JPS5928575B2 - 塩化ビニルのホモ−及びコポリマ−の水分散液からモノマ−夾雑物を連続的に除去する方法 - Google Patents
塩化ビニルのホモ−及びコポリマ−の水分散液からモノマ−夾雑物を連続的に除去する方法Info
- Publication number
- JPS5928575B2 JPS5928575B2 JP50103366A JP10336675A JPS5928575B2 JP S5928575 B2 JPS5928575 B2 JP S5928575B2 JP 50103366 A JP50103366 A JP 50103366A JP 10336675 A JP10336675 A JP 10336675A JP S5928575 B2 JPS5928575 B2 JP S5928575B2
- Authority
- JP
- Japan
- Prior art keywords
- dispersion
- vinyl chloride
- degasser
- flow tube
- copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006185 dispersion Substances 0.000 title claims description 61
- 238000000034 method Methods 0.000 title claims description 23
- 239000000178 monomer Substances 0.000 title claims description 19
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 18
- 229920001577 copolymer Polymers 0.000 title claims description 8
- 239000000356 contaminant Substances 0.000 title claims description 5
- 239000000203 mixture Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 description 11
- 239000003995 emulsifying agent Substances 0.000 description 9
- 238000007872 degassing Methods 0.000 description 7
- 229920000915 polyvinyl chloride Polymers 0.000 description 7
- 239000004800 polyvinyl chloride Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- -1 ethylene, propylene, isobutylene Chemical group 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000001256 steam distillation Methods 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- VAXCXSDAWONRLI-UHFFFAOYSA-N 2,3-dihydroxypropyl hydrogen sulfate Chemical compound OCC(O)COS(O)(=O)=O VAXCXSDAWONRLI-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 101710095439 Erlin Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical group 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940045845 sodium myristate Drugs 0.000 description 1
- 229950005425 sodium myristyl sulfate Drugs 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- HDRLZNWDSGYGBZ-KVVVOXFISA-M sodium;(z)-octadec-9-ene-1-sulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCCS([O-])(=O)=O HDRLZNWDSGYGBZ-KVVVOXFISA-M 0.000 description 1
- MWZFQMUXPSUDJQ-KVVVOXFISA-M sodium;[(z)-octadec-9-enyl] sulfate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCCOS([O-])(=O)=O MWZFQMUXPSUDJQ-KVVVOXFISA-M 0.000 description 1
- KQFAFFYKLIBKDE-UHFFFAOYSA-M sodium;ethanesulfonate Chemical compound [Na+].CCS([O-])(=O)=O KQFAFFYKLIBKDE-UHFFFAOYSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- KBAFDSIZQYCDPK-UHFFFAOYSA-M sodium;octadecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCS([O-])(=O)=O KBAFDSIZQYCDPK-UHFFFAOYSA-M 0.000 description 1
- JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/16—Purification
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2440957 | 1974-08-27 | ||
| DE19742440957 DE2440957B2 (de) | 1974-08-27 | 1974-08-27 | Kontinuierliches verfahren zur entfernung von monomeren verunreinigungen aus waessrigen dispersionen von homo- und copolymerisaten des vinylchlorids |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5150389A JPS5150389A (en) | 1976-05-01 |
| JPS5928575B2 true JPS5928575B2 (ja) | 1984-07-13 |
Family
ID=5924159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50103366A Expired JPS5928575B2 (ja) | 1974-08-27 | 1975-08-26 | 塩化ビニルのホモ−及びコポリマ−の水分散液からモノマ−夾雑物を連続的に除去する方法 |
Country Status (10)
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2450464A1 (de) * | 1974-10-24 | 1976-04-29 | Basf Ag | Verfahren zur emissionsarmen entfernung von vinylchlorid aus polymerisaten des vinylchlorids |
