JPS5945924A - 硫酸カルシウムに含まれる放射性物質を低減する方法 - Google Patents
硫酸カルシウムに含まれる放射性物質を低減する方法Info
- Publication number
- JPS5945924A JPS5945924A JP58116256A JP11625683A JPS5945924A JP S5945924 A JPS5945924 A JP S5945924A JP 58116256 A JP58116256 A JP 58116256A JP 11625683 A JP11625683 A JP 11625683A JP S5945924 A JPS5945924 A JP S5945924A
- Authority
- JP
- Japan
- Prior art keywords
- hemihydrate
- stone
- gypsum
- radioactive
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 title claims description 9
- 239000000126 substance Substances 0.000 title description 3
- 230000009467 reduction Effects 0.000 title description 2
- 238000000034 method Methods 0.000 claims description 63
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 50
- 239000002002 slurry Substances 0.000 claims description 35
- 239000004575 stone Substances 0.000 claims description 33
- 239000010440 gypsum Substances 0.000 claims description 29
- 229910052602 gypsum Inorganic materials 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- 229910001868 water Inorganic materials 0.000 claims description 28
- 239000002245 particle Substances 0.000 claims description 27
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 25
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 19
- 230000036571 hydration Effects 0.000 claims description 18
- 238000006703 hydration reaction Methods 0.000 claims description 18
- HCWPIIXVSYCSAN-IGMARMGPSA-N Radium-226 Chemical compound [226Ra] HCWPIIXVSYCSAN-IGMARMGPSA-N 0.000 claims description 17
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 16
- 229910052698 phosphorus Inorganic materials 0.000 claims description 16
- 239000011574 phosphorus Substances 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 12
- 229910052791 calcium Inorganic materials 0.000 claims description 11
- 239000011575 calcium Substances 0.000 claims description 11
- 230000002285 radioactive effect Effects 0.000 claims description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 10
- 210000000481 breast Anatomy 0.000 claims description 10
- 239000000356 contaminant Substances 0.000 claims description 10
- 239000002699 waste material Substances 0.000 claims description 9
- 239000000941 radioactive substance Substances 0.000 claims description 8
- 239000010419 fine particle Substances 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 5
- 150000004684 trihydrates Chemical class 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 210000000038 chest Anatomy 0.000 claims description 2
- 239000011362 coarse particle Substances 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 claims 4
- 239000012857 radioactive material Substances 0.000 claims 4
- 238000000926 separation method Methods 0.000 claims 4
- 241000972773 Aulopiformes Species 0.000 claims 1
- 235000009581 Balanites aegyptiaca Nutrition 0.000 claims 1
- 102100025597 Caspase-4 Human genes 0.000 claims 1
- 101000933112 Homo sapiens Caspase-4 Proteins 0.000 claims 1
- 241000219991 Lythraceae Species 0.000 claims 1
- 235000014360 Punica granatum Nutrition 0.000 claims 1
- 238000003869 coulometry Methods 0.000 claims 1
- 235000013305 food Nutrition 0.000 claims 1
- 238000007429 general method Methods 0.000 claims 1
- 230000000887 hydrating effect Effects 0.000 claims 1
- 230000002262 irrigation Effects 0.000 claims 1
- 238000003973 irrigation Methods 0.000 claims 1
- 210000003127 knee Anatomy 0.000 claims 1
- 235000013372 meat Nutrition 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 235000019515 salmon Nutrition 0.000 claims 1
- 239000013078 crystal Substances 0.000 description 24
- 238000004458 analytical method Methods 0.000 description 11
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 150000004683 dihydrates Chemical class 0.000 description 7
- 239000011505 plaster Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000002367 phosphate rock Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- 230000029087 digestion Effects 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052705 radium Inorganic materials 0.000 description 4
- HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 102000029797 Prion Human genes 0.000 description 3
- 108091000054 Prion Proteins 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000005250 beta ray Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002050 diffraction method Methods 0.000 description 2
- 210000004907 gland Anatomy 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000005389 magnetism Effects 0.000 description 2
- -1 phosphorus ions Chemical class 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000951471 Citrus junos Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 240000000220 Panda oleosa Species 0.000 description 1
- 235000016496 Panda oleosa Nutrition 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- JCXGWMGPZLAOME-BKFZFHPZSA-N bismuth-214 Chemical compound [214Bi] JCXGWMGPZLAOME-BKFZFHPZSA-N 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- GJYLKIZKRHDRER-UHFFFAOYSA-N calcium;sulfuric acid Chemical compound [Ca].OS(O)(=O)=O GJYLKIZKRHDRER-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010367 cloning Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000011507 gypsum plaster Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000011268 mixed slurry Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000019691 monocalcium phosphate Nutrition 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 150000003017 phosphorus Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910021489 α-quartz Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
- C01B25/222—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen
- C01B25/228—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen one form of calcium sulfate being formed and then converted to another form
- C01B25/229—Hemihydrate-dihydrate process
