¹èŸŒã¿æ圢ãè¡ãªãããš
ãå¯èœã§ãããåŸããããã³ã¯å æ²¢ã«å¯ãå¹³æ»ãª
å€èŠ³ããã€ãŠãããããªããªãŒã ãäºã也ç¥ãã
å¿ èŠã¯ãªããå¹èŸŒã¿ã®å質ãæããããšãªããäº
軞延䌞段éã«ãããããªããªãŒã ã®æ°Žå«æéãã
ãªãå€æŽããããšãå¯èœã§ããã 60âã«ãããŠç空也ç¥åŸã延䌞被èŠã®å±æçã
枬å®ãããã®æž¬å®ã¯æã¡æãããµã³ãã«ã䜿çšã
ãŠãã³ïŒè¢«èŠè€åäœã«ã€ããŠçŽæ¥ã«è¡ãªãã 以äžã®å€ãåŸãããã
ãè¡šã
ãã€ãšé¡èãªå»¶äŒžã®å¹æã®äžã«ç¬¬ïŒæ¹æ³ã§èšé²
ãããå€ãããå®è³ªçã«äœãå¹³åå€ãåŸãããã
ãã©ãã被èŠã®çµæ¶åºŠã¯20âã«ãããŠèæ°Žæ§ã§ã
ãããåã¯æ¹¿ã€ãæã®æ¥è§Šã«å¯ŸããŠæµææ§ã§ã
ããå€èŠ³ãå®å®æ§ãæãªãããšã®ãªã被èŠãäžã
ãã«ã¯å åã§ãã€ãããã®è¢«èŠã¯60âã®æ°Žã«15å
é浞挬ããŠãèæ°Žæ§ã§ãã€ãã äŸ ïŒ äŸïŒãšåãããªããã«ã¢ã«ã³ãŒã«ãã¬ãŒã¯èª¿è£œ
æ¡ä»¶ã䜿çšããããANDOUARDæŒåºãæ©ã®æŒåº
ã枩床ã¯äžå€®éšã®æž©åºŠã140âãããªãã¡åé¡ã®
ããªããã«ã¢ã«ã³ãŒã«ãšæ°Žã®å¹³è¡¡èç¹ããçŽ82â
ã ãé«ã枩床ããè¶ããªãããã«äœäžãããã 被èŠãã€ã«ã ã®è¡šé¢ç¶æ ãããç²ãå€èŠ³ãæã
ãã®ã§ã95âã«ä¿ããããã€ã¹ãééãã補åã®
æµãã«å°é£ã芳å¯ãããã ãã®è¢«èŠã®å±æçãäºã管ããåé¢ãç空äž60
âã§å®åžžééã«ãŸã§ä¹Ÿç¥ããæªå»¶äŒžããªããã«ã¢
ã«ã³ãŒã«çã«ã€ããŠèª¿ã¹ãã 以äžã®å€ãåŸãããã
ãããå€ãããå®è³ªçã«äœãå¹³åå€ãåŸãããã
ãã©ãã被èŠã®çµæ¶åºŠã¯20âã«ãããŠèæ°Žæ§ã§ã
ãããåã¯æ¹¿ã€ãæã®æ¥è§Šã«å¯ŸããŠæµææ§ã§ã
ããå€èŠ³ãå®å®æ§ãæãªãããšã®ãªã被èŠãäžã
ãã«ã¯å åã§ãã€ãããã®è¢«èŠã¯60âã®æ°Žã«15å
é浞挬ããŠãèæ°Žæ§ã§ãã€ãã äŸ ïŒ äŸïŒãšåãããªããã«ã¢ã«ã³ãŒã«ãã¬ãŒã¯èª¿è£œ
æ¡ä»¶ã䜿çšããããANDOUARDæŒåºãæ©ã®æŒåº
ã枩床ã¯äžå€®éšã®æž©åºŠã140âãããªãã¡åé¡ã®
ããªããã«ã¢ã«ã³ãŒã«ãšæ°Žã®å¹³è¡¡èç¹ããçŽ82â
ã ãé«ã枩床ããè¶ããªãããã«äœäžãããã 被èŠãã€ã«ã ã®è¡šé¢ç¶æ ãããç²ãå€èŠ³ãæã
ãã®ã§ã95âã«ä¿ããããã€ã¹ãééãã補åã®
æµãã«å°é£ã芳å¯ãããã ãã®è¢«èŠã®å±æçãäºã管ããåé¢ãç空äž60
âã§å®åžžééã«ãŸã§ä¹Ÿç¥ããæªå»¶äŒžããªããã«ã¢
ã«ã³ãŒã«çã«ã€ããŠèª¿ã¹ãã 以äžã®å€ãåŸãããã
ãè¡šã
ãã®è¢«èŠã¯å®å
šãªèæ°Žæ§ããã€ãŠããªãããšã
å€æããã ããªããã«ã¢ã«ã³ãŒã«ãšæ°Žã®å¹³è¡¡èç¹ããã
100âé«ãæŒåºæž©åºŠå³ã¡158âã®æŒåºæž©åºŠãçšã
ãŠãäŸïŒãå埩ããããããã®æ¡ä»¶äžã§ã¯ããã€
ã¹ãééãã溶è補åã®æµãã¯æ£åžžã§ããããã
ãŠè¢«èŠã¯20âã§æ°Žäžã«äžæº¶æ§ã§ãã€ãã äŸ ïŒ äŸïŒã«èšèŒãããå®éšãç¹°ãè¿ãããäžç©ºè£œå
ã®è£œé ã«ç¬¬ïŒæ¹æ³ãéžã³ãã¯ã©ã¬ç€Ÿã®POVALH
ãšãããåæšã®ããªããã«ã¢ã«ã³ãŒã«ã䜿çšã
ãããã®ç¹åŸŽã¯ä»¥äžã®éãã§ããã âãšã¹ãã«å€ïŒ ïŒ âïŒééïŒ åŒ·åºŠã®æ°Žæº¶æ¶²ã®ç²åºŠïŒ 30ã»ã³ããã€
㺠âç°åå«æéïŒ ïŒééïŒ æªæº âã·ã³ãžãªã¿ã¯ãçšåºŠïŒ 52.5ïŒ âïŒïŒïŒâã°ãªã³ãŒã«é£éïŒ åéäœåäœ100åœ