| DE2521401C3 (de) * | 1975-05-14 | 1985-07-18 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur kontinuierlichen Entfernung von monomeren Verunreinigungen aus wäßrigen Dispersionen von Homo- und Copolymerisaten des Vinylchlorids |
| JPS51135990A (en) * | 1975-05-20 | 1976-11-25 | Shin Etsu Chem Co Ltd | Method of removing residual monomers f rom polyvinylchloride slurries |
| DE2744462C2 (de) * | 1977-10-03 | 1982-09-16 | Wacker-Chemie GmbH, 8000 München | Verfahren zur Verhinderung der Schaumbildung bei der Restmonomerentfernung aus wäßrigen Polymerdispersionen |
| US4151141A (en) * | 1977-11-16 | 1979-04-24 | The Dow Chemical Company | Process for continuously removing volatile organic material from aqueous dispersions of synthetic polymers |
| US4130527A (en) * | 1977-12-29 | 1978-12-19 | Stauffer Chemical Company | Method of treating a polymer latex to remove unreacted monomer by treatment in a column |
| IT1121511B (it) * | 1979-05-28 | 1986-04-02 | Montedison Spa | Procedimento per l'estrazione del cloruro di vinile monomero dai lattici di cloruro di polivinile ed apparecchiatura per la sua realizzazione |
| IT1127306B (it) * | 1979-12-20 | 1986-05-21 | Montedison Spa | Processo continuo per il recupero di polimeri da loro lattici |
| US5266211A (en) * | 1990-06-13 | 1993-11-30 | Bunawerke Huls Gmbh | Process for precipitating polymers |
| ES2589352T3 (es) * | 2006-10-12 | 2016-11-11 | Ineos Manufacturing Belgium Nv | Transferencia de corriente de polímero |
| EP1914249A1 (en) * | 2006-10-12 | 2008-04-23 | INEOS Manufacturing Belgium NV | Polymer stream transfer |
| WO2008141270A2 (en) | 2007-05-10 | 2008-11-20 | Mora Assad F | Stereoscopic three dimensional visualization system and method of use |
| KR102132753B1 (ko) * | 2016-10-31 | 2020-07-13 | 주식회사 엘지화학 | 염화비닐계 중합체 및 이의 제조방법 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3371059A (en) * | 1963-02-21 | 1968-02-27 | Teknika Inc | Monomer stripping |
| DE1248943C2 (de) * | 1965-07-20 | 1974-03-07 | Basf Ag | Verfahren und Vorrichtung zur diskontinuierlichen Entfernung von Geruchs-stoffen auswaessrigen Polymerisatdispersionen |
-
1974
- 1974-08-27 DE DE19742440957 patent/DE2440957B2/de active Granted
-
1975
- 1975-05-23 GB GB22562/75A patent/GB1499685A/en not_active Expired
- 1975-08-13 FR FR7525253A patent/FR2283155A1/fr active Granted
- 1975-08-21 US US05/606,736 patent/US4020032A/en not_active Expired - Lifetime
- 1975-08-22 CH CH1091275A patent/CH596242A5/xx not_active IP Right Cessation
- 1975-08-25 BR BR7505430*A patent/BR7505430A/pt unknown
- 1975-08-25 IT IT51050/75A patent/IT1041512B/it active
- 1975-08-26 JP JP50103366A patent/JPS5928575B2/ja not_active Expired
- 1975-08-26 SE SE7509477A patent/SE419225B/xx not_active IP Right Cessation
- 1975-08-26 BE BE159491A patent/BE832774A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1499685A (en) | 1978-02-01 |
| FR2283155A1 (fr) | 1976-03-26 |
| IT1041512B (it) | 1980-01-10 |
| JPS5150389A (en) | 1976-05-01 |
| SE7509477L (sv) | 1976-03-01 |
| FR2283155B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1980-04-25 |
| BE832774A (fr) | 1975-12-16 |
| BR7505430A (pt) | 1976-08-03 |
| CH596242A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1978-03-15 |
| SE419225B (sv) | 1981-07-20 |
| DE2440957B2 (de) | 1977-07-14 |
| DE2440957C3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1985-01-31 |
| US4020032A (en) | 1977-04-26 |
| DE2440957A1 (de) | 1976-03-11 |
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