- C01B25/2295—Hemihydrate-dihydrate process the conversion being performed in one or more vessels different from those used for reaction after separation of phosphoric acid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
- C01B25/222—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen
- C01B25/223—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen only one form of calcium sulfate being formed
- C01B25/225—Dihydrate process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
- C01F11/468—Purification of calcium sulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/393,232 US4424196A (en) | 1982-06-29 | 1982-06-29 | Phosphohemihydrate process for purification of gypsum |
| US393232 | 1982-06-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5945924A true JPS5945924A (ja) | 1984-03-15 |
Family
ID=23553844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58116256A Pending JPS5945924A (ja) | 1982-06-29 | 1983-06-29 | 硫酸カルシウムに含まれる放射性物質を低減する方法 |
Country Status (11)
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2652076B1 (fr) * | 1989-09-20 | 1992-03-20 | Rhone Poulenc Chimie | Procede de recuperation des valeurs de terres rares dans les gypses. |
| US5732367A (en) * | 1990-03-16 | 1998-03-24 | Sevenson Environmental Services, Inc. | Reduction of leachability and solubility of radionuclides and radioactive substances in contaminated soils and materials |
| US6635796B2 (en) | 1990-03-16 | 2003-10-21 | Sevenson Environmental Services, Inc. | Reduction of leachability and solubility of radionuclides and radioactive substances in contaminated soils and materials |
| US6409824B1 (en) | 2000-04-25 | 2002-06-25 | United States Gypsum Company | Gypsum compositions with enhanced resistance to permanent deformation |
| US7585485B2 (en) | 2006-07-03 | 2009-09-08 | Tripoliven, C.A. | Process for the physiochemical conditioning of chemical gypsum or phospho-gypsum for use in formulation for cement and other construction materials |
| US8445101B2 (en) | 2007-03-21 | 2013-05-21 | Ashtech Industries, Llc | Sound attenuation building material and system |
| WO2008116188A1 (en) * | 2007-03-21 | 2008-09-25 | Ash Tech Industries, L.L.C. | Utility materials incorporating a microparticle matrix |
| US20090239429A1 (en) | 2007-03-21 | 2009-09-24 | Kipp Michael D | Sound Attenuation Building Material And System |
| CN102123950B (zh) * | 2008-07-31 | 2017-03-29 | 吉野石膏株式会社 | 二水石膏的连续式改性方法及用该方法改性了的改性二水石膏 |
| US8591677B2 (en) | 2008-11-04 | 2013-11-26 | Ashtech Industries, Llc | Utility materials incorporating a microparticle matrix formed with a setting agent |
| CN113185160B (zh) * | 2021-04-21 | 2022-03-29 | 中国五环工程有限公司 | 控制半水石膏粗大结晶的方法 |
| US20240182375A1 (en) * | 2022-12-02 | 2024-06-06 | Peregrine Hydrogen Inc. | System and method for production of calcium oxide with reduced carbon footprint |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4841155A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1971-09-27 | 1973-06-16 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1250191A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1968-07-04 | 1971-10-20 | ||
| US3632307A (en) * | 1969-04-09 | 1972-01-04 | Albatros Super Fosfaatfabrieke | Process for the preparation of phosphoric acid and gypsum from phosphate rock |
| GB1394734A (en) | 1972-04-26 | 1975-05-21 | Unie Van Kunstmestfab Bv | Process for the purification of waste product calcium sulphate |
| FR2201682A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1972-10-02 | 1974-04-26 | Cerphos | |
| US4146568A (en) | 1977-08-01 | 1979-03-27 | Olin Corporation | Process for reducing radioactive contamination in waste product gypsum |
| FR2409230A1 (fr) * | 1977-11-16 | 1979-06-15 | Rhone Poulenc Ind | Procede de fabrication d'acide phosphorique |
| US4311677A (en) | 1979-12-03 | 1982-01-19 | Swiss Aluminium Ltd. | Process for producing phosphoric acid |
| IL59206A (en) | 1980-01-23 | 1982-12-31 | Israel State | Recovery of uranium from rock phosphate |
| US4282192A (en) | 1980-02-27 | 1981-08-04 | Olin Corporation | Process for producing a calcium sulfate product containing low amounts of radium |
| US4388292A (en) * | 1981-12-14 | 1983-06-14 | United States Gypsum Company | Process for reducing radioactive contamination in phosphogypsum |
-
1982
- 1982-06-29 US US06/393,232 patent/US4424196A/en not_active Expired - Lifetime
-
1983
- 1983-06-15 GB GB08316293A patent/GB2122595B/en not_active Expired
- 1983-06-16 AU AU15856/83A patent/AU570921B2/en not_active Ceased
- 1983-06-16 IE IE1425/83A patent/IE55482B1/en unknown
- 1983-06-28 BR BR8303457A patent/BR8303457A/pt unknown
- 1983-06-28 DE DE19833323294 patent/DE3323294A1/de active Granted
- 1983-06-29 MX MX197854A patent/MX166397B/es unknown
- 1983-06-29 JP JP58116256A patent/JPS5945924A/ja active Pending
- 1983-06-29 FR FR8310776A patent/FR2529190B1/fr not_active Expired
- 1983-06-29 CA CA000431425A patent/CA1181925A/en not_active Expired
- 1983-06-29 PH PH29135A patent/PH17723A/en unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4841155A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1971-09-27 | 1973-06-16 |
Also Published As
| Publication number | Publication date |
|---|---|
| PH17723A (en) | 1984-11-21 |
| GB8316293D0 (en) | 1983-07-20 |
| GB2122595B (en) | 1985-10-02 |
| DE3323294C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1988-05-05 |
| FR2529190A1 (fr) | 1983-12-30 |
| GB2122595A (en) | 1984-01-18 |
| IE831425L (en) | 1983-12-29 |
| DE3323294A1 (de) | 1984-01-12 |
| IE55482B1 (en) | 1990-09-26 |
| AU1585683A (en) | 1984-01-05 |
| US4424196A (en) | 1984-01-03 |
| FR2529190B1 (fr) | 1987-02-13 |
| CA1181925A (en) | 1985-02-05 |
| BR8303457A (pt) | 1984-02-07 |
| MX166397B (es) | 1993-01-05 |
| AU570921B2 (en) | 1988-03-31 |
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