ã0.40é£éã æ°Žã35ééïŒ å«æãããã¬ãŒã¯ãGUITTARD
ãããµã䜿çšããŠèª¿è£œãããã¬ãŒã¯ã
ANDOUARTæŒåºãæ©ã§210âã§æŒåºãããã®é
æŒåºãææã®æž©åºŠããã€ã¹ãééããåã«95âã«
äœäžãããããå¶åŸ¡ããã被èŠããããªããªãŒã
ãš100âã§é¢å»¶äŒžç11.5ã«å»¶äŒžããäºè»žå»¶äŒžãã³
ã«ã€ããŠéåžžã®èª¿æ»è©Šéšãè¡ãªã€ããäž¡è ãšãã«
çŽæ¥èæ°Žæ§ãåŸãããæ°Žãé€å»ããããŸã§ç空äž
60âã§ä¹Ÿç¥ããåŸæž¬å®ããå¹³åå±æçã¯ããªããª
ãŒã ã§ã¯1.5420åã³ãã³ã§ã¯1.5380ã§ãã€ãã 40ééïŒ ã®æ°Žãå«æãããã¬ãŒã¯ãçšããŠäŸïŒ
ãå埩ãããæŒåºæž©åºŠã¯200âã§ãã€ãããã®ã
ãã«ããŠè¢«èŠãã管ã¯ãå·åŽãããã也ç¥ãããª
ã被èŠã®ããããã®ç²ç床ãçããåŸåãããã
ã䜿çšããã®ãå°ãå°é£ã§ããããšã芳å¯ãã
ãã äŸ ïŒ ããŒãã»ããŒã©ã³ç€Ÿããå ¥æãã
RHODOVIOL30âïŒåããªããã«ã¢ã«ã³ãŒã«ã
䜿çšããŠæ°Žã®å«æéã®å¢å ãããã¬ãŒã¯ã調補ã
ãããã®ãã¬ãŒã¯ã®æ°Žå«æéã¯55ééïŒ ã«ããã
ãã¬ãŒã¯ããããµãŒããåºããšå¡åããåŸåãé¡
èã§ãããANDOUARDæŒåºãæ©ã®é絊ãå°é£ãš
ãªãäžåäžãšãªãã ãã¬ãŒã¯ã®æ°Žå«æéãé«ãã®ã§è£œåã¯ROSSå
å·åŽè£ 眮ãéããã«çŽæ¥ã«æŒåºãããããã¯ãã®
å Žåã«ã¯æŒåºãæ©ã®æ¬äœæž©åºŠã135âã«åºå®ããŠ
ããããã§ãããåã«æº¶èæŒåºç©ã®éééãå€ã
ãã ãã§ãã€ã¹äžã®æŒåºç©ã®æž©åºŠãç®çã®95âã«
ããããšãå¯èœã§ãããããªããã«ã¢ã«ã³ãŒã«ã¯
åèšå®æœäŸã«èšèŒãããŠãããã®ãšåãããªãšã
ã¬ã³ãã¬ãã¿ã¬ãŒãã§ã§ããæŒåºã管äžã«ä»çã
ãã ãã®ããã«ããŠè¢«èŠãã管ã¯ãå·åŽãããã也
ç¥ãããªã被èŠã®ç²ç床ãé«ããªãåŸåãæãã
ãã䜿çšããã®ãå°é£ã§ããããšã芳å¯ãããã ç空äž60âã§ä¹Ÿç¥ããæªå»¶äŒžè¢«èŠã®å±æçã調
ã¹ããšããã以äžã®å±æçãåŸãããã
å€æããã ããªããã«ã¢ã«ã³ãŒã«ãšæ°Žã®å¹³è¡¡èç¹ããã
100âé«ãæŒåºæž©åºŠå³ã¡158âã®æŒåºæž©åºŠãçšã
ãŠãäŸïŒãå埩ããããããã®æ¡ä»¶äžã§ã¯ããã€
ã¹ãééãã溶è補åã®æµãã¯æ£åžžã§ããããã
ãŠè¢«èŠã¯20âã§æ°Žäžã«äžæº¶æ§ã§ãã€ãã äŸ ïŒ äŸïŒã«èšèŒãããå®éšãç¹°ãè¿ãããäžç©ºè£œå
ã®è£œé ã«ç¬¬ïŒæ¹æ³ãéžã³ãã¯ã©ã¬ç€Ÿã®POVALH
ãšãããåæšã®ããªããã«ã¢ã«ã³ãŒã«ã䜿çšã
ãããã®ç¹åŸŽã¯ä»¥äžã®éãã§ããã âãšã¹ãã«å€ïŒ ïŒ âïŒééïŒ åŒ·åºŠã®æ°Žæº¶æ¶²ã®ç²åºŠïŒ 30ã»ã³ããã€
㺠âç°åå«æéïŒ ïŒééïŒ æªæº âã·ã³ãžãªã¿ã¯ãçšåºŠïŒ 52.5ïŒ âïŒïŒïŒâã°ãªã³ãŒã«é£éïŒ åéäœåäœ100åœ
ã0.40é£éã æ°Žã35ééïŒ å«æãããã¬ãŒã¯ãGUITTARD
ãããµã䜿çšããŠèª¿è£œãããã¬ãŒã¯ã
ANDOUARTæŒåºãæ©ã§210âã§æŒåºãããã®é
æŒåºãææã®æž©åºŠããã€ã¹ãééããåã«95âã«
äœäžãããããå¶åŸ¡ããã被èŠããããªããªãŒã
ãš100âã§é¢å»¶äŒžç11.5ã«å»¶äŒžããäºè»žå»¶äŒžãã³
ã«ã€ããŠéåžžã®èª¿æ»è©Šéšãè¡ãªã€ããäž¡è ãšãã«
çŽæ¥èæ°Žæ§ãåŸãããæ°Žãé€å»ããããŸã§ç空äž
