JPS6142942B2 - - Google Patents
Info
- Publication number
- JPS6142942B2 JPS6142942B2 JP4300482A JP4300482A JPS6142942B2 JP S6142942 B2 JPS6142942 B2 JP S6142942B2 JP 4300482 A JP4300482 A JP 4300482A JP 4300482 A JP4300482 A JP 4300482A JP S6142942 B2 JPS6142942 B2 JP S6142942B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- styrene
- polycarbonate
- acrylonitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 57
- 239000000203 mixture Substances 0.000 claims description 54
- 239000004417 polycarbonate Substances 0.000 claims description 40
- 229920000515 polycarbonate Polymers 0.000 claims description 40
- 229920000578 graft copolymer Polymers 0.000 claims description 32
- 229920001577 copolymer Polymers 0.000 claims description 24
- 238000000465 moulding Methods 0.000 claims description 20
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 19
- 239000002245 particle Substances 0.000 claims description 18
- 239000005062 Polybutadiene Substances 0.000 claims description 13
- 229920002857 polybutadiene Polymers 0.000 claims description 13
- 229920001971 elastomer Polymers 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 12
- 239000005060 rubber Substances 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 125000001118 alkylidene group Chemical group 0.000 claims description 3
- 125000002993 cycloalkylene group Chemical group 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims 1
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 27
- 239000000243 solution Substances 0.000 description 14
- 125000003118 aryl group Chemical group 0.000 description 11
- 238000010559 graft polymerization reaction Methods 0.000 description 9
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- 238000007720 emulsion polymerization reaction Methods 0.000 description 5
- 229920000126 latex Polymers 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 2
- 229920000638 styrene acrylonitrile Polymers 0.000 description 2
- BUZMJVBOGDBMGI-UHFFFAOYSA-N 1-phenylpropylbenzene Chemical compound C=1C=CC=CC=1C(CC)C1=CC=CC=C1 BUZMJVBOGDBMGI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 1
- UDKBLXVYLPCIAZ-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-3,6-di(propan-2-yl)phenyl]phenol Chemical compound C=1C=C(O)C=CC=1C=1C(C(C)C)=CC=C(C(C)C)C=1C1=CC=C(O)C=C1 UDKBLXVYLPCIAZ-UHFFFAOYSA-N 0.000 description 1
- RQTDWDATSAVLOR-UHFFFAOYSA-N 4-[3,5-bis(4-hydroxyphenyl)phenyl]phenol Chemical compound C1=CC(O)=CC=C1C1=CC(C=2C=CC(O)=CC=2)=CC(C=2C=CC(O)=CC=2)=C1 RQTDWDATSAVLOR-UHFFFAOYSA-N 0.000 description 1
- CIEGINNQDIULCT-UHFFFAOYSA-N 4-[4,6-bis(4-hydroxyphenyl)-4,6-dimethylheptan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)CC(C)(C=1C=CC(O)=CC=1)CC(C)(C)C1=CC=C(O)C=C1 CIEGINNQDIULCT-UHFFFAOYSA-N 0.000 description 1
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- -1 aromatic vinyl hydrocarbon Chemical class 0.000 description 1
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2259565.9 | 1972-12-06 | ||
| DE19722259565 DE2259565C3 (de) | 1972-12-06 | 1972-12-06 | Formmassen auf der Basis von Polycarbonat und einem Polybutadien-Pfropfmischpolymerisat |
| DE2353428.3 | 1973-10-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5837049A JPS5837049A (ja) | 1983-03-04 |
| JPS6142942B2 true JPS6142942B2 (pt) | 1986-09-25 |
Family
ID=5863609
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4300482A Granted JPS5837049A (ja) | 1972-12-06 | 1982-03-19 | 成形用組成物 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS5837049A (pt) |
