JPS6050192A - 銅電解液の浄液法 - Google Patents
銅電解液の浄液法Info
- Publication number
- JPS6050192A JPS6050192A JP58156972A JP15697283A JPS6050192A JP S6050192 A JPS6050192 A JP S6050192A JP 58156972 A JP58156972 A JP 58156972A JP 15697283 A JP15697283 A JP 15697283A JP S6050192 A JPS6050192 A JP S6050192A
- Authority
- JP
- Japan
- Prior art keywords
- ions
- hydrochloric acid
- copper electrolyte
- group
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 29
- 239000010949 copper Substances 0.000 title claims abstract description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000003792 electrolyte Substances 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims description 32
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 104
- 150000002500 ions Chemical class 0.000 claims abstract description 27
- 229910052742 iron Inorganic materials 0.000 claims abstract description 24
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 22
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 4
- 239000011347 resin Substances 0.000 claims description 37
- 229920005989 resin Polymers 0.000 claims description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 36
- 239000013522 chelant Substances 0.000 claims description 22
- 239000007864 aqueous solution Substances 0.000 claims description 16
- 229910021645 metal ion Inorganic materials 0.000 claims description 15
- -1 arsenic ions Chemical class 0.000 claims description 12
- 238000010828 elution Methods 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 229910001451 bismuth ion Inorganic materials 0.000 claims description 7
- 238000000746 purification Methods 0.000 claims description 7
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 6
- 229910001439 antimony ion Inorganic materials 0.000 claims description 6
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 5
- 229910001431 copper ion Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 229910001453 nickel ion Inorganic materials 0.000 claims description 3
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 125000006295 amino methylene group Chemical group [H]N(*)C([H])([H])* 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 abstract description 22
- 229910052759 nickel Inorganic materials 0.000 abstract description 2
- 229920001429 chelating resin Polymers 0.000 abstract 4
- 150000001455 metallic ions Chemical class 0.000 abstract 4
- KDTXFXOVUDTJPI-UHFFFAOYSA-N aminomethanedisulfonic acid Chemical group OS(=O)(=O)C(N)S(O)(=O)=O KDTXFXOVUDTJPI-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000003480 eluent Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 13
- 238000004821 distillation Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 238000001577 simple distillation Methods 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 125000003282 alkyl amino group Chemical group 0.000 description 2
- HAYXDMNJJFVXCI-UHFFFAOYSA-N arsenic(5+) Chemical compound [As+5] HAYXDMNJJFVXCI-UHFFFAOYSA-N 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000005363 electrowinning Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical compound [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58156972A JPS6050192A (ja) | 1983-08-27 | 1983-08-27 | 銅電解液の浄液法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58156972A JPS6050192A (ja) | 1983-08-27 | 1983-08-27 | 銅電解液の浄液法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6050192A true JPS6050192A (ja) | 1985-03-19 |
| JPS648715B2 JPS648715B2 (enrdf_load_stackoverflow) | 1989-02-15 |
Family
ID=15639348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58156972A Granted JPS6050192A (ja) | 1983-08-27 | 1983-08-27 | 銅電解液の浄液法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6050192A (enrdf_load_stackoverflow) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61227190A (ja) * | 1985-03-29 | 1986-10-09 | Miyoshi Oil & Fat Co Ltd | 銅電解液中の不純金属イオンの除去方法 |
| CN103526230A (zh) * | 2013-10-08 | 2014-01-22 | 铜陵有色金属集团股份有限公司金昌冶炼厂 | 一种铜电解液净化过程高效生产高品质阴极铜的方法 |
| CN105714117A (zh) * | 2016-02-19 | 2016-06-29 | 金川集团股份有限公司 | 一种以含砷铜电解液制备砷酸铜的方法 |
| CN108517538A (zh) * | 2018-04-08 | 2018-09-11 | 长沙华时捷环保科技发展股份有限公司 | 铜电解废液综合回收处理的方法 |
-
1983
- 1983-08-27 JP JP58156972A patent/JPS6050192A/ja active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61227190A (ja) * | 1985-03-29 | 1986-10-09 | Miyoshi Oil & Fat Co Ltd | 銅電解液中の不純金属イオンの除去方法 |
| CN103526230A (zh) * | 2013-10-08 | 2014-01-22 | 铜陵有色金属集团股份有限公司金昌冶炼厂 | 一种铜电解液净化过程高效生产高品质阴极铜的方法 |
| CN105714117A (zh) * | 2016-02-19 | 2016-06-29 | 金川集团股份有限公司 | 一种以含砷铜电解液制备砷酸铜的方法 |
| CN108517538A (zh) * | 2018-04-08 | 2018-09-11 | 长沙华时捷环保科技发展股份有限公司 | 铜电解废液综合回收处理的方法 |
| CN108517538B (zh) * | 2018-04-08 | 2019-11-29 | 长沙华时捷环保科技发展股份有限公司 | 铜电解废液综合回收处理的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS648715B2 (enrdf_load_stackoverflow) | 1989-02-15 |
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