60âã§ä¹Ÿç¥ããåŸæž¬å®ããå¹³åå±æçã¯ããªããª
ãŒã ã§ã¯1.5420åã³ãã³ã§ã¯1.5380ã§ãã€ãã 40ééïŒ ã®æ°Žãå«æãããã¬ãŒã¯ãçšããŠäŸïŒ
ãå埩ãããæŒåºæž©åºŠã¯200âã§ãã€ãããã®ã
ãã«ããŠè¢«èŠãã管ã¯ãå·åŽãããã也ç¥ãããª
ã被èŠã®ããããã®ç²ç床ãçããåŸåãããã
ã䜿çšããã®ãå°ãå°é£ã§ããããšã芳å¯ãã
ãã äŸ ïŒ ããŒãã»ããŒã©ã³ç€Ÿããå ¥æãã
RHODOVIOL30âïŒåããªããã«ã¢ã«ã³ãŒã«ã
䜿çšããŠæ°Žã®å«æéã®å¢å ãããã¬ãŒã¯ã調補ã
ãããã®ãã¬ãŒã¯ã®æ°Žå«æéã¯55ééïŒ ã«ããã
ãã¬ãŒã¯ããããµãŒããåºããšå¡åããåŸåãé¡
èã§ãããANDOUARDæŒåºãæ©ã®é絊ãå°é£ãš
ãªãäžåäžãšãªãã ãã¬ãŒã¯ã®æ°Žå«æéãé«ãã®ã§è£œåã¯ROSSå
å·åŽè£ 眮ãéããã«çŽæ¥ã«æŒåºãããããã¯ãã®
å Žåã«ã¯æŒåºãæ©ã®æ¬äœæž©åºŠã135âã«åºå®ããŠ
ããããã§ãããåã«æº¶èæŒåºç©ã®éééãå€ã
ãã ãã§ãã€ã¹äžã®æŒåºç©ã®æž©åºŠãç®çã®95âã«
ããããšãå¯èœã§ãããããªããã«ã¢ã«ã³ãŒã«ã¯
åèšå®æœäŸã«èšèŒãããŠãããã®ãšåãããªãšã
ã¬ã³ãã¬ãã¿ã¬ãŒãã§ã§ããæŒåºã管äžã«ä»çã
ãã ãã®ããã«ããŠè¢«èŠãã管ã¯ãå·åŽãããã也
ç¥ãããªã被èŠã®ç²ç床ãé«ããªãåŸåãæãã
ãã䜿çšããã®ãå°é£ã§ããããšã芳å¯ãããã ç空äž60âã§ä¹Ÿç¥ããæªå»¶äŒžè¢«èŠã®å±æçã調
ã¹ããšããã以äžã®å±æçãåŸãããã
ãè¡šã
ãã®è¢«èŠã¯20âã§æ°Žã«æº¶ããããšãããã€ãã
被èŠããåé¢ãããµã³ãã«ã«ã€ããŠå ç±ç©ºæ°çã
䜿çšããŠ95âã«äºåå ç±ããŠäžè»žå»¶äŒžãè¡ãªã€
ãã延䌞æ¯çãïŒã®ãšããç空äž60âã§ä¹Ÿç¥ãã
ãšãã«ä»¥äžã®å±æçãæãããã€ã«ã ãåŸãã
ãã
被èŠããåé¢ãããµã³ãã«ã«ã€ããŠå ç±ç©ºæ°çã
䜿çšããŠ95âã«äºåå ç±ããŠäžè»žå»¶äŒžãè¡ãªã€
ãã延䌞æ¯çãïŒã®ãšããç空äž60âã§ä¹Ÿç¥ãã
ãšãã«ä»¥äžã®å±æçãæãããã€ã«ã ãåŸãã
ãã
ãè¡šã
ãã®å»¶äŒžãµã³ãã«ã¯äŸç¶ãšããŠ20âã§æ°Žæº¶æ§ã§
ããã äŸ ïŒ çŽ30ééïŒ ã®æ°Žãå«æãããã¬ãŒã¯ãäŸïŒã«èš
èŒããããªããã«ã¢ã«ã³ãŒã«ãRHODOVIOL30
âïŒãã調補ãã次ãã§æŒåºãã«ããçŽåŸ25mmå
ã³å£å300ÎŒã®ããªããã«ã¢ã«ã³ãŒã«è£œã±ãŒã·ã³
ã°ã補é ãããããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©
ã®æº¶èãæ··ç·Žåã³é«æž©æŒåºãã次ãã§ãã€ã¹éé
åã®å·åŽã¯äŸïŒã«èšèŒã®æ¡ä»¶äžã§è¡ãªã€ãã ç°ç¶ãã€ã¹ãééããéã«åœ¢æãããã±ãŒã·ã³
ã°ã¯å åŽã®åºæïŒäŸïŒã®ããã«ããã€ã¹ã®è»žãšå
å¿ã«ãªãããã«æ¡å ããã管ïŒã®äžã«ã§ã¯ãªãã
å¹³æ»ãªå£ããã€ïŒã€ã®åéåã«ãããããã®åŽã«
ãã±ãŒã·ã³ã°ãå²ãå¯åã·ãšãŒãäžã«æ¯æããã
該åéåã¯å¯åã«ã¿ãã©ã®äžéšåã³äžéšã®éèŠçŽ
ãæ§æããŠããã圢æãããã±ãŒã·ã³ã°ã®ç«¯éšã
å§æŸãããšããã®å¯åéåå ã§å éšã«ç©ºæ°ãå¹ã
蟌ãããšã«ãã€ãŠå¹èŸŒã¿æ圢ããããšãã§ããã 圢æãããã±ãŒã·ã³ã°ã¯100mmã®é·ããæãã
èŠçŽ ã«åæãããããã®èŠçŽ ãçäž60âã§60åé
ç©ããã«ä¹Ÿç¥ãããWIKOLIN瀟ããå ¥æããæ¥
