JPS5860686A - リン酸質肥料の製造方法 - Google Patents
リン酸質肥料の製造方法Info
- Publication number
- JPS5860686A JPS5860686A JP15836681A JP15836681A JPS5860686A JP S5860686 A JPS5860686 A JP S5860686A JP 15836681 A JP15836681 A JP 15836681A JP 15836681 A JP15836681 A JP 15836681A JP S5860686 A JPS5860686 A JP S5860686A
- Authority
- JP
- Japan
- Prior art keywords
- phosphoric acid
- reaction
- product
- acid solution
- concentrated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003337 fertilizer Substances 0.000 title claims description 39
- 238000004519 manufacturing process Methods 0.000 title claims description 18
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 320
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 154
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 112
- 238000006243 chemical reaction Methods 0.000 claims description 93
- 229910001868 water Inorganic materials 0.000 claims description 63
- 239000000843 powder Substances 0.000 claims description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 57
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 42
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 40
- 239000002893 slag Substances 0.000 claims description 40
- -1 alkaline earth metal carbonates Chemical class 0.000 claims description 38
- 239000000203 mixture Substances 0.000 claims description 34
- 239000010459 dolomite Substances 0.000 claims description 24
- 229910000514 dolomite Inorganic materials 0.000 claims description 24
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 20
- 235000011007 phosphoric acid Nutrition 0.000 description 159
- 239000000243 solution Substances 0.000 description 88
- 239000000047 product Substances 0.000 description 77
- 238000005469 granulation Methods 0.000 description 29
- 230000003179 granulation Effects 0.000 description 29
- 238000000034 method Methods 0.000 description 27
- 239000007795 chemical reaction product Substances 0.000 description 25
- 239000002245 particle Substances 0.000 description 23
- 238000001035 drying Methods 0.000 description 22
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 19
- 239000002994 raw material Substances 0.000 description 19
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 18
- 229910019142 PO4 Inorganic materials 0.000 description 18
- 235000021317 phosphate Nutrition 0.000 description 18
- 239000002253 acid Substances 0.000 description 16
- 230000008569 process Effects 0.000 description 16
- 238000000354 decomposition reaction Methods 0.000 description 15
- 239000004571 lime Substances 0.000 description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 13
- 239000010452 phosphate Substances 0.000 description 13
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 12
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 12
- 235000011941 Tilia x europaea Nutrition 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 230000032683 aging Effects 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 9
- 239000002689 soil Substances 0.000 description 9
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000000395 magnesium oxide Substances 0.000 description 8
- 239000002426 superphosphate Substances 0.000 description 8
- 150000001342 alkaline earth metals Chemical class 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- 150000004649 carbonic acid derivatives Chemical group 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 230000004720 fertilization Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- 230000033001 locomotion Effects 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 5
- 238000007873 sieving Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 239000004137 magnesium phosphate Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000001506 calcium phosphate Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 150000001875 compounds Chemical group 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 3
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 3
- 229960002261 magnesium phosphate Drugs 0.000 description 3
- 235000010994 magnesium phosphates Nutrition 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 239000002686 phosphate fertilizer Substances 0.000 description 3
