JPS6156360B2 - - Google Patents
Info
- Publication number
- JPS6156360B2 JPS6156360B2 JP7972576A JP7972576A JPS6156360B2 JP S6156360 B2 JPS6156360 B2 JP S6156360B2 JP 7972576 A JP7972576 A JP 7972576A JP 7972576 A JP7972576 A JP 7972576A JP S6156360 B2 JPS6156360 B2 JP S6156360B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- reaction
- added
- sizing agent
- urea
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004513 sizing Methods 0.000 claims description 24
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 12
- 239000004202 carbamide Substances 0.000 claims description 12
- 150000001336 alkenes Chemical class 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 37
- 239000011347 resin Substances 0.000 description 23
- 229920005989 resin Polymers 0.000 description 23
- 238000007127 saponification reaction Methods 0.000 description 15
- 239000007787 solid Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 10
- 239000002585 base Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 7
- 239000003518 caustics Substances 0.000 description 7
- 229910001873 dinitrogen Inorganic materials 0.000 description 7
- 229910052700 potassium Inorganic materials 0.000 description 7
- 239000011591 potassium Substances 0.000 description 7
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 6
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000003208 petroleum Substances 0.000 description 6
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 238000004945 emulsification Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000010009 beating Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000000691 measurement method Methods 0.000 description 4
- RQFVHGAXCJVPBZ-UHFFFAOYSA-N propylene pentamer Chemical compound CC=C.CC=C.CC=C.CC=C.CC=C RQFVHGAXCJVPBZ-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- OOKDYUQHMDBHMB-UHFFFAOYSA-N 3,6-dichloro-2-methoxybenzoic acid;2-(2,4-dichlorophenoxy)acetic acid;n-methylmethanamine Chemical compound CNC.CNC.COC1=C(Cl)C=CC(Cl)=C1C(O)=O.OC(=O)COC1=CC=C(Cl)C=C1Cl OOKDYUQHMDBHMB-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000012969 di-tertiary-butyl peroxide Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 ethylene, propylene, butylene, pentene Chemical class 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Paper (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compounds Of Unknown Constitution (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7972576A JPS535117A (en) | 1976-07-05 | 1976-07-05 | Process for manufacturing size agent for paper manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7972576A JPS535117A (en) | 1976-07-05 | 1976-07-05 | Process for manufacturing size agent for paper manufacture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS535117A JPS535117A (en) | 1978-01-18 |
| JPS6156360B2 true JPS6156360B2 (enrdf_load_stackoverflow) | 1986-12-02 |
Family
ID=13698166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7972576A Granted JPS535117A (en) | 1976-07-05 | 1976-07-05 | Process for manufacturing size agent for paper manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS535117A (enrdf_load_stackoverflow) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58214598A (ja) * | 1982-06-07 | 1983-12-13 | 三菱石油株式会社 | 製紙用サイズ剤 |
| JP2003020594A (ja) * | 2001-07-06 | 2003-01-24 | Arakawa Chem Ind Co Ltd | 製紙用サイズ剤組成物、その製造方法およびサイジング方法 |
-
1976
- 1976-07-05 JP JP7972576A patent/JPS535117A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS535117A (en) | 1978-01-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4347100A (en) | Strength of paper from mechanical or thermomechanical pulp | |
| US4842691A (en) | Sizing agents in neutral range and sizing methods using the same | |
| US4514544A (en) | Paper sizing agent comprised of reaction product of maleic anhydride and propylene oligomers | |
| US5266165A (en) | Paper sizing using copolymers of long-chain olefins and maleic anhydride in the form of the semiamides with morpholine | |
| US3211683A (en) | Sizing emulsions comprising a petroleum resin-maleic anhydride addition product and rosin | |
| JPS6156360B2 (enrdf_load_stackoverflow) | ||
| US3804788A (en) | Paper sizing agent | |
| DE2534603A1 (de) | Verfahren zur herstellung von copolymerisaten mit n-dialkyl-n-amido-gruppen | |
| US3379663A (en) | Petroleum resin and sizing composition prepared from an unsaturated dicarboxylic acid adduct thereof | |
| JP3382006B2 (ja) | サイズ剤用分散剤および水性エマルジョンサイズ剤の製造方法 | |
| US10781555B2 (en) | Method for producing a sizing agent composition, a sizing agent composition and use thereof | |
| EP0513802B1 (en) | Sizing agent for paper | |
| JPS6270479A (ja) | 撥水性組成物 | |
| US3211681A (en) | Sizing emulsions comprising a petroleum resin-maleic anhydride addition product and a fatty acid | |
| US3299034A (en) | Sizing agents and processes for preparation thereof | |
| US3400117A (en) | Process for the preparation of fumarated rosin size of low crystallizing and low foam-producing properties | |
| JP3491325B2 (ja) | ロジン系エマルション組成物、その製造方法、サイズ剤、サイジング方法及びサイズされた紙 | |
| JPS62250297A (ja) | 中性抄紙用サイズ剤及び中性抄紙サイジング方法 | |
| JPS59179898A (ja) | 紙サイズ剤 | |
| CA1224598A (en) | Paper sizing agent | |
| WO1992017645A1 (en) | Rosin emulsion size for papermaking and process for sizing paper | |
| JPH01162896A (ja) | 紙サイズ剤組成物 | |
| JPS6028599A (ja) | 製紙用添加剤及び製紙方法 | |
| KR100221053B1 (ko) | 제지용 양이온성 사이즈제 | |
| JPH07279092A (ja) | 製紙用中性サイズ剤 |