çå€PENTACOLL ET691Aã®10ééïŒ åŒ·åºŠé ¢é ž
ãšãã«æº¶æ¶²ããããã®ã¹ãªãŒãã®å åŽã«åŽé§ãã
ã¹ãªãŒãå åŽãå°ã也ç¥ãããåŸãããã®æ¥çå€
ã§åŠçããèŠçŽ ããéé55ïœãããªãšã¹ãã«ã®å
åïŒmmãçŽåŸ24.8mmã®éæ¶è³ªããªãšãã¬ã³ãã¬ã
ã¿ã¬ãŒã補ããªããªãŒã ã®ççŽãªéšåã®å€åŽã«é©
çšããããããã®ããªããªãŒã ã¯ããŒãã»ããŒã©
ã³ç€Ÿã®RHODESTER85TXã䜿çšããŠå°åºæ圢ã«
ãã調補ãããããã¯åºéšãšåºéšã®éã«åºããã
ãªããªãŒã ã®å»¶äŒžå¯èœãªççŽãªéšåã®å šäœïŒ100
mmïŒãäžèšã®ããã«è¢«èŠãããä»çããæ¥çå€ã®
éã¯ã溶åªé€å»åŸã®æž¬å®ã§ããã®ããã«é©çšãã
ã±ãŒã·ã³ã°ã®m2åœãïŒãªããïŒïœã§ããã ãã®ããã«è¢«èŠããããªããªãŒã ã¯ç°å¢æž©åºŠ
ïŒ20âïŒã§24æé貯èµããŠãããå ç±ç©ºæ°çäžã§
äºåå ç±ããåŸã95âã§äºè»žå»¶äŒžïŒçžŠå»¶äŒžæ¯çïŒ
2.5ã暪延䌞æ¯çïŒïŒïŒããã ãã®ããã«ããŠåœ¢æãããäºè»žå»¶äŒžãã³ã«ã¯å
æã®å²ãããåã¯ãã®ãããªæ¹æ³ã§é©çšãäºè»žå»¶
䌞ãããããªããã«ã¢ã«ã³ãŒã«å±€ã®ä»çåã®æ¬ åŠ
ããçãããããªå€èŠ³äžã®æ¬ é¥ã芳å¯ãããªãã€
ãã ãã®ããã«ããŠè£œé ããè€åäœã®ããªã€æ§è³ªã
è©Šéšããããã«ãã³ã®å£ããåæ¿ãåãåºããã
ã®é žçŽ ééçãã¬ã¹ã¯ãããã°ã©ãã€ãŒã§èª¿ã¹
ãã䜿çšãããµã³ãã«ã®åãã¯ããªããã«ã¢ã«ã³
ãŒã«ã®20ÎŒãå«ããŠ320ÎŒã§ãã€ãã30âçžå¯Ÿæ¹¿
床60ïŒ ã®å¹³è¡¡æ¡ä»¶äžã§è¡ãªããã枬å®ã«ããå£ã®
é žçŽ ééçã¯ãããªããã«ã¢ã«ã³ãŒã«ãå¡åžããª
ãã³ã³ãããŒã«ã®ããªãšã¹ãã«ã®ééçã«æ¯èŒã
ãŠïŒå¯ŸïŒã«æžå°ããããšã瀺ãããã çžå¯Ÿæ¹¿åºŠ60ïŒ ã§åŸããããããã®åªããæåç¹
æ§ããåã³æ¬çºæã«ãã被èŠã®èæ°Žæ§ãéåžžã«è¯
奜ã§ããããšã確èªãããã
ããã äŸ ïŒ çŽ30ééïŒ ã®æ°Žãå«æãããã¬ãŒã¯ãäŸïŒã«èš
èŒããããªããã«ã¢ã«ã³ãŒã«ãRHODOVIOL30
âïŒãã調補ãã次ãã§æŒåºãã«ããçŽåŸ25mmå
ã³å£å300ÎŒã®ããªããã«ã¢ã«ã³ãŒã«è£œã±ãŒã·ã³
ã°ã補é ãããããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©
ã®æº¶èãæ··ç·Žåã³é«æž©æŒåºãã次ãã§ãã€ã¹éé
åã®å·åŽã¯äŸïŒã«èšèŒã®æ¡ä»¶äžã§è¡ãªã€ãã ç°ç¶ãã€ã¹ãééããéã«åœ¢æãããã±ãŒã·ã³
ã°ã¯å åŽã®åºæïŒäŸïŒã®ããã«ããã€ã¹ã®è»žãšå
å¿ã«ãªãããã«æ¡å ããã管ïŒã®äžã«ã§ã¯ãªãã
å¹³æ»ãªå£ããã€ïŒã€ã®åéåã«ãããããã®åŽã«
ãã±ãŒã·ã³ã°ãå²ãå¯åã·ãšãŒãäžã«æ¯æããã
該åéåã¯å¯åã«ã¿ãã©ã®äžéšåã³äžéšã®éèŠçŽ
ãæ§æããŠããã圢æãããã±ãŒã·ã³ã°ã®ç«¯éšã
å§æŸãããšããã®å¯åéåå ã§å éšã«ç©ºæ°ãå¹ã
蟌ãããšã«ãã€ãŠå¹èŸŒã¿æ圢ããããšãã§ããã 圢æãããã±ãŒã·ã³ã°ã¯100mmã®é·ããæãã
èŠçŽ ã«åæãããããã®èŠçŽ ãçäž60âã§60åé
ç©ããã«ä¹Ÿç¥ãããWIKOLIN瀟ããå ¥æããæ¥
çå€PENTACOLL ET691Aã®10ééïŒ åŒ·åºŠé ¢é ž
ãšãã«æº¶æ¶²ããããã®ã¹ãªãŒãã®å åŽã«åŽé§ãã
ã¹ãªãŒãå åŽãå°ã也ç¥ãããåŸãããã®æ¥çå€