- 230000005070 ripening Effects 0.000 description 3
- 235000019739 Dicalciumphosphate Nutrition 0.000 description 2
- 229910000863 Ferronickel Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000006114 decarboxylation reaction Methods 0.000 description 2
- NEFBYIFKOOEVPA-UHFFFAOYSA-K dicalcium phosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])([O-])=O NEFBYIFKOOEVPA-UHFFFAOYSA-K 0.000 description 2
- 229910000390 dicalcium phosphate Inorganic materials 0.000 description 2
- 229940038472 dicalcium phosphate Drugs 0.000 description 2
- MHJAJDCZWVHCPF-UHFFFAOYSA-L dimagnesium phosphate Chemical compound [Mg+2].OP([O-])([O-])=O MHJAJDCZWVHCPF-UHFFFAOYSA-L 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000003979 granulating agent Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000004904 shortening Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000009852 Cucurbita pepo Nutrition 0.000 description 1
- 241000219104 Cucurbitaceae Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229910015427 Mo2O3 Inorganic materials 0.000 description 1
- MSKSOBAQMWJYTJ-UHFFFAOYSA-N [Mg].OP(O)(O)=O Chemical compound [Mg].OP(O)(O)=O MSKSOBAQMWJYTJ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003413 degradative effect Effects 0.000 description 1
- 235000019700 dicalcium phosphate Nutrition 0.000 description 1
- 229910000395 dimagnesium phosphate Inorganic materials 0.000 description 1
- 235000019791 dimagnesium phosphate Nutrition 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical class [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 230000010198 maturation time Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- DJDSLBVSSOQSLW-UHFFFAOYSA-N mono(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(O)=O DJDSLBVSSOQSLW-UHFFFAOYSA-N 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 238000004856 soil analysis Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Landscapes
- Fertilizers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15836681A JPS5860686A (ja) | 1981-10-05 | 1981-10-05 | リン酸質肥料の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15836681A JPS5860686A (ja) | 1981-10-05 | 1981-10-05 | リン酸質肥料の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5860686A true JPS5860686A (ja) | 1983-04-11 |
| JPH0159239B2 JPH0159239B2 (enrdf_load_stackoverflow) | 1989-12-15 |
Family
ID=15670108
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15836681A Granted JPS5860686A (ja) | 1981-10-05 | 1981-10-05 | リン酸質肥料の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5860686A (enrdf_load_stackoverflow) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60155590A (ja) * | 1984-01-25 | 1985-08-15 | 株式会社木村研究所 | 非飛散性肥料 |
| JP2005075645A (ja) * | 2003-09-01 | 2005-03-24 | Palfinger Ag | クレーン及びその滑動手段 |
| JP2010189238A (ja) * | 2009-02-20 | 2010-09-02 | Furuta Sangyo:Kk | リン酸肥料 |
| JP2018188314A (ja) * | 2017-04-28 | 2018-11-29 | 小野田化学工業株式会社 | 固結抑制リン酸肥料とその製造方法 |
| JP2019123636A (ja) * | 2018-01-15 | 2019-07-25 | 太平洋セメント株式会社 | けい酸質肥料の製造方法 |
| KR20200048882A (ko) * | 2018-10-31 | 2020-05-08 | 대한민국(농촌진흥청장) | 이탈리안 라이그라스 재배를 위한 시비 방법 및 이를 위한 복합비료 |
| JP2021011527A (ja) * | 2019-07-05 | 2021-02-04 | 宮城石灰工業株式会社 | 苦土タンカル及び苦土タンカルの製造方法 |
-
1981
- 1981-10-05 JP JP15836681A patent/JPS5860686A/ja active Granted
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60155590A (ja) * | 1984-01-25 | 1985-08-15 | 株式会社木村研究所 | 非飛散性肥料 |
| JP2005075645A (ja) * | 2003-09-01 | 2005-03-24 | Palfinger Ag | クレーン及びその滑動手段 |
| JP2010189238A (ja) * | 2009-02-20 | 2010-09-02 | Furuta Sangyo:Kk | リン酸肥料 |
| JP2018188314A (ja) * | 2017-04-28 | 2018-11-29 | 小野田化学工業株式会社 | 固結抑制リン酸肥料とその製造方法 |
| JP2019123636A (ja) * | 2018-01-15 | 2019-07-25 | 太平洋セメント株式会社 | けい酸質肥料の製造方法 |
| KR20200048882A (ko) * | 2018-10-31 | 2020-05-08 | 대한민국(농촌진흥청장) | 이탈리안 라이그라스 재배를 위한 시비 방법 및 이를 위한 복합비료 |
| JP2021011527A (ja) * | 2019-07-05 | 2021-02-04 | 宮城石灰工業株式会社 | 苦土タンカル及び苦土タンカルの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0159239B2 (enrdf_load_stackoverflow) | 1989-12-15 |
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