JPS61120804A - 発光性人造石成形品の製造方法 - Google Patents
発光性人造石成形品の製造方法Info
- Publication number
- JPS61120804A JPS61120804A JP24050984A JP24050984A JPS61120804A JP S61120804 A JPS61120804 A JP S61120804A JP 24050984 A JP24050984 A JP 24050984A JP 24050984 A JP24050984 A JP 24050984A JP S61120804 A JPS61120804 A JP S61120804A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- weight
- luminescent
- radical
- syrup
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002969 artificial stone Substances 0.000 title claims description 10
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000000465 moulding Methods 0.000 title description 3
- 239000011347 resin Substances 0.000 claims abstract description 38
- 229920005989 resin Polymers 0.000 claims abstract description 38
- 239000006188 syrup Substances 0.000 claims abstract description 26
- 235000020357 syrup Nutrition 0.000 claims abstract description 26
- 239000000049 pigment Substances 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 239000011256 inorganic filler Substances 0.000 claims abstract description 9
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003999 initiator Substances 0.000 claims abstract description 7
- 239000000454 talc Substances 0.000 claims abstract description 5
- 229910052623 talc Inorganic materials 0.000 claims abstract description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 4
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 4
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 150000004684 trihydrates Chemical class 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 12
- 238000010526 radical polymerization reaction Methods 0.000 claims description 6
- 239000004925 Acrylic resin Substances 0.000 claims description 5
- 229920000178 Acrylic resin Polymers 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 4
- 229920006337 unsaturated polyester resin Polymers 0.000 claims 1
- 239000000945 filler Substances 0.000 abstract description 15
- 239000000178 monomer Substances 0.000 abstract description 15
- 238000005266 casting Methods 0.000 abstract description 8
- 238000004020 luminiscence type Methods 0.000 abstract description 5
- 239000004342 Benzoyl peroxide Substances 0.000 abstract description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002928 artificial marble Substances 0.000 abstract description 3
- 238000013019 agitation Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 description 13
- 239000000047 product Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 230000005281 excited state Effects 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 238000010137 moulding (plastic) Methods 0.000 description 2
- 238000005215 recombination Methods 0.000 description 2
- 230000006798 recombination Effects 0.000 description 2
- 229920006305 unsaturated polyester Polymers 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 description 1
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- HNPDNOZNULJJDL-UHFFFAOYSA-N ethyl n-ethenylcarbamate Chemical compound CCOC(=O)NC=C HNPDNOZNULJJDL-UHFFFAOYSA-N 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003192 poly(bis maleimide) Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24050984A JPS61120804A (ja) | 1984-11-16 | 1984-11-16 | 発光性人造石成形品の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24050984A JPS61120804A (ja) | 1984-11-16 | 1984-11-16 | 発光性人造石成形品の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61120804A true JPS61120804A (ja) | 1986-06-07 |
| JPH0412724B2 JPH0412724B2 (enExample) | 1992-03-05 |
Family
ID=17060573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24050984A Granted JPS61120804A (ja) | 1984-11-16 | 1984-11-16 | 発光性人造石成形品の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61120804A (enExample) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04159316A (ja) * | 1990-10-23 | 1992-06-02 | Uuden De-Le:Kk | 造形用組成物 |
