JPS5951937B2 - スルホン化方法 - Google Patents
スルホン化方法Info
- Publication number
- JPS5951937B2 JPS5951937B2 JP52062058A JP6205877A JPS5951937B2 JP S5951937 B2 JPS5951937 B2 JP S5951937B2 JP 52062058 A JP52062058 A JP 52062058A JP 6205877 A JP6205877 A JP 6205877A JP S5951937 B2 JPS5951937 B2 JP S5951937B2
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- sulfonating agent
- organic reactant
- conduit
- reaction mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 30
- 238000006277 sulfonation reaction Methods 0.000 title description 21
- 241000234435 Lilium Species 0.000 claims description 102
- 239000000376 reactant Substances 0.000 claims description 86
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 72
- 239000007788 liquid Substances 0.000 claims description 55
- 239000007795 chemical reaction product Substances 0.000 claims description 53
- 238000001816 cooling Methods 0.000 claims description 47
- 239000011541 reaction mixture Substances 0.000 claims description 41
- 238000006243 chemical reaction Methods 0.000 claims description 39
- 239000003795 chemical substances by application Substances 0.000 claims description 36
- 239000002245 particle Substances 0.000 claims description 25
- 239000000110 cooling liquid Substances 0.000 claims description 14
- 239000000047 product Substances 0.000 claims description 11
- 238000010791 quenching Methods 0.000 claims description 9
- 230000000171 quenching effect Effects 0.000 claims description 9
- 150000004996 alkyl benzenes Chemical group 0.000 claims description 6
- 239000002826 coolant Substances 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 5
- 230000002776 aggregation Effects 0.000 claims description 4
- 238000005054 agglomeration Methods 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 238000004220 aggregation Methods 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 230000001112 coagulating effect Effects 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 description 37
- 238000002347 injection Methods 0.000 description 9
- 239000007924 injection Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 5
- 238000000889 atomisation Methods 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 238000003763 carbonization Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000003134 recirculating effect Effects 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- -1 alkylbenzene sulfonate Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000029087 digestion Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000003701 inert diluent Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 229910052815 sulfur oxide Inorganic materials 0.000 description 2
- 241000282693 Cercopithecidae Species 0.000 description 1
- 241001591518 Norape Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000006053 organic reaction Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003459 sulfonic acid esters Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/14—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by sulfoxidation, i.e. by reaction with sulfur dioxide and oxygen with formation of sulfo or halosulfonyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
- B01J10/002—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor carried out in foam, aerosol or bubbles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B45/00—Formation or introduction of functional groups containing sulfur
- C07B45/02—Formation or introduction of functional groups containing sulfur of sulfo or sulfonyldioxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00065—Pressure measurement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S261/00—Gas and liquid contact apparatus
- Y10S261/54—Venturi scrubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S261/00—Gas and liquid contact apparatus
- Y10S261/56—Variable venturi
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69065276A | 1976-05-27 | 1976-05-27 | |
| US000000690652 | 1976-05-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS52144626A JPS52144626A (en) | 1977-12-02 |
| JPS5951937B2 true JPS5951937B2 (ja) | 1984-12-17 |
Family
ID=24773357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52062058A Expired JPS5951937B2 (ja) | 1976-05-27 | 1977-05-27 | スルホン化方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4113438A (en, 2012) |
| JP (1) | JPS5951937B2 (en, 2012) |
| BR (1) | BR7703415A (en, 2012) |
| CA (1) | CA1089486A (en, 2012) |
| DE (1) | DE2723333A1 (en, 2012) |
