JPS5870878A - チタンの酸処理液より有価成分の回収方法 - Google Patents
チタンの酸処理液より有価成分の回収方法Info
- Publication number
- JPS5870878A JPS5870878A JP16728781A JP16728781A JPS5870878A JP S5870878 A JPS5870878 A JP S5870878A JP 16728781 A JP16728781 A JP 16728781A JP 16728781 A JP16728781 A JP 16728781A JP S5870878 A JPS5870878 A JP S5870878A
- Authority
- JP
- Japan
- Prior art keywords
- hydrochloric acid
- titanium
- ions
- exchange resin
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 17
- 239000010936 titanium Substances 0.000 title claims description 27
- 229910052719 titanium Inorganic materials 0.000 title claims description 27
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims description 26
- 230000002378 acidificating effect Effects 0.000 title 1
- 238000011084 recovery Methods 0.000 title 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 77
- 238000000034 method Methods 0.000 claims abstract description 35
- 150000002500 ions Chemical class 0.000 claims abstract description 26
- 230000003647 oxidation Effects 0.000 claims abstract description 20
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 20
- 239000003957 anion exchange resin Substances 0.000 claims abstract description 19
- 238000000638 solvent extraction Methods 0.000 claims abstract description 16
- 239000012535 impurity Substances 0.000 claims abstract description 15
- 238000001179 sorption measurement Methods 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 8
- 238000010306 acid treatment Methods 0.000 claims description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- BAKALPNAEUOCDL-UHFFFAOYSA-N titanium hydrochloride Chemical compound Cl.[Ti] BAKALPNAEUOCDL-UHFFFAOYSA-N 0.000 claims description 4
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 claims description 3
- ZMBHCYHQLYEYDV-UHFFFAOYSA-N trioctylphosphine oxide Chemical compound CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC ZMBHCYHQLYEYDV-UHFFFAOYSA-N 0.000 claims description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- 229910001882 dioxygen Inorganic materials 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract description 3
- 230000001590 oxidative effect Effects 0.000 abstract description 3
- 229910021655 trace metal ion Inorganic materials 0.000 abstract 1
- RMZAYIKUYWXQPB-UHFFFAOYSA-N trioctylphosphane Chemical compound CCCCCCCCP(CCCCCCCC)CCCCCCCC RMZAYIKUYWXQPB-UHFFFAOYSA-N 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 150000001450 anions Chemical class 0.000 description 5
- 150000002739 metals Chemical group 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- 238000005530 etching Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- SVEJTXIHPDUQLZ-ABLWVSNPSA-N (2s)-2-[[4-[2-(2-amino-4-oxo-5,6,7,8-tetrahydro-1h-pteridin-6-yl)ethylamino]benzoyl]amino]pentanedioic acid Chemical compound C1NC=2NC(N)=NC(=O)C=2NC1CCNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 SVEJTXIHPDUQLZ-ABLWVSNPSA-N 0.000 description 1
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- DKAGJZJALZXOOV-UHFFFAOYSA-N hydrate;hydrochloride Chemical compound O.Cl DKAGJZJALZXOOV-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- -1 titanium ions Chemical class 0.000 description 1
Landscapes
- Treatment Of Water By Ion Exchange (AREA)
- Physical Water Treatments (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16728781A JPS5870878A (ja) | 1981-10-21 | 1981-10-21 | チタンの酸処理液より有価成分の回収方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16728781A JPS5870878A (ja) | 1981-10-21 | 1981-10-21 | チタンの酸処理液より有価成分の回収方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5870878A true JPS5870878A (ja) | 1983-04-27 |
| JPH0141394B2 JPH0141394B2 (enrdf_load_stackoverflow) | 1989-09-05 |
Family
ID=15846951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16728781A Granted JPS5870878A (ja) | 1981-10-21 | 1981-10-21 | チタンの酸処理液より有価成分の回収方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5870878A (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63261197A (ja) * | 1987-04-02 | 1988-10-27 | シーメンス、アクチエンゲゼルシャフト | 所定の化学成分に対するイオン交換器の容量変更方法 |
| RU2755300C1 (ru) * | 2020-10-21 | 2021-09-15 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский химико-технологический университет имени Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) | Способ извлечения высокодисперсного гидроксида титана (IV) из водных растворов |
-
1981
- 1981-10-21 JP JP16728781A patent/JPS5870878A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63261197A (ja) * | 1987-04-02 | 1988-10-27 | シーメンス、アクチエンゲゼルシャフト | 所定の化学成分に対するイオン交換器の容量変更方法 |
| RU2755300C1 (ru) * | 2020-10-21 | 2021-09-15 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский химико-технологический университет имени Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) | Способ извлечения высокодисперсного гидроксида титана (IV) из водных растворов |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0141394B2 (enrdf_load_stackoverflow) | 1989-09-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN113896211B (zh) | 一种废旧磷酸铁锂电池资源化的处理方法 | |
| CN104641018B (zh) | 用于从金属盐溶液中产生或回收盐酸的方法和设备 | |
| CN111394745A (zh) | 一种从含锂低镁卤水中制备氢氧化锂的方法 | |
| JP2023090706A (ja) | 水酸化リチウムの製造方法 | |
| JP3383334B2 (ja) | 硫酸の再生利用方法 | |
| CN112299451A (zh) | 一种通过磷酸锂的形式从含锂低镁卤水中制备氢氧化锂的方法 | |
| WO2021215486A1 (ja) | 水酸化リチウムの製造方法 | |
| DE2939911A1 (de) | Verfahren zur gewinnung von gallium | |
| CN116802886A (zh) | 用于回收利用磷酸铁锂电池的方法 | |
| CN118749033A (zh) | 从废锂离子电池中回收锂的方法 | |
| CN101554994B (zh) | X-ct系列造影剂生产废液中碘的回收方法 | |
| KR20170019246A (ko) | Led 또는 전자제품 폐기물로부터 유가금속의 회수 방법 | |
| JP2023073299A (ja) | 水酸化リチウムの製造方法 | |
| JP2650065B2 (ja) | 硫酸の回収方法 | |
| CN102191380A (zh) | 回收钴的方法 | |
| EP0301700A1 (en) | Neutralization of sulfuric acid containing iron ions | |
| CN1942608B (zh) | 镓的回收方法 | |
| JPS5870878A (ja) | チタンの酸処理液より有価成分の回収方法 | |
| CN118145611A (zh) | 一种回收磷酸铁锂提锂渣的方法 | |
| JP2002088494A (ja) | 金属電極から白金族金属を回収する方法 | |
| JP4292454B2 (ja) | 金属フッ化物を含有する水溶液の処理方法 | |
| CN111573641A (zh) | 一种电极箔废液联产硝酸和银的方法 | |
| EP0192426A2 (en) | Removal of sodium ions from alkaline aqueous solutions by means of an electrolytic membrane process | |
| JPH0141395B2 (enrdf_load_stackoverflow) | ||
| JP2023135553A (ja) | リチウムイオン二次電池の処理方法 |