JPS5926338B2 - 使用済み銀担持触媒の活性の改善方法 - Google Patents
使用済み銀担持触媒の活性の改善方法Info
- Publication number
- JPS5926338B2 JPS5926338B2 JP52096189A JP9618977A JPS5926338B2 JP S5926338 B2 JPS5926338 B2 JP S5926338B2 JP 52096189 A JP52096189 A JP 52096189A JP 9618977 A JP9618977 A JP 9618977A JP S5926338 B2 JPS5926338 B2 JP S5926338B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- rubidium
- cesium
- concentration
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 109
- 238000000034 method Methods 0.000 title claims description 25
- 230000000694 effects Effects 0.000 title claims description 13
- 239000007788 liquid Substances 0.000 claims description 38
- 229910052792 caesium Inorganic materials 0.000 claims description 26
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 26
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 24
- 239000005977 Ethylene Substances 0.000 claims description 24
- 229910052701 rubidium Inorganic materials 0.000 claims description 21
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 19
- 230000003647 oxidation Effects 0.000 claims description 18
- 238000007254 oxidation reaction Methods 0.000 claims description 18
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 15
- 229910052709 silver Inorganic materials 0.000 claims description 15
- 239000004332 silver Substances 0.000 claims description 15
- 239000007789 gas Substances 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 8
- 150000003298 rubidium compounds Chemical class 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 5
- 229910001882 dioxygen Inorganic materials 0.000 claims description 5
- 239000011261 inert gas Substances 0.000 claims description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 150000004675 formic acid derivatives Chemical class 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 150000002823 nitrates Chemical class 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 description 14
- 150000001340 alkali metals Chemical class 0.000 description 14
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 12
- 238000002474 experimental method Methods 0.000 description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 150000001339 alkali metal compounds Chemical class 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- -1 cesium compound Chemical class 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010981 drying operation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 1
- NPPQSCRMBWNHMW-UHFFFAOYSA-N Meprobamate Chemical compound NC(=O)OCC(C)(CCC)COC(N)=O NPPQSCRMBWNHMW-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 238000000295 emission spectrum Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- AIRCTMFFNKZQPN-UHFFFAOYSA-N oxidoaluminium Chemical compound [Al]=O AIRCTMFFNKZQPN-UHFFFAOYSA-N 0.000 description 1
- 150000004707 phenolate Chemical class 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- RTHYXYOJKHGZJT-UHFFFAOYSA-N rubidium nitrate Inorganic materials [Rb+].[O-][N+]([O-])=O RTHYXYOJKHGZJT-UHFFFAOYSA-N 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- KHAUBYTYGDOYRU-IRXASZMISA-N trospectomycin Chemical compound CN[C@H]([C@H]1O2)[C@@H](O)[C@@H](NC)[C@H](O)[C@H]1O[C@H]1[C@]2(O)C(=O)C[C@@H](CCCC)O1 KHAUBYTYGDOYRU-IRXASZMISA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/485—Impregnating or reimpregnating with, or deposition of metal compounds or catalytically active elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2636680A DE2636680C3 (de) | 1976-08-14 | 1976-08-14 | Verfahren zur Verbesserung der Wirksamkeit von Silber-Trägerkatalysatoren |
| DE000P26366803 | 1976-08-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5322893A JPS5322893A (en) | 1978-03-02 |
| JPS5926338B2 true JPS5926338B2 (ja) | 1984-06-26 |
Family
ID=5985473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52096189A Expired JPS5926338B2 (ja) | 1976-08-14 | 1977-08-12 | 使用済み銀担持触媒の活性の改善方法 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4123385A (en, 2012) |
| JP (1) | JPS5926338B2 (en, 2012) |
| AU (1) | AU511144B2 (en, 2012) |
| BE (1) | BE857824A (en, 2012) |
| BR (1) | BR7705359A (en, 2012) |
| CA (1) | CA1103651A (en, 2012) |
| DD (1) | DD131841A5 (en, 2012) |
| DE (1) | DE2636680C3 (en, 2012) |
| ES (1) | ES461441A1 (en, 2012) |
| FR (1) | FR2361155A1 (en, 2012) |
| GB (1) | GB1556115A (en, 2012) |
| IT (1) | IT1083946B (en, 2012) |
| NL (1) | NL7708778A (en, 2012) |
| PL (1) | PL200192A1 (en, 2012) |
| RO (1) | RO73097A (en, 2012) |
| SE (1) | SE435139B (en, 2012) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2740480B2 (de) * | 1977-09-08 | 1979-07-05 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Verbesserung der Wirksamkeit von Silber-Trägerkatalysatoren |
| EP0002045B1 (de) * | 1977-11-19 | 1981-09-02 | BASF Aktiengesellschaft | Verfahren zur Herstellung eines Äthylenoxydkatalysators |
| DE2904919A1 (de) * | 1979-02-09 | 1980-08-21 | Basf Ag | Verfahren zur herstellung und regenerierung von traegerkatalysatoren sowie deren verwendung fuer die herstellung von aethylenoxid |
| US4224194A (en) * | 1979-02-26 | 1980-09-23 | Texaco Development Corp. | Process for preparing an ethylene oxide catalyst |
| DE2916887C2 (de) * | 1979-04-26 | 1981-12-17 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zum Aktivieren oder Reaktivieren von Silber-Träger-Katalysatoren |
| US4248741A (en) * | 1979-05-29 | 1981-02-03 | The Dow Chemical Company | Method of making catalysts for the production of ethylene oxide |
| DE2938245A1 (de) * | 1979-09-21 | 1981-04-09 | Hoechst Ag, 6000 Frankfurt | Verfahren zur verbesserung der wirksamkeit von silber-traegerkatalysatoren |
| SE8203955L (sv) * | 1981-07-17 | 1983-01-18 | Northern Petro Chem Co | Forfarande for avlegsnande av kalium fran anvenda etenoxidkatalysatorer? |
| US4760042A (en) * | 1982-03-24 | 1988-07-26 | Scientific Design Company, Inc. | Process for preparing an alkali metal-promoted silver catalyst |
| US4774222A (en) * | 1982-06-16 | 1988-09-27 | Scientific Design Company, Inc. | Catalyst for oxidation of ethylene to ethylene oxide and process for preparing the catalyst |
| DE3229541A1 (de) * | 1982-08-07 | 1984-02-09 | Hoechst Ag, 6230 Frankfurt | Verfahren zur verbesserung der wirksamkeit von gebrauchten silber-traegerkatalysatoren |
| US4575494A (en) * | 1984-02-08 | 1986-03-11 | The Dow Chemical Company | Alumina compositions useful as catalyst supports for ethylene oxidation |
| JPS60216844A (ja) * | 1984-04-13 | 1985-10-30 | Nippon Shokubai Kagaku Kogyo Co Ltd | エチレンオキシド製造用銀触媒 |
| DE3426699A1 (de) * | 1984-07-20 | 1986-01-23 | Hoechst Ag, 6230 Frankfurt | Verfahren zur verbesserung der wirksamkeit von silbertraegerkatalysatoren |
| GB8611121D0 (en) * | 1986-05-07 | 1986-06-11 | Shell Int Research | Silver catalyst |
| US4908343A (en) * | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
| DE3905578A1 (de) * | 1989-02-23 | 1990-08-30 | Basf Ag | Verfahren zur herstellung eines silberkatalysators |
| US5008413A (en) * | 1989-10-23 | 1991-04-16 | Scientific Design Company, Inc. | Catalyst for oxidation of ethylene to ethylene oxide |
| US5102848A (en) * | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US5112795A (en) * | 1990-10-12 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Supported silver catalyst, and processes for making and using same |
| FR2851246A1 (fr) * | 2003-02-14 | 2004-08-20 | Bp Lavera Snc | Procede de fabrication d'oxyde d'ethylene |
| US7977274B2 (en) | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
| US7932408B2 (en) | 2006-09-29 | 2011-04-26 | Scientific Design Company, Inc. | Catalyst with bimodal pore size distribution and the use thereof |
| US7696368B2 (en) * | 2007-05-11 | 2010-04-13 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Start-up of high selectivity catalysts in olefin oxide plants |
| US7507845B1 (en) | 2007-08-27 | 2009-03-24 | Sd Lizenzverwertungsgesellschaft Mbh & Co Kg | Process for production of an olefin oxide |
| EP2350033B1 (de) | 2008-10-08 | 2012-09-19 | Basf Se | Verfahren zur herstellung eines alkylenoxids |
| US9115104B2 (en) | 2009-01-27 | 2015-08-25 | Scientific Design Company, Inc. | Ethylene oxide catalyst with optimized cesium content |
| CN107960063B (zh) | 2015-08-28 | 2021-08-24 | 利安德化学技术有限公司 | 环氧化工艺及其使用的催化剂 |
| US11931725B2 (en) | 2022-07-19 | 2024-03-19 | Scientific Design Company, Inc. | Ethylene oxide high selectivity catalyst conditioning process |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2831870A (en) * | 1956-05-07 | 1958-04-22 | Allied Chem & Dye Corp | Production of ethylene oxide |
