JPS60149536A - 第２級ブタノ−ルの製造方法 - Google Patents
第２級ブタノ−ルの製造方法Info
- Publication number
- JPS60149536A JPS60149536A JP59003636A JP363684A JPS60149536A JP S60149536 A JPS60149536 A JP S60149536A JP 59003636 A JP59003636 A JP 59003636A JP 363684 A JP363684 A JP 363684A JP S60149536 A JPS60149536 A JP S60149536A
- Authority
- JP
- Japan
- Prior art keywords
- butene
- secondary butanol
- reaction
- heteropolyacid
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000006243 chemical reaction Methods 0.000 claims abstract description 30
- 238000006703 hydration reaction Methods 0.000 claims abstract description 16
- 239000011964 heteropoly acid Substances 0.000 claims abstract description 15
- 239000007864 aqueous solution Substances 0.000 claims abstract description 13
- 239000012071 phase Substances 0.000 claims abstract description 12
- 230000036571 hydration Effects 0.000 claims abstract description 10
- 239000008346 aqueous phase Substances 0.000 claims abstract description 4
- 239000011541 reaction mixture Substances 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 14
- 239000000110 cooling liquid Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 5
- 239000002253 acid Substances 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 239000007791 liquid phase Substances 0.000 description 5
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- CGFYHILWFSGVJS-UHFFFAOYSA-N silicic acid;trioxotungsten Chemical compound O[Si](O)(O)O.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 CGFYHILWFSGVJS-UHFFFAOYSA-N 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 description 1
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59003636A JPS60149536A (ja) | 1984-01-13 | 1984-01-13 | 第２級ブタノ−ルの製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59003636A JPS60149536A (ja) | 1984-01-13 | 1984-01-13 | 第２級ブタノ−ルの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60149536A true JPS60149536A (ja) | 1985-08-07 |
| JPH0224257B2 JPH0224257B2 (en, 2012) | 1990-05-29 |
Family
ID=11562965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59003636A Granted JPS60149536A (ja) | 1984-01-13 | 1984-01-13 | 第２級ブタノ−ルの製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60149536A (en, 2012) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0717022A2 (en) | 1994-12-15 | 1996-06-19 | Mitsui Toatsu Chemicals, Incorporated | Process for producing isopropyl alcohol by hydrating propylene |
| JP2002220384A (ja) * | 2001-01-24 | 2002-08-09 | Asahi Kasei Corp | トリオキサンの合成方法 |
| WO2007099804A1 (ja) * | 2006-03-02 | 2007-09-07 | Idemitsu Kosan Co., Ltd. | 第２級ブタノールの精製方法及び製造方法 |
| CN106622386A (zh) * | 2017-01-11 | 2017-05-10 | 王艺霖 | 一种生产仲丁醇的高效催化剂的制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4936203A (en, 2012) * | 1972-07-08 | 1974-04-04 |
-
1984
- 1984-01-13 JP JP59003636A patent/JPS60149536A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4936203A (en, 2012) * | 1972-07-08 | 1974-04-04 |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0717022A2 (en) | 1994-12-15 | 1996-06-19 | Mitsui Toatsu Chemicals, Incorporated | Process for producing isopropyl alcohol by hydrating propylene |
| US5714646A (en) * | 1994-12-15 | 1998-02-03 | Mitsui Toatsu Chemicals, Inc. | Process for producing isopropyl alcohol |
| JP2002220384A (ja) * | 2001-01-24 | 2002-08-09 | Asahi Kasei Corp | トリオキサンの合成方法 |
| WO2007099804A1 (ja) * | 2006-03-02 | 2007-09-07 | Idemitsu Kosan Co., Ltd. | 第２級ブタノールの精製方法及び製造方法 |
| CN106622386A (zh) * | 2017-01-11 | 2017-05-10 | 王艺霖 | 一种生产仲丁醇的高效催化剂的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0224257B2 (en, 2012) | 1990-05-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |