JPS605654B2 - イツトリウムの分離法 - Google Patents
イツトリウムの分離法Info
- Publication number
- JPS605654B2 JPS605654B2 JP51068332A JP6833276A JPS605654B2 JP S605654 B2 JPS605654 B2 JP S605654B2 JP 51068332 A JP51068332 A JP 51068332A JP 6833276 A JP6833276 A JP 6833276A JP S605654 B2 JPS605654 B2 JP S605654B2
- Authority
- JP
- Japan
- Prior art keywords
- extraction
- mol
- extracted
- aqueous solution
- solution containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000926 separation method Methods 0.000 title description 6
- 238000000034 method Methods 0.000 claims description 19
- 239000007864 aqueous solution Substances 0.000 claims description 17
- 230000002378 acidificating effect Effects 0.000 claims description 11
- 229910052727 yttrium Inorganic materials 0.000 claims description 11
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 10
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 10
- 150000002910 rare earth metals Chemical class 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 4
- 229960003330 pentetic acid Drugs 0.000 claims description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- 238000000605 extraction Methods 0.000 description 37
- 229910019142 PO4 Inorganic materials 0.000 description 11
- 235000021317 phosphate Nutrition 0.000 description 11
- 239000012074 organic phase Substances 0.000 description 10
- 239000010452 phosphate Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- -1 phosphate ester Chemical class 0.000 description 9
- LJKDOMVGKKPJBH-UHFFFAOYSA-N 2-ethylhexyl dihydrogen phosphate Chemical compound CCCCC(CC)COP(O)(O)=O LJKDOMVGKKPJBH-UHFFFAOYSA-N 0.000 description 8
- 239000003085 diluting agent Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000003350 kerosene Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 229910052691 Erbium Inorganic materials 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229910052692 Dysprosium Inorganic materials 0.000 description 3
- 229910052689 Holmium Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229910052769 Ytterbium Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- WRKCIHRWQZQBOL-UHFFFAOYSA-N octyl dihydrogen phosphate Chemical compound CCCCCCCCOP(O)(O)=O WRKCIHRWQZQBOL-UHFFFAOYSA-N 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical compound CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 239000002635 aromatic organic solvent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- SCIGVHCNNXTQDB-UHFFFAOYSA-N decyl dihydrogen phosphate Chemical compound CCCCCCCCCCOP(O)(O)=O SCIGVHCNNXTQDB-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- 239000012527 feed solution Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- FRNOGLGSGLTDKL-UHFFFAOYSA-N thulium atom Chemical compound [Tm] FRNOGLGSGLTDKL-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- ORZHVTYKPFFVMG-UHFFFAOYSA-N xylenol orange Chemical compound OC(=O)CN(CC(O)=O)CC1=C(O)C(C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C=C(CN(CC(O)=O)CC(O)=O)C(O)=C(C)C=2)=C1 ORZHVTYKPFFVMG-UHFFFAOYSA-N 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/10—Preparation or treatment, e.g. separation or purification
- C01F17/17—Preparation or treatment, e.g. separation or purification involving a liquid-liquid extraction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Catalysts (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51068332A JPS605654B2 (ja) | 1976-06-11 | 1976-06-11 | イツトリウムの分離法 |
| FR7717242A FR2354290A1 (fr) | 1976-06-11 | 1977-06-06 | Extraction selective des ions yttrium |
| US05/804,465 US4104358A (en) | 1976-06-11 | 1977-06-07 | Selective extraction of yttrium ions |
| NO772020A NO151552C (no) | 1976-06-11 | 1977-06-09 | Fremgangsmaate til selektiv ekstraksjon av yttrium-ioner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51068332A JPS605654B2 (ja) | 1976-06-11 | 1976-06-11 | イツトリウムの分離法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS52150717A JPS52150717A (en) | 1977-12-14 |
| JPS605654B2 true JPS605654B2 (ja) | 1985-02-13 |
Family
ID=13370765
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51068332A Expired JPS605654B2 (ja) | 1976-06-11 | 1976-06-11 | イツトリウムの分離法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4104358A (enExample) |
| JP (1) | JPS605654B2 (enExample) |
| FR (1) | FR2354290A1 (enExample) |
| NO (1) | NO151552C (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2843574A1 (de) * | 1977-10-11 | 1979-04-19 | Mitsubishi Chem Ind | Verfahren zur abtrennung von yttriumionen |
| US4477260A (en) * | 1982-05-05 | 1984-10-16 | Alfred University Research Foundation, Inc. | Process for preparing a carbonaceous slurry |
