JPS61152754A - ポリプロピレンの改質方法 - Google Patents
ポリプロピレンの改質方法Info
- Publication number
- JPS61152754A JPS61152754A JP27507484A JP27507484A JPS61152754A JP S61152754 A JPS61152754 A JP S61152754A JP 27507484 A JP27507484 A JP 27507484A JP 27507484 A JP27507484 A JP 27507484A JP S61152754 A JPS61152754 A JP S61152754A
- Authority
- JP
- Japan
- Prior art keywords
- polypropylene
- organic peroxide
- weight
- heat
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 polypropylene Polymers 0.000 title claims abstract description 41
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 37
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 37
- 238000012986 modification Methods 0.000 title description 4
- 230000004048 modification Effects 0.000 title description 4
- 150000001451 organic peroxides Chemical class 0.000 claims abstract description 18
- 238000004132 cross linking Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 8
- 239000000155 melt Substances 0.000 abstract description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 6
- 238000000354 decomposition reaction Methods 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract description 3
- DZCCLNYLUGNUKQ-UHFFFAOYSA-N n-(4-nitrosophenyl)hydroxylamine Chemical compound ONC1=CC=C(N=O)C=C1 DZCCLNYLUGNUKQ-UHFFFAOYSA-N 0.000 abstract description 2
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 abstract 1
- 230000002411 adverse Effects 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 230000035939 shock Effects 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 description 8
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- BOOBDAVNHSOIDB-UHFFFAOYSA-N (2,3-dichlorobenzoyl) 2,3-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC=CC(C(=O)OOC(=O)C=2C(=C(Cl)C=CC=2)Cl)=C1Cl BOOBDAVNHSOIDB-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- UBRWPVTUQDJKCC-UHFFFAOYSA-N 1,3-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC(C(C)(C)OOC(C)(C)C)=C1 UBRWPVTUQDJKCC-UHFFFAOYSA-N 0.000 description 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical group O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- 150000003923 2,5-pyrrolediones Chemical class 0.000 description 1
- IYMZEPRSPLASMS-UHFFFAOYSA-N 3-phenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C=CC=CC=2)=C1 IYMZEPRSPLASMS-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 101100208721 Mus musculus Usp5 gene Proteins 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27507484A JPS61152754A (ja) | 1984-12-26 | 1984-12-26 | ポリプロピレンの改質方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27507484A JPS61152754A (ja) | 1984-12-26 | 1984-12-26 | ポリプロピレンの改質方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61152754A true JPS61152754A (ja) | 1986-07-11 |
JPH0559143B2 JPH0559143B2 (enrdf_load_stackoverflow) | 1993-08-30 |
Family
ID=17550465
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP27507484A Granted JPS61152754A (ja) | 1984-12-26 | 1984-12-26 | ポリプロピレンの改質方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61152754A (enrdf_load_stackoverflow) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6153710A (en) * | 1997-02-18 | 2000-11-28 | Chisso Corporation | Preactivated catalyst for olefin (CO)polymer, catalyst for olefin (CO)polymerization, olefin (CO)polymer composition, and process for producing the same |
US6231804B1 (en) | 1997-04-02 | 2001-05-15 | Chisso Corporation | Modified olefin (co)polymer composition, process for preparing the same, and modified olefin (co)polymer composition molding |
US6235845B1 (en) | 1997-08-07 | 2001-05-22 | Chisso Corporation | Olefin (co)polymer composition |
US6303696B1 (en) | 1997-04-11 | 2001-10-16 | Chisso Corporation | Propylene (co)polymer composition using metallocene catalyst |
US6313225B2 (en) | 1995-10-18 | 2001-11-06 | Chisso Corporation | Catalyst for olefin (co-)polymerization and method for producing the same |
JP2001524565A (ja) * | 1997-11-21 | 2001-12-04 | アクゾ ノーベル ナムローゼ フェンノートシャップ | ポリプロピレンの溶融強度を増強するための押出し方法 |
US6437048B1 (en) | 1995-12-01 | 2002-08-20 | Chisso Corporation | Molded resin articles |
US6444736B1 (en) | 1998-04-24 | 2002-09-03 | Chisso Corporation | Flame retardant polyolefin composition |
US6515037B2 (en) | 2000-02-29 | 2003-02-04 | Chisso Corporation | Polypropylene base resin composition for foam-molding, foamed article using the same composition, production process for the same foamed article and foam-molded product using the foamed-article |
US6710130B2 (en) | 2001-03-30 | 2004-03-23 | Chisso Corporation | Propylene polymer composition and its foam moldings |
US6780914B2 (en) | 1999-12-30 | 2004-08-24 | Samsung General Chemicals Co., Ltd. | Flame retardant polypropylene resin composition |
US7470727B2 (en) | 2001-05-30 | 2008-12-30 | Basell Poliolefine Italia S.P.A. | Polypropylene resin composition |
WO2010024286A1 (ja) | 2008-09-01 | 2010-03-04 | 三井化学株式会社 | アイオノマー樹脂およびこれを含んでなる樹脂組成物ならびにこれらの用途 |
WO2011046103A1 (ja) | 2009-10-13 | 2011-04-21 | 株式会社カネカ | ポリプロピレン系樹脂、ポリプロピレン系樹脂組成物、および射出発泡成形体 |
CN104448536A (zh) * | 2013-09-18 | 2015-03-25 | 中国石油天然气股份有限公司 | 一种高刚性tpv增韧聚丙烯组合物及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59223740A (ja) * | 1983-06-02 | 1984-12-15 | Mitsui Petrochem Ind Ltd | ポリプロピレン組成物の製造方法 |
-
1984
- 1984-12-26 JP JP27507484A patent/JPS61152754A/ja active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59223740A (ja) * | 1983-06-02 | 1984-12-15 | Mitsui Petrochem Ind Ltd | ポリプロピレン組成物の製造方法 |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6313225B2 (en) | 1995-10-18 | 2001-11-06 | Chisso Corporation | Catalyst for olefin (co-)polymerization and method for producing the same |
US6437048B1 (en) | 1995-12-01 | 2002-08-20 | Chisso Corporation | Molded resin articles |
US6153710A (en) * | 1997-02-18 | 2000-11-28 | Chisso Corporation | Preactivated catalyst for olefin (CO)polymer, catalyst for olefin (CO)polymerization, olefin (CO)polymer composition, and process for producing the same |
US6231804B1 (en) | 1997-04-02 | 2001-05-15 | Chisso Corporation | Modified olefin (co)polymer composition, process for preparing the same, and modified olefin (co)polymer composition molding |
US6303696B1 (en) | 1997-04-11 | 2001-10-16 | Chisso Corporation | Propylene (co)polymer composition using metallocene catalyst |
US6235845B1 (en) | 1997-08-07 | 2001-05-22 | Chisso Corporation | Olefin (co)polymer composition |
JP2001524565A (ja) * | 1997-11-21 | 2001-12-04 | アクゾ ノーベル ナムローゼ フェンノートシャップ | ポリプロピレンの溶融強度を増強するための押出し方法 |
US6444736B1 (en) | 1998-04-24 | 2002-09-03 | Chisso Corporation | Flame retardant polyolefin composition |
US6780914B2 (en) | 1999-12-30 | 2004-08-24 | Samsung General Chemicals Co., Ltd. | Flame retardant polypropylene resin composition |
US6515037B2 (en) | 2000-02-29 | 2003-02-04 | Chisso Corporation | Polypropylene base resin composition for foam-molding, foamed article using the same composition, production process for the same foamed article and foam-molded product using the foamed-article |
US6710130B2 (en) | 2001-03-30 | 2004-03-23 | Chisso Corporation | Propylene polymer composition and its foam moldings |
US7470727B2 (en) | 2001-05-30 | 2008-12-30 | Basell Poliolefine Italia S.P.A. | Polypropylene resin composition |
WO2010024286A1 (ja) | 2008-09-01 | 2010-03-04 | 三井化学株式会社 | アイオノマー樹脂およびこれを含んでなる樹脂組成物ならびにこれらの用途 |
WO2011046103A1 (ja) | 2009-10-13 | 2011-04-21 | 株式会社カネカ | ポリプロピレン系樹脂、ポリプロピレン系樹脂組成物、および射出発泡成形体 |
US8552116B2 (en) | 2009-10-13 | 2013-10-08 | Kaneka Corporation | Polypropylene resin, polypropylene resin composition, and foam-injection-molded article |
CN104448536A (zh) * | 2013-09-18 | 2015-03-25 | 中国石油天然气股份有限公司 | 一种高刚性tpv增韧聚丙烯组合物及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
JPH0559143B2 (enrdf_load_stackoverflow) | 1993-08-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
EXPY | Cancellation because of completion of term |