| FR (1) | FR2352767A1 (en, 2012) |
| GB (2) | GB1584002A (en, 2012) |
| IN (1) | IN146339B (en, 2012) |
| IT (1) | IT1109117B (en, 2012) |
| SU (2) | SU898955A3 (en, 2012) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3009594A1 (de) * | 1979-03-14 | 1980-09-25 | Plasmine Corp | Verfahren zur herstellung von leimungsmitteln fuer zelluloseprodukte |
| US4606791A (en) * | 1979-03-14 | 1986-08-19 | Reichhold Chemicals, Inc. | Sizing agents for cellulosic products |
| US4483744A (en) * | 1979-03-14 | 1984-11-20 | The Plasmine Corporation | Sizing agents for cellulosic products |
| US4322367A (en) * | 1979-11-26 | 1982-03-30 | Colgate-Palmolive Company | Deoiling of aqueous solutions of sodium lauryl sulfate |
| DE3330445A1 (de) * | 1983-08-24 | 1985-03-21 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von als feststoffe anfallenden chemischen verbindungen aus fluessigen ausgangsstoffen |
| DE3402622C2 (de) * | 1984-01-26 | 1986-10-30 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Diphenyl-4,4'-disulfonsäure |
| US4554078A (en) * | 1984-05-21 | 1985-11-19 | At&T Technologies, Inc. | Methods of and apparatus for effluent disposal |
| GB2189237B (en) * | 1986-03-20 | 1990-06-13 | Wessex Water Authority | Anaerobic digester |
| HU205724B (en) * | 1986-11-28 | 1992-06-29 | Istvan Kenyeres | Method for incereasing the performance and dissolving degree of impact jet gas-imput |
| US4812292A (en) * | 1987-10-26 | 1989-03-14 | Joslyn Valve Corporation | Chemical sterilant recovery and conversion |
| WO1993017992A1 (en) * | 1990-08-23 | 1993-09-16 | The Chemithon Corporation | Sulfonation process for viscous sulfonic acid |
| US5136088A (en) * | 1990-08-23 | 1992-08-04 | The Chemithon Corporation | Sulfonation process for viscous sulfonic acid |
| US5211916A (en) * | 1991-12-24 | 1993-05-18 | Praxair Technology, Inc. | Stripping system |
| US5942020A (en) * | 1996-01-11 | 1999-08-24 | Tensor Machinery Limited | Apparatus for evacuating air from curing area of UV lamps for fiber-like substrates |
| CN101423482B (zh) * | 2008-11-27 | 2012-07-25 | 中国日用化学工业研究院 | 一种磺化中和反应一体化的方法 |
| CN111362780B (zh) * | 2020-04-21 | 2022-12-27 | 哈密盛典科技有限公司 | 一种利用三氧化硫生产间苯二酚的方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2897062A (en) * | 1954-02-05 | 1959-07-28 | Phillips Petroleum Co | Gas reactor |
| NL278901A (en, 2012) * | 1961-05-26 | |||
| GB1041592A (en) * | 1962-02-21 | 1966-09-07 | Daikin Ind Ltd | Apparatus for the pyrolysis of chlorodifluoromethane |
| NL136581C (en, 2012) * | 1962-12-12 | 1900-01-01 | ||
| US3535339A (en) * | 1965-12-17 | 1970-10-20 | Procter & Gamble | Process and apparatus for the continuous reaction of organic compounds with undiluted sulfur trioxide |
| DE1926795A1 (de) * | 1969-05-24 | 1970-11-26 | Metallgesellschaft Ag | Sulfierverfahren |
| GB1279559A (en) * | 1969-05-24 | 1972-06-28 | Metallgesellschaft Ag | A sulphonation and/or sulphonation process |
| DE2343407A1 (de) * | 1972-08-30 | 1974-03-14 | Allied Chem | Reaktionsprozess und vorrichtung zur durchfuehrung desselben |
-
1976
- 1976-12-01 US US05/746,242 patent/US4113438A/en not_active Expired - Lifetime
-
1977
- 1977-05-03 CA CA277,481A patent/CA1089486A/en not_active Expired
- 1977-05-10 IN IN697/CAL/77A patent/IN146339B/en unknown
- 1977-05-24 IT IT68185/77A patent/IT1109117B/it active
- 1977-05-24 DE DE19772723333 patent/DE2723333A1/de active Granted
- 1977-05-25 FR FR7715951A patent/FR2352767A1/fr active Granted
- 1977-05-25 GB GB16097/79A patent/GB1584002A/en not_active Expired
- 1977-05-25 GB GB22159/77A patent/GB1584001A/en not_active Expired
- 1977-05-26 BR BR7703415A patent/BR7703415A/pt unknown
- 1977-05-27 SU SU772489552A patent/SU898955A3/ru active
- 1977-05-27 JP JP52062058A patent/JPS5951937B2/ja not_active Expired
-
1979
- 1979-06-25 SU SU792790956A patent/SU1148558A3/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| IN146339B (en, 2012) | 1979-05-05 |
| GB1584001A (en) | 1981-02-04 |
| BR7703415A (pt) | 1978-02-28 |
| US4113438A (en) | 1978-09-12 |
| SU898955A3 (ru) | 1982-01-15 |
| DE2723333A1 (de) | 1977-12-15 |
| IT1109117B (it) | 1985-12-16 |
| FR2352767A1 (fr) | 1977-12-23 |
| CA1089486A (en) | 1980-11-11 |
| JPS52144626A (en) | 1977-12-02 |
| GB1584002A (en) | 1981-02-04 |
| DE2723333C2 (en, 2012) | 1989-12-28 |
| SU1148558A3 (ru) | 1985-03-30 |
| FR2352767B1 (en, 2012) | 1983-10-21 |
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