JPS59149907A - 結晶性ポリプロピレンおよびその製造方法 - Google Patents
結晶性ポリプロピレンおよびその製造方法Info
- Publication number
- JPS59149907A JPS59149907A JP2200583A JP2200583A JPS59149907A JP S59149907 A JPS59149907 A JP S59149907A JP 2200583 A JP2200583 A JP 2200583A JP 2200583 A JP2200583 A JP 2200583A JP S59149907 A JPS59149907 A JP S59149907A
- Authority
- JP
- Japan
- Prior art keywords
- polypropylene
- crystalline
- polymerization
- stage
- limiting viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 polypropylene Polymers 0.000 title claims description 32
- 239000004743 Polypropylene Substances 0.000 title claims description 29
- 229920001155 polypropylene Polymers 0.000 title claims description 29
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 26
- 239000000155 melt Substances 0.000 claims abstract description 7
- 239000003054 catalyst Substances 0.000 claims description 8
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims 1
- 235000017491 Bambusa tulda Nutrition 0.000 claims 1
- 241001330002 Bambuseae Species 0.000 claims 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims 1
- 239000011425 bamboo Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 21
- 229920000642 polymer Polymers 0.000 abstract description 8
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 abstract description 5
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 abstract description 3
- 238000000465 moulding Methods 0.000 abstract description 3
- 238000000071 blow moulding Methods 0.000 abstract description 2
- 239000002685 polymerization catalyst Substances 0.000 abstract 2
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 230000007423 decrease Effects 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000012442 inert solvent Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000011437 continuous method Methods 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 241000190020 Zelkova serrata Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Chemical class 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2200583A JPS59149907A (ja) | 1983-02-15 | 1983-02-15 | 結晶性ポリプロピレンおよびその製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2200583A JPS59149907A (ja) | 1983-02-15 | 1983-02-15 | 結晶性ポリプロピレンおよびその製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59149907A true JPS59149907A (ja) | 1984-08-28 |
JPH0375562B2 JPH0375562B2 (enrdf_load_stackoverflow) | 1991-12-02 |
Family
ID=12070886
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2200583A Granted JPS59149907A (ja) | 1983-02-15 | 1983-02-15 | 結晶性ポリプロピレンおよびその製造方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59149907A (enrdf_load_stackoverflow) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1988000212A1 (en) * | 1986-07-04 | 1988-01-14 | Mitsui Petrochemical Industries, Ltd. | Polyolefin composition for injection molding |
US4950720A (en) * | 1988-04-29 | 1990-08-21 | Exxon Chemical Patents Inc. | Modified polypropylene, process for making and article made from the same |
US4981938A (en) * | 1987-02-04 | 1991-01-01 | Chisso Corporation | Highly crystalline polypropylene |
JPH03111404A (ja) * | 1989-09-26 | 1991-05-13 | Chisso Corp | 高立体規則性ポリプロピレン |
JPH04120145A (ja) * | 1990-09-12 | 1992-04-21 | Idemitsu Petrochem Co Ltd | ブロー成形用樹脂組成物 |
JPH059226A (ja) * | 1991-06-28 | 1993-01-19 | Idemitsu Petrochem Co Ltd | ポリプロピレン樹脂及びその組成物 |
JPH06210811A (ja) * | 1992-12-03 | 1994-08-02 | Himont Inc | 二軸延伸プロピレンポリマーのフィルム又はシート物品 |