ã§åŠçããèŠçŽ ããéé55ïœãããªãšã¹ãã«ã®å
åïŒmmãçŽåŸ24.8mmã®éæ¶è³ªããªãšãã¬ã³ãã¬ã
ã¿ã¬ãŒã補ããªããªãŒã ã®ççŽãªéšåã®å€åŽã«é©
çšããããããã®ããªããªãŒã ã¯ããŒãã»ããŒã©
ã³ç€Ÿã®RHODESTER85TXã䜿çšããŠå°åºæ圢ã«
ãã調補ãããããã¯åºéšãšåºéšã®éã«åºããã
ãªããªãŒã ã®å»¶äŒžå¯èœãªççŽãªéšåã®å šäœïŒ100
mmïŒãäžèšã®ããã«è¢«èŠãããä»çããæ¥çå€ã®
éã¯ã溶åªé€å»åŸã®æž¬å®ã§ããã®ããã«é©çšãã
ã±ãŒã·ã³ã°ã®m2åœãïŒãªããïŒïœã§ããã ãã®ããã«è¢«èŠããããªããªãŒã ã¯ç°å¢æž©åºŠ
ïŒ20âïŒã§24æé貯èµããŠãããå ç±ç©ºæ°çäžã§
äºåå ç±ããåŸã95âã§äºè»žå»¶äŒžïŒçžŠå»¶äŒžæ¯çïŒ
2.5ã暪延䌞æ¯çïŒïŒïŒããã ãã®ããã«ããŠåœ¢æãããäºè»žå»¶äŒžãã³ã«ã¯å
æã®å²ãããåã¯ãã®ãããªæ¹æ³ã§é©çšãäºè»žå»¶
䌞ãããããªããã«ã¢ã«ã³ãŒã«å±€ã®ä»çåã®æ¬ åŠ
ããçãããããªå€èŠ³äžã®æ¬ é¥ã芳å¯ãããªãã€
ãã ãã®ããã«ããŠè£œé ããè€åäœã®ããªã€æ§è³ªã
è©Šéšããããã«ãã³ã®å£ããåæ¿ãåãåºããã
ã®é žçŽ ééçãã¬ã¹ã¯ãããã°ã©ãã€ãŒã§èª¿ã¹
ãã䜿çšãããµã³ãã«ã®åãã¯ããªããã«ã¢ã«ã³
ãŒã«ã®20ÎŒãå«ããŠ320ÎŒã§ãã€ãã30âçžå¯Ÿæ¹¿
床60ïŒ ã®å¹³è¡¡æ¡ä»¶äžã§è¡ãªããã枬å®ã«ããå£ã®
é žçŽ ééçã¯ãããªããã«ã¢ã«ã³ãŒã«ãå¡åžããª
ãã³ã³ãããŒã«ã®ããªãšã¹ãã«ã®ééçã«æ¯èŒã
ãŠïŒå¯ŸïŒã«æžå°ããããšã瀺ãããã çžå¯Ÿæ¹¿åºŠ60ïŒ ã§åŸããããããã®åªããæåç¹
æ§ããåã³æ¬çºæã«ãã被èŠã®èæ°Žæ§ãéåžžã«è¯
奜ã§ããããšã確èªãããã
第ïŒå³ã¯ããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©ã®å¹³
è¡¡èç¹ãšæ°Žãšã®ééåçã®é¢ä¿ã瀺ã代衚çã°ã©
ãã§ããã瞊軞ã¯å¹³è¡¡èç¹ïŒâïŒåã³æšªè»žã¯æ°Žã®
ééåçïŒïŒ°H2OïŒãè¡šããã
è¡¡èç¹ãšæ°Žãšã®ééåçã®é¢ä¿ã瀺ã代衚çã°ã©
ãã§ããã瞊軞ã¯å¹³è¡¡èç¹ïŒâïŒåã³æšªè»žã¯æ°Žã®
ééåçïŒïŒ°H2OïŒãè¡šããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãŸãããªããã«ã¢ã«ã³ãŒã«ç³»ããªã€ææã§è¢«
èŠããã管ç¶ãã©ã³ã¯ãããªãœã³åã¯ããªããªãŒ
ã ã補é ãã次ãã§ããã®ç®¡ç¶ãã©ã³ã¯ãããªãœ
ã³åã¯ããªããªãŒã ãæ £çšã®äºè»žå»¶äŒžæž©åºŠæ¡ä»¶ã§
äºè»žå»¶äŒžå¹èŸŒæ圢ããããšããæãã¬ã¹äžééæ§
ã®èæ°Žæ§è¢«èŠãåããç±å¯å¡æ§æš¹è補äºè»žå»¶äŒžäž
空äœã®è£œé æ¹æ³ã«ãããŠãäžèšç®¡ç¶ãã©ã³ã¯ãã
ãªãœã³åã¯ããªããªãŒã ã®è£œé ãã以äžã®äžé£ã®
å·¥çšã (a) 20æªæºã®ãšã¹ãã«äŸ¡ãæããçŽããªããã«ã¢
ã«ã³ãŒã«ãšæ°Žãšããæãå«æ°Žéã25ã35ééïŒ
ã§ãããã¬ãŒã¯ãæŒåºãæ©ã«å°å ¥ããå·¥çšã (b) åèšãã¬ãŒã¯ãæŒåºãæ©ã«ãããŠè©²ãã¬ãŒã¯
ãæ§æããããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©ã®
平衡èç¹ããã100â以äžé«ã枩床ã§æ··ç·Žè解
ããå·¥çšã (c) å·åŽã«ããããã€ã¹å ã®æº¶èæŒåºç©ã®æž©åºŠ
ããåœè©²ããªããã«ã¢ã«ã³ãŒã«âæ°Žæ··åç©ã®å¹³