| US3121099A (en) * | 1960-03-04 | 1964-02-11 | Montedison Spa | Process for the oxidation of olefins on silver catalyst graduated selectivity |
| GB1491447A (en) * | 1973-12-05 | 1977-11-09 | Ici Ltd | Alkylene oxide production and catalysts therefor |
| CA1026763A (en) * | 1974-05-20 | 1978-02-21 | Robert P. Nielsen | Silver catalysts used in ethylene oxide production |
| ES447348A1 (es) * | 1975-05-02 | 1977-07-01 | Hoechst Ag | Procedimiento para la reactivacion de catalizadores de platausados para obtener oxido de etileno de acuerdo con el pro- cedimiento de oxidacion directa. |
-
1976
- 1976-08-14 DE DE2636680A patent/DE2636680C3/de not_active Expired
-
1977
- 1977-08-08 ES ES461441A patent/ES461441A1/es not_active Expired
- 1977-08-09 US US05/823,032 patent/US4123385A/en not_active Expired - Lifetime
- 1977-08-09 NL NL7708778A patent/NL7708778A/xx not_active Application Discontinuation
- 1977-08-11 PL PL20019277A patent/PL200192A1/xx unknown
- 1977-08-12 GB GB33925/77A patent/GB1556115A/en not_active Expired
- 1977-08-12 CA CA284,612A patent/CA1103651A/en not_active Expired
- 1977-08-12 SE SE7709149A patent/SE435139B/xx not_active IP Right Cessation
- 1977-08-12 DD DD7700200554A patent/DD131841A5/xx unknown
- 1977-08-12 JP JP52096189A patent/JPS5926338B2/ja not_active Expired
- 1977-08-12 RO RO7791351A patent/RO73097A/ro unknown
- 1977-08-12 IT IT26715/77A patent/IT1083946B/it active
- 1977-08-12 BR BR7705359A patent/BR7705359A/pt unknown
- 1977-08-15 AU AU27898/77A patent/AU511144B2/en not_active Expired
- 1977-08-16 BE BE180204A patent/BE857824A/xx not_active IP Right Cessation
- 1977-08-16 FR FR7725011A patent/FR2361155A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| US4123385A (en) | 1978-10-31 |
| RO73097A (ro) | 1982-05-10 |
| ES461441A1 (es) | 1978-12-01 |
| SE7709149L (sv) | 1978-02-15 |
| SE435139B (sv) | 1984-09-10 |
| AU511144B2 (en) | 1980-07-31 |
| FR2361155B1 (en, 2012) | 1981-08-28 |
| BR7705359A (pt) | 1978-06-06 |
| JPS5322893A (en) | 1978-03-02 |
| BE857824A (fr) | 1978-02-16 |
| PL200192A1 (pl) | 1978-04-10 |
| DE2636680C3 (de) | 1979-04-05 |
| IT1083946B (it) | 1985-05-25 |
| NL7708778A (nl) | 1978-02-16 |
| DD131841A5 (de) | 1978-07-26 |
| DE2636680B2 (de) | 1978-08-03 |
| AU2789877A (en) | 1979-02-22 |
| GB1556115A (en) | 1979-11-21 |
| DE2636680A1 (de) | 1978-04-27 |
| CA1103651A (en) | 1981-06-23 |
| FR2361155A1 (fr) | 1978-03-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS5926338B2 (ja) | 使用済み銀担持触媒の活性の改善方法 | |
| US4186106A (en) | Process for improving the activity of used supported silver catalysts | |
| RU2437871C2 (ru) | Способ уменьшения концентрации альдегида в целевом потоке | |
| US4822900A (en) | Production of ethylene oxide | |
| US4471071A (en) | Silver catalysts, and a process for their preparation | |
| JPS581629B2 (ja) | エチレンオキシドセイゾウヨウシヨクバイ | |
| EP0075938B1 (en) | Method for the preparation of a silver catalyst for the manufacture of ethylene oxide | |
| US6600056B1 (en) | Catalyst for production of epoxides and methods for production thereof and epoxides | |
| JPS6041989B2 (ja) | 使用ずみ銀触媒の再活性化方法 | |
| US11213806B1 (en) | Catalyst supports—composition and process of manufacture | |
| US4177169A (en) | Process for improving the activity of used supported silver catalysts | |
| US4335014A (en) | Process for improving the activity of supported silver catalysts | |
| EP0076504B1 (en) | Silver catalyst and method for the manufacture of ethylene oxide | |
| US3830834A (en) | Process for the continuous preparation of vinyl acetate | |
| US4654461A (en) | Production of high (Z,Z) content 1,5,9-tetradecatriene | |
| CS196309B2 (en) | Method of reactivation of the spent silver catalysts on the carrier | |
| US4478948A (en) | Process for improving the activity of used supported silver catalysts | |
| JPS60227834A (ja) | ルテニウム触媒の製造方法 | |
| JPS6039653B2 (ja) | 酸素含有炭化水素化合物の製造方法 | |
| US12251686B2 (en) | Catalyst supports—composition and process of manufacture | |
| JPH0155265B2 (en, 2012) | ||
| GB2101495A (en) | Process for the removal of potassium from used ethylene oxide catalysts | |
| US4425439A (en) | Upflow drying of regenerated ethylene oxide catalysts | |
| US4841080A (en) | Process for the oxidation of ethylene to ethylene oxide | |
| US4094919A (en) | Hydrocarbon conversion processes and catalysts |