WO1998054233A1 (fr) * | 1997-05-30 | 1998-12-03 | Grand Polymer Co., Ltd. | Composition de resine de polypropylene et article moule par injection |
JP2003073507A (ja) * | 2001-09-06 | 2003-03-12 | Sumitomo Chem Co Ltd | ポリプロピレン系樹脂組成物 |
JP2008545054A (ja) * | 2005-07-01 | 2008-12-11 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 広い分子量分布を示すプロピレンポリマー |
WO2013125702A1 (ja) | 2012-02-23 | 2013-08-29 | 日本ポリプロ株式会社 | ポリプロピレン系樹脂組成物および発泡シート |
WO2013125700A1 (ja) | 2012-02-23 | 2013-08-29 | 日本ポリプロ株式会社 | ポリプロピレン系樹脂組成物および発泡シート |
WO2025115954A1 (ja) * | 2023-11-30 | 2025-06-05 | 株式会社プライムポリマー | 積層フィルム、無延伸フィルム、ポリプロピレン系重合体組成物、および、プロピレン系重合体 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5670014A (en) * | 1979-11-13 | 1981-06-11 | Mitsui Toatsu Chem Inc | Propylene copolymer for forming sheet |
JPS57185304A (en) * | 1981-05-11 | 1982-11-15 | Mitsubishi Chem Ind Ltd | Preparation of propylene polymer |
JPS58201806A (ja) * | 1982-05-19 | 1983-11-24 | Chisso Corp | 後加工シ−ト用および吹込成形用高溶融粘弾性ポリプロピレンとその製造法 |
-
1983
- 1983-02-15 JP JP2200583A patent/JPS59149907A/ja active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5670014A (en) * | 1979-11-13 | 1981-06-11 | Mitsui Toatsu Chem Inc | Propylene copolymer for forming sheet |
JPS57185304A (en) * | 1981-05-11 | 1982-11-15 | Mitsubishi Chem Ind Ltd | Preparation of propylene polymer |
JPS58201806A (ja) * | 1982-05-19 | 1983-11-24 | Chisso Corp | 後加工シ−ト用および吹込成形用高溶融粘弾性ポリプロピレンとその製造法 |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1988000212A1 (en) * | 1986-07-04 | 1988-01-14 | Mitsui Petrochemical Industries, Ltd. | Polyolefin composition for injection molding |
US4981938A (en) * | 1987-02-04 | 1991-01-01 | Chisso Corporation | Highly crystalline polypropylene |
US4950720A (en) * | 1988-04-29 | 1990-08-21 | Exxon Chemical Patents Inc. | Modified polypropylene, process for making and article made from the same |
JPH03111404A (ja) * | 1989-09-26 | 1991-05-13 | Chisso Corp | 高立体規則性ポリプロピレン |
JPH04120145A (ja) * | 1990-09-12 | 1992-04-21 | Idemitsu Petrochem Co Ltd | ブロー成形用樹脂組成物 |
JPH059226A (ja) * | 1991-06-28 | 1993-01-19 | Idemitsu Petrochem Co Ltd | ポリプロピレン樹脂及びその組成物 |
JPH06210811A (ja) * | 1992-12-03 | 1994-08-02 | Himont Inc | 二軸延伸プロピレンポリマーのフィルム又はシート物品 |
JP2007185964A (ja) * | 1992-12-03 | 2007-07-26 | Basell North America Inc | 二軸延伸プロピレンポリマーのフィルム又はシート物品 |
US6320009B1 (en) | 1997-05-30 | 2001-11-20 | Grand Polymer Co Ltd | Polypropylene resin composition and injection-molded article |
WO1998054233A1 (fr) * | 1997-05-30 | 1998-12-03 | Grand Polymer Co., Ltd. | Composition de resine de polypropylene et article moule par injection |
JP2003073507A (ja) * | 2001-09-06 | 2003-03-12 | Sumitomo Chem Co Ltd | ポリプロピレン系樹脂組成物 |
JP2008545054A (ja) * | 2005-07-01 | 2008-12-11 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 広い分子量分布を示すプロピレンポリマー |
WO2013125702A1 (ja) | 2012-02-23 | 2013-08-29 | 日本ポリプロ株式会社 | ポリプロピレン系樹脂組成物および発泡シート |
WO2013125700A1 (ja) | 2012-02-23 | 2013-08-29 | 日本ポリプロ株式会社 | ポリプロピレン系樹脂組成物および発泡シート |
US9284427B2 (en) | 2012-02-23 | 2016-03-15 | Japan Polypropylene Corporation | Polypropylene-based resin composition and foam sheet |
US9505894B2 (en) | 2012-02-23 | 2016-11-29 | Japan Polypropylene Corporation | Polypropylene-based resin composition and foam sheet |
WO2025115954A1 (ja) * | 2023-11-30 | 2025-06-05 | 株式会社プライムポリマー | 積層フィルム、無延伸フィルム、ポリプロピレン系重合体組成物、および、プロピレン系重合体 |
Also Published As
Publication number | Publication date |
---|---|
JPH0375562B2 (enrdf_load_stackoverflow) | 1991-12-02 |
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