è¡¡èç¹ä»¥äžã®å€ã§ããããããæŒåºãæ©å€ã§æ°
泡圢æã«ããææã®è¢«èŠã®èšåŒµãèµ·ããã®ã«å
åãªæ°Žã®èžæ°å§ãçãã枩床ããã¯äœãå€ã«ãª
ãããå¶åŸ¡ããªãããç±å¯å¡æ§æš¹è補ã®ç®¡ãã
ãªãœã³åã¯ããªããªãŒã ãå¡åžããã®ã«é©ãã
被èŠãã€ã¹ãéããŠæº¶èææãæŒåºãããã®å Ž
åã«ãåèšã®æº¶èæŒåºç©ã®å·åŽãã溶èæŒåºç©
ããã€ã¹ãééããåã«ãæŒåºãæ©ã®ã·ãŒã¹ç«¯
éšãšè¢«èŠãã€ã¹ãšã®éã«æ¿å ¥ãããå·åŽãã¢ãž
ãã€ã¶ã䜿çšããŠå®æœããå·¥çšãåã³ (d) ãã®ããã«ããŠè¢«èŠããã管ãããªãœã³åã¯
ããªããªãŒã ãå·»åãã管ã®å Žåã«ã¯ããã«æ
æã®é·ãã«åæããããšã«ãã€ãŠç®¡ç¶ãã©ã³
ã¯ãããªãœã³ãåã¯ããªããªãŒã ã®åé§äœã®ç®¡
åçã«è»¢æããå·¥çšã ãå«ãããšãç¹åŸŽãšããæ¹æ³ã ïŒ äœ¿çšããããªããã«ã¢ã«ã³ãŒã«ã¯ãã·ã³ãžãª
ã¿ã¯ã床ã50ééïŒ è¶ ãç°åå«æéã1.5ééïŒ
æªæºåã³ïŒïŒïŒâã°ãªã³ãŒã«é£éæ¯çãåéäœå
äœ100åœã1.5é£éæªæºã§ããããšãç¹åŸŽãšããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®æ¹æ³ã ïŒ è¢«èŠãã€ã¹äžã®æº¶èæŒåºç©ã®æž©åºŠã105âã
ãäœãå€ã§ããããšãç¹åŸŽãšããç¹èš±è«æ±ã®ç¯å²
第ïŒé ã«èšèŒã®æ¹æ³ã ïŒ è¢«èŠãã€ã¹äžã®æº¶èæŒåºç©ã®æž©åºŠãåé¡ã®ã
ãªããã«ã¢ã«ã³ãŒã«ãšæ°Žã®æ··åç©ã®å¹³è¡¡èç¹ãš98
âã®éã®å€ã§ããããšãç¹åŸŽãšããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé ã«èšèŒã®æ¹æ³ã ïŒ å·¥çš(c)ã«ãããŠãé©åœãªè¢«èŠãã€ã¹ãéããŠ
溶èææãç±å¯å¡æ§æš¹è補ã®ç®¡äžã«æŒåºãããšã
ç¹åŸŽãšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®æ¹æ³ã ïŒ åºæãæ§æããç±å¯å¡æ§æš¹èãããªïŒã¢ã«ã
ã¬ã³ã°ãªã³ãŒã«ïŒãã¬ãã¿ã¬ãŒãã§ããããšãç¹
城ãšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®æ¹æ³ã
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8111119A FR2507125A1 (fr) | 1981-06-03 | 1981-06-03 | Procede de preparation de corps creux biorientes en matiere thermoplastique, comportant un revetement impermeable aux gaz et resistant a l'eau et les corps creux obtenus conformement a ce procede |
FR81/11119 | 1981-06-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5816825A JPS5816825A (ja) | 1983-01-31 |
JPS6210811B2 true JPS6210811B2 (ja) | 1987-03-09 |
Family
ID=9259207
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57091491A Granted JPS5816825A (ja) | 1981-06-03 | 1982-05-31 | ã¬ã¹äžééæ§ã®èæ°Žæ§è¢«èŠãåããç±å¯å¡æ§æš¹è補äºè»žå»¶äŒžäžç©ºäœã®è£œé æ¹æ³åã³åæ¹æ³ã«ããåŸãããäžç©ºäœ |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0069682B1 (ja) |