| FR2794032B1 (fr) | 1999-05-27 | 2002-06-14 | Univ Claude Bernard Lyon | Procede pour separer en milieu aqueux des lanthanides et/ou des actinides par complexation-nanofiltration, et nouveaux complexants mis en oeuvre dans ce procede |
| RU2320738C1 (ru) * | 2006-06-19 | 2008-03-27 | Государственное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный горный институт имени Г.В. Плеханова (технический университет)" | Способ разделения иттрия и церия |
| RU2373299C1 (ru) * | 2008-06-26 | 2009-11-20 | Государственное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный горный институт имени Г.В. Плеханова (технический университет)" | Способ извлечения и разделения ионов церия и иттрия |
| RU2456359C1 (ru) * | 2011-03-03 | 2012-07-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный горный университет" | Способ извлечения церия из растворов солей |
| RU2463369C1 (ru) * | 2011-04-08 | 2012-10-10 | Государственное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный горный институт имени Г.В. Плеханова (технический университет)" | СПОСОБ ИЗВЛЕЧЕНИЯ КАТИОНОВ ЛАНТАНА La+3 ИЗ ВОДНЫХ РАСТВОРОВ |
| RU2463370C1 (ru) * | 2011-04-22 | 2012-10-10 | Государственное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный горный институт имени Г.В. Плеханова (технический университет)" | Способ извлечения катионов гольмия (iii) из нитратных растворов |
| RU2478724C1 (ru) * | 2011-11-10 | 2013-04-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный горный университет" | Способ извлечения иттрия (iii) из растворов солей |
| RU2482201C1 (ru) * | 2011-11-10 | 2013-05-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный горный университет" | Способ извлечения европия (iii) из растворов солей |
| RU2548353C1 (ru) * | 2013-12-17 | 2015-04-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Национальный минерально-сырьевой университет "Горный" | СПОСОБ ИЗВЛЕЧЕНИЯ КАТИОНОВ Еu3+ ИЗ ВОДНО-СОЛЕВЫХ РАСТВОРОВ |
| RU2567634C1 (ru) * | 2014-07-17 | 2015-11-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Национальный минерально-сырьевой университет "Горный" | Способ извлечения тербия (iii) из водно-солевых растворов |
| RU2602112C1 (ru) * | 2015-08-03 | 2016-11-10 | федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский горный университет" | Способ извлечения лантана(iii) из растворов солей |
| RU2616748C1 (ru) * | 2015-11-10 | 2017-04-18 | федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский горный университет" | Способ извлечения солей гольмия (iii) из водных растворов |
| RU2690129C1 (ru) * | 2018-10-15 | 2019-05-30 | федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский горный университет" | СПОСОБ ИЗВЛЕЧЕНИЯ КАТИОНОВ Gd (3+) ДОДЕЦИЛСУЛЬФАТОМ НАТРИЯ |
| CN112575188B (zh) * | 2020-11-24 | 2022-08-19 | 福建省长汀金龙稀土有限公司 | 一种二烷基氨基苯氧乙酸萃取剂及其制备方法和应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3192012A (en) * | 1962-08-09 | 1965-06-29 | Andrew C Rice | Process for separating the rare earth elements by means of solvent extraction |
| US3230036A (en) * | 1963-09-18 | 1966-01-18 | Frederick A Kappelmann | Method for separating americium and curium from the lanthanide rare earths and yttrium |
| US3323857A (en) * | 1965-12-16 | 1967-06-06 | Donald J Bauer | Selective extraction and separation of lanthanides with a quaternary ammonium compound |
| FR1534888A (fr) * | 1967-06-21 | 1968-08-02 | Commissariat Energie Atomique | Procédé de séparation des éléments des groupes actinides et lanthanides |
| AT273047B (de) * | 1967-11-08 | 1969-07-25 | Goldschmidt Ag Th | Verfahren zur Trennung der Elemente Yttrium und Lanthan bis Lutetium durch Verteilen ihrer Thiocyanate |
| US3463619A (en) * | 1968-07-12 | 1969-08-26 | Atomic Energy Commission | Solvent extraction process for purifying americium and curium |
| JPS4818691B1 (enExample) * | 1968-08-27 | 1973-06-07 | ||
| US3578391A (en) * | 1969-09-16 | 1971-05-11 | Sylvania Electric Prod | Yttrium purification |
| US3640678A (en) * | 1970-06-01 | 1972-02-08 | Molybdenum Corp | Yttrium purification process |
| NO127964B (enExample) * | 1971-07-20 | 1973-09-10 | Sjeldne Jordarter Forskning |
-
1976
- 1976-06-11 JP JP51068332A patent/JPS605654B2/ja not_active Expired
-
1977
- 1977-06-06 FR FR7717242A patent/FR2354290A1/fr active Granted
- 1977-06-07 US US05/804,465 patent/US4104358A/en not_active Expired - Lifetime
- 1977-06-09 NO NO772020A patent/NO151552C/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2354290A1 (fr) | 1978-01-06 |
| NO772020L (no) | 1977-12-13 |
| US4104358A (en) | 1978-08-01 |
| JPS52150717A (en) | 1977-12-14 |
| FR2354290B1 (enExample) | 1981-06-12 |
| NO151552C (no) | 1985-05-02 |
| NO151552B (no) | 1985-01-14 |
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