| BE (1) | BE808227A (pt) |
| BR (1) | BR7309563D0 (pt) |
| DE (1) | DE2259565C3 (pt) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6431749U (pt) * | 1987-08-21 | 1989-02-27 | ||
| EP3599101A1 (en) | 2018-07-25 | 2020-01-29 | Miyakoshi Printing Machinery Co., Ltd. | Ink drying apparatus |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4172859A (en) * | 1975-05-23 | 1979-10-30 | E. I. Du Pont De Nemours And Company | Tough thermoplastic polyester compositions |
| DE2818679A1 (de) * | 1978-04-27 | 1979-10-31 | Bayer Ag | Thermoplastische formmassen |
| DE2853574A1 (de) * | 1978-12-12 | 1980-07-03 | Bayer Ag | Waermestandfeste thermoplastisch- elastomere polymermischung |
| DE2929229A1 (de) * | 1979-07-19 | 1981-02-12 | Bayer Ag | Stabilisierte thermoplastische formmassen |
| DE3537100A1 (de) * | 1985-10-18 | 1987-04-23 | Basf Ag | Formmasse auf basis von polycarbonat, san-copolymerisaten und einem pfropfmischpolymerisat |
| DE3712116A1 (de) * | 1987-04-10 | 1988-10-20 | Bayer Ag | Thermoplastische formmasse mit verbessertem spannungsrissverhalten |
| US4786686A (en) * | 1987-05-06 | 1988-11-22 | The Dow Chemical Company | Fire retardant impact modified carbonate polymer composition |
| DE3930137A1 (de) * | 1989-09-09 | 1991-03-21 | Bayer Ag | Stossdaempfer in form eines schockabsorbers |
| FR2661184A1 (fr) * | 1990-04-19 | 1991-10-25 | Borg Warner Chemical Europ Bv | Compositions de moulage a base de resine de polycarbonate aromatique, de polymerisat abs et de copolymere san ayant un aspect superficiel mat. |
| DE4014308C2 (de) * | 1990-05-04 | 1994-01-27 | Bayer Ag | Polycarbonat/ABS-Formmassen mit hoher Schlagzähigkeit |
| EP2657294A1 (de) | 2012-04-27 | 2013-10-30 | Bayer MaterialScience AG | Verarbeitungsstabile PC/ABS-Zusammensetzungen |
| EP2657298A1 (de) | 2012-04-27 | 2013-10-30 | Bayer MaterialScience AG | PC/ABS-Zusammensetzungen mit guter thermischer und chemischer Beständigkeit |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3130177A (en) * | 1961-03-24 | 1964-04-21 | Borg Warner | Blends of polycarbonates with polybutadiene, styrene, acrylonitrile graft copolymers |
| US3162695A (en) * | 1961-06-26 | 1964-12-22 | Borg Warner | Blends of polycarbonates with butadiene-styrene, methyl methacrylate, styrene graft copolymer |
| DE1247665B (de) * | 1963-02-07 | 1967-08-17 | Bayer Ag | Verfahren zur Herstellung elastisch-thermoplastischer Formmassen |
| DE1269360B (de) * | 1964-10-07 | 1968-05-30 | Bayer Ag | Verfahren zur Herstellung von thermoplastisch-elastischen Formmassen |
| JPS4829308B1 (pt) * | 1969-07-31 | 1973-09-08 |
-
1972
- 1972-12-06 DE DE19722259565 patent/DE2259565C3/de not_active Expired
-
1973
- 1973-12-05 BE BE138518A patent/BE808227A/xx not_active IP Right Cessation
- 1973-12-05 BR BR956373A patent/BR7309563D0/pt unknown
-
1982
- 1982-03-19 JP JP4300482A patent/JPS5837049A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6431749U (pt) * | 1987-08-21 | 1989-02-27 | ||
| EP3599101A1 (en) | 2018-07-25 | 2020-01-29 | Miyakoshi Printing Machinery Co., Ltd. | Ink drying apparatus |
Also Published As
| Publication number | Publication date |
|---|---|
| BE808227A (fr) | 1974-06-05 |
| DE2259565B2 (de) | 1978-01-05 |
| DE2259565C3 (de) | 1985-08-22 |
| DE2259565A1 (de) | 1974-07-04 |
| BR7309563D0 (pt) | 1974-09-05 |
| JPS5837049A (ja) | 1983-03-04 |
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