JP (1) | JPS5816825A (ja) |
AT (1) | ATE14091T1 (ja) |
CA (1) | CA1192363A (ja) |
DE (1) | DE3264550D1 (ja) |
ES (1) | ES8304486A1 (ja) |
FR (1) | FR2507125A1 (ja) |
GR (1) | GR76819B (ja) |
NO (1) | NO159779C (ja) |
PT (1) | PT74993B (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60245236A (ja) * | 1984-05-21 | 1985-12-05 | Hitachi Ltd | åå°äœè£œé è£ çœ® |
DE102015012937A1 (de) * | 2015-10-01 | 2017-04-06 | Kocher-Plastik Maschinenbau Gmbh | Vorrichtung zur Reduzierung der mikrobiologischen Kontaminaten von BehÀltererzeugnissen |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3600487A (en) * | 1969-09-08 | 1971-08-17 | Phillips Petroleum Co | Forming parisons with nucleated inner layer |
SE428542B (sv) * | 1976-02-18 | 1983-07-11 | Montedison Spa | Forfarande for framstellning av tva- eller flerskiktsprodukter tillverkade av termoplastmaterial |
-
1981
- 1981-06-03 FR FR8111119A patent/FR2507125A1/fr active Granted
-
1982
- 1982-05-28 EP EP82420068A patent/EP0069682B1/fr not_active Expired
- 1982-05-28 DE DE8282420068T patent/DE3264550D1/de not_active Expired
- 1982-05-28 AT AT82420068T patent/ATE14091T1/de not_active IP Right Cessation
- 1982-05-31 JP JP57091491A patent/JPS5816825A/ja active Granted
- 1982-06-01 GR GR68315A patent/GR76819B/el not_active IP Right Cessation
- 1982-06-01 NO NO821815A patent/NO159779C/no unknown
- 1982-06-02 ES ES512774A patent/ES8304486A1/es not_active Expired
- 1982-06-02 CA CA000404320A patent/CA1192363A/fr not_active Expired
- 1982-06-02 PT PT74993A patent/PT74993B/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
PT74993B (fr) | 1985-05-17 |
DE3264550D1 (en) | 1985-08-08 |
PT74993A (fr) | 1982-07-01 |
ES512774A0 (es) | 1983-03-01 |
NO159779C (no) | 1989-02-08 |
NO159779B (no) | 1988-10-31 |
GR76819B (ja) | 1984-09-04 |
ES8304486A1 (es) | 1983-03-01 |
EP0069682B1 (fr) | 1985-07-03 |
NO821815L (no) | 1982-12-06 |
FR2507125A1 (fr) | 1982-12-10 |
EP0069682A1 (fr) | 1983-01-12 |
JPS5816825A (ja) | 1983-01-31 |
CA1192363A (fr) | 1985-08-27 |
FR2507125B1 (ja) | 1984-01-13 |
ATE14091T1 (de) | 1985-07-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4731266A (en) | Water-resistant polyvinyl alcohol film and its application to the preparation of gas-impermeable composite articles | |
EP0079215B2 (en) | Process for preparation of coated oriented plastic container | |
US4254170A (en) | Process for rendering polyester hollow bodies gastight | |
US4267143A (en) | Process for the manufacturing of bioriented hollow bodies | |
US4534930A (en) | Process for producing stretched multilayer polyester bottle | |
JPS58208046A (ja) | é åããã被èŠãæãããã©ã¹ããã¯å®¹åšåã³ãã®è£œæ³ | |
US3260776A (en) | Production of biaxially stretch oriented polypropylene film | |
US5152946A (en) | Producing low shrink packaging film | |
FR2535248A1 (fr) | Film feuillete composite retractable a la chaleur et procede pour le preparer | |
CS210611B2 (en) | Manufacturing method of two-layer or multiple-layer objects made from thermoplastic materials | |
US3048895A (en) | Process for producing biaxially oriented plastic film | |
JPS60244519A (ja) | äžç©ºã³ããªã¢ããç©åããã³ãã®è£œé æ¹æ³ | |
JPS6210811B2 (ja) | ||
JPH08238667A (ja) | 容åšåã³å®¹åšã®è£œé æ¹æ³äžŠã³ã«ããªãã©ãŒã | |
FR2828129A1 (fr) | Procedes de fabrication de preformes et de contenants en pet tels que bouteilles alimentaires, contenants et preformes intermediaires obtenus | |
WO1999030150A1 (en) | Technique for free-blowing plastic preforms | |
US3541196A (en) | Method for forming silicone composition coated polyolefin articles | |
JPS5944970B2 (ja) | æãã¬ã©ã¹èª¿è¡šé¢ãæããäžç©ºå®¹åšã®è£œé æ¹æ³ | |
EP4342654A1 (en) | Crystal clear high barrier thermoformed plastic bottle | |
JPS59184627A (ja) | å€å±€å»¶äŒžããªãããã¬ã³ããã«ã®è£œæ³ | |
JPH0150574B2 (ja) | ||
JPH0214180B2 (ja) | ||
EP4395995A1 (en) | Barrier additive compositions for containers | |
JPS582052B2 (ja) | ãã³ ã ã»ã€ã±ã€ããŠã㊠| |
JPS5941232A (ja) | ãã©ã¹ããã¯å»¶äŒžãã€ãã®é£ç¶æ圢æ¹æ³ããã³è£ 眮 |