| EP0644241A1 (fr) * | 1993-09-21 | 1995-03-22 | Aluminium Pechiney | Hydrate d'alumine contenant un additif colorant, procédé de production et applications |
| JPH08217885A (ja) * | 1995-02-14 | 1996-08-27 | Toshio Yamamoto | 蓄光性樹脂材料の製法と、その製法によって得た蓄光性樹脂材料 |
| WO2003057796A1 (en) * | 2001-12-28 | 2003-07-17 | Availvs Corporation | Highly luminous light-emitting material and manufacturing method thereof |
| JPWO2003057796A1 (ja) * | 2002-12-27 | 2005-05-19 | 株式会社アベイラス | 高蓄光発光材とその製造方法 |
| JP2007291269A (ja) * | 2006-04-26 | 2007-11-08 | Agc Matex Co Ltd | 繊維強化樹脂成形品用樹脂組成物、樹脂含浸補強繊維材および繊維強化樹脂成形品 |
| JP2009507964A (ja) * | 2005-09-14 | 2009-02-26 | ポルヤコブ、ミハール | 高透光性の合成石、その製造方法および使用 |
| KR20210074935A (ko) * | 2019-12-12 | 2021-06-22 | (주)엘지하우시스 | 인조대리석 및 이의 제조방법 |
-
1984
- 1984-11-16 JP JP24050984A patent/JPS61120804A/ja active Granted
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04159316A (ja) * | 1990-10-23 | 1992-06-02 | Uuden De-Le:Kk | 造形用組成物 |
| EP0644241A1 (fr) * | 1993-09-21 | 1995-03-22 | Aluminium Pechiney | Hydrate d'alumine contenant un additif colorant, procédé de production et applications |
| FR2710345A1 (fr) * | 1993-09-21 | 1995-03-31 | Pechiney Aluminium | Hydrate d'alumine contenant un additif colorant, procédé de production et applications. |
| JPH08217885A (ja) * | 1995-02-14 | 1996-08-27 | Toshio Yamamoto | 蓄光性樹脂材料の製法と、その製法によって得た蓄光性樹脂材料 |
| WO2003057796A1 (en) * | 2001-12-28 | 2003-07-17 | Availvs Corporation | Highly luminous light-emitting material and manufacturing method thereof |
| AU2002359941B2 (en) * | 2001-12-28 | 2005-04-21 | Availvs Corporation | Highly luminous light-emitting material and manufacturing method thereof |
| US7074345B2 (en) | 2001-12-28 | 2006-07-11 | Availvs Corporation | Highly luminous light-emitting material and manufacturing method thereof |
| KR100900727B1 (ko) | 2001-12-28 | 2009-06-05 | 아바일브스 코포레이션 | 고축광 발광재와 그 제조방법 |
| JPWO2003057796A1 (ja) * | 2002-12-27 | 2005-05-19 | 株式会社アベイラス | 高蓄光発光材とその製造方法 |
| JP2009507964A (ja) * | 2005-09-14 | 2009-02-26 | ポルヤコブ、ミハール | 高透光性の合成石、その製造方法および使用 |
| JP2007291269A (ja) * | 2006-04-26 | 2007-11-08 | Agc Matex Co Ltd | 繊維強化樹脂成形品用樹脂組成物、樹脂含浸補強繊維材および繊維強化樹脂成形品 |
| KR20210074935A (ko) * | 2019-12-12 | 2021-06-22 | (주)엘지하우시스 | 인조대리석 및 이의 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0412724B2 (enExample) | 1992-03-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2188465C (en) | Acrylic sheet having uniform distribution of coloring and mineral filler before and after thermoforming | |
| EP2377896B1 (en) | Marble chips for an artificial marble, manufacturing method thereof, and artificial marble comprising same | |
| DE68908324T2 (de) | Granitähnlicher Kunststein. | |
| JPS61120804A (ja) | 発光性人造石成形品の製造方法 | |
| EP2051951B1 (en) | Marble chip, method for preparing the same and artificial marble using the same | |
| US4961995A (en) | Polishable, flame retarded, synthetic mineral product | |
| US8211536B2 (en) | Composite solid surface article comprising at least one of randomly shaped fibers and powder particles | |
| CA1336109C (en) | Polishable, flame retarded, synthetic mineral product and method | |
| KR100715606B1 (ko) | 고투명 인조대리석 마블칩, 그 제조방법 및 이를 이용한 인조대리석 | |
| JP2813527B2 (ja) | 強度の向上した大理石状物品及びその製法 | |
| JPH09110502A (ja) | テラゾ調人工大理石 | |
| JPH0741345A (ja) | 強度の向上した天然石状物品及びその製法 | |
| JPH0717424B2 (ja) | 人造石及びその製法 | |
| KR100231515B1 (ko) | 아크릴계 인광성 인조대리석 조성물 및 이를 포함하는 인조대리석의 제조방법 | |
| KR100688025B1 (ko) | 침강현상이 없는 인조대리석 마블칩의 제조방법 | |
| KR102706091B1 (ko) | 높은 광 투과도를 갖는 인조대리석 | |
| JP2570032B2 (ja) | 加飾成形品 | |
| US5032625A (en) | Polishable, flame retarded, synthetic mineral product and method | |
| JPH0354706B2 (enExample) | ||
| JP3075021B2 (ja) | 人工石 | |
| JP3108148B2 (ja) | 有色樹脂成形物 | |
| KR100609987B1 (ko) | 반투명 인조 대리석 조성물 | |
| JPS60199053A (ja) | 大理石調物品の製法 | |
| CN111362679A (zh) | 一种高分子树脂发光复合陶瓷及其制备方法 | |
| JPS5931134A (ja) | 合成